All Stories

  1. Unexpectedly High Levels of Organic Compounds Released by Indoor Photocatalytic Paints

    Article • Environmental Science & Technology, September 2018, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  2. Selective On/Off-Nitroxides as Radical Probes to Investigate Non-radical Enzymatic Activity by Electron Paramagnetic Resonance

    Article • Chemistry - A European Journal, May 2018, Wiley

    Professor Sylvain MARQUE

  3. Orthogonal Tyrosine and Cysteine Site-Directed Spin Labeling for Dipolar Pulse EPR Spectroscopy on Proteins

    Article • The Journal of Physical Chemistry Letters, September 2017, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  4. Normal, Leveled, and Enhanced Steric Effects in Alkoxyamines Carrying a β-Phosphorylated Nitroxyl Fragment

    Article • The Journal of Organic Chemistry, May 2017, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  5. C–ON bond homolysis of alkoxyamines: when too high polarity is detrimental

    Article • Organic & Biomolecular Chemistry, January 2017, Royal Society of Chemistry

    Professor Sylvain MARQUE

  6. How intramolecular hydrogen bonding (IHB) controls the C–ON bond homolysis in alkoxyamines

    Article • Organic & Biomolecular Chemistry, January 2017, Royal Society of Chemistry

    Professor Sylvain MARQUE

  7. One year monitoring by FTIR of γ-irradiated multilayer film PE/EVOH/PE

    Article • Radiation Physics and Chemistry, August 2016, Elsevier

    Professor Sylvain MARQUE

  8. FTIR study of ageing of γ-irradiated biopharmaceutical EVA based film

    Article • Polymer Degradation and Stability, July 2016, Elsevier

    Professor Sylvain MARQUE

  9. Mass spectrometry of nitroxide-terminated poly(4-vinylpyridine): A case of unwanted reactive MALDI

    Article • International Journal of Mass Spectrometry, July 2016, Elsevier

    Professor Sylvain MARQUE

  10. Computational and mechanistic studies of the acylation of cyclopropanes

    Article • Tetrahedron Letters, April 2016, Elsevier

    Professor Sylvain MARQUE

  11. C–ON Bond Homolysis of Alkoxyamines, Part 11: Activation of the Nitroxyl Fragment

    Article • The Journal of Organic Chemistry, February 2016, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  12. Solvent effect in β-phosphorylated nitroxides. Part 4: detection of traces of water by electron paramagnetic resonance

    Article • Organic & Biomolecular Chemistry, January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  13. β-Phosphorus hyperfine coupling constant in nitroxides: 5. Solvent effect

    Article • RSC Advances, January 2016, Royal Society of Chemistry

    Kuanysh Kabytaev, Professor Sylvain MARQUE

  14. C–ON bond homolysis in alkoxyamines. Part 12: the effect of the para-substituent in the 1-phenylethyl fragment

    Article • Organic & Biomolecular Chemistry, January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  15. The β-phosphorus hyperfine coupling constant in nitroxides: 6. Solvent effects in non-cyclic nitroxides

    Article • Organic & Biomolecular Chemistry, January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  16. Degradation of γ-irradiated polyethylene-ethylene vinyl alcohol-polyethylene multilayer films: An ESR study

    Article • Polymer Degradation and Stability, December 2015, Elsevier

    Professor Sylvain MARQUE

  17. Enzymatically Shifting Nitroxides for EPR Spectroscopy and Overhauser‐Enhanced Magnetic Resonance Imaging

    Article • Angewandte Chemie International Edition, November 2015, Wiley

    Professor Sylvain MARQUE

  18. Energetics of the biosynthesis of prostanes from arachidonate

    Article • Tetrahedron, September 2015, Elsevier

    Professor Sylvain MARQUE

  19. Computational Studies on Intramolecular Cycloadditions of Azidoenynes and Azidobutenenitriles to Give 6H-Pyrrolo[1,2-c][1,2,3]triazoles and 5H-Pyrrolo[1,2-d]tetrazoles

