What is it about?
Taniaphos is an important chiral ligand for various transition catalyzed-reactions and its diastereoisomer has not been easily available. We have showb in this paper that it can be prepared by two sequential lithiations.
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Why is it important?
Our work broaden possibilities in catalysis, because previously unaccesible configuration of important chiral ligand can be now synthesized.
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This page is a summary of: Synthesis of epimer of Taniaphos ligand, Journal of Organometallic Chemistry, March 2016, Elsevier,
DOI: 10.1016/j.jorganchem.2016.01.004.
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