All Stories

  1. Oxidative Imidation of Benzylic and Cycloalkane C(sp3)–H Bond Donors Using N-Aroyloxyquinuclidinium Salts and Nitriles under Photoredox Catalysis

    Article • Organic Letters, July 2023, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  2. Oxidative Trifluoroacetoxylation of 1°, 2°, and 3° Benzylic C(sp3)–H Bond Donors Using N-Trifluoroacetoxyquinuclidinium Salts under Photoredox Catalysis

    Article • Organic Letters, October 2022, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  3. Oxidative CH Bond Functionalization Mediated by Organopalladium(II) Complexes with Oxygen as Terminal Oxidant

    Article • October 2022, Wiley

    Dr Andrei N Vedernikov

  4. Oxidation of Methylplatinum(II) Complexes K[(L)PtIIMe] with O2 and C(sp3)-X (X = O and C) Reductive Elimination Reactivity of Methylplatinum(IV) Products (L)PtIVMe(OH): The Effect of Structure of Sulfo...

    Article • Organometallics, September 2022, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  5. Spectroscopic studies of methyl paraoxon decomposition over mesoporous Ce-doped titanias for toxic chemical filtration

    Article • Journal of Hazardous Materials, September 2022, Elsevier

    Dr Andrei N Vedernikov

  6. Synthesis and Bond Activation Chemistry of Palladium(II) Pincer Complexes with a Weakly Coordinating Side Arm

    Article • Organometallics, February 2022, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  7. Trivalent and Tetravalent Palladium and Platinum Organometallic Complexes

    Article • January 2022, Elsevier

    Dr Andrei N Vedernikov

  8. Reversible PtII–CH3 deuteration without methane loss: metal–ligand cooperation vs. ligand-assisted PtII-protonation

    Article • Chemical Science, January 2021, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  9. High-Valent Platinum Complexes

    Article • January 2021, Elsevier

    Dr Andrei N Vedernikov

  10. Aryl C(sp2)–X Coupling (X = C, N, O, Cl) and Facile Control of N-Mono- and N,N-Diarylation of Primary Alkylamines at a Pt(IV) Center

    Article • Journal of the American Chemical Society, November 2020, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  11. Catalytic Deuteration of C(sp2)–H Bonds of Substituted (Hetero)arenes in a Pt(II) CNN-Pincer Complex/2,2,2-Trifluoroethanol-d1 System: Effect of Substituents on the Reaction Rate and Selectivity

    Article • Organometallics, November 2020, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  12. CH3–X Reductive Elimination Reactivity of PtIVMe Complexes Supported by a Sulfonated CNN Pincer Ligand (X = OH, CF3CO2, PhNMe2+)

    Article • Organometallics, December 2019, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  13. An Electron-Poor Dioxa-[2.1.1]-(2,6)-pyridinophane Ligand and Its Application in Cu-Catalyzed Olefin Aziridination

    Article • Inorganic Chemistry, November 2019, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  14. Methyl transfer reactivity of pentachloromethylplatinate(IV) anion with a series of N-nucleophiles

    Article • Journal of Organometallic Chemistry, February 2019, Elsevier

    Dr Andrei N Vedernikov

  15. Organometallic C–H Oxidation with O2 Mediated by Soluble Group 10 Metal Complexes

    Article • January 2019, Springer Science + Business Media

    Dr Andrei N Vedernikov

  16. Consecutive C–H and O2 Activation at a Pt(II) Center To Produce Pt(IV) Aryls

    Article • Organometallics, November 2018, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  17. Novel Sulfonated CNN Pincer Ligands for Facile C−H Activation at a Pt(II) Center

    Article • Israel Journal of Chemistry, October 2017, Wiley

    Dr Andrei N Vedernikov

  18. Reductive C(sp2)–N Elimination from Isolated Pd(IV) Amido Aryl Complexes Prepared Using H2O2 as Oxidant

    Article • Journal of the American Chemical Society, January 2017, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  19. Oxidative Functionalization of Late Transition Metal–Carbon Bonds

