All Stories

  1. Efficient access to polysubstituted tetrahydrofurans by electrophilic cyclization of vinylsilyl alcohols

    Article • RSC Advances, January 2015, Royal Society of Chemistry

    Professor Asuncion Barbero

  2. Competitive Silyl-Prins Cyclization versus Tandem Sakurai-Prins Cyclization: An Interesting Substitution Effect

    Article • Chemistry - A European Journal, September 2014, Wiley

    Professor Asuncion Barbero

  3. Multicomponent Prins Cyclization from Allylsilyl Alcohols Leading to Dioxaspirodecanes

    Article • Organic Letters, October 2013, American Chemical Society (ACS)

    Professor Asuncion Barbero

  4. Efficiency of Acid- and Mercury-Catalyzed Cyclization Reactions in the Synthesis of Tetrahydrofurans from Allylsilyl Alcohols

    Article • European Journal of Organic Chemistry, August 2012, Wiley

    Professor Asuncion Barbero

  5. One-Pot Synthesis of 2,7-Dioxabicyclo[2.2.1]heptanes from Oxoallylsilanes

    Article • European Journal of Organic Chemistry, October 2011, Wiley

    Professor Asuncion Barbero

  6. ChemInform Abstract: Silyl and Stannyl Derivatives of Organocopper Compounds

    Article • ChemInform, January 2011, Wiley

    Professor Asuncion Barbero

  7. Silyl and Stannyl Derivatives of Organocopper Compounds

    Article • January 2011, Wiley

    Professor Asuncion Barbero

  8. One-pot multicoupling reaction of silylcopper reagents, organolithium compounds and α,β-unsaturated nitriles

    Article • Organic & Biomolecular Chemistry, January 2011, Royal Society of Chemistry

    Professor Asuncion Barbero

  9. Synthesis of 3-Methylenecyclohexan-1-ols by Lewis Acid Catalyzed Cyclization of (Epoxy-allyl)silanes

    Article • European Journal of Organic Chemistry, March 2010, Wiley

    Professor Asuncion Barbero

  10. Pd-catalyzed cross-coupling of allylsilane-vinylcopper species with aryl and vinyl halides: the first total synthesis of (−)-nomadone

    Article • Tetrahedron, July 2009, Elsevier

    Professor Asuncion Barbero

  11. Isopropenyllithium

    Article • March 2008, Wiley

    Professor Asuncion Barbero

  12. Allene

    Article • March 2007, Wiley

    Professor Asuncion Barbero

  13. Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy

    Article • Beilstein Journal of Organic Chemistry, January 2007, Beilstein Institut

    Professor Asuncion Barbero

  14. Peterson olefination from α-silyl aldehydes

    Article • Nature Protocols, November 2006, Springer Science + Business Media

    Professor Asuncion Barbero

  15. Isopropenyllithium

    Article • April 2006, Wiley

    Professor Asuncion Barbero

  16. Intramolecular Ene Reaction of Epoxyallylsilanes:  Synthesis of Allyl- and Vinylsilane-Functionalized Cyclohexanols

    Article • The Journal of Organic Chemistry, December 2005, American Chemical Society (ACS)

    Professor Asuncion Barbero

  17. Silylcuprates from Allene and Their Reaction with α,β-Unsaturatedd Nitriles and Imines. Synthesis of Silylated Oxo Compounds Leading to Cyclopentane and Cycloheptane Ring Formation

    Article • The Journal of Organic Chemistry, August 2005, American Chemical Society (ACS)

    Professor Asuncion Barbero

  18. Spiro-Cyclopropanation from Oxoallylsilanes

    Article • Journal of the American Chemical Society, June 2005, American Chemical Society (ACS)

    Professor Asuncion Barbero

  19. Allylstannanes and vinylstannanes from stannylcupration of C–C multiple bonds. Recent advances and applications in organic synthesis

    Article • Chemical Society Reviews, January 2005, Royal Society of Chemistry

    Professor Asuncion Barbero

  20. Allylsilanes and Vinylsilanes from Silylcupration of Carbon−Carbon Multiple Bonds:  Scope and Synthetic Applications

    Article • Accounts of Chemical Research, October 2004, American Chemical Society (ACS)

    Professor Asuncion Barbero

  21. The regiochemistry of the stannylcupration of allenes: synthesis of allylstannanes using the lower order cuprate (Bu3Sn)CuCNLi

    Article • Tetrahedron Letters, May 2004, Elsevier

    Professor Asuncion Barbero

  22. Acid-Catalyzed Cyclization of Epoxyallylsilanes. An Unusual Rearrangement Cyclization Process.

    Article • ChemInform, March 2004, Wiley

    Professor Asuncion Barbero

  23. Allene: As Small in Size as Versatile in Synthesis. A General Scope of its Usefulness as a C 3 -Synthon for Carbocyclic Annulations

