All Stories

  1. Imidazol-2-ylidene Reactivity towards Cyanocarbon
  2. Synthesis and Oxidative Desulfurization of PV-Functionalized Imidazole-2-thiones: Easy Access to P-Functional Ionic Liquids*
  3. Role of Electronegative Substituents on the Bond Energies in the Grubbs Metathesis Catalysts for M = Fe, Ru, Os
  4. Electronic structure predictions of the properties of non-innocent P-ligands in group 6B transition metal complexes
  5. The Zwitterionic Structure of the Parent Amidinium Tetrazolide and a Rare Tetrazole Ring-Opening Reaction
  6. Inside Cover: Fused Spirocyclic Imidazolone Ketals (Angew. Chem. Int. Ed. 41/2013)
  7. Innentitelbild: Fused Spirocyclic Imidazolone Ketals (Angew. Chem. 41/2013)
  8. Fused Spirocyclic Imidazolone Ketals
  9. Fused Spirocyclic Imidazolone Ketals
  10. Synthesis of Highly Substituted 2-13C-Imidazolium Salts and Metal NHC ­Complexes for the Investigation of Electronic Unsymmetry by NMR
  11. Synthesis and Complexes of Fluoroalkoxy Carbenes
  12. Synthesis and Complexes of Fluoroalkoxy Carbenes
  13. ChemInform Abstract: Synthesis of Bis(imidazole-2-thion-4-yl)phosphanes.
  14. Synthesis and first complexes of C4/5 P-bifunctional imidazole-2-thiones
  15. Computational Studies of the Properties of Azole· x BH 3 Adducts for Chemical Hydrogen Storage Systems
  16. Synthesis of Backbone P -Functionalized Imidazol-2-ylidene Complexes: En Route to Novel Functional Ionic Liquids
  17. Synthesis of Bis(imidazole-2-thion-4-yl)phosphanes
  18. Synthesis, structure and reactivity of 4-phosphanylated 1,3-dialkyl-imidazole-2-thiones
  19. On the Dual Role of N-Heterocyclic Carbenes as Bases and Nucleophiles in Reactions with Organic Halides
  20. Bond Energies in Models of the Schrock Metathesis Catalyst
  21. NMR Studies of 1-tert-Butyl-3-methyl-2,4-bis(2,4,6-tri-tert-butylphenyl)-1,3-diphosphacyclobutane-2,4-diyl
  22. Diverse Reactions of Sterically Protected 1,3-Diphosphacyclobutane-2,4-diyls with Hydride
  23. Modeling the Direct Activation of Dihydrogen by a P2C2-Cyclic Biradical: Formation of a Cyclic Bis(P-H λ5-phosphorane)
  24. When Sterics Overcome Electronics: An Unusual Haptotropic P→N Pentacarbonyltungsten Shift
  25. N-Heterocyclic Carbenes
  26. Synthesis of Stabilized Phosphinidenoid Complexes Using Weakly Coordinating Cations
  27. Carbene-Based Lewis Pairs for Hydrogen Activation
  28. Intensive NMR study of 1-t-butyl-3-methyl-2,4-bis(2,4,6-tri-t-butylphenyl)-1,3-diphosphacyclobutane-2,4-diyl
  29. Final Report: Main Group Element Chemistry in Service of Hydrogen Storage and Activation
  30. Synthesis and physicochemical properties of stable 1,3-diphosphacyclobutane-2,4-diyls bearing sulfanyl groups
  31. Diverse reactions of sterically-protected 1,3-diphosphacyclobutane-2,4-diyls with hydride
  32. Synthesis and properties of oligo(biradicals) composed of 1,3-diphosphacyclobutane-2,4-diyl units and benzyl-type linkers
  33. Modeling the Direct Activation of Dihydrogen by a P 2 C 2 Cyclic Biradical: Formation of a Cyclic Bis(P−H λ 5 -phosphorane)
  34. Carbenes Introduction