    Article • Helvetica Chimica Acta, July 2015, Wiley

    Professor Sylvain MARQUE

  20. Design of Wall-Functionalized Hybrid Silicas Containing Diazene Radical Precursors. EPR Investigation of Their Photolysis and Thermolysis

    Article • The Journal of Physical Chemistry C, March 2015, American Chemical Society (ACS)

    Dr Stéphane Gastaldi, Professor Sylvain MARQUE

  21. Solvent Effect in β-Phosphorylated Nitroxides: Model Nitroxides

    Article • Applied Magnetic Resonance, February 2015, Springer Science + Business Media

    Professor Sylvain MARQUE

  22. On the structure–control relationship of amide-functionalized SG1-based alkoxyamines for nitroxide-mediated polymerization and conjugation

    Article • Polymer Chemistry, January 2015, Royal Society of Chemistry

    Professor Sylvain MARQUE

  23. Part 10: chemically triggered alkoxyamine C–ON bond homolysis in ionic liquid solvents

    Article • RSC Advances, January 2015, Royal Society of Chemistry

    Professor Sylvain MARQUE

  24. The β-phosphorus hyperfine coupling constant in nitroxide: part 3: titration of water by electron paramagnetic resonance

    Article • Organic & Biomolecular Chemistry, January 2015, Royal Society of Chemistry

    Professor Sylvain MARQUE

  25. Chapter 2. Kinetic Aspects of Nitroxide Mediated Polymerization

    Article • January 2015, Royal Society of Chemistry

    Professor Sylvain MARQUE

  26. Development and Application of Spin Traps, Spin Probes, and Spin Labels

    Article • January 2015, Elsevier

    Professor Sylvain MARQUE

  27. Hydrogen-Bonding Effects for the C-ON Bond Homolysis and Reformation Reactions of Alkoxyamines

    Article • Macromolecular Chemistry and Physics, December 2014, Wiley

    Professor Sylvain MARQUE

  28. Energetics of the biosynthesis of cyclopentenones from unsaturated fatty acids

    Article • Tetrahedron, November 2014, Elsevier

    Professor Sylvain MARQUE

  29. Addition and corrections published 31st October 2013 to 10th July 2014

    Article • Chemical Communications, July 2014, Royal Society of Chemistry

    Professor Sylvain MARQUE, Prof. In-Hyeok Park

  30. Alkoxyamines: Toward a New Family of Theranostic Agents against Cancer

    Article • Molecular Pharmaceutics, July 2014, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  31. Scavenging of Organic C-Centered Radicals by Nitroxides

    Article • Chemical Reviews, May 2014, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  32. In vivoOverhauser-enhanced MRI of proteolytic activity

    Article • Contrast Media & Molecular Imaging, April 2014, Wiley

    Professor Sylvain MARQUE

  33. Calculated linear free energy relationships in the course of the Suzuki–Miyaura coupling reaction

    Article • Tetrahedron, April 2014, Elsevier

    Professor Sylvain MARQUE

  34. Revised Structure, Total Synthesis, and Absolute Configuration of Kopeolin and Kopeolone

    Article • The Journal of Organic Chemistry, March 2014, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  35. Chemically triggered C-ON bond homolysis in alkoxyamines. Part 7. Remote polar effect

    Article • Journal of Physical Organic Chemistry, January 2014, Wiley

    Professor Sylvain MARQUE

  36. Alkoxyamines: a new family of pro-drugs against cancer. Concept for theranostics

    Article • Organic & Biomolecular Chemistry, January 2014, Royal Society of Chemistry

    Professor Sylvain MARQUE

  37. Diversification of EPR signatures in site directed spin labeling using a β-phosphorylated nitroxide

    Article • Physical Chemistry Chemical Physics, January 2014, Royal Society of Chemistry

