All Stories

  1. Synthesis of Biologically Relevant Compounds by Ruthenium Porphyrin Catalyzed Amination of Benzylic C–H Bonds

    Article • Organometallics, April 2014, American Chemical Society (ACS)

    Alessandro Caselli, Prof. Piero Macchi

  2. Mild Regiospecific Synthesis of 1-Alkoxy-isochromenes Catalyzed by Well-Defined [Silver(I)(Pyridine-Containing Ligand)] Complexes

    Article • The Journal of Organic Chemistry, March 2014, American Chemical Society (ACS)

    Alessandro Caselli

  3. Highly diastereoselective cyclopropanation of α-methylstyrene catalysed by a C2-symmetrical chiral iron porphyrin complex

    Article • Chemical Communications, January 2014, Royal Society of Chemistry

    Alessandro Caselli

  4. Continuos flow asymmetric cyclopropanations in CO2 catalysed by supported [Cu(I)Pc-L*] complexes

    Article • Green Chemistry, January 2014, Royal Society of Chemistry

    Alessandro Caselli, Dr Vladimiro Dal Santo

  5. ChemInform Abstract: Thiosemicarbazone Copper Complexes as Competent Catalysts for Olefin Cyclopropanations.

    Article • ChemInform, January 2013, Wiley

    Alessandro Caselli

  6. Asymmetric cyclopropanation of olefins catalysed by Cu(i) complexes of chiral pyridine-containing macrocyclic ligands (Pc-L*)

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Alessandro Caselli, Prof. Piero Macchi

  7. Silica “SHB” chiral Pc-L* copper complexes for halogen-free solvent cyclopropanation reactions

    Article • RSC Advances, January 2013, Royal Society of Chemistry

    Alessandro Caselli, Dr Vladimiro Dal Santo

  8. Co(porphyrin)-catalysed amination of 1,2-dihydronaphthalene derivatives by aryl azides

    Article • Journal of Organometallic Chemistry, October 2012, Elsevier

    Alessandro Caselli

  9. Thiosemicarbazone copper complexes as competent catalysts for olefin cyclopropanations

    Article • Journal of Organometallic Chemistry, September 2012, Elsevier

    Alessandro Caselli

  10. [Ru(TPP)CO]‐Catalysed Intramolecular Benzylic CH Bond Amination, Affording Phenanthridine and Dihydrophenanthridine Derivatives

    Article • Chemistry - A European Journal, July 2012, Wiley

    Alessandro Caselli

  11. Insights into the Mechanism of the Ruthenium-Porphyrin-Catalysed Allylic Amination of Olefins by Aryl Azides

    Article • European Journal of Inorganic Chemistry, November 2011, Wiley

    Alessandro Caselli, Prof. Piero Macchi

  12. Henry reaction catalyzed by copper(I) complexes of a new pyridine‐containing macrocyclic ligand

    Article • Applied Organometallic Chemistry, October 2011, Wiley

    Alessandro Caselli

  13. Cyclopropanation Reactions Mediated by Group 9 Metal Porphyrin Complexes

    Article • European Journal of Inorganic Chemistry, October 2011, Wiley

    Alessandro Caselli

  14. Synthesis of Heterocycles by Intramolecular Cyclization of Organic Azides

    Article • Current Organic Chemistry, May 2011, Bentham Science Publishers

    Alessandro Caselli

  15. Mapping Palladium Reduction by Carbon Monoxide in a Catalytically Relevant System. A Novel Palladium(I) Dimer

    Article • Organometallics, March 2011, American Chemical Society (ACS)

    Alessandro Caselli, Prof. Piero Macchi

  16. Polyoxometalates: Powerful Catalysts for Atom‐Efficient Cyclopropanations

    Article • Advanced Synthesis & Catalysis, September 2010, Wiley

    Alessandro Caselli

  17. Catalytic Polymer Membranes under Forcing Conditions: Reduction of Nitrobenzene by CO/H2O Catalyzed by Ruthenium Bis(arylimino)acenaphthene Complexes

    Article • ChemCatChem, September 2010, Wiley

    Alessandro Caselli, Professor Enrico Drioli

  18. Synthesis and characterization of new tetra-substituted porphyrins with exo-donor carboxylic groups as building blocks for supramolecular architectures: Catalytic and structural studies of their metalated derivatives

    Article • Journal of Porphyrins and Phthalocyanines, September 2010, World Scientific Pub Co Pte Lt

    Alessandro Caselli, Professor Davide M Proserpio

  19. Ruthenium porphyrins-catalyzed atom-efficient amination of C-H bonds by arylazides

    Article • Journal of Porphyrins and Phthalocyanines, August 2010, World Scientific Pub Co Pte Lt

    Alessandro Caselli

  20. Chiral "basket handle" binaphthyl porphyrins: synthesis, catalytic epoxidation and NMR conformational studies

    Article • Journal of Porphyrins and Phthalocyanines, July 2010, World Scientific Pub Co Pte Lt

