What is it about?
Kumada and Suzuki catalyst-transfer condensation polymerization were investigated for synthesis of poly(p-phenylenevinylene) (PPV).
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Why is it important?
Monomers containing a carbon-carbon double bond did not undergo catalyst-tansfer condensatin polymerization, affording PPV with broad molecular wight distribution.
Perspectives
The reason why monomers containing a carbon-carbon double bond do not undergo catalyst-tansfer condensatin polymerization was clarified by the following our report: J. Am. Chem. Soc., 2015, 137 (17) 5682-5685.
Tsutomu Yokozawa
Kanagawa Daigaku
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This page is a summary of: Investigation of catalyst-transfer condensation polymerization for synthesis of poly(p-phenylenevinylene), Journal of Polymer Science Part A Polymer Chemistry, June 2014, Wiley,
DOI: 10.1002/pola.27281.
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