All Stories

  1. Pd-Catalyzed Directedortho-C–H Alkenylation of Phenylalanine Derivatives
  2. Pd-catalysed ortho-alkoxylation of benzamides N-protected with an iminophosphorane functionality
  3. Bis-cyclometalated complexes of Pd(II) and Pd(IV) from iminophosphoranes: Synthesis, structure and reactivity
  4. ChemInform Abstract: Coordination-Directed Metallation Strategy for C-H Functionalization
  5. Cyclopalladation and Reactivity of Amino Esters through CH Bond Activation: Experimental, Kinetic, and Density Functional Theory Mechanistic Studies
  6. ChemInform Abstract: High Catalytic Performance of Palladium Nanoparticles Supported on Multiwalled Carbon Nanotubes in Alkene Hydrogenation Reactions.
  7. ChemInform Abstract: Primary Amines as Directing Groups in the Ru-Catalyzed Synthesis of Isoquinolines, Benzoisoquinolines, and Thienopyridines.
  8. Primary Amines as Directing Groups in the Ru-Catalyzed Synthesis of Isoquinolines, Benzoisoquinolines, and Thienopyridines
  9. ChemInform Abstract: Cyclometallation of Heterocycles: A Reliable Strategy for Selective Functionalization
  10. Synthesis, Structure, and Reactivity of Pd Complexes with Mixed P,S-Bis(ylide), Ylide-Sulfide, and Ylide-Methanide Ligands
  11. Reduced graphene oxide: firm support for catalytically active palladium nanoparticles and game changer in selective hydrogenation reactions
  12. High catalytic performance of palladium nanoparticles supported on multiwalled carbon nanotubes in alkene hydrogenation reactions
  13. Cycloruthenated Complexes from Imine-Based Heterocycles: Synthesis, Characterization, and Reactivity toward Alkynes
  14. Synthesis of conformationally restricted glutamate and glutamine derivatives from carbonylation of orthopalladated phenylglycine derivatives
  15. ChemInform Abstract: Reactivity of Unsaturated 5(4H)‐Oxazolones with Hg(II) Acetate: Synthesis of Methyl N‐Benzoylamino‐3‐arylacrylates.
  16. Regioselective CH Bond Activation on Stabilized Nitrogen Ylides Promoted by Pd(II) Complexes: Scope and Limitations
  17. ChemInform Abstract: Orthometallation as a Strategy in Pd-Mediated Organic Synthesis
  18. 31P NMR spectroscopy and pattern-recognition techniques as tools for the identification and enantiodiscrimination of α-amino acids
  19. Cyclometallation of Heterocycles: A Reliable Strategy for Selective Functionalization
  20. Reactivity of Unsaturated 5(4H)-Oxazolones with Hg(II) Acetate: Synthesis of Methyl N-Benzoylamino-3-arylacrylates
  21. Novel Cyclopalladated Imino-thiophenes: Synthesis and Reactivity Toward Alkynes and Carbon Monoxide
  22. Regioselective Orthopalladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones: Scope, Kinetico-Mechanistic, and Density Functional Theory Studies of the C–H Bond Activation
  23. Editorial [ Hot Topic:New Trends in Palladium Chemistry: Synthesis, Structure, Reactivity and Applications (Guest Editor: Dr. Esteban P. Urriolabeitia)]
  24. Orthometallation as a Strategy in Pd-mediated Organic Synthesis
  25. Efficient access to (1H)-isoindolin-1-one-3-carboxylic acid derivatives by orthopalladation and carbonylation of methyl arylglycinate substrates
  26. Unsaturated 4,4′-bis-[5(4H)-oxazolones]: Synthesis and evaluation of their ortho-palladation through C–H bond activation
  27. Cycloruthenated Complexes from Iminophosphoranes: Synthesis, Structure, and Reactivity with Internal Alkynes
  28. One-step microwave synthesis of palladium–carbon nanotube hybrids with improved catalytic performance
  29. ChemInform Abstract: Selectivity on the Coordination Site and the Bonding Mode of Phosphorus Ylides Towards Palladium and Platinum Substrates
  30. Novel Thiophene-Based Cycloruthenated Compounds: Synthesis, Characterization, and Reactivity
  31. Al-promoted increase of surface area and adsorption capacity in ordered mesoporous silica materials with a cubic structure
  32. ChemInform Abstract: Ylide Ligands
  33. Synthesis, Structure, and Reactivity ofN-Benzoyl IminophosphoranesOrthoLithiated at the Benzoyl Group
  34. ChemInform Abstract: Synthesis and X-Ray Crystal Structure of (Pd(C6F5)(η2-((Ph2P)3C))( PPh3)), a Mononuclear Compound Containing η2-Tris( diphenylphosphine)methanide.
