All Stories

  1. Complexes of [(dadi)Ti(L/X)]m That Reveal Redox Non-Innocence and a Stepwise Carbene Insertion into a Carbon–Carbon Bond

    Article • Organometallics, July 2018, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  2. Activation of Carbon–Hydrogen Bonds via 1,2-RH-Addition/-Elimination to Early Transition Metal Imides

    Article • Organometallics, February 2018, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  3. Dispersion forces play a role in (Me2IPr)Fe(NAd)R2 (Ad = adamantyl; R = neoPe, 1-nor) insertions and Fe–R bond dissociation enthalpies (BDEs)

    Article • Dalton Transactions, January 2018, Royal Society of Chemistry

    Professor Peter T Wolczanski

  4. Rare Examples of Fe(IV) Alkyl-Imide Migratory Insertions: Impact of Fe—C Covalency in (Me2IPr)Fe(═NAd)R2 (R = neoPe, 1-nor)

    Article • Journal of the American Chemical Society, August 2017, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  5. Redox non-innocence permits catalytic nitrene carbonylation by (dadi)TiNAd (Ad = adamantyl)

    Article • Chemical Science, January 2017, Royal Society of Chemistry

    Professor Peter T Wolczanski

  6. A Career in Catalysis: John E. Bercaw

    Article • ACS Catalysis, March 2015, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  7. Fe(iv) alkylidenes via protonation of Fe(ii) vinyl chelates and a comparative Mössbauer spectroscopic study

    Article • Chemical Science, January 2015, Royal Society of Chemistry

    Professor Peter T Wolczanski

  8. Disparate reactivity from isomeric {Me2C(CH2NCHpy)2} and {Me2C(CHNCH2py)2} chelates in iron complexation

    Article • Polyhedron, December 2014, Elsevier

    Professor Peter T Wolczanski

  9. Iron and Chromium Complexes Containing Tridentate Chelates Based on Nacnac and Imino- and Methyl-Pyridine Components: Triggering C—X Bond Formation

    Article • Inorganic Chemistry, July 2014, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  10. Iron Complexes Derived from {nacnac-(CH 2 py) 2 } − and {nacnac-(CH 2 py)(CHpy)} n Ligands: Stabilization of Iron(II) via Redox Noninnocence

    Article • Inorganic Chemistry, May 2014, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  11. Lewis Bases Trigger Intramolecular CH-Bond Activation: (tBu3SiO)2W=NtBu [rlhar2] (tBu3SiO)(κO,κC-tBu2SiOCMe2CH2)HW=NtBu

    Article • European Journal of Inorganic Chemistry, May 2013, Wiley

    Professor Peter T Wolczanski

  12. C–C Bond Formation and Related Reactions at the CNC Backbone in (smif)FeX (smif = 1,3-Di-(2-pyridyl)-2-azaallyl): Dimerizations, 3 + 2 Cyclization, and Nucleophilic Attack; Transfer Hydrogenations and Alkyne Trimerization (X = N(TMS) 2 , dpma = (Di-(2...

    Article • Inorganic Chemistry, March 2013, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  13. Selective Extraction of N 2 from Air by Diarylimine Iron Complexes

    Article • Journal of the American Chemical Society, March 2013, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  14. Syntheses and characterizations of α-iminopyridine compounds (alkylNCHpy)2Fe(L/Xn), and an assessment of redox non-innocence

    Article • Polyhedron, March 2013, Elsevier

    Professor Peter T Wolczanski

  15. Exploring the limits of redox non-innocence: pseudo square planar [{κ4-Me2C(CH2NCHpy)2}Ni]n (n = 2+, 1+, 0, −1, −2) favor Ni(ii)

    Article • Chemical Science, January 2013, Royal Society of Chemistry

    Professor Peter T Wolczanski

  16. Synthetic Approaches to (smif) 2 Ti (smif = 1,3-di-(2-pyridyl)-2-azaallyl) Reveal Redox Non-Innocence and C–C Bond-Formation

    Article • Inorganic Chemistry, August 2012, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  17. Alkane Binding Implicated in Reactions of ( t Bu 3 SiN═) 3 WHK and Alkyl Halides

