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Why is it important?
Organonitrogen compounds are some of the key building blocks of the life on Earth. Such compounds are highly valued and find numerous applications. They are often prepared by chemists using palladium complexes as catalysts. In this work we disclose an important mechanism by which palladium compounds can mediate the formation of organonitrogen compounds' C-N bonds by utilizing hydrogen peroxide as an environmentally friendly and cheap oxidant. Remarkably, the reactions involve exotic palladium(IV) species that were isolated and fully characterized in this work using single crystal X-ray diffraction, 1H NMR experiments and kinetics study.
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This page is a summary of: Reductive C(sp2)–N Elimination from Isolated Pd(IV) Amido Aryl Complexes Prepared Using H2O2 as Oxidant, Journal of the American Chemical Society, January 2017, American Chemical Society (ACS),
DOI: 10.1021/jacs.6b12648.
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