Mixed - ligand complexes of zinc(II) with 1,1-dicyanoethylene-2,2-dithiolate and N-donor ligands: A combined experimental and theoretical study

Mixed - ligand complexes of zinc(II) with 1,1-dicyanoethylene-2,2-dithiolate and N-donor ligands: A combined experimental and theoretical study

Mahesh Kumar Singh, Sanjit Sutradhar, Bijaya Paul, Suman Adhikari, Folguni Laskar, Sandeep Acharya, Debabrata Chakraborty, Surajit Biswas, Arijit Das, Subhadip Roy, Antonio Frontera

Journal of Molecular Structure, July 2018, Elsevier
DOI: 10.1016/j.molstruc.2018.03.073

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http://dx.doi.org/10.1016/j.molstruc.2018.03.073

The following have contributed to this page: Dr ARIJIT DAS and Dr Antonio Frontera

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Mixed - ligand complexes of zinc(II) with 1,1-dicyanoethylene-2,2-dithiolate and N-donor ligands: A combined experimental and theoretical study
Two Zn(II) coordination complexes [Zn2(dap)2(i-MNT)2] (1) and {[Zn(dap)(i-MNT)(4-MePy)]·2H2O}n (2) were obtained. Complex 1 is a discrete 0D dimer, whereas 2 is a 1D coordination polymer. DFT calculations were performed to rationalize the influence of different noncovalent interactions in crystal packing. Compound 2 exhibits moderate to appreciable antifungal activity.