    Article • Organometallics, December 2011, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  18. Reactivity Studies of ( t Bu 3 SiNH)( t Bu 3 SiN═) 2 WH Including Anionic Derivatives Featuring the Tris-tri- tert -butylsilylimide Tungsten Core

    Article • Organometallics, December 2011, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  19. Synthesis and Characterization of (smif)2Mn (n = 0, M = V, Cr, Mn, Fe, Co, Ni, Ru; n = +1, M = Cr, Mn, Co, Rh, Ir; smif =1,3-di-(2-pyridyl)-2-azaallyl)

    Article • Inorganic Chemistry, November 2011, American Chemical Society (ACS)

    Dr Mitk'El Benedikt Santiago-Berríos, Professor Peter T Wolczanski

  20. Carbon–Carbon Bond Formation from Azaallyl and Imine Couplings about Metal–Metal Bonds

    Article • Journal of the American Chemical Society, November 2011, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  21. A Theoretical Study of the 3d-M(smif)2 Complexes: Structure, Magnetism, and Oxidation States

    Article • ChemPhysChem, September 2011, Wiley

    Professor Peter T Wolczanski

  22. Carbon dioxide reduction by early metal compounds: A propensity for oxygen atom transfer

    Article • Inorganica Chimica Acta, April 2011, Elsevier

    Professor Peter T Wolczanski

  23. Aryl−Oxazoline Chelates of First-Row Transition Metals: Structures of {κ- C , N -( o -C 6 H 4 )CMe 2 (COCH 2 CMe 2 N)}FeCl(py) and [(κ- C , N -( o -C 6 H 4 )CMe 2 (COCH 2 CMe 2 N)}Cr(μ-Cl)] 2 ‡

    Article • Organometallics, December 2010, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  24. Pnictogen-Hydride Activation by (silox) 3 Ta (silox = t Bu 3 SiO); Attempts to Circumvent the Constraints of Orbital Symmetry in N 2 Activation

    Article • Inorganic Chemistry, September 2010, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  25. ChemInform Abstract: Ketyl Complexes of (silox)3Ti (silox: tBu3SiO-).

    Article • ChemInform, August 2010, Wiley

    Professor Peter T Wolczanski

  26. ChemInform Abstract: Preparation of Lanthanoid Nitrides via Ammonolysis of Molten ((Me3Si) 2N)3Ln: Onset of Crystallization Catalyzed by LiNH2 and LiCl.

    Article • ChemInform, August 2010, Wiley

    Professor Peter T Wolczanski

  27. ChemInform Abstract: Methane vs Benzene Activation via Transient tBu3SiNHTa(=NSitBu3)2: Structure of (py)2MeTa(=NSitBu3)2.

    Article • ChemInform, August 2010, Wiley

    Professor Peter T Wolczanski

  28. ChemInform Abstract: Hydrocarbon Activation via Reversible 1,2-RH-Elimination from ( tBu3SiNH)3ZrR: Synthetic, Structural, and Mechanistic Investigations.

    Article • ChemInform, August 2010, Wiley

    Professor Peter T Wolczanski

  29. ChemInform Abstract: Polyamidoimidonitride Clusters of Zirconium. - A Molecular Orbital Study

    Article • ChemInform, August 2010, Wiley

    Professor Peter T Wolczanski

  30. Aryl-Containing Pyridine-Imine and Azaallyl Chelates of Iron toward Strong Field Coordination Compounds

    Article • Organometallics, January 2010, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  31. Aryl-Containing Chelates and Amine Debenzylation to Afford 1,3-Di-2-pyridyl-2-azaallyl (smif): Structures of {κ-C,N,N py 2 -(2-pyridylmethyl) 2 N(CH 2 (4- t Bu-phenyl-2-yl))}FeBr and (smif)CrN(TMS) 2

    Article • Inorganic Chemistry, December 2009, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  32. ChemInform Abstract: Structure and Reactivity Studies of Transition Metals Ligated by tBuSi3X (X: O, NH, N, S, and CC)

    Article • ChemInform, May 2009, Wiley

    Professor Peter T Wolczanski

  33. Unusual Electronic Features and Reactivity of the Dipyridylazaallyl Ligand: Characterizations of (smif) 2 M [M = Fe, Co, Co + , Ni; smif = {(2-py)CH} 2 N] and [(TMS) 2 NFe] 2 (smif) 2

