All Stories

  1. Oxidation triggers extensive conjugation and unusual stabilization of two di-heme dication diradical intermediates: role of bridging group for electronic communication

    Article • Chemical Science, January 2016, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  2. Spin-State Ordering in Hydroxo-Bridged Diiron(III)bisporphyrin Complexes

    Article • Inorganic Chemistry, February 2015, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  3. Hydrogen-Bonding Interactions Trigger a Spin-Flip in Iron(III) Porphyrin Complexes

    Article • Angewandte Chemie International Edition, February 2015, Wiley

    Professor Sankar Prasad Rath

  4. Iron(III) and copper(II) complexes of trans-bis(ferrocenyl)porphyrin: Effect of metal ions on long-range electronic communication

    Article • Journal of Chemical Sciences, February 2015, Springer Science + Business Media

    Professor Sankar Prasad Rath

  5. Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn(ii) bisporphyrin

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  6. Aggregation-controlled excimer emission in an axial anthracene–Sn(iv)porphyrin–anthracene triad in the solid and solution phases

    Article • New Journal of Chemistry, January 2015, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  7. An ethane-bridged porphyrin dimer as a model of di-heme proteins: inorganic and bioinorganic perspectives and consequences of heme–heme interactions

    Article • Dalton Transactions, January 2015, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  8. Metal-coordination-driven mixed ligand binding in supramolecular bisporphyrin tweezers

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  9. Controlled generation of highly saddled (porphyrinato)iron(iii) iodide, tri-iodide and one-electron oxidized complexes

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  10. Axial Thiophenolate Coordination on Diiron(III)bisporphyrin: Influence of Heme–Heme Interactions on Structure, Function and Electrochemical Properties of the Individual Heme Center

    Article • Inorganic Chemistry, November 2014, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  11. Building-up novel coordination polymer with Zn(II) porphyrin dimer: Synthesis, structures, surface morphology and effect of axial ligands

    Article • Journal of Chemical Sciences, September 2014, Springer Science + Business Media

    Professor Sankar Prasad Rath

  12. Highly Enhanced Bisignate Circular Dichroism of Ferrocene-Bridged Zn(II) Bisporphyrin Tweezer with Extended Chiral Substrates due to Well-Matched Host–Guest System

    Article • Inorganic Chemistry, March 2014, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  13. Synthesis, Structure, and Properties of a Series of Chiral Tweezer–Diamine Complexes Consisting of an Achiral Zinc(II) Bisporphyrin Host and Chiral Diamine Guest: Induction and Rationalization of Supramolecular Chirality

    Article • Inorganic Chemistry, January 2014, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  14. Syn–anti conformational switching in an ethane-bridged Co(ii)bisporphyrin induced by external stimuli: effects of inter-macrocyclic interactions, axial ligation and chemical and electrochemical oxidations

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  15. Self-assembly of cobalt(ii) and zinc(ii) tetranitrooctaethylporphyrin via bidentate axial ligands: synthesis, structure, surface morphology and effect of axial coordination

    Article • New Journal of Chemistry, January 2014, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  16. Transfer and control of molecular chirality in the 1 : 2 host–guest supramolecular complex consisting of Mg(ii)bisporphyrin and chiral diols: the effect of H-bonding on the rationalization of chirality

    Article • Chemical Communications, January 2014, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  17. Effect of Heme-Heme Interactions and Modulation of Metal Spins by Counter Anions in a Series of Diiron(III)-μ-hydroxo Bisporphyrins: Unusual Stabilization of Two Different Spins in a Single Molecular Framework

    Article • Chemistry - A European Journal, November 2013, Wiley

    Professor Sankar Prasad Rath

  18. Unusual Stabilization of an Intermediate Spin State of Iron upon the Axial Phenoxide Coordination of a Diiron(III)-Bisporphyrin: Effect of Heme-Heme Interactions

    Article • Chemistry - A European Journal, September 2013, Wiley

    Professor Sankar Prasad Rath

  19. Formation of exo–exo, exo–endo and tweezer conformation induced by axial ligand in a Zn(II) bisporphyrin: Synthesis, structure and properties

    Article • Polyhedron, March 2013, Elsevier

    Professor Sankar Prasad Rath

  20. Supramolecular BODIPY-Zn(ii)-bisporphyrin dyad and trinitrofluorenone encapsulated triad as models of antenna-reaction center: synthesis, structure and photophysical properties

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  21. Switching Orientation of Two Axial Imidazole Ligands between Parallel and Perpendicular in Low-Spin Fe(III) and Fe(II) Nonplanar Porphyrinates

    Article • Inorganic Chemistry, November 2012, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  22. Building-up Remarkably Stable Magnesium Porphyrin Polymers Self-Assembled via Bidentate Axial Ligands: Synthesis, Structure, Surface Morphology, and Effect of Bridging Ligands

    Article • Inorganic Chemistry, September 2012, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  23. Protonation of an Oxo-Bridged Diiron Unit Gives Two Different Iron Centers: Synthesis and Structure of a New Class of Diiron(III)-μ-hydroxo Bisporphyrins and the Control of Spin States by Using Counterions

