What is it about?
The two-step synthesis of title compounds (IV) is based on the radical addition of dioxolane (II) to perfluoroalk-1-enes (I) with high yields for each step. The additions are completely chemoselective and almost completely regioselective. The factors influencing fluoroolefin and dioxolane regioselectivity are discussed.
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Why is it important?
The two-step synthesis of title compounds (IV) is based on the radical addition of dioxolane (II) to perfluoroalk-1-enes (I) with high yields for each step. The additions are completely chemoselective and almost completely regioselective. The factors influencing fluoroolefin and dioxolane regioselectivity are discussed.
Perspectives
The two-step synthesis of title compounds (IV) is based on the radical addition of dioxolane (II) to perfluoroalk-1-enes (I) with high yields for each step. The additions are completely chemoselective and almost completely regioselective. The factors influencing fluoroolefin and dioxolane regioselectivity are discussed.
Dr Vladimír Církva
Institute of Chemical Process Fundamentals
Read the Original
This page is a summary of: ChemInform Abstract: Radical Addition Reactions of Fluorinated Species. Part 7. Highly Selective Two‐Step Synthesis of 1‐(Polyfluoroalkyl)ethane‐1,2‐diols; Regioselectivity of the Additions of Methylated 1,3‐Dioxolanes to Perfluoroolefins., ChemInform, August 1999, Wiley,
DOI: 10.1002/chin.199935137.
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