    Article • Journal of the American Chemical Society, March 2009, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  34. [(silox)3M]2(μ:η1,η1-P2) (M = Nb, Ta) and [(silox)3Nb]2{μ:η2,η2-(cP3–cP3)} from (silox)3M (M = NbPMe3, Ta) and P4 (silox = tBu3SiO)

    Article • Chemical Communications, January 2009, Royal Society of Chemistry

    Professor Peter T Wolczanski

  35. Structure and reactivity studies of transition metals ligated by tBuSi3X (X = O, NH, N, S, and CC)

    Article • Chemical Communications, January 2009, Royal Society of Chemistry

    Professor Peter T Wolczanski

  36. Four-Coordinate Mo(II) as (silox) 2 Mo(PMe 3 ) 2 and Its W(IV) Congener (silox) 2 HW(η 2 -CH 2 PMe 2 )(PMe 3 ) (silox = t Bu 3 SiO)

    Article • Inorganic Chemistry, November 2008, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  37. Low Coordinate, Monomeric Molybdenum and Tungsten(III) Complexes: Structure, Reactivity and Calculational Studies of (silox) 3 Mo and (silox) 3 ML (M = Mo, W; L = PMe 3 , CO; silox = t Bu 3 SiO)

    Article • Journal of the American Chemical Society, October 2008, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  38. Molybdenum and Tungsten Structural Differences are Dependent on n d z 2 /( n + 1)s Mixing: Comparisons of (silox) 3 MX/R (M = Mo, W; silox = t Bu 3 SiO)

    Article • Inorganic Chemistry, August 2008, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  39. Olefin Substitution in (silox) 3 M(olefin) (silox = t Bu 3 SiO; M = Nb, Ta):  The Role of Density of States in Second vs Third Row Transition Metal Reactivity

    Article • Journal of the American Chemical Society, January 2008, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  40. Synthesis and Reactivity of [(silox) 2 MoNR] 2 Hg (R = t Bu, t Amyl; silox = OSi t Bu 3 ):  Unusual Thermal Stability and Ready Nucleophilic Cleavage Rationalized by Electronic Factors

    Article • Inorganic Chemistry, November 2007, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  41. Heterolytic CH-bond activation in the synthesis of Ni{(2-aryl-κC2)pyridine-κN}2 and derivatives

    Article • Journal of Organometallic Chemistry, October 2007, Elsevier

    Professor Peter T Wolczanski

  42. Evidence for Strong Tantalum-to-Boron Dative Interactions in (silox) 3 Ta(BH 3 ) and (silox) 3 Ta(η 2 -B,Cl-BCl 2 Ph) (silox = t Bu 3 SiO) 1

    Article • Inorganic Chemistry, February 2007, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  43. The Butterfly Dimer [( t Bu 3 SiO)Cr] 2 (μ-OSi t Bu 3 ) 2 and Its Oxidative Cleavage to ( t Bu 3 SiO) 2 Cr(N−NCPh 2 ) 2 and ( t Bu 3 SiO) 2 CrN(2,6-Ph 2 -C 6 H 3 )

    Article • Inorganic Chemistry, March 2006, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  44. PC Bond Cleavage of (silox) 3 NbPMe 3 (silox = t Bu 3 SiO) under Dihydrogen Leads to (silox) 3 NbCH 2 , (silox) 3 NbPH or (silox) 3 NbP(H)Nb(silox) 3 , and CH 4

    Article • Journal of the American Chemical Society, February 2006, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  45. Synthesis and reactivity of (silox)2R2WO (R=Cl, Me, Et, nPr and nBu; silox=OSitBu3) and (silox)2MO2 (M=Mo and W)

    Article • Polyhedron, January 2006, Elsevier

    Professor Peter T Wolczanski

  46. Aggregation of [( t Bu 3 SiS)MX]:  Structures of {[Br 2 Fe(μ-SSi t Bu 3 ) 2 FeBr(THF)]Na(THF) 4 } ∞ , cis -[(THF)FeI] 2 (μ-SSi t Bu 3 ) 2 , [( t Bu 3 SiS)Fe] 2 (μ-SSi t Bu 3 ) 2 , and Comparative Structure and Magnetism Studies of [( t...

