Chiral Dawson-Type Hybrid Polyoxometalate Catalyzes Enantioselective Diels-Alder Reactions

Wen-Jing Xuan, Candice Botuha, Bernold Hasenknopf, Serge Thorimbert
  • Chemistry - A European Journal, September 2015, Wiley
  • DOI: 10.1002/chem.201502839

What is it about?

We demonstrate in this publication how a chiral POM, in which only the inorganic framework is chiral, induces good enantioselectivities in C-C bond formation.

Why is it important?

Usually, organic-inorganics are chiral due to the organic side chain. We are demonstrating that the chiral inorganic part alone is enough!

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http://dx.doi.org/10.1002/chem.201502839

The following have contributed to this page: Professor Serge THORIMBERT