    Professor Sylvain MARQUE, Kuanysh Kabytaev

  38. Arylsulfanyl radical lifetime in nanostructured silica: dramatic effect of the organic monolayer structure

    Article • Chemical Science, January 2014, Royal Society of Chemistry

    Dr Stéphane Gastaldi, Professor Sylvain MARQUE

  39. Labile alkoxyamines: past, present, and future

    Article • Chemical Communications, January 2014, Royal Society of Chemistry

    Professor Sylvain MARQUE

  40. Theoretical modelling of the epoxidation of vinylallenes to give cyclopentenones

    Article • Tetrahedron Letters, November 2013, Elsevier

    Professor Sylvain MARQUE

  41. Chemically Triggered C–ON Bond Homolysis of Alkoxyamines. 8. Quaternization and Steric Effects

    Article • The Journal of Organic Chemistry, October 2013, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  42. Nazarov reagents and their use in organic synthesis

    Article • Tetrahedron, September 2013, Elsevier

    Professor Sylvain MARQUE

  43. Chemically Triggered C–ON Bond Homolysis in Alkoxyamines. 6. Effect of the Counteranion

    Article • The Journal of Organic Chemistry, August 2013, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  44. Structural Equilibrium in New Nitroxide-Capped Cyclodextrins: CW and Pulse EPR Study

    Article • The Journal of Physical Chemistry, July 2013, American Chemical Society (ACS)

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  45. Enlarging the Panoply of Site-Directed Spin Labeling Electron Paramagnetic Resonance (SDSL-EPR): Sensitive and Selective Spin-Labeling of Tyrosine Using an Isoindoline-Based Nitroxide

    Article • Bioconjugate Chemistry, June 2013, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  46. Chemically triggered C–ON bond homolysis in alkoxyamines: regioselectivity and chemoselectivity

    Article • Organic & Biomolecular Chemistry, January 2013, Royal Society of Chemistry

    Professor Sylvain MARQUE

  47. Dynamics of the intrinsically disordered protein CP12 in its association with GAPDH in the green alga Chlamydomonas reinhardtii: a fuzzy complex

    Article • Molecular BioSystems, January 2013, Royal Society of Chemistry

    Professor Sylvain MARQUE

  48. Intramolecular proton transfer (IPT) in alkoxyamine: a theoretical investigation

    Article • Physical Chemistry Chemical Physics, January 2013, Royal Society of Chemistry

    Professor Sylvain MARQUE

  49. H-transfer reaction during decomposition of N -(2-methylpropyl)- N -(1-diethylphosphono-2,2-dimethylpropyl)-N -oxyl (SG1)-based alkoxyamines

    Article • Journal of Polymer Science Part A Polymer Chemistry, December 2012, Wiley

    Professor Sylvain MARQUE, Kuanysh Kabytaev

  50. Chemically Triggered C–ON Bond Homolysis of Alkoxyamines. 5. Cybotactic Effect

    Article • The Journal of Organic Chemistry, November 2012, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  51. EPR Investigation of Zinc/Iodine Exchange between Propargyl Iodides and Diethylzinc: Detection of Propargyl Radical by Spin Trapping

    Article • The Journal of Organic Chemistry, October 2012, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  52. Hyperfine Coupling Constants of β-Phosphorylated Nitroxides: A Tool to Probe the Cybotactic Effect by Electron Paramagnetic Resonance

    Article • ChemPhysChem, August 2012, Wiley

    Professor Sylvain MARQUE

  53. Direct functionalization of labile alkoxyamines

    Article • Tetrahedron Letters, August 2012, Elsevier

    Professor Sylvain MARQUE, Kuanysh Kabytaev

  54. Alkoxyamine Re-Formation Reaction. Effects of the Nitroxide Fragment: A Multiparameter Analysis.

    Article • The Journal of Organic Chemistry, June 2012, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  55. Aminomethylation of Michael Acceptors: Complementary Radical and Polar Approaches Mediated by Dialkylzincs

    Article • Chemistry - A European Journal, February 2012, Wiley

    Professor Sylvain MARQUE

  56. β-Fragmentation of Tertiary Alkoxyl Radicals: G3(MP2)-RAD and Natural Bond Orbital Investigations