    Article • January 2017, Elsevier

    Dr Andrei N Vedernikov

  20. C–H and O2 Activation at a Pt(II) Center Enabled by a Novel Sulfonated CNN Pincer Ligand

    Article • Organometallics, September 2016, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  21. Aerobic Epoxidation of Olefin by Platinum Catalysts Supported on Mesoporous Silica Nanoparticles

    Article • ACS Catalysis, July 2016, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  22. Oxidation of a Monomethylpalladium(II) Complex with O 2 in Water: Tuning Reaction Selectivity to Form Ethane, Methanol, or Methylhydroperoxide

    Article • Journal of the American Chemical Society, February 2016, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  23. Concurrent B-to-Pt Methyl Migration and B-Center Retention in Aerobic Oxidation of Methylborato Platinum(II) Complexes

    Article • Organometallics, October 2015, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  24. Aryl-F Bond Cleavage vs. C-E Reductive Elimination: Competitive Pathways of Metal-Ligand-Cooperation-Based E-H Bond Activation (E = N, S)

    Article • European Journal of Inorganic Chemistry, September 2015, Wiley

    Dr Andrei N Vedernikov

  25. Selective Aryl-Fluoride Reductive Elimination from a Platinum(IV) Complex

    Article • Angewandte Chemie, June 2015, Wiley

    Dr Andrei N Vedernikov

  26. Selective Aryl-Fluoride Reductive Elimination from a Platinum(IV) Complex

    Article • Angewandte Chemie International Edition, June 2015, Wiley

    Dr Andrei N Vedernikov

  27. ChemInform Abstract: Mechanism of the Kumada-Corriu Cross-Coupling Catalyzed by Low-Coordinate Bis(amido)-Nickel Complexes: Identification of Nickel(I)-(III) Catalytic Intermediates

    Article • ChemInform, November 2014, Wiley

    Dr Andrei N Vedernikov

  28. Mechanism of the Kumada-Corriu Cross-Coupling Catalyzed by Low-Coordinate Bis(amido)-Nickel Complexes: Identification of Nickel(I)-(III) Catalytic Intermediates

    Article • ChemCatChem, August 2014, Wiley

    Dr Andrei N Vedernikov

  29. ChemInform Abstract: PdII/PdIV Redox Couple Mediated C-X Bond Formation

    Article • ChemInform, May 2014, Wiley

    Dr Andrei N Vedernikov

  30. Mechanistic Study of the Oxidation of a Methyl Platinum(II) Complex with O 2 in Water: Pt II Me-to-Pt IV Me and Pt II Me-to-Pt IV Me 2 Reactivity

    Article • Journal of the American Chemical Society, March 2014, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  31. Mechanism of O 2 Activation and Methanol Production by (Di(2-pyridyl)methanesulfonate)Pt II Me(OH n ) (2– n )– Complex from Theory with Validation from Experiment

    Article • Journal of the American Chemical Society, February 2014, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  32. Oxidative C(sp3)–H bond cleavage, C–C and CC coupling at a boron center with O2 as the oxidant mediated by platinum(ii)

    Article • Chemical Communications, January 2014, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  33. Palladium(IV) Monohydrocarbyls: Mechanistic Study of the Ligand-Enabled Oxidation of Palladium(II) Complexes with H2O2in Water

    Article • Organometallics, October 2013, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  34. Aerobic C–H Acetoxylation of 8-Methylquinoline in PdII–Pyridinecarboxylic Acid Systems: Some Structure–Reactivity Relationships

    Article • Organometallics, September 2013, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  35. Unprecedented 1,3-migration of the aryl ligand in metallacyclic aryl α-naphthyl Pt(iv) difluorides to produce β-arylnaphthyl Pt(ii) complexes

    Article • Chemical Communications, January 2013, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  36. ChemInform Abstract: Surprising Acid/Base and Ion-Sequestration Chemistry of Sn94-: HSn93-, Ni@HSn93-, and the Sn93-Ion Revisited.