    Alessandro Caselli

  21. From homogeneously to heterogeneously catalyzed cyclopropanation reactions: New polymeric membranes embedding cobalt chiral schiff base complexes

    Article • Journal of Molecular Catalysis A Chemical, February 2010, Elsevier

    Alessandro Caselli, Professor Enrico Drioli

  22. Chiral cyclopropylamines in the synthesis of new ligands; first asymmetric Alkyl-BIAN compounds

    Article • Chemical Communications, January 2010, Royal Society of Chemistry

    Alessandro Caselli, Prof. Piero Macchi

  23. Mechanistic Study of the Palladium-Phenanthroline Catalyzed Carbonylation of Nitroarenes and Amines: Palladium-Carbonyl Intermediates and Bifunctional Effects

    Article • Chemistry - A European Journal, August 2009, Wiley

    Alessandro Caselli, Prof. Piero Macchi

  24. Synthesis and characterization of some transition metal complexes with a novel Schiff base ligand and their use as catalysts for olefin cyclopropanation

    Article • Journal of Molecular Catalysis A Chemical, August 2009, Elsevier

    Alessandro Caselli

  25. Synthesis and characterisation of new Schiff base metal complexes and their use as catalysts for olefin cyclopropanation

    Article • Inorganica Chimica Acta, April 2009, Elsevier

    Alessandro Caselli

  26. Rearrangement of N‐Aryl‐2‐Vinylaziridines to Benzoazepines and Dihydropyrroles: A Synthetic and Theoretical Study

    Article • Chemistry - A European Journal, January 2009, Wiley

    Alessandro Caselli

  27. Nitrene transfer reactions mediated by metallo-porphyrin complexes

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Alessandro Caselli

  28. The key intermediate in the amination of saturated C–H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)2 (Ar = 3,5-(CF3)2C6H3)

    Article • Chemical Communications, January 2009, Royal Society of Chemistry

    Alessandro Caselli, Prof. Piero Macchi

  29. Asymmetric Cyclopropanation of Olefins Catalyzed by Chiral Cobalt(II)-Binaphthyl Porphyrins

    Article • Organometallics, November 2008, American Chemical Society (ACS)

    Alessandro Caselli

  30. Allylic Amination and Aziridination of Olefins by Aryl Azides Catalyzed by CoII(tpp): A Synthetic and Mechanistic Study

    Article • European Journal of Inorganic Chemistry, June 2008, Wiley

    Alessandro Caselli

  31. Heterogenization of ruthenium porphyrin complexes in polymeric membranes: Catalytic aziridination of styrenes

    Article • Journal of Molecular Catalysis A Chemical, March 2008, Elsevier

    Alessandro Caselli, Professor Enrico Drioli

  32. New ruthenium porphyrin polymeric membranes: Preparation and characterization

    Article • Applied Catalysis A General, February 2008, Elsevier

    Alessandro Caselli, Professor Enrico Drioli

  33. Designing new ligands: asymmetric cyclopropanation by Cu(i) complexes based on functionalised pyridine-containing macrocyclic ligands

    Article • Dalton Transactions, January 2008, Royal Society of Chemistry

    Alessandro Caselli, Prof. Piero Macchi

  34. The (Porphyrin)ruthenium‐Catalyzed Aziridination of Olefins Using Aryl Azides as Nitrogen Sources

    Article • European Journal of Organic Chemistry, December 2007, Wiley

    Alessandro Caselli

  35. The [Ru(CO)(porphyrin)]‐Catalyzed Synthesis of N‐Aryl‐2‐vinylaziridines.

    Article • ChemInform, April 2007, Wiley

    Alessandro Caselli

  36. The [Ru(CO)(porphyrin)]‐Catalyzed Synthesis of N‐Aryl‐2‐vinylaziridines

    Article • European Journal of Organic Chemistry, January 2007, Wiley

    Alessandro Caselli

  37. Fine Chemicals by Reductive Carbonylation of Nitroarenes, Catalyzed by Transition‐Metal Complexes

    Article • ChemInform, October 2006, Wiley

    Alessandro Caselli

  38. Chiral porphyrin complexes of cobalt(II) and ruthenium(II) in catalytic cyclopropanation and amination reactions

    Article • Inorganica Chimica Acta, June 2006, Elsevier

    Alessandro Caselli

  39. Synthesis of Indoles by Intermolecular Cyclization of Unfunctionalized Nitroarenes and Alkynes, Catalyzed by Palladium−Phenanthroline Complexes

    Article • The Journal of Organic Chemistry, April 2006, American Chemical Society (ACS)

    Alessandro Caselli

  40. The palladium–phenanthroline catalyzed carbonylation of nitroarenes to diarylureas: Effect of chloride and diphenylphosphinic acid