    Article • ChemPhysChem, January 2012, Wiley

    Professor Sylvain MARQUE

  57. Chemically Triggered C–ON Bond Homolysis of Alkoxyamines. Quaternization of the Alkyl Fragment

    Article • Organic Letters, January 2012, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  58. Chemically triggered C–ON bond homolysis of alkoxyamines. Part 4: solvent effect

    Article • Polymer Chemistry, January 2012, Royal Society of Chemistry

    Professor Sylvain MARQUE

  59. In vivo high-resolution 3D Overhauser-enhanced MRI in mice at 0.2 T

    Article • Contrast Media & Molecular Imaging, January 2012, Wiley

    Professor Sylvain MARQUE

  60. Chemically Triggered C-ON Bond Homolysis in Alkoxyamines. Part 2: DFT Investigation and Application of the pH Effect on NMP

    Article • Macromolecular Rapid Communications, November 2011, Wiley

    Professor Sylvain MARQUE

  61. Time-Resolved and Pulse EPR Study of Triplet States of Alkylketones in β-Cyclodextrin

    Article • Applied Magnetic Resonance, October 2011, Springer Science + Business Media

    Professor Sylvain MARQUE

  62. Linear-Free Energy Relationships for Modeling Structure–Reactivity Trends in Controlled Radical Polymerization

    Article • Macromolecules, October 2011, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  63. Tyrosine-Targeted Spin Labeling and EPR Spectroscopy: An Alternative Strategy for Studying Structural Transitions in Proteins

    Article • Angewandte Chemie International Edition, August 2011, Wiley

    Professor Sylvain MARQUE

  64. Spin-Trapping Evidence for the Formation of Alkyl, Alkoxyl, and Alkylperoxyl Radicals in the Reactions of Dialkylzincs with Oxygen

    Article • Chemistry - A European Journal, January 2011, Wiley

    Professor Sylvain MARQUE

  65. First proton triggered C–ON bond homolysis in alkoxyamines

    Article • Chemical Communications, January 2011, Royal Society of Chemistry

    Professor Sylvain MARQUE

  66. Kinetic subtleties of nitroxide mediated polymerization

    Article • Chemical Society Reviews, January 2011, Royal Society of Chemistry

    Professor Sylvain MARQUE

  67. Chemically Induced Dynamic Nuclear Polarization during the Thermolysis of Alkoxyamines: A New Approach to Detect the Occurrence of H-Transfer Reactions

    Article • Polymers, September 2010, MDPI AG

    Professor Sylvain MARQUE

  68. Diasteromeric Effect on the Homolysis of the C–ON Bond in Alkoxyamines: A DFT Investigation of 1,3-Diphenylbutyl-TEMPO

    Article • Polymers, September 2010, MDPI AG

    Professor Sylvain MARQUE

  69. A Step Towards High‐Molecular‐Weight Living/Controlled Polystyrene Using SG1‐Mediated Polymerization

    Article • Macromolecular Reaction Engineering, June 2010, Wiley

    Dr Muriel Lansalot, Professor Sylvain MARQUE

  70. Role of the alkyl fragment of initiating alkoxyamine in nitroxide mediated polymerization of styrene

    Article • Polymer Science Series B, June 2010, Pleiades Publishing Ltd

    Professor Sylvain MARQUE

  71. Polypropylene degradation: Theoretical and experimental investigations

    Article • Polymer Degradation and Stability, May 2010, Elsevier

    Professor Sylvain MARQUE

  72. Linear Free-Energy Relationships for the Alkyl Radical Affinities of Nitroxides: A Theoretical Study

    Article • Macromolecules, April 2010, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  73. Regio-Defined Amino[5]Oxa- and Thiahelicenes: A Dramatic Impact of the Nature of the Heteroatom on the Helical Shape and Racemization Barriers