    Article • ChemInform, September 2012, Wiley

    Dr Andrei N Vedernikov

  37. Electrophilic Fluorination of Organoplatinum(II) Iodides: Iodine and Platinum Atoms as Competing Fluorination Sites

    Article • Journal of the American Chemical Society, August 2012, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  38. Direct Functionalization of M–C (M = PtII, PdII) Bonds Using Environmentally Benign Oxidants, O2and H2O2

    Article • Accounts of Chemical Research, June 2012, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  39. Surprising Acid/Base and Ion-Sequestration Chemistry of Sn 9 4– : HSn 9 3– , Ni@HSn 9 3– , and the Sn 9 3– Ion Revisited

    Article • Journal of the American Chemical Society, June 2012, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  40. Oxidation of dimethyldi(2-pyridyl)borato PtIIMen complexes, n = 1, 0, with H2O2: tandem B-to-Pt methyl group migration and formation of C–O bond

    Article • Dalton Transactions, January 2012, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  41. Selective and efficient oxidation of ethylene to ethylene glycol acetates with H2O2 catalyzed by Pd(OAc)2–di(2-pyridyl)ketone–di(2-pyridyl)methanesulfonate system

    Article • Journal of Organometallic Chemistry, December 2011, Elsevier

    Dr Andrei N Vedernikov

  42. Allylic C–H Deprotonation of Olefins with PtII(OH) to Form η3-Allyl PtIIComplexes in Water and Aprotic Organic Solvents

    Article • Organometallics, June 2011, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  43. Stoichiometric aerobic aminohydroxylation of ethylene mediated by dpms–platinum complexes (dmps=di(2-pyridyl)methanesulfonate)

    Article • Inorganica Chimica Acta, April 2011, Elsevier

    Dr Andrei N Vedernikov

  44. ChemInform Abstract: C-O Reductive Elimination from High Valent Pt and Pd Centers

    Article • ChemInform, December 2010, Wiley

    Dr Andrei N Vedernikov

  45. Preparation and C−X Reductive Elimination Reactivity of Monoaryl Pd IV −X Complexes in Water (X = OH, OH 2 , Cl, Br)

    Article • Journal of the American Chemical Society, October 2010, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  46. Aryl-bromide reductive elimination from an isolated Pt(iv) complex

    Article • Chemical Communications, January 2010, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  47. C–O Reductive Elimination from High Valent Pt and Pd Centers

    Article • January 2010, Springer Science + Business Media

    Dr Andrei N Vedernikov

  48. ChemInform Abstract: Ligand-Enabled PtII-C(sp3) Bond Functionalization with Dioxygen as a Direct Oxidant

    Article • ChemInform, November 2009, Wiley

    Dr Andrei N Vedernikov

  49. Ligand-enabled PtII–C(sp3) bond functionalization with dioxygen as a direct oxidant

    Article • Chemical Communications, January 2009, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  50. Homogeneous catalytic transfer dehydrogenation of alkanes with a group 10 metal center

    Article • Chemical Communications, January 2009, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  51. Study of aerobic oxidation of phenyl Pt II complexes (dpms)Pt II Ph(L) (dpms = di(2-pyridyl)methanesulfonate; L = water, methanol, or aniline)

    Article • Canadian Journal of Chemistry, January 2009, Canadian Science Publishing

    Dr Andrei N Vedernikov

  52. ChemInform Abstract: Catalytic Aerobic Oxidation of Substituted 8-Methylquinolines in PdII-2,6-Pyridinedicarboxylic Acid Systems.

    Article • ChemInform, December 2008, Wiley

    Dr Andrei N Vedernikov

  53. ChemInform Abstract: Recent Advances in the Platinum-Mediated C-H Bond Functionalization

    Article • ChemInform, October 2008, Wiley

    Dr Andrei N Vedernikov

  54. Bidirectional Transfer of Phenyl and Methyl Groups between PtIVand Boron in Platinum Dipyridylborato Complexes

    Article • Journal of the American Chemical Society, August 2008, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  55. Direct C(sp 3 )−O Reductive Elimination of Olefin Oxides from Pt IV -Oxetanes Prepared by Aerobic Oxidation of Pt II Olefin Derivatives (Olefin = cis -Cyclooctene, Norbornene)