  35. Mechanistic Insights into the One‐Pot Synthesis of Propargylamines from Terminal Alkynes and Amines in Chlorinated Solvents Catalyzed by Gold Compounds and Nanoparticles
  36. ChemInform Abstract: Separation of Pd Complexes from a Homogeneous Solution Using Zeolite Membranes.
  37. ChemInform Abstract: Oxidative Addition and Transmetallation
  38. Ortho-Palladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones. Structure and Functionalization
  39. Regioselective functionalization of iminophosphoranes through Pd-mediated C–H bond activation: C–C and C–X bond formation
  40. Functionalization of Methyl (R)-Phenylglycinate Through Orthopalladation: C−Hal, C−O, C−N, and C−C Bond Coupling
  41. Ylide Ligands
  42. Experimental and Computational Study of the Bonding Properties of Mixed Bis−Ylides of Phosphorus and Sulfur
  43. ChemInform Abstract: Gold(III) Iminophosphorane Complexes as Catalysts in C—C and C—O Bond Formations.
  44. ChemInform Abstract: Bonding Properties and Bond Activation of Ylides: Recent Findings and Outlook
  45. Gold(III) iminophosphorane complexes as catalysts in C–C and C–O bond formations
  46. Unexpected [2 + 2] C–C bond coupling due to photocycloaddition on orthopalladated (Z)-2-aryl-4-arylidene-5(4H)-oxazolones
  47. Different bonding modes of sulfur bis-ylides in Pd complexes: Crystal structure of [Pd(μ-OAc){μ-[CH(SMe2)]2C(O)}(acac-O,O′)2]ClO4
  48. Novel gas sensors based on carbon nanotube networks
  49. Regioselective Ortho Palladation of Stabilized Iminophosphoranes in Exo Positions: Scope, Limitations, and Mechanistic Insights
  50. Synthesis and structure of orthopalladated complexes derived from prochiral iminophosphoranes and phosphorus ylides
  51. Bonding properties and bond activation of ylides: recent findings and outlook
  52. Synthesis and structure of tetranuclear orthometallated Pd(ii) complexes derived from bis-iminophosphoranes
  53. Orthopalladation of iminophosphoranes: synthesis, structure and study of stability
  54. Versatility of Iminophosphoranes and Noninnocent Behavior of the 1,5-Cyclooctadiene Ligand in Palladium(II) Complexes. Synthesis of σ-Allyl Derivatives
  55. Selective Cyclopalladation of R 3 PNCH 2 Aryl Iminophosphoranes. Experimental and Computational Study
  56. Organogold(III) Iminophosphorane Complexes as Efficient Catalysts in the Addition of 2-Methylfuran and Electron-Rich Arenes to Methyl Vinyl Ketone
  57. Divergent Behavior in the Cyclopalladation of Phosphorus Ylides and Iminophosphoranes
  58. Preparation of palladium loaded carbon nanotubes and activated carbons for hydrogen sorption
  59. Synthesis and Structure of Pd and Pt Complexes with Doubly Stabilized Phosphorus Ylides
  60. Single-walled carbon nanotube-supported platinum nanoparticles as fuel cell electrocatalysts
  61. Mixed P−N and As−N Bis-Ylide Palladium Complexes:  Cooperative Intramolecular Interactions, Conformational Preferences, and C−H Bond Activations†
  62. Palladium Complexes of a Phosphorus Ylide with Two Stabilizing Groups:  Synthesis, Structure, and DFT Study of the Bonding Modes†
  63. Hydrogen Capacity of Palladium-Loaded Carbon Materials
  64. Synthesis, Structure, Reactivity, and Catalytic Activity ofC,N- andC,N,N-Orthopalladated Iminophosphoranes
  65. Hydrogen sensors based on carbon nanotubes thin films
  66. Selective separation of homogeneous catalysts using silicalite membranes
  67. Synthesis and Characterization of PdIIComplexes with Bis-Pyridinium and Isoquinolinium N-Ylides:  Moderate CH···OC Intramolecular Hydrogen Bonds as Source of Conformational Preferences
  68. Stabilized Bis-ylides as a Source of Carbene Ligands in Palladium(II) and Platinum(II) Complexes
  69. Influence of Noncovalent Interactions on Uracil Tautomer Selection:  Coordination of Both N1 and N3 Uracilate to the Same Metal in the Solid State
