What is it about?
This article describes a simple allylic amination reaction promoted by copper(I).
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Why is it important?
The reaction is important as : (a) Reagent is prepared by in-situ reduction of copper(II) perchlorate by copper. (b) Provides selectivity in ratio of regiomers of allylic amines prepared through such reactions.
Perspectives
The mildness, selectivity C-N bond formation from C-Cl bonds are of general interest.
Professor Jubaraj Bikash Baruah
IIT Guwahati
Read the Original
This page is a summary of: Allylic amination promoted by copper, Tetrahedron, November 1991, Elsevier,
DOI: 10.1016/s0040-4020(01)80891-7.
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