    Article • Journal of the American Chemical Society, February 2008, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  56. Catalytic aerobic oxidation of substituted 8-methylquinolines in PdII-2,6-pyridinedicarboxylic acid systems

    Article • Chemical Communications, January 2008, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  57. Competitive Aryl−Iodide vs Aryl−Aryl Reductive Elimination Reactions in Pt(IV) Complexes:  Experimental and Theoretical Studies

    Article • Journal of the American Chemical Society, January 2008, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  58. Recent Advances in the Platinum-mediated CH Bond Functionalization

    Article • Current Organic Chemistry, November 2007, Bentham Science Publishers

    Dr Andrei N Vedernikov

  59. Oxidatively Induced Methyl Transfer from Boron to Platinum in Dimethyldi(2-pyridyl)boratoplatinum Complexes

    Article • Angewandte Chemie, August 2007, Wiley

    Dr Andrei N Vedernikov

  60. Oxidatively Induced Methyl Transfer from Boron to Platinum in Dimethyldi(2-pyridyl)boratoplatinum Complexes

    Article • Angewandte Chemie International Edition, July 2007, Wiley

    Dr Andrei N Vedernikov

  61. NO binds to unsaturated Os(IV) polyhydrides as a redox reagent

    Article • Journal of Organometallic Chemistry, July 2007, Elsevier

    Dr Andrei N Vedernikov

  62. C−O Coupling of LPtIVMe(OH)X Complexes in Water (X =18OH, OH, OMe; L = di(2-pyridyl)methane sulfonate)

    Article • Organometallics, July 2007, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  63. Facile Aerobic Oxidation of dpms−Platinum(II) Ethylene Complexes (dpms = di(2-pyridyl)methanesulfonate)

    Article • Organometallics, April 2007, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  64. Facile Arene C−H Bond Activation and Alkane Dehydrogenation with Anionic LPt II Me 2 - in Hydrocarbon−Water Systems (L = Dimethyldi(2-pyridyl)borate)

    Article • Journal of the American Chemical Society, October 2006, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  65. Stoichiometric Aerobic Pt II −Me Bond Cleavage in Aqueous Solutions to Produce Methanol and a Pt II (OH) Complex

    Article • Journal of the American Chemical Society, January 2006, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  66. A Practical, Fast, and High-Yielding Aziridination Procedure Using Simple Cu(II) Complexes Containing N-Donor Pyridine-Based Ligands

    Article • The Journal of Organic Chemistry, June 2005, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  67. Synthesis and Reactivity of Dimethyl Platinum(IV) Hydrides in Water

    Article • Journal of the American Chemical Society, September 2004, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  68. Competition Experiments as a Means of Evaluating Linear Free Energy Relationships. An Experiment for the Advanced Undergraduate Organic Chemistry Lab

    Article • Journal of Chemical Education, September 2004, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  69. Influence of the [2.1.1]-(2,6)-Pyridinophane Macrocycle Ring Size Constraint on the Structure and Reactivity of Copper Complexes

    Article • Inorganic Chemistry, July 2004, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  70. Hydrocarbyl Ligand “Tuning” of the PtII/IVRedox Potential

    Article • Inorganic Chemistry, June 2004, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  71. Facile Alkane Functionalization in Copper-[2.1.1]-(2,6)-pyridinophane-PhINTs Systems.

    Article • ChemInform, April 2004, Wiley

    Dr Andrei N Vedernikov

  72. Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systemsElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b309519c/

    Article • Chemical Communications, January 2004, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  73. Reactivity of the Hydrido/Nitrosyl Radical MHCl(NO)(CO)(P i Pr 3 ) 2 , M = Ru, Os

    Article • Inorganic Chemistry, January 2004, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  74. Angular Ligand Constraint Yields an Improved Olefin Aziridination Catalyst.