  35. Catenation of 1,3-Diphosphacyclobutane-2,4-diyl Units Having 2,4,6-Tri-tert-butylphenyl Protecting Groups and a P-sec-Butyl Group in the Ring
  36. Diammoniosilane: Computational Prediction of the Thermodynamic Properties of a Potential Chemical Hydrogen Storage System
  37. Fused polycyclic nucleophilic carbenes – synthesis, structure, and function
  38. Poly(Biradicals): Oligomers of 1,3-Diphosphacyclobutane-2,4-diyl Units
  39. Poly(Biradicals): Oligomers of 1,3-Diphosphacyclobutane-2,4-diyl Units
  40. Studies on Stable 1,3-Diphosphacyclobutane-2,4-diyls
  41. The Heats of Formation of Diazene, Hydrazine, N 2 H 3 + , N 2 H 5 + , N 2 H, and N 2 H 3 and the Methyl Derivatives CH 3 NNH, CH 3 NNCH 3 , and CH 3 HNNHCH 3
  42. Reaction of tetramethylimidazol-2-ylidene with (TptBu,Me)YbE(thf) (E=I, CH2SiMe3): simple adduct and a hydrocarbyl tethered carbene ligand
  43. Preparation and Characterization of an Air-Tolerant 1,3-Diphosphacyclobuten-4-yl Radical
  44. Preparation and Characterization of an Air-Tolerant 1,3-Diphosphacyclobuten-4-yl Radical
  45. Accurate Heats of Formation of the “Arduengo-Type” Carbene and Various Adducts Including H 2 from ab Initio Molecular Orbital Theory
  46. Oxidation of 1,3-Diphosphacyclobutane-2,4-diyl with Ammoniumyl Antimonate and EPR Study of the Corresponding Cation Radical
  47. The Generation of a Metallocene-Fused Imidazol-2-ylidene and Its Mercury Complex
  48. The Generation of a Metallocene-Fused Imidazol-2-ylidene and Its Mercury Complex
  49. A Bimetallic Complex Containing a Cyclopentadienyl-Annulated Imidazol-2-ylidene
  50. A zwitterionic cyclopentadienyl annulated imidazolium salt
  51. Heteroferrocene: The Synthesis of Bis[(3a,4,5,6,6a-η)-1,3,4,5,6-pentamethylcyclopenta[d]imidazo-2-thionoyl]iron(II)
  52. 1,3-Dimethylimidazole-2-thione
  53. A Stable Dirhodium Tetracarboxylate Carbenoid:  Crystal Structure, Bonding Analysis, and Catalysis
  54. Carbene Complexes of Pnictogen Pentafluorides and Boron Trifluoride
  55. C−H Insertion Reactions of Nucleophilic Carbenes
  56. Imidazolylidenes, imidazolinylidenes and imidazolidines
  57. Carbene Adducts of Dimethylcadmium
  58. Looking for Stable Carbenes:  The Difficulty in Starting Anew
  59. A Tris(trifluoromethyl)antimony Adduct of a Nucleophilic Carbene: Geometric Distortions in Carbene Adducts
  60. Carbene-Lithium Interactions.
  61. 1,3,4,5-Tetraphenylimidazol-2-ylidene: The Realization of Wanzlick's Dream
  62. 1,3,4,5-Tetraphenylimidazol-2-yliden: die Realisierung von Wanzlicks Traum
  63. 1,3,4,5-Tetraphenylimidazol-2-yliden: die Realisierung von Wanzlicks Traum
  64. Adducts of Carbenes with Group II and XII Metallocenes †
  65. Auf der Suche nach Stabilen Carbenen
  66. An Air Stable Carbene and Mixed Carbene “Dimers”
  67. Carbene−Pnictinidene Adducts
  68. A Carbene−Phosphorus(V) Adduct
  69. A Stable Thiazol-2-ylidene and Its Dimer
  70. Nature of the bonding in a carbene–phosphinidene: a main group analogue of a Fischer carbene complex? Isolation and characterisation of a bis(borane) adduct
