BaTiO3–CoFe2O4–BaTiO3 trilayer thin films prepared by chemical solution deposition

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paper: https://www.researchgate.net/publication/283300814_BaTiO3-CoFe2O4-BaTiO3_trilayer_composite_thin_films_prepared_by_chemical_solution_deposition Abstract: Multiferroic BaTiO3–CoFe2O4–BaTiO3thin films were synthesized by spin coating of Co(NO3)2–Fe(NO3)3and Ba(OAc)2–Ti(i-OPr)4 dissolved in a mixture of acetic acid and dimethylformamide. Stepwise thermal treatment at 200, 400 and 800◦C led to the desired phases. The phase formation process was monitored by thermoanalytic, XRD, IR and Raman measurements. SEM was used to characterize the structure and thickness of each layer. Two samples with different thicknesses of perovskite and spinel layers are discussed. Sample 1 consists of 120 nm CoFe2O4 between two 70 nm BaTiO3 layers. For sample 2, the 90 nm BaTiO3 top and bottom layers are enclosing 220 nm CoFe2O4. The surface qualities were determined by AFM indicating rms roughness values of about 4 nm. Magnetic investigations reveal slightly anisotropic behavior. Polarization measurements show hysteresis loops (PS(max)= 29 µC cm−2; PR(max)= 17 µC cm−2)with switching peaks at the corresponding coercive fields.

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