What is it about?
Thermally initiated addition reaction of perfluoroalkyl iodides to perfluoroallyl chloride (I) provides terminal perfluoroolefins (III) as the sole reaction products. The product yields depend on the reaction temperature and the chain length of the perfluoroalkyl iodides. The presence of a catalyst or initiator has a negative influence on the yields of the products.
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Why is it important?
Thermally initiated addition reaction of perfluoroalkyl iodides to perfluoroallyl chloride (I) provides terminal perfluoroolefins (III) as the sole reaction products. The product yields depend on the reaction temperature and the chain length of the perfluoroalkyl iodides. The presence of a catalyst or initiator has a negative influence on the yields of the products.
Perspectives
Thermally initiated addition reaction of perfluoroalkyl iodides to perfluoroallyl chloride (I) provides terminal perfluoroolefins (III) as the sole reaction products. The product yields depend on the reaction temperature and the chain length of the perfluoroalkyl iodides. The presence of a catalyst or initiator has a negative influence on the yields of the products.
Dr Vladimír Církva
Institute of Chemical Process Fundamentals
Read the Original
This page is a summary of: ChemInform Abstract: Radical Additions to Fluoroolefins. Thermal Reaction of Perfluoroallyl Chloride with Perfluoroalkyl Iodides as a Selective Synthesis of Terminal Perfluoroolefins., ChemInform, April 1996, Wiley,
DOI: 10.1002/chin.199614091.
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