    Article • The Journal of Organic Chemistry, March 2010, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  74. EPR, NMR, and Thermodynamic Evidences for Forced Nuclear Spin–Electron Spin Interactions in the Case of 1-Phenyl-2-Methylpropyl-1,1-Dimethyl-2-Nitroxide (TIPNO) Attached to Permethylated β-Cyclodextrin

    Article • Applied Magnetic Resonance, November 2009, Springer Science + Business Media

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  75. Kinetic study of H‐atom transfer in imidazoline‐, imidazolidine‐, and pyrrolidine‐based alkoxyamines: Consequences for nitroxide‐mediated polymerization

    Article • Journal of Polymer Science Part A Polymer Chemistry, October 2009, Wiley

    Professor Sylvain MARQUE

  76. Imidazoline-N-oxyl: A DFT Study of Its Protonation Reaction

    Article • ChemPhysChem, October 2009, Wiley

    Professor Sylvain MARQUE

  77. New Concepts in Molecular Imaging: Non-Invasive MRI Spotting of Proteolysis Using an Overhauser Effect Switch

    Article • PLoS ONE, April 2009, PLOS

    Professor Sylvain MARQUE

  78. Role of the Adducted Cation in the Release of Nitroxide End Group of Controlled Polymer in Mass Spectrometry

    Article • Macromolecules, March 2009, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  79. Is Experimental Evidence Sufficient Enough To Account for the Stabilization Effect of Bisnitroxide on the Fate of NMP Experiments?

    Article • Macromolecules, February 2009, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  80. Electron Paramagnetic Resonance Spin Trapping of Glutathiyl Radicals by PBN in the Presence of Cyclodextrins and by PBN Attached to β-Cyclodextrin

    Article • The Journal of Physical Chemistry, October 2008, American Chemical Society (ACS)

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  81. Hydrogen-transfer reaction in nitroxide mediated polymerization of methyl methacrylate: 2,2-Diphenyl-3-phenylimino-2,3-dihydroindol-1-yloxyl nitroxide (DPAIO) vs. TEMPO

    Article • Journal of Polymer Science Part A Polymer Chemistry, September 2008, Wiley

    Professor Sylvain MARQUE

  82. Can the First Addition of Alkyl Radicals Play a Role in the Fate of NMP?

    Article • Macromolecular Chemistry and Physics, July 2008, Wiley

    Professor Sylvain MARQUE

  83. Synthesis of Highly Labile SG1-Based Alkoxyamines under Photochemical Conditions

    Article • The Journal of Organic Chemistry, June 2008, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  84. Reduced sample recovery in liquid chromatography at critical adsorption point of high molar mass polystyrene

    Article • European Polymer Journal, February 2008, Elsevier

    Professor Sylvain MARQUE

  85. Effect of the Carboxylate Salt on the CON Bond Homolysis of SG1-Based Alkoxyamines

    Article • ChemPhysChem, February 2008, Wiley

    Professor Sylvain MARQUE

  86. Effect of the Penultimate Unit on the CON Bond Homolysis in SG1-Based Alkoxyamines

    Article • Macromolecular Chemistry and Physics, January 2008, Wiley

    Professor Sylvain MARQUE

  87. α-Phenyl-N-tert-butylnitrone-Type Derivatives Bound to β-Cyclodextrins: Syntheses, Thermokinetics of Self-Inclusion and Application to Superoxide Spin-Trapping

    Article • Chemistry - A European Journal, November 2007, Wiley

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  88. Intermolecular radical addition of alkoxyamines onto olefins: An easy access to advanced macromolecular architectures precursors

    Article • Polymer, August 2007, Elsevier

    Professor Sylvain MARQUE

  89. A DFT study of the hydrogen atom abstraction from 2,4,6-trimethylheptane: A model of peroxidic degradation for syndio polypropylene

    Article • Journal of Molecular Structure THEOCHEM, June 2007, Elsevier

    Professor Sylvain MARQUE

  90. First Effective Nitroxide-Mediated Polymerization of Methyl Methacrylate

    Article • Macromolecules, May 2007, American Chemical Society (ACS)

    Dr Paola Astolfi, Professor Sylvain MARQUE

  91. Synthetic Studies toward Highly Functionalized 5β-Lanosterol Derivatives:  A Versatile Approach Utilizing Anionic Cycloaddition.