    Article • Chemistry - A European Journal, September 2012, Wiley

    Professor Sankar Prasad Rath

  24. Encapsulation of TCNQ and the Acridinium Ion within a Bisporphyrin Cavity: Synthesis, Structure, and Photophysical and HOMO-LUMO-Gap-Mediated Electron-Transfer Properties

    Article • Chemistry - A European Journal, May 2012, Wiley

    Professor Sankar Prasad Rath

  25. Induction of supramolecular chirality in di-zinc(ii) bisporphyrin via tweezer formation: synthesis, structure and rationalization of chirality

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  26. Axial phenoxide coordination on di-iron(III) bisporphyrin: Insights from experimental and DFT studies

    Article • Journal of Chemical Sciences, November 2011, Springer Science + Business Media

    Professor Sankar Prasad Rath

  27. Efficient Complexation of Pyrrole-Bridged Dizinc(II) Bisporphyrin with Fluorescent Probe Pyrene: Synthesis, Structure, and Photoinduced Singlet-Singlet Energy Transfer

    Article • Chemistry - A European Journal, August 2011, Wiley

    Professor Sankar Prasad Rath

  28. Syn–anti conformational switching: Synthesis and X-ray structures of tweezer and anti form in a zinc porphyrin dimer induced by axial ligands

    Article • Inorganica Chimica Acta, June 2011, Elsevier

    Professor Sankar Prasad Rath

  29. Control of spins by ring deformation in a diiron(iii)bisporphyrin: reversal of ClO4− and CF3SO3− ligand field strength in the magnetochemical series

    Article • Chemical Communications, January 2011, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  30. A Remarkably Bent Diiron(III)-μ-Hydroxo Bisporphyrin: Unusual Stabilization of Two Spin States of Iron in a Single Molecular Framework

    Article • Journal of the American Chemical Society, December 2010, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  31. Binding of Catechols to Iron(III)-Octaethylporphyrin: An Experimental and DFT Investigation

    Article • European Journal of Inorganic Chemistry, October 2010, Wiley

    Professor Sankar Prasad Rath

  32. Synthesis, structure and photocatalytic activity of a remarkably bent, cofacial ethene-linked diiron (III) μ-oxobisporphyrin

    Article • Inorganica Chimica Acta, October 2010, Elsevier

    Professor Sankar Prasad Rath

  33. Synthesis and Characterization ofanti-bisFe(III) Porphyrins,syn-bisFe(III)-μ-oxo Porphyrin, andsyn-bisFe(III)-μ-oxo Porphyrin Cation Radical

    Article • Inorganic Chemistry, April 2010, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  34. Axial Ligand Orientations in a Distorted Porphyrin Macrocycle: Synthesis, Structure, and Properties of Low-Spin Bis(imidazole)iron(III) and Iron(II) Porphyrinates†† Dedicated to Prof. Animesh Chakravorty on the occasion of his 75th birthday.

    Article • Inorganic Chemistry, March 2010, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  35. Effects of axial pyridine coordination on a saddle-distorted porphyrin macrocycle: stabilization of hexa-coordinated high-spin Fe(iii) and air-stable low-spin iron(ii) porphyrinates

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Professor Sankar Prasad Rath

  36. Cyanide binding to iron in a highly distorted porphyrin macrocycle: Synthesis and structure of low-spin Fe(II) dicyano porphyrin

    Article • Inorganic Chemistry Communications, June 2009, Elsevier

    Professor Sankar Prasad Rath

  37. The Effect of Steric Crowding on Porphyrin Conformation and Ring Orientations in a Series of Iron(III) μ-Oxo Dimers Containingmeso-Nitrooctaethylporphyrins

    Article • European Journal of Inorganic Chemistry, February 2009, Wiley

    Professor Sankar Prasad Rath

  38. Remarkably Bent, Ethane-Linked, Diiron(III) μ-Oxobisporphyrin: Synthesis, Structure, Conformational Switching, and Photocatalytic Oxidation

    Article • Inorganic Chemistry, November 2008, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  39. Axial Ligand Coordination in Sterically Strained Vanadyl Porphyrins: Synthesis, Structure, and Properties

    Article • Inorganic Chemistry, November 2008, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  40. Modulation of Metal Displacements in a Saddle Distorted Macrocycle: Synthesis, Structure, and Properties of High-Spin Fe(III) Porphyrins and Implications for the Hemoproteins

    Article • Inorganic Chemistry, September 2008, American Chemical Society (ACS)

    Professor Sankar Prasad Rath

  41. ChemInform Abstract: Dioxygen Reactivity of meso-Hydroxylated Hemes: Intermediates in Heme Degradation Process Catalyzed by Heme Oxygenase

    Article • ChemInform, January 2008, Wiley

    Professor Sankar Prasad Rath

  42. Dioxygen reactivity ofmeso-hydroxylated hemes: Intermediates in heme degradation process catalyzed by heme oxygenase

    Article • Journal of Chemical Sciences, November 2006, Springer Science + Business Media

    Professor Sankar Prasad Rath