  71. A CarbenePhosphinidene Adduct: "Phosphaalkene''.
  72. Investigation of a mercury(II) carbene complex: bis(1,3‐dimethylimidazol‐2‐ylidene) mercury chloride
  73. Investigation of a mercury(II) carbene complex: bis(1,3-dimethylimidazol-2-ylidene) mercury chloride
  74. A stable diaminocarbene
  75. On the proposed existence of a ketene derived from carbon monoxide and 1,3-di-1-adamantylimidazol-2-ylidene
  76. Subchronic Toxicity Study in Rats with 1-Methyl-3-propylimidazole-2-thione (PTI): Effects on the Thyroid
  77. A Bis(carbene)-Proton Complex: Structure of a C-H-C Hydrogen Bond
  78. Carbene-Lanthanide Complexes
  79. Photoelectron Spectroscopy of a Carbene/Silylene/Germylene Series
  80. Low coordinate hypervalent phosphorus
  81. Chemical Shielding Tensor of a Carbene
  82. Electron Distribution in a Stable Carbene
  83. Low-Coordinate Carbene Complexes of Nickel(0) and Platinum(0)
  84. A Bis(carbene) Adduct of Iodine(1+)
  85. Coordination Chemistry of ADPO
  86. Macro-cyclic aramids (2n-AZA[2n ]paracyclophane-2n-ones):new intermediates for the synthesis of p -aramids
  87. Carbene adducts of magnesium and zinc
  88. Homoleptic carbene-silver(I) and carbene-copper(I) complexes
  89. Dihalo derivatives of 3-coordinate hypervalent phosphorus compounds
  90. A carbene germanium diiodide adduct: model of the non-least-motion pathway for dimerization of singlet carbenes
  91. A stable carbene-alane adduct
  92. Electronic stabilization of nucleophilic carbenes
  93. A 3-coordinate 4-electron phosphorus donor
  94. Synthesis of a reverse ylide from a nucleophilic carbene
  95. Electronic structure of .lambda.5-phosphaacetylene and corresponding triplet methylenes
  96. Edge inversion in tricoordinated main group IV anions
  97. A novel mode of coordination for phosphorus
  98. The syntheses and structures of iron carbonyl adducts of tricoordinated hypervalent phosphorus compounds
  99. Electronic structure of a stable nucleophilic carbene
  100. A stable crystalline carbene [Erratum to document cited in CA114(7):62009r]
  101. Pentacoordinate 10-electron pnicogen-manganese adducts: verification of the 10-Pn-3 arrangement in ADPnO molecules
  102. Application of local-density functional theory to molecules containing a hypervalent bond
  103. LOWEST ENERGY DISTORTIONS IN HYPERVALENT SULFUR COMPOUNDS: THIAPENTALENES
  104. A stable crystalline carbene
  105. Complexes of tricoordinate hypervalent pnictogens with pentamethylcyclopentadienylruthenium
  106. Molecular control of self-assembled monolayer films of imidazole-2-thiones: adsorption and reactivity
  107. Electronic and molecular structure of protonated fluoro isocyano krypton [FKrNCH]+. The question of hypervalent bonding
  108. Electronic structures of trifluorodixenon(+) and xenon iodide trifluoride. Examples of 5c,6e hypervalent bonding
  109. Tetrakis(trifluoromethyl)cyclopentadienyl ligands for transition metals
  110. Edge inversion barrier at a four-coordinate main group IV center
  111. Solvent stabilization of the edge inversion transition state in tetrahedral molecules
  112. The chemistry and structure of a 10-Sn-4 system: Pseudo-trigonal-bipyramidal 4-coordinate, 10-electron tin centers
  113. Spectroscopic properties and the edge inversion process in tetrahedral AF4 molecules
  114. The Chemistry of 10-Pn-3 Systems1: Tricoordinate Hypervalent Pnictogen Compounds and Related Systems
  115. The synthesis, structure, and chemistry of 10-Pn-3 systems: tricoordinate hypervalent pnicogen compounds
  116. Electronic and substituent effects on the barrier to edge inversion
  117. Periodic trends in the edge and vertex inversion barriers for tricoordinate pnicogen hydrides and fluorides
  118. Chemistry of tricoordinate hypervalent pnictogens
  119. A new class of pnicogen-transition metal adducts: a stereo active lone pair at a 10-Sb-4 antimony center
  120. Direct determination of the barrier to edge inversion at trivalent phosphorus: verification of the edge inversion mechanism
  121. A new inversion process at Group VA (Group 15) elements. Edge inversion through a planar T-shaped structure
  122. Reversible transformation of 10-P-3 ADPO to an 8-P-3 ADPO.cntdot.PtI2 adduct
  123. Chemistry and structure of the first 10-Sb-3 species
  124. Synthesis and structure of the first 20-Bi-9 system: a discrete nine-coordinate 20-electron bismuth
  125. The synthesis and structure of the first 10-As-3 species
  126. Synthesis and structure of the first 10-P-3 species
  127. The synthesis and structure of a stabilized nitrilium ylide
  128. Structure of an electronically stabilized carbonyl ylide
  129. Diazotetrakis(trifluoromethyl)cyclopentadiene and ylides of electronegative elements
  130. Intramolecular oxidative cyclization reactions of trivalent phosphorus and carbonyl functions