All Stories

  1. Pushing the Lewis Acidity Boundaries of Boron Compounds With Non-Planar Triarylboranes Derived from Triptycenes
  2. Pushing the Lewis Acidity Boundaries of Boron Compounds With Non‐Planar Triarylboranes Derived from Triptycenes
  3. Complementary Synthetic Approaches toward 9-Phosphatriptycene and Structure–Reactivity Investigations of Its Association with Sterically Hindered Lewis Acids
  4. The Halogen-Samarium Exchange Reaction: Synthetic Applications and Kinetics
  5. Preparation of Functionalized Diaryl- and Diheteroaryllanthanum Reagents by Fast Halogen-Lanthanum Exchange
  6. Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles
  7. Barbier Continuous Flow Preparation and Reactions of Carbamoyllithiums for Nucleophilic Amidation
  8. Mechanistic Studies of Formal Thioboration Reactions of Alkynes
  9. Superelectrophilicity in Michael-Type Reactions: Water Addition to 4-Nitrobenzodifuroxan
  10. Nucleophilicities and Lewis Basicities of Sterically Hindered Pyridines
  11. Reactivity-Tuning in Frustrated Lewis Pairs: Nucleophilicity and Lewis Basicity of Sterically Hindered Phosphines
  12. Structures, Lewis Acidities, Electrophilicities, and Protecting Group Abilities of Phenylfluorenylium and Tritylium Ions
  13. Nucleophilicity of Alkyl Zirconocene and Titanocene Precatalysts, and Kinetics of Activation by Carbenium Ions and by B(C6F5)3
  14. Scope and Mechanisms of Frustrated Lewis Pair Catalyzed Hydrogenation Reactions of Electron-Deficient CC Double Bonds
  15. Structure and Reactivity of Indolylmethylium Ions: Scope and Limitations in Synthetic Applications
  16. Structure and Reactivity of Boron-Ate Complexes Derived from Primary and Secondary Boronic Esters
  17. Fine-Tuning the Nucleophilic Reactivities of Boron Ate Complexes Derived from Aryl and Heteroaryl Boronic Esters
  18. Feineinstellung der nucleophilen Reaktivität von Bor-at-Komplexen aus Aryl- und Heteroarylboronsäureestern
  19. Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position
  20. Stereoselektive Synthese und Reaktionen von in Position 3 funktionalisierten sekundären Alkyllithiumverbindungen
  21. Aromaticity Evaluations of Planar [6]Radialenes
  22. Di- and Triarylmethylium Ions as Probes for the Ambident Reactivities of Carbanions Derived from 5-Benzylated Meldrum’s Acid
  23. New In Situ Trapping Metalations of Functionalized Arenes and Heteroarenes with TMPLi in the Presence of ZnCl2and Other Metal Salts
  24. Mechanistic studies and quantification of the electrophilicity of aromatic triflones in σ-complexation and SNAr reactions
  25. Diastereoselective Synthesis of Open-Chain Secondary Alkyllithium Compounds and Trapping Reactions with Electrophiles
  26. Diastereoselektive Synthese von offenkettigen sekundären Alkyllithiumverbindungen und Abfangreaktionen mit Elektrophilen
  27. Electronic and solvent effects on kinetics of SNAr substitution reactions of substituted anilines with 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole in MeOH–Me2SO mixtures of varying composition: one reaction with two mechanistic pathways
  28. Electrophilic Aromatic Substitutions of Aryltrifluoroborates with Retention of the BF 3 – Group: Quantification of the Activating and Directing Effects of the Trifluoroborate Group
  29. 5-[(E)-Methoxy(phenyl)methylidene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole
  30. Potassium [1-(tert-butoxycarbonyl)-1H-indol-3-yl]trifluoroborate hemihydrate
  31. Nucleophilicity parameters for designing transition metal-free C–C bond forming reactions of organoboron compounds
  32. The N-Alkylation of Substituted 4-Tetrazolo[1,5-a]pyridines: Easy Access to a New Series of Electrophiles
  33. Synthesis and Reactivity of Highly Nucleophilic Pyridines
  34. Understanding the Diels-Alder Reactivity of Superelectrophilic Nitrobenzofuroxans and Related 10Π-Heteroaromatics through DFT-Based Electrophilicity Descriptors
  35. Electrochemical and spectrophotometrical investigation of the electron-accepting strength of organic superelectrophiles: X-ray structure of their charge transfer complexes with tetrathiafulvalene
  36. The Diels-Alder Reaction of 4,6-Dinitrobenzofuroxan with 1-Trimethylsilyloxybuta-1,3-diene: A Case Example of a Stepwise Cycloaddition
  37. X-ray Structure of a CT Complex Relevant to Diels−Alder Reactivity of Anthracenes
  38. Theoretical and experimental 1 H, 13 C and 15 N NMR studies of N -alkylation of substituted tetrazolo[1,5-a]pyridines
  39. Supramolecular association of 1,2,5-chalcogenadiazoles: an unexpected self-assembled dissymetric [Se⋯N]2 four-membered ring
  40. ChemInform Abstract: Michael Addition of Manganese Enolates to Nitroolefins.
  41. Michael Addition of Manganese Enolates to Nitroolefins
  42. Superelectrophilicity of the Nitroolefinic Fragment of 4-Nitrobenzodifuroxan in Michael-Type Reactions with Indoles: A Kinetic Study in Acetonitrile