    Article • Journal of Organometallic Chemistry, October 2005, Elsevier

    Alessandro Caselli

  41. Origin of the Deactivation in Styrene Aziridination by Aryl Azides, Catalyzed by Ruthenium Porphyrin Complexes. Structural Characterization of a Δ2-1,2,3-Triazoline RuII(TPP)CO Complex

    Article • Organometallics, August 2005, American Chemical Society (ACS)

    Alessandro Caselli, Prof. Piero Macchi

  42. Catalytic amination reactions mediated by Co(II) Schiff base complexes

    Article • Journal of Organometallic Chemistry, April 2005, Elsevier

    Alessandro Caselli

  43. Structural Determination of Ruthenium−Porphyrin Complexes Relevant to Catalytic Epoxidation of Olefins

    Article • Inorganic Chemistry, February 2005, American Chemical Society (ACS)

    Alessandro Caselli

  44. Allylic Amination of Unfunctionalyzed Olefins by Nitroarenes and CO, Catalyzed by Ru3(CO)12/Ph‐BIAN (Ph‐BIAN = Bis(phenylimino)acenaphthenequinone): Extension to the Synthesis of Allylic Amines with Strongly Electron‐Withdrawing o...

    Article • ChemInform, August 2004, Wiley

    Alessandro Caselli

  45. Allylic amination of unfunctionalyzed olefins by nitroarenes and CO, catalyzed by Ru3(CO)12/Ph-BIAN (Ph-BIAN=bis(phenylimino)acenaphthenequinone): extension to the synthesis of allylic amines with strongly electron-withdrawing or electron-donating grou...

    Article • Tetrahedron, May 2004, Elsevier

    Alessandro Caselli

  46. Synthesis of mixed Ar,Ar′-BIAN ligands (Ar,Ar′-BIAN = bis(aryl)acenaphthenequinonediimine). Measurement of the coordination strength of hemilabile ligands with respect to their symmetric counterparts

    Article • Dalton Transactions, January 2004, Royal Society of Chemistry

    Alessandro Caselli, Prof. Piero Macchi

  47. Synthesis of C2-symmetrical diamine based on (1R)-(+)-camphor and application to oxidative aryl coupling of naphthols

    Article • Tetrahedron Asymmetry, June 2003, Elsevier

    Alessandro Caselli

  48. A new entry to β-hydroxyphosphonates: the SmI2-mediated reaction of diethyl iodomethylphosphonate with carbonyl compounds

    Article • Tetrahedron Letters, September 2002, Elsevier

    Alessandro Caselli

  49. SmI2-mediated reactions of diethyl iodomethylphosphonate with esters and lactones: a highly stereoselective synthesis of a precursor of the C-glycosyl analogue of thymidine 5′-(β-l-rhamnosyl)diphosphate

    Article • Tetrahedron Letters, September 2002, Elsevier

    Alessandro Caselli

  50. Dinitrogen Rearranging over a Metal−Oxo Surface and Cleaving to Nitride:  From the End-On to the Side-On Bonding Mode, to the Stepwise Cleavage of the N⋮N Bonds Assisted by NbIII-calix[4]arene

    Article • Journal of the American Chemical Society, April 2000, American Chemical Society (ACS)

    Alessandro Caselli

  51. The Stepwise Four- and Six-Electron Reduction of Carbon Monoxide to Oxyalkylidyne, to Carbide and Oxide, Then to Carbide over an Nb−Oxo Surface Modeled by Calix[4]arene1

    Article • Journal of the American Chemical Society, December 1999, American Chemical Society (ACS)

    Alessandro Caselli

  52. A Synthetic Methodology to Niobium Alkylidenes:  Reactivity of a NbNb Double Bond Anchored to a Calix[4]arene Oxo Surface with Ketones, Aldehydes, Imines, and Isocyanides

    Article • Journal of the American Chemical Society, August 1999, American Chemical Society (ACS)

    Alessandro Caselli

  53. Zirconium−Butadiene Bonded over a Planar Set of Oxygens Derived from Calix[4]arene and Its Behavior as a Source of Zirconium(II)

    Article • Organometallics, December 1997, American Chemical Society (ACS)

    Alessandro Caselli

  54. Organometallic Reactivity on a Calix[4]arene Oxo Surface. Synthesis and Rearrangement of Zr−C Functionalities Anchored to a Calix[4]arene Moiety

    Article • Journal of the American Chemical Society, October 1997, American Chemical Society (ACS)

    Alessandro Caselli

  55. Organometallic Reactivity on a Calix[4]arene Oxo Surface. The Stepwise Migratory Insertion of Carbon Monoxide and Isocyanides into Zirconium−Carbon Bonds Anchored to a Calix[4]arene Moiety

    Article • Journal of the American Chemical Society, October 1997, American Chemical Society (ACS)

    Alessandro Caselli