    Article • Inorganic Chemistry, January 2006, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  47. Covalent Attachment of a Transition Metal Coordination Complex to Functionalized Oligo(phenylene-ethynylene) Self-Assembled Monolayers

    Article • Journal of the American Chemical Society, October 2005, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  48. 3-Center-4-Electron Bonding in [(silox) 2 MoN t Bu] 2 (μ-Hg) Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum π-Bond Energy Estimate

    Article • Journal of the American Chemical Society, June 2005, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  49. Transition Metal Complexes of Cyclic and Open Ozone and Thiozone.

    Article • ChemInform, May 2005, Wiley

    Professor Peter T Wolczanski

  50. Thermodynamics, Kinetics, and Mechanism of (silox) 3 M(olefin) to (silox) 3 M(alkylidene) Rearrangements (silox = t Bu 3 SiO; M = Nb, Ta)

    Article • Journal of the American Chemical Society, April 2005, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  51. Low-Coordinate Chromium Siloxides:  The “Box” [Cr(μ-Cl)(μ-OSi t Bu 3 )] 4 , Distorted Trigonal [( t Bu 3 SiO) 3 Cr][Na(benzene)] and [( t Bu 3 SiO) 3 Cr][Na(dibenzo-18-c-6)], and Trigonal ( t Bu 3 SiO) 3 Cr

    Article • Inorganic Chemistry, April 2005, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  52. Transition Metal Complexes of Cyclic and Open Ozone and Thiozone

    Article • Journal of the American Chemical Society, February 2005, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  53. Syntheses and electrochemistry of (p-XC6H4O)6W (1-X, X=H, CH3, OCH3, Cl, Br, OH, OCH2Ph) and (p-XC6H4O)5W(OC6H4OH) (X=H, CH3, OCH3, Cl, Br): an approach to electrocatalytic CH bond activation

    Article • Polyhedron, November 2004, Elsevier

    Professor Peter T Wolczanski

  54. The Course of (R 2 R‘SiO) 3 TaCl 2 (R = t Bu, R‘ = H, Me, Ph, t Bu (silox); R = i Pr, R‘ = t Bu, i Pr) Reduction Is Dependent on Siloxide Size

    Article • Inorganic Chemistry, May 2004, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  55. First row wheels, {(tBu3SiS)MX}12(M = Co, X = Cl; M = Ni, X = Br), are common amongst both simpler and more complex aggregates

    Article • Chemical Communications, January 2004, Royal Society of Chemistry

    Professor Peter T Wolczanski

  56. Symmetry and Geometry Considerations of Atom Transfer:  Deoxygenation of (silox) 3 WNO and R 3 PO (R = Me, Ph, t Bu) by (silox) 3 M (M = V, NbL (L = PMe 3 , 4-Picoline), Ta; silox = t Bu 3 SiO)

    Article • Inorganic Chemistry, October 2003, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  57. Ferrous Wheels, Ellipse [(tBu3SiS)FeX]n, and Cube [(tBu3SiS)Fe(CCSitBu3)]4

    Article • Angewandte Chemie International Edition, June 2003, Wiley

    Professor Peter T Wolczanski

  58. Amide derivatives of tantalum and a niobium-promoted ring opening of 3,5-lutidine

    Article • Inorganica Chimica Acta, March 2003, Elsevier

    Professor Peter T Wolczanski

  59. Ethylene and Alkyne Carbon−Carbon Bond Cleavage across Tungsten−Tungsten Multiple Bonds

    Article • Organometallics, June 2002, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  60. Carbon−Hydrogen Bond Activation by Titanium Imido Complexes. Computational Evidence for the Role of Alkane Adducts in Selective C−H Activation

    Article • Journal of the American Chemical Society, February 2002, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  61. (silox)3RePMe3 (silox = tBu3SiO) is carbonylated to the double insertion product (silox)(Me3P){cis-(CO)2}Re{ trans-(CO2SitBu3)2 }

    Article • Chemical Communications, December 2001, Royal Society of Chemistry

    Professor Peter T Wolczanski

  62. Dehydrogenation of [{(silox)3Nb}2(η-1,2;η-5,6-C8H8)] (silox=tBu3SiO) to [{(silox)3Nb}2(η-1,2;η-5,6-C8H6)] and Its Subsequent Alkene-to-Alkylidene Rearrangement

