What is it about?
(Perfluoroalkyl)methyloxiranes (II) are prepared in excellent yields and chemoselectivities, reaching best results in hexane. A change of the solvent strongly influences the epoxide yield and the amount of unsaturated by-products. Regioisomers (Ia) and (III) give a different pattern of by-products.
Featured Image
Why is it important?
(Perfluoroalkyl)methyloxiranes (II) are prepared in excellent yields and chemoselectivities, reaching best results in hexane. A change of the solvent strongly influences the epoxide yield and the amount of unsaturated by-products. Regioisomers (Ia) and (III) give a different pattern of by-products.
Perspectives
(Perfluoroalkyl)methyloxiranes (II) are prepared in excellent yields and chemoselectivities, reaching best results in hexane. A change of the solvent strongly influences the epoxide yield and the amount of unsaturated by-products. Regioisomers (Ia) and (III) give a different pattern of by-products.
Dr Vladimír Církva
Institute of Chemical Process Fundamentals
Read the Original
This page is a summary of: ChemInform Abstract: Highly Selective Synthesis of ((Perfluoroalkyl)methyl)oxiranes (by the Addition of Iodoperfluoroalkanes to Allyl Acetate)., ChemInform, October 1997, Wiley,
DOI: 10.1002/chin.199743112.
You can read the full text:
Contributors
The following have contributed to this page