    Article • Synthesis, January 2004, Thieme Publishing Group

    Professor Asuncion Barbero

  24. Silylcupration of Allene with the Lower Order Cuprate ( t -BuPh 2 Si)CuCNLi and Reaction with α,β-Unsaturated Nitriles. An Unusual Diaddition Process Leading to Disilyl Functionalised Ketones

    Article • Synlett, January 2004, Thieme Publishing Group

    Professor Asuncion Barbero

  25. Isoxazoles as Latent Siloxybutadienes: An Easy Entry to Polyfunctionalized Benzene Systems via Diels-Alder Reaction with Acetylenes

    Article • Synthesis, January 2004, Thieme Publishing Group

    Professor Asuncion Barbero

  26. Acid-Catalyzed Cyclization of Epoxyallylsilanes. An Unusual Rearrangement Cyclization Process

    Article • Organic Letters, October 2003, American Chemical Society (ACS)

    Professor Asuncion Barbero

  27. Addition of Organometallic Compounds to Tin-Containing Cyclic Ketones. Remote Stereocontrol Induced by the Stannyl Group

    Article • Journal of the American Chemical Society, October 2003, American Chemical Society (ACS)

    Professor Asuncion Barbero

  28. Intramolecular Cyclization of tert -Butyldiphenylallylsilane Units and Carbonyl Groups:  Allylsilane Terminated Cyclization versus the Ene Reaction

    Article • The Journal of Organic Chemistry, November 2001, American Chemical Society (ACS)

    Professor Asuncion Barbero

  29. Remote Stereocontrol in Carbonyl Additions Promoted by Vinylstannanes

    Article • Angewandte Chemie, June 2001, Wiley

    Professor Asuncion Barbero

  30. Remote Stereocontrol in Carbonyl Additions Promoted by Vinylstannanes

    Article • Angewandte Chemie International Edition, June 2001, Wiley

    Professor Asuncion Barbero

  31. Remote Stereocontrol in Carbonyl Additions Promoted by Vinylstannanes

    Article • Angewandte Chemie International Edition, June 2001, Wiley

    Professor Asuncion Barbero

  32. A tandem allylsilane–vinylsilane difunctionalization by silylcupration of allene followed by reaction with α,β-unsaturated nitriles

    Article • Chemical Communications, January 2001, Royal Society of Chemistry

    Professor Asuncion Barbero

  33. Synthesis of Silyloxyvinylstannanes from BHT Ester Enolates and Stannyllithium Reagents. Copper(I)-Mediated Coupling with Alkenyl Halides

    Article • Synlett, January 2001, Thieme Publishing Group

    Professor Asuncion Barbero

  34. Allylsilane-Vinylcopper Reagents: Palladium-Mediated Coupling with Alkenyl Halides. Synthesis and Photochemical [2 + 2] Cyclization of (±)-Ipsdienol

    Article • Synlett, January 2001, Thieme Publishing Group

    Professor Asuncion Barbero

  35. The Peterson Olefination Using the tert-Butyldiphenylsilyl Group: Stereoselective Synthesis of Di- and Trisubstituted Alkenes

    Article • Synthesis, January 2000, Thieme Publishing Group

    Professor Asuncion Barbero

  36. Silylcupration of allenes followed by reaction with enones. A new strategy for the synthesis of methylenecyclopentanols

    Article • Tetrahedron Letters, September 1999, Elsevier

    Professor Asuncion Barbero

  37. Stannylcupration of Acetylenes Followed by Reaction with Epoxides:  A Novel Annulation Strategy for the Synthesis of Cyclobutenes

    Article • The Journal of Organic Chemistry, October 1998, American Chemical Society (ACS)

    Professor Asuncion Barbero

  38. Stereochemical Control in Organic Synthesis Using Silicon-Containing Compounds

    Article • Chemical Reviews, October 1997, American Chemical Society (ACS)

    Professor Asuncion Barbero

  39. Cycloaddition Reactions of (Z)-β-Siloxyacrylonitriles with Enones: Synthesis of 4H-Pyrans and Dihydro-2H-pyrans

    Article • Synthesis, June 1997, Thieme Publishing Group

    Professor Asuncion Barbero

  40. Open chain 1,3-stereocontrol

    Article • Pure and Applied Chemistry, January 1996, De Gruyter

    Professor Asuncion Barbero

  41. Ring-formation from allyl- and vinylstannanes initiated by treatment with butyl-lithium

    Article • Tetrahedron Letters, September 1992, Elsevier

    Professor Asuncion Barbero