    Article • Angewandte Chemie, October 2001, Wiley

    Professor Peter T Wolczanski

  63. Synthesis of ( t Bu 3 SiNH) 2 ClW⋮WCl(NHSi t Bu 3 ) 2 and Its Degradation via NH Bond Activation

    Article • Journal of the American Chemical Society, October 2001, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  64. Dehydrogenation of [{(silox)3Nb}2(η-1,2;η-5,6-C8H8)] (silox=tBu3SiO) to [{(silox)3Nb}2(η-1,2;η-5,6-C8H6)] and Its Subsequent Alkene-to-Alkylidene Rearrangement We thank the US National Science Foundation for support of this research.

    Article • Angewandte Chemie International Edition, October 2001, Wiley

    Professor Peter T Wolczanski

  65. Deoxygenations of (silox) 3 WNO and R 3 PO by (silox) 3 M (M = V, Ta) and (silox) 3 NbL (silox = t Bu 3 SiO):  Consequences of Electronic Effects

    Article • Journal of the American Chemical Society, July 2001, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  66. Insertion of H 2 CCHX (X = F, Cl, Br, O i Pr) into ( t Bu 3 SiO) 3 TaH 2 and β-X-Elimination from ( t Bu 3 SiO) 3 HTaCH 2 CH 2 X (X = OR):  Relevance to Ziegler−Natta Copolymerizations

    Article • Journal of the American Chemical Society, May 2001, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  67. Covalent Titanium Aryldioxy One-, Two-, and Three-Dimensional Networks and Their Examination as Ziegler−Natta Catalysts

    Article • Inorganic Chemistry, April 2001, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  68. Hydrogen bonds between polyphenol (p-HOC6H4O)6W and bipyridines: (4,4′-bipy·HOC6H4O)6W and 3-D networks [{4,4′-(NC5H4)2(CH2CH2)}n{(HOC6H4O)6W}]∞ (n = 2, 3)

    Article • Chemical Communications, January 2001, Royal Society of Chemistry

    Professor Peter T Wolczanski

  69. A Covalent Vanadium(III) 2-Dimensional Network and Vanadyl Chains Linked by Aryldioxides

    Article • Inorganic Chemistry, January 2001, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  70. Covalent Metal−Organic Networks:  Pyridines Induce 2-Dimensional Oligomerization of (μ-OC 6 H 4 O) 2 Mpy 2 (M = Ti, V, Zr)

    Article • Inorganic Chemistry, October 2000, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  71. Inter- and Intramolecular Experimental and Calculated Equilibrium Isotope Effects for (silox) 2 ( t Bu 3 SiND)TiR + RH (silox = t Bu 3 SiO):  Inferred Kinetic Isotope Effects for RH/D Addition to Transient (silox) 2 TiNSi t Bu 3

    Article • Journal of the American Chemical Society, August 2000, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  72. Covalent Titanium(IV)–Aryloxide Network Materials: 4,4′-Biphenoxide 3D and Polyphenolic 2D Motifs

    Article • Journal of Solid State Chemistry, June 2000, Elsevier

    Professor Peter T Wolczanski

  73. (Silox)3Nb(η2-N,C-4-picoline) as a source of (silox)3Nb: structure of [(silox)3Nb]2(μ-η2,η2-C6H6) (silox=tBu3SiO)

    Article • Journal of Organometallic Chemistry, December 1999, Elsevier

    Professor Peter T Wolczanski

  74. Covalent Three-Dimensional Titanium(IV)−Aryloxide Networks

    Article • Inorganic Chemistry, July 1999, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  75. Structural Dichotomy in Six-Coordinate d 0 Complexes:  Trigonal Prismatic ( t Bu 3 SiC⋮C) 6 Ta - and Octahedral ( t Bu 3 SiC⋮C) 6 M 2- (M = Zr, Hf)

    Article • Journal of the American Chemical Society, October 1998, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  76. d 0 Alkane Complexes ( t Bu 3 SiN) 3 W(RH) Precede CH Activation and Formation of ( t Bu 3 SiN) 2 ( t BuSiNH)WR/R‘

