What is it about?
This article describes a simple efficient catalytic reactions to prepare silicon sulphur bonded compounds from phenylsilane.
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Why is it important?
Functionalisation of a trihydrosilane is very important for preparing various silicon based compounds. This paper provides a means to use RhCI(PPh3)3 as catalyst to trifunctionalise phenylsilane to form C-Si bond and Si-S bonds.
Perspectives
This paper presents improvisation of competitive catalytic reactions to cause new Si-X bonds through hydrosilylation and Si-S bond formation, and should be easily exploitable to make various silicon polymers.
Professor Jubaraj Bikash Baruah
IIT Guwahati
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This page is a summary of: Catalytic tri-functionalisation of phenylsilane, Polyhedron, August 1996, Elsevier,
DOI: 10.1016/0277-5387(96)00150-7.
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