    Article • The Journal of Organic Chemistry, February 2007, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  92. Living Character of Polymer Chains Prepared via Nitroxide-Mediated Controlled Free-Radical Polymerization of Methyl Methacrylate in the Presence of a Small Amount of Styrene at Low Temperature

    Article • Macromolecules, November 2006, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  93. Alkoxyamines of Stable Aromatic Nitroxides: NOvs. CO Bond Homolysis

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Dr Paola Astolfi, Professor Sylvain MARQUE

  94. Re-formation Reaction of Cyclic Nitroxide-Based Alkoxyamines: Steric and Polar/Stabilization Effects

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Professor Sylvain MARQUE

  95. Intramolecular Hydrogen Bonding: The Case ofβ-Phosphorylated Nitroxide (= Aminoxyl) Radical

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Professor Sylvain MARQUE

  96. Absolute Rate Constants for the Addition of the 1-(tert-Butoxy)carbonylethyl Radical onto Cyclic Alkenes in Solution

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Professor Sylvain MARQUE

  97. 2,5-Dihydro-1H-imidazole-Based Nitroxides as Prospective Mediators in Living Radical Polymerization

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Professor Sylvain MARQUE

  98. Persilylated Phosphoranyl Radicals: The First Persistent Noncyclic Phosphoranyl Radicals

    Article • Chemistry - A European Journal, September 2006, Wiley

    Professor Sylvain MARQUE

  99. Nitroxide Bound β-Cyclodextrin:  Is There an Inclusion Complex?

    Article • The Journal of Organic Chemistry, September 2006, American Chemical Society (ACS)

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  100. Nitroxide-Mediated Polymerization:  The Pivotal Role of the k d Value of the Initiating Alkoxyamine and the Importance of the Experimental Conditions

    Article • Macromolecules, August 2006, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  101. Laser Flash Photolysis and CIDNP Studies of Steric Effects on Coupling Rate Constants of Imidazolidine Nitroxide with Carbon-Centered Radicals, Methyl Isobutyrate-2-yl and tert -Butyl Propionate-2-yl ⊥

    Article • The Journal of Organic Chemistry, August 2006, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  102. Nitroxide-Mediated Polymerization of Methyl Methacrylate Using an SG1-Based Alkoxyamine: How the Penultimate Effect Could Lead to Uncontrolled and Unliving Polymerization

    Article • Macromolecular Chemistry and Physics, July 2006, Wiley

    Professor Sylvain MARQUE

  103. Long-range polar and steric effects in propionate-SG1-type alkoxyamines (SG1-CHMeCOOX): a multiparameter analysis

    Article • Journal of Physical Organic Chemistry, April 2006, Wiley

    Professor Sylvain MARQUE

  104. Alkoxyamine C–ON Bond Homolysis: Stereoelectronic Effects

    Article • European Journal of Organic Chemistry, April 2006, Wiley

    Professor Sylvain MARQUE

  105. Polystyrene-block-poly(ethylene oxide) from nitroxide mediated polymerization: detection of minor species by coupled chromatographic techniques

    Article • Polymer, January 2006, Elsevier

    Professor Sylvain MARQUE

  106. Steric and Polar Effects of the Cyclic Nitroxyl Fragment on the C−ON Bond Homolysis Rate Constant

    Article • Macromolecules, November 2005, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  107. SG1 based alkoxyamines as radical initiators for the synthesis of lactones and lactames

    Article • Tetrahedron, September 2005, Elsevier

    Professor Sylvain MARQUE

  108. Polar, Steric, and Stabilization Effects in Alkoxyamines C−ON Bond Homolysis:  A Multiparameter Analysis

    Article • Macromolecules, April 2005, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  109. Reactivity of Phosphorus Centered Radicals