  70. Different Coordination Modes of the Polyfunctional Ylide Ph3P=C(H)C(O)CH2C(O)OEt:C- vs.O,O′-Bonding in PdII, PtII and AuI Complexes
  71. Strong 1,4 P–O intramolecular interactions as a source of conformational preferences in α-stabilised phosphorus ylides. Part 2: metallic complexes
  72. C−P and C−H Bond Activations and C−C Coupling in Bis-Phosphonium Salts Induced by Platinum(II) Complexes
  73. Synthesis and characterization of PdII complexes containing cyclic bis-ylides
  74. Stabilized Bis-ylides as a Source of Carbene Ligands in Palladium(II) and Platinum(II) Complexes
  75. 31P NMR Spectroscopy as a Powerful Tool for the Determination of Enantiomeric Excess and Absolute Configurations of α-Amino Acids
  76. Preparation and characterization of Pd-zeolite composite membranes for hydrogen separation
  77. Synthesis, characterization and catalytic activity in Heck-type reactions of orthometallated PdII and PtII complexes derived from (1R,2R)-1,2-diaminocyclohexane
  78. Separation of Pd complexes from a homogeneous solution using zeolite membranes
  79. Strong 1,4-P−O Intramolecular Interactions as a Source of Conformational Preferences in α-Stabilized Phosphorus Ylides
  80. Saccharinate as a Versatile Polyfunctional Ligand. Four Distinct Coordination Modes, Misdirected Valence, and a Dominant Aggregate Structure from a Single Reaction System
  81. C−H Activation in Phosphonium Salts Promoted by Platinum(II) Complexes
  82. Synthesis, structure and reactivity of PdII complexes with the terdentate imino alcohol ligand C6H3-3,4-(OMe)2–C(H)NCH2CH2OH
  83. Reactivity of Pd(0) Complexes with the Phosphino Ylide [Ph2PCH2PPh2C(H)C(O)Me]. Molecular Structure of [Pd(PPh2CHPPh2C(H)C(O)Me)2]
  84. Reactivity of Pd(II) complexes containing the orthometallated C,C-chelating ligand C6H4-2-PPh2C(H)COCH2PPh3 towards deprotonating reagents. Part 2
  85. Synthesis and reactivity of PtII complexes containing the orthometallated ligand [C6H4-2-PPh2C(H)COCH2PPh3]
  86. Reactivity of Palladium(II) Complexes Containing the Orthometalated C,C-Chelating Ligand C 6 H 4 -2-PPh 2 C (H)COCH 2 PPh 3 toward Deprotonating Reagents
  87. Tunable Molecular Distortion in a Nickel Complex Coupled to a Reversible Phase Transition in the Crystalline State
  88. Redetermination of (diazoaminobenzene)copper(I) at 150K
  89. Different coordinating behaviour of the imino-phosphoranes Ph3PξNC(O)CH2Cl and Ph3PξNC(O)-2-NC5H4 towards MII complexes (M=Pd, Pt)
  90. α-Stabilized phosphoylides as versatile multifunctional ligands
  91. A Simple Method for Determining the Absolute Configuration of alpha-Amino Acids
  92. Ligand-Induced and Thermally-Induced Orthometalation of the Bis(ylide) Ligand [Ph3PC(H)]2CO. Generation of the C,C-Chelating GroupC6H4-2-PPh2C((H)COCH2PPh3
  93. Synthesis and Structure of Pd II Complexes Containing the C,C-Chelating Bis-Ylide Ligand [Ph 3 PC(H)] 2 CO. X-ray Crystal Structure of {Pd(μ-Cl){[C(H)PPh 3 ] 2 CO}} 2 (ClO 4 ) 2 ·CH 2 Cl 2
  94. Synthesis, structure and reactivity of PtII complexes containing the [o-(di-o-tolylphosphino)benzyl] cyclometalated ligand towards α-stabilized phosphorus ylides
  95. Synthesis and structure of PdII and PtII complexes containing chiral diphosphazane ligands
  96. Synthesis and characterization of palladium(II) complexes with the α-stabilized phosphoylide ligand Ph3PC(H)CONMe2
  97. Synthesis and characterization of complexes of PdII and PtII containing the iminophosphorane ligand Ph3PNCN
  98. The Cyanurate Ribbon in Structural Coordination Chemistry:  An Aggregate Structure That Persists across Different Coordination Environments and Structural Types
  99. Evidence of CH activation of acetone by a platinum(II) comlex. Synthesis and structural characterization of [Pt(CH2COCH3)Cl(bipy)] (bipy = 2,2′-bipyridyl)
