All Stories

  1. Structure–Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent

    Article • The Journal of Organic Chemistry, March 2015, American Chemical Society (ACS)

    Professor Qilong Shen

  2. Pd-Catalyzed Difluoromethylation of Vinyl Bromides, Triflates, Tosylates, and Nonaflates

    Article • Chemistry - A European Journal, March 2015, Wiley

    Professor Qilong Shen

  3. BrØsted acid-catalyzed electrophilic trifluoromethylthiolation of indoles using thermally stable trifluoromethylthiolating reagent

    Article • Journal of Fluorine Chemistry, March 2015, Elsevier

    Professor Qilong Shen

  4. ChemInform Abstract: Copper-Catalyzed Trifluoromethylthiolation of Primary and Secondary Alkylboronic Acids.

    Article • ChemInform, February 2015, Wiley

    Professor Qilong Shen

  5. ChemInform Abstract: N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent.

    Article • ChemInform, February 2015, Wiley

    Professor Qilong Shen

  6. ChemInform Abstract: Chincona Alkaloid-Catalyzed Enantioselective Trifluoromethylthiolation of Oxindoles.

    Article • ChemInform, February 2015, Wiley

    Professor Qilong Shen

  7. Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Professor Qilong Shen

  8. ChemInform Abstract: Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion.

    Article • ChemInform, November 2014, Wiley

    Professor Qilong Shen

  9. Cooperative dual palladium/silver catalyst for direct difluoromethylation of aryl bromides and iodides

    Article • Nature Communications, November 2014, Springer Science + Business Media

    Professor Qilong Shen

  10. Nickel-Catalyzed α-Arylation of Zinc Enolates with Polyfluoroarenes via C–F Bond Activation under Neutral Conditions

    Article • Organic Letters, November 2014, American Chemical Society (ACS)

    Professor Qilong Shen

  11. Copper-Catalyzed Trifluoromethylthiolation of Primary and Secondary Alkylboronic Acids

    Article • Organic Letters, September 2014, American Chemical Society (ACS)

    Professor Qilong Shen

  12. ChemInform Abstract: Palladium-Catalyzed Trifluoromethylthiolation of Aryl C-H Bonds.

    Article • ChemInform, August 2014, Wiley

    Professor Qilong Shen

  13. Chincona Alkaloid-Catalyzed Enantioselective Trifluoromethylthiolation of Oxindoles

    Article • Chinese Journal of Chemistry, August 2014, Wiley

    Professor Qilong Shen

  14. N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent

    Article • Angewandte Chemie, July 2014, Wiley

    Professor Qilong Shen

  15. N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent

    Article • Angewandte Chemie International Edition, July 2014, Wiley

    Professor Qilong Shen

  16. Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion

    Article • Angewandte Chemie, April 2014, Wiley

    Professor Qilong Shen

  17. Silver-Catalyzed Decarboxylative Trifluoromethylthiolation of Aliphatic Carboxylic Acids in Aqueous Emulsion

    Article • Angewandte Chemie International Edition, April 2014, Wiley

    Professor Qilong Shen

  18. ChemInform Abstract: Enantioselective Electrophilic Trifluoromethylthiolation of β-Ketoesters: A Case of Reactivity and Selectivity Bias for Organocatalysis.

    Article • ChemInform, April 2014, Wiley

    Professor Qilong Shen

  19. Palladium-Catalyzed Trifluoromethylthiolation of Aryl C–H Bonds

    Article • Organic Letters, April 2014, American Chemical Society (ACS)

    Professor Qilong Shen

  20. ChemInform Abstract: A General and Highly Selective Method for the Asymmetric Synthesis of Trifluoromethyl-Substituted α- and β-Aminophosphonates.

    Article • ChemInform, January 2014, Wiley

    Professor Qilong Shen

  21. ChemInform Abstract: Palladium-Catalyzed Cross-Coupling of Fluorinated Vinyl Chlorides with Terminal Alkynes: A General Protocol to Fluorinated Enynes.

    Article • ChemInform, January 2014, Wiley

    Professor Qilong Shen

  22. Copper-catalyzed trifluoromethylthiolation of aryl and vinyl boronic acids with a shelf-stable electrophilic trifluoromethylthiolating reagent

    Article • Organic Chemistry Frontiers, January 2014, Royal Society of Chemistry

    Professor Qilong Shen

  23. Enantioselective Electrophilic Trifluoromethylthiolation of β-Ketoesters: A Case of Reactivity and Selectivity Bias for Organocatalysis

    Article • Angewandte Chemie, September 2013, Wiley

    Professor Qilong Shen

  24. Enantioselective Electrophilic Trifluoromethylthiolation of β-Ketoesters: A Case of Reactivity and Selectivity Bias for Organocatalysis

    Article • Angewandte Chemie International Edition, September 2013, Wiley

    Professor Qilong Shen

  25. ChemInform Abstract: An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation.

    Article • ChemInform, July 2013, Wiley

    