What is it about?
Very important results for the [3+2]-cycloaddition (interaction of substituted terminal alkynes with para-azido tetraflurobenzoates) was obtained. The effective catalytic system (CuBr/Et3N in DCM) was elaborated.
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Why is it important?
Effective, simple procedure for the click-reaction was developed.
Perspectives
This catalytic system should applied for the synthesis of valuable compounds, including derivatives of other types.
Kirill Zaitsev
Moscow State University
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This page is a summary of: Substituted 4-(1H-1,2,3-triazol-1-yl)-tetrafluorobenzoates: Selective synthesis and structure, Journal of Fluorine Chemistry, July 2016, Elsevier,
DOI: 10.1016/j.jfluchem.2016.05.005.
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