What is it about?
Study the effect of active site substitutions in sulfite dehydrogenase
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Why is it important?
Provides an explanation of for non-sigmoidal voltammetric responses
Perspectives
This is the key paper from my PhD. I was seeing odd shaped voltammograms similar to that observed by Prof Fraser Armstrong. We were able to show that the unexpected results were due to changes in the pathway of electron transfer from the catalytic center to the electrode.
Trevor Rapson
CSIRO
Read the Original
This page is a summary of: Short circuiting a sulfite oxidising enzyme with direct electrochemistry: Active site substitutions and their effect on catalysis and electron transfer, Biochimica et Biophysica Acta (BBA) - Bioenergetics, January 2011, Elsevier,
DOI: 10.1016/j.bbabio.2010.09.005.
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