    Article • ChemInform, December 2003, Wiley

    Dr Andrei N Vedernikov

  75. Design and Synthesis of Tridentate Facially Chelating Ligands of the [2.n.1]-(2,6)-Pyridinophane Family.

    Article • ChemInform, September 2003, Wiley

    Dr Andrei N Vedernikov

  76. Angular Ligand Constraint Yields an Improved Olefin Aziridination Catalyst

    Article • Organic Letters, July 2003, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  77. Design and Synthesis of Tridentate Facially Chelating Ligands of the [2.n.1]-(2,6)-Pyridinophane Family

    Article • The Journal of Organic Chemistry, June 2003, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  78. [2.1.1]-(2,6)-Pyridinophane(L)-controlled alkane C–H bond cleavage: (L)PtMe2H+ as a precursor to the geometrically “tense” transient (L)PtMe+Electronic supplementary information (ESI) available: complete experimental and characterization data. See http...

    Article • New Journal of Chemistry, March 2003, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  79. Evaluation of energies of isomeric SO2 complexesElectronic supplementary information (ESI) available: DFT geometry optimized structures of isomeric RuCl(CO)(PMe3)2HSO2. See http://www.rsc.org/suppdata/nj/b2/b212025a/

    Article • New Journal of Chemistry, February 2003, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  80. N–PtIV–H/N–H⋯PtII intramolecular redox equilibrium in a product of H–C(sp2) cleavage and unusual alkane/arene C–H bond selectivity of ([2.1.1]pyridinophane)PtII(CH3)+Electronic supplementary information (ESI) available: experimental details. See http:/...

    Article • Chemical Communications, January 2003, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  81. Coordination Chemistry of Tripyridinedimethane

    Article • Inorganic Chemistry, December 2002, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  82. [n.1.1]-(2,6)-Pyridinophanes:  A New Ligand Type Imposing Unusual Metal Coordination Geometries

    Article • Inorganic Chemistry, December 2002, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  83. Control of HC(sp3) Bond Cleavage Stoichiometry: Clean Reversible Alkyl Ligand Exchange with Alkane in [LPt(Alk)(H)2] (L=[2.1.1]-(2,6)-Pyridinophane)

    Article • Angewandte Chemie International Edition, November 2002, Wiley

    Dr Andrei N Vedernikov

  84. An Electron-Excessive Nitrosyl Complex:  Reactivity of a Ligand-Centered Radical Leading to Coordinated HNO

    Article • Inorganic Chemistry, August 2002, American Chemical Society (ACS)

    Dr Andrei N Vedernikov

  85. Cu(I) and Cu(II) complexes of a pyridine-based pincer ligand

    Article • Inorganica Chimica Acta, March 2002, Elsevier

    Dr Andrei N Vedernikov

  86. Evolving approaches to integration of computational with experimental chemistry: an example from osmium hydrido (η1/η2-)nitrosyl/nitroxyl chemistry

    Article • New Journal of Chemistry, January 2002, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  87. Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane

    Article • Mendeleev Communications, January 2002, Elsevier

    Dr Andrei N Vedernikov

  88. Photoinduced activation of arene CH bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H

    Article • Mendeleev Communications, January 2000, Elsevier

    Dr Andrei N Vedernikov

  89. Mild alkane functionalisation leading to ethers: oxidative alkoxylation of cyclohexane with the dibromobis(phosphine)palladium(II)–sodium alkoxide system

    Article • Mendeleev Communications, January 1997, Elsevier

    Dr Andrei N Vedernikov

  90. Mild selective metathesis of alkane CH bonds and CX bonds of polyhalogenomethane CH4–nXn (X Cl, n 4; Br, I, n 3) catalysed with chlorotris(triphenylphosphine)rhodium(I)

    Article • Mendeleev Communications, January 1996, Elsevier

    Dr Andrei N Vedernikov

  91. Reversible thermal carbon–hydrogen bond cleavage in alkanes and arenes with dihalogenobis(triphenylphosphine)palladium(II) complexes

    Article • Journal of the Chemical Society Chemical Communications, January 1994, Royal Society of Chemistry

    Dr Andrei N Vedernikov

  92. Lanthanide Porphyrins as Styrene Oxidation Catalysts

    Article • Mendeleev Communications, January 1991, Elsevier

    Dr Andrei N Vedernikov

  93. CHAPTER 4. PdII/PdIV Redox Couple Mediated C–X Bond Formation

    Article • Royal Society of Chemistry

    Dr Andrei N Vedernikov