    Article • Journal of the American Chemical Society, May 1998, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  77. Extracting absolute titanium-alkyl and-hydride bond enthalpies from relative D(TiR(H)) in (silox)2(tBu3SiNH)TiR: electronegativity and ECT models

    Article • Inorganica Chimica Acta, April 1998, Elsevier

    Professor Peter T Wolczanski

  78. [(silox)2ReO]2 (silox = tBu3SiO) contains a ReRe bond and terminal oxo ligands

    Article • Chemical Communications, January 1998, Royal Society of Chemistry

    Professor Peter T Wolczanski

  79. Selectivities in Hydrocarbon Activation:  Kinetic and Thermodynamic Investigations of Reversible 1,2-RH-Elimination from (silox) 2 ( t Bu 3 SiNH)TiR (silox = t Bu 3 SiO)

    Article • Journal of the American Chemical Society, November 1997, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  80. Carbon-oxygen and related RX bond cleavages mediated by (silox)3Ti and other Group 4 derivatives (silox = tBu3SiO)

    Article • Inorganica Chimica Acta, October 1997, Elsevier

    Professor Peter T Wolczanski

  81. Covalent 3- and 2-Dimensional Titanium−Quinone Networks

    Article • Journal of the American Chemical Society, September 1997, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  82. Ti(μ:η1,η1-OCMe2CH2PPh2)3Rh has a cylindrically symmetric triple bond

    Article • Chemical Communications, January 1997, Royal Society of Chemistry

    Professor Peter T Wolczanski

  83. Pyridine CN Bond Cleavage Mediated by (silox) 3 Nb (silox = t Bu 3 SiO)

    Article • Journal of the American Chemical Society, January 1997, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  84. Polyamidoimidonitride Clusters of Zirconium - a molecular orbital study

    Article • Zeitschrift für anorganische und allgemeine Chemie, March 1996, Wiley

    Professor Peter T Wolczanski

  85. Ditungsten Siloxide Hydrides, [(silox) 2 WH n ] 2 ( n = 1, 2; silox = t BuSiO), and Related Complexes

    Article • Inorganic Chemistry, January 1996, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  86. Hydrocarbon Activation via Reversible 1,2-RH-Elimination from ( t Bu 3 SiNH) 3 ZrR:  Synthetic, Structural, and Mechanistic Investigations

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  87. Conversion of [( t BuCH 2 ) 2 TaN] 5 to Cubic TaN:  Related Syntheses, EHMO Calculations, and MAS and Spin Echo 15 N NMR Spectroscopies

    Article • Chemistry of Materials, January 1996, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  88. Arylamine C−N Bond Oxidative Addition to (silox) 3 Ta (silox = t Bu 3 SiO)

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  89. Chemistry of electrophilic metal centres coordinated by silox (tBu3SiO), tritox (tBu3CO) and related binfunctional ligands

    Article • Polyhedron, October 1995, Elsevier

    Professor Peter T Wolczanski

  90. Carbon-carbon bond activation via formal β-methyl-elimination from [η5-6,6-dimethylcyclohexadienyl)Ru(DPPE)(CH2Cl2)]PF6

    Article • Polyhedron, January 1995, Elsevier

    Professor Peter T Wolczanski

  91. Arsinidene, Phosphinidene, and Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E = N, P, As): Structures of (silox)3Ta:EPh (E = P, As)

    Article • Journal of the American Chemical Society, November 1994, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  92. Does Methane Bind to d0 (tBu3SiNH)2Zr:NSitBu3 Prior to C-H Bond Activation? An Inter vs Intramolecular Isotope Effect Study

    Article • Journal of the American Chemical Society, May 1994, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  93. Energetics of C-H Bond Activation and Ethylene Binding to d0 Transient (silox)2Ti:NSitBu3

    Article • Journal of the American Chemical Society, March 1994, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  94. Carbide formation via carbon monoxide dissociation across a tungsten-tungsten triple bond

    Article • Journal of the American Chemical Society, November 1993, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  95. Syntheses, carbonylations, and dihydrogen exchange studies of monomeric and dimeric silox (tert-Bu3SiO-) hydrides of tantalum: structure of [(silox)2TaH2]2