  100. Selective cleavage of a PN bond promoted by alcohols in cis-[Cl2M{S-(Ph2P)2NC(H)(R′)(R″)}] complexes (M = Pd, Pt) X-ray crystal structure of cis-[Cl2Pt(PPh2OMe) {S-Ph2PN(H) C(H) (Me) (Ph)}] · 0.75MeOH
  101. Synthesis and characterization of dinuclear complexes of PdII containing the (μ-NCS)2 skeleton
  102. Neutral and cationic monocarbonyl derivatives of palladium (II). X-ray crystal structure of [Pd(8-mq) (CO) (SPPh3)] ClO4
  103. Coordination Chemistry of Pd(II) Complexes with P-Donor Ligands: An Introduction to Synthesis and Structural Characterization in Coordination Chemistry
  104. Nitrogen- vs Carbon-Coordination of the α-Cyano-Stabilized Phosphorus Ylide Ph 3 PC(H)CN. X-ray Crystal Structure of {Pd(dmba)[P(OMe) 3 ][N⋮CC(H)PPh 3 ]}(ClO 4 )
  105. Oxygen vs. carbon co-ordination of α-keto-stabilized phosphorus ylides Ph3PC(H)COR (R = Me, Ph or OMe) to palladium(II) cationic complexes
  106. A practical method for the absolute configuration assignment of α-amino acids using their Pd(dmba) amino acidato complexes
  107. Importance of steric effects upon the synthesis of {(η6-arene)RuCl}-C,N-cyclometallated amines
  108. Chiral Pd organometallic complexes as catalysts in cyclopropanation reactions
  109. Synthesis and Characterization of {Pd(dmba)(py)[OC(CH 3 )C(H)PPh 3 ]}(ClO 4 )·CH 2 Cl 2 . Unusual O-Coordination of the (Acetylmethylene)triphenylphosphorane Ligand to a Soft Metal Center
  110. Reactivity of (NBu4)[Pt(C6F5)2(acac)] toward Electrophilic Metal Centers:  Metal−MetalvsMetal−Cγ(acac) Bond Formation. Crystal Structure of [PtAg(C6F5)2(acac)(CH2Cl2)]2, a Complex Containing a μ2-acac-O,O‘ Bridging Ligand and a Coordinated Dichloromethane
  111. Synthesis and Nucleophilic Behavior ofcis-[M(C6F5)2(Ph2PCHPPh2)]-(M = Pd, Pt):  C-Alkylation, Metalation, and Halogenation of Coordinated Bis(diphenylphosphino)methane. X-ray Crystal Structure of [Pt(C6F5)2(Ph2PCHIPPh2)]·C5H12
  112. Synthesis and reactivity of acetylacetonato-Cγ complexes of MII (M  Pd or Pt): X-ray crystal structure of [Pd(C6F5)(OOCPh)(bipy)]·CHCl3
  113. Synthesis and characterization of asymmetric C,N-cyclometallated complexes of Mo(II). X-ray crystal structures of [η5-C5H5)MoC6H2-(OCH2O)-2,3-CH2NMe2-6(I)(NO)] and [(η5-C5H5)MoS-C6H4CH(Me)NMe2-2(I)(NO)]
  114. Metal complexes of biologically important ligands: Synthesis of amino acidato complexes of PdII containing a C,N-cyclometallated group as an ancillary ligand
  115. Effects of Ortho-Substituents in the Synthesis and Stability of Cyclomanganated Benzylamine Derivatives. X-ray Crystal Structure of Mn{C6H2(OCH3)2-4,6-CH2NMe2-2}(CO)4
  116. Synthesis and characterisation of homo- and hetero-trinuclear complexes containing the triply-bridging diphenylthiophosphinito [µ3-SPPh2]–ligand: molecular structure of [Pd3(µ3-SPPh2)
  117. Synthesis of homo- and hetero-dinuclear complexes containing alkynyl bridges. Molecular structure of cis,trans-[(OC)(C6F5)2Pt(µ-η2-CCPh)Pt(CCPh)(PPh3)2]
  118. Synthesis and reactivity of palladium(II) complexes with the [C(PPh2)3]–ligand. Crystal structures of [Pd(C6F5){(PPh2)2CPPh2}(PPh3)] and [Pd{(...
  119. Mono- and polynuclear complexes of palladium(II) and platinum(II) with HC(PPh2)3
  120. Different behavior of (NBu4)[M(C6F5)2(acac)] (M = Pd, Pt) toward AgClO4. X-ray crystal structures of (NBu4)[M2Ag(C6F5)4(acac)2] (M = Pd, Pt)
  121. Different co-ordination modes of the ligand [SPPh2]–in complexes of PdIIand PtII. Crystal structures of [{Pd(µ-SPPh2)(C6F5)(PPh3)}2] and [Pd(SPPh2...
  122. Synthesis and reactivity of palladium and platinum complexes containing the bis(diphenylphosphino) methanide ligand
  123. Synthesis and X-ray crystal structure of [Pd(C6F5)(η2-{(Ph2P)3C})(PPh3)], a mononuclear compound containing η2-tris(diphenylphosphine)methanide
  124. Oxidative Addition and Transmetallation
  125. CHAPTER 8. Coordination‐Directed Metallation Strategy for C–H Functionalization