    Article • February 2005, Springer Science + Business Media

    Professor Sylvain MARQUE

  110. β-Fragmentation of alkoxyl radicals: Natural bond orbital analysis

    Article • International Journal of Quantum Chemistry, January 2005, Wiley

    Professor Sylvain MARQUE

  111. Selective and efficient fluorination of chlorodiazines under solvent-free phase transfer catalysis

    Article • Journal of Fluorine Chemistry, December 2004, Elsevier

    Professor Sylvain MARQUE

  112. Factors Influencing C−ON Bond Homolysis in Alkoxyamines:  Unexpected Behavior of SG1 ( N -(2-methyl-2-propyl)- N -(1-diethylphosphono-2,2-dimethylpropyl)- N -oxyl)-Based Alkoxyamines

    Article • The Journal of Organic Chemistry, July 2004, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  113. Leveled Steric Effect in Alkoxyamines of SG1-Type

    Article • Macromolecular Chemistry and Physics, May 2004, Wiley

    Professor Sylvain MARQUE

  114. Diastereomeric excess upon cleavage and reformation of diastereomeric alkoxyamines

    Article • Organic & Biomolecular Chemistry, January 2004, Royal Society of Chemistry

    Professor Sylvain MARQUE

  115. Switched external magnetic field CIDNP studies of coupling reaction of carbon-centered radicals with TEMPO

    Article • Physical Chemistry Chemical Physics, January 2004, Royal Society of Chemistry

    Professor Sylvain MARQUE

  116. Synthesis of a series of SG1 2-[N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)aminoxyl] based alkoxyamines, SG1-CH(Me)CO2R, and measurement of the homolysis rate constants of the C?ON bond

    Article • Journal of Polymer Science Part A Polymer Chemistry, January 2004, Wiley

    Professor Sylvain MARQUE

  117. Long-Range Polar Effect on the C-ON Bond Homolysis in (tert-Butyl[1-(diethylphosphonyl)-2,2-dimethylpropyl]aminoxyl) SG1-Based Alkoxyamines

    Article • Collection of Czechoslovak Chemical Communications, January 2004, Institute of Organic Chemistry & Biochemistry

    Professor Sylvain MARQUE

  118. Alkoxyamine-Mediated Radical Synthesis of Indolinones and Indolines

    Article • Organic Letters, December 2003, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  119. Influence of the Nitroxide Structure on the Homolysis Rate Constant of Alkoxyamines:  A Taft−Ingold Analysis

    Article • The Journal of Organic Chemistry, October 2003, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  120. Steric Effects of Ring Substituents on the Decay and Reformation Kinetics of Piperazinone-Based Alkoxyamines

    Article • Macromolecules, May 2003, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  121. Tetrathiophosphoric acid tri(1-phenylethyl) ester and1-phenylethyl-diphenylphosphinodithioate as controlled radical polymerization agents

    Article • Tetrahedron Letters, February 2003, Elsevier

    Professor Sylvain MARQUE

  122. Design and use ofβ-phosphorus nitroxides and alkoxyamines in controlled/“living” free radical polymerizations

    Article • Macromolecular Symposia, June 2002, Wiley

    Dr Muriel Lansalot, Professor Sylvain MARQUE

  123. Lack of Chain Length Effect on the Rate of Homolysis of Polystyryl-SG1 Alkoxyamines

    Article • Macromolecules, May 2002, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  124. Absolute Rate Constants for the Addition of the 1-(tert-Butoxy)carbonylethyl Radical to Alkenes in Solution

    Article • Helvetica Chimica Acta, August 2001, Wiley

    Professor Sylvain MARQUE

  125. Factors Influencing the C−O Bond Homolysis of Alkoxyamines:  Effects of H−Bonding and Polar Substituents

    Article • The Journal of Organic Chemistry, February 2001, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  126. Factors Influencing the C−O−Bond Homolysis of Trialkylhydroxylamines

    Article • Macromolecules, June 2000, American Chemical Society (ACS)

    Professor Sylvain MARQUE