What is it about?

Acrylic esters are interesting building blocks for today’s chemical industry. They are widely used for the production of high-performance polymers with applications in plexiglass and paints. The vinyl function of the acrylic esters makes it possible to cross-link the monomers through radical polymerisation of the double bond. Hence a wide variety of polyacrylates can be produced with a broad range of characteristics. In the paper, the novozym 435 reactions of different alcohols with different esters were evaluated. The reaction using n-octanol and methyl acrylate as ester and alcohol substrate, respectively was further optimised.

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Why is it important?

In the production of green chemicals, new compounds are sought to polymerise to new materials with the desired and improved proporties. Enzymatic conversion instead of a chemical process is more environmentally friendly.

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This page is a summary of: Investigation of the Enzyme-Catalysed Transesterification of Methyl Acrylate and Sterically Hindered Alcohol Substrates, ChemistrySelect, May 2018, Wiley,
DOI: 10.1002/slct.201703136.
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