    Article • Journal of the American Chemical Society, June 1993, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  96. Methane vs benzene activation via transient tantalum amido-imido complex tert-Bu3SiNHTa(:NSiBu3-tert)2: structure of (py)2MeTa(:NSiBu3-tert)2

    Article • Inorganic Chemistry, January 1993, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  97. Polyamidoimidonitride clusters of zirconium

    Article • Journal of the American Chemical Society, May 1992, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  98. Preparation of lanthanide nitrides via ammonolysis of molten {(Me3Si)2N}3Ln: onset of crystallization catalyzed by lithium amide and lithium chloride

    Article • Inorganic Chemistry, April 1992, American Chemical Society (ACS)

    Robert LaDuca, Professor Peter T Wolczanski

  99. Ketyl titanium complexes of (silox)3Ti (silox = tert-Bu3SiO-)

    Article • Inorganic Chemistry, January 1992, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  100. Ein Komplex mit dreifach koordiniertem Wolframatom: [(silox)2 W = NtBu] (silox =tBu3SiO)

    Article • Angewandte Chemie, May 1991, Wiley

    Professor Peter T Wolczanski

  101. A Complex with Three-Coordinate Tungsten Atom:[(silox)2WNtBu](silox=tBu3SiO)

    Article • Angewandte Chemie International Edition in English, May 1991, Wiley

    Professor Peter T Wolczanski

  102. Pyridine and related adducts, (silox)3ML (M = scandium, titanium, vanadium, tantalum): .eta.1-pyridine-N vs .eta.2-pyridine-N,C ligation

    Article • Inorganic Chemistry, May 1991, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  103. Tri-tert-butylsilyl)imido complexes of titanium: benzene carbon-hydrogen activation and structure of [(tert-Bu3SiNH)Ti]2(.mu.-NSi-tert-Bu3)2

    Article • Journal of the American Chemical Society, April 1991, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  104. Carbonylation of zirconium complex [tert-Bu3SiNH]3ZrH and x-ray structural study of [tert-Bu3SiNH]3ZrCH3

    Article • Organometallics, January 1991, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  105. The ladder structure of [(tert-BuCH2)2TaN]5.cntdot.NH3.cntdot.2C7H8 and its relationship to cubic tantalum nitride

    Article • Journal of the American Chemical Society, October 1990, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  106. Construction of heterobimetallics bridged by (oxyalkyl)phosphines: syntheses of trans-Me2Ta(.mu.-CH2)(.mu.-OCMe2CH2Ph2P)2PtMe and [cyclic] (TMEDA)Ta(.mu.-CH2)(.mu.-Me)(.mu.-OCMe2CH2Ph2P)2Ni

    Article • Organometallics, September 1990, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  107. Synthesis and properties of (.eta.5-6,6-Dimethylcyclohexadienyl)molybdenum ((dmCh)MoLn) complexes. X-ray structure of [(dmCh)(CO)2Mo]2

    Article • Organometallics, April 1990, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  108. Ammonolysis of tantalum alkyls: formation of cubic tantalum nitride and a trimeric nitride, [Cp*MeTaN]3 tris[(.eta.5-pentamethylcyclopentadienyl)(methyl)nitridotantalum]

    Article • Inorganic Chemistry, April 1990, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  109. Reversible dimerization of a titanium ketyl: (silox)3TiOCPh2.bul. (silox = tert-Bu3SiO-)

    Article • Inorganic Chemistry, December 1989, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  110. Carbon monoxide cleavage by (silox)3Ta (silox = tert-Bu3SiO-): physical, theoretical, and mechanistic investigations

    Article • Journal of the American Chemical Society, December 1989, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  111. Improved synthesis, redox chemistry, and magnetism of the mixed-valence isopolyanion of vanadate V10O264-

    Article • Inorganic Chemistry, August 1989, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  112. Methane and benzene activation via transient (tert-Bu3SiNH)2Zr:NSi-tert-Bu3

    Article • Journal of the American Chemical Society, December 1988, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  113. Synthesis and reactivity of heterobimetallic "A-frames" and rhodium-zirconium bonded complexes: structure of Cp*Zr(.mu.-OCH2Ph2P)2RhMe2

    Article • Organometallics, September 1988, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  114. Mechanistic investigation of the ZrMe/PtMe exchange in Cp*ZrMe(.mu.-OCH2PPh2)2PtMe2

    Article • Journal of the American Chemical Society, June 1988, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  115. .eta.2-(N,C)-pyridine and .mu.-.eta.2(1,2):.eta.2(4,5)-benzene complexes of (silox)3Ta (silox = t-Bu3SiO-)

    Article • Journal of the American Chemical Society, June 1988, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  116. Carbon monoxide hydrogenation, deoxygenation, and carbon-carbon coupling promoted by [(silox)2TaH2]2

    Article • Journal of the American Chemical Society, November 1987, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  117. New sandwich complexes containing 6,6-dimethylcyclohexadienyl (dmCh): (dmCh)2M (M = Ti, V, Cr, Fe) and (dmCh)2M-CO (M = Ti, V)

    Article • Organometallics, September 1987, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  118. Dioxygen activation by Group 4 tritox alkyls [tritox = (tert-Bu)3CO-]: insertion and oxygen atom transfer

    Article • Journal of the American Chemical Society, January 1987, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  119. Oxygenate formation from electrophilic attack of a rhodium/zirconium A-frame containing a .mu.2:.eta.2-acetyl bridge

    Article • Journal of the American Chemical Society, December 1986, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  120. Carbon monoxide cleavage by (silox)3Ta (silox = tert-Bu3SiO-)

    Article • Journal of the American Chemical Society, October 1986, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  121. Silox hydrides [silox = (Me3C)3SiO-] of Group 5: Do [(Me3C)3SiO]2MH2]2 (M = Nb, Ta) contain unbridged M-M bonds?

    Article • Journal of the American Chemical Society, June 1986, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  122. Reactions of alkyl and hydride derivatives of permethylscandocene and zirconocene with nitriles and amines. Catalytic hydrogenation of tert-butyl cyanide with permethylscandocene hydride

    Article • Organometallics, March 1986, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  123. Tantalum organometallics containing bulky oxy donors: utilization of tri-tert-butylsiloxide and 9-oxytriptycene

    Article • Organometallics, October 1985, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  124. Early/late metal binuclear complexes bridged by .mu.-OCH2Ph2P: structure of (.eta.5-C5Me5)Zr(.mu.-OCH2Ph2P)3NiCO.cntdot.C7H8

    Article • Organometallics, September 1985, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  125. Reactivity of dioxygen with group 4A alkoxy alkyls: epoxidation via metal alkyl mediated oxygen atom transfer

    Article • Journal of the American Chemical Society, February 1985, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  126. Preparation of Group 4B complexes containing tri-tert-butylmethoxide (tritox), a steric cyclopentadienyl equivalent

    Article • Organometallics, July 1984, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  127. X-ray crystal structure determination of [.eta.5-C5(CH3)5]Ta[P(CH3)3]2H4 and high-field NMR studies of phosphine derivatives of (pentamethylcyclopentadienyl)tantalum(V) hydrides

    Article • Inorganic Chemistry, April 1983, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  128. Alkyl and hydride derivatives of (pentamethylcyclopentadienyl)zirconium(IV)

    Article • Organometallics, June 1982, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  129. Mechanisms of carbon monoxide reduction with zirconium hydrides

    Article • Accounts of Chemical Research, April 1980, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  130. Dihydrogen reduction of isocyanides promoted by permethylzirconocene dihydride. A modeling study of carbon monoxide reduction

    Article • Journal of the American Chemical Society, October 1979, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  131. Reduction of coordinated carbon monoxide to "zirconoxy" carbenes with permethylzirconocene dihydride

    Article • Journal of the American Chemical Society, January 1979, American Chemical Society (ACS)

    Professor Peter T Wolczanski

  132. Photoelectrolysis of water by irradiation of platinized n-type semiconducting metal oxides

    Article • Journal of Solid State Chemistry, September 1977, Elsevier

    Professor Peter T Wolczanski

  133. Strontium titanate photoelectrodes. Efficient photoassisted electrolysis of water at zero applied potential

    Article • Journal of the American Chemical Society, May 1976, American Chemical Society (ACS)

    Professor Peter T Wolczanski