What is it about?
During "normal" work up in enantioselective synthesis nonracemic mixtures of enantiomers may be separated unexpected.
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Why is it important?
Review If a nonracemic (1≠1) mixture of two enantiomers is applied to a standard chromatographic purification procedure (e. g. SiO2) the enantiomers may be separated from each other.
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This page is a summary of: Purification of Enantiomeric Mixtures in Enantioselective Synthesis: Overlooked Errors and Scientific Basis of Separation in Achiral Environment, Helvetica Chimica Acta, February 2014, Wiley,
DOI: 10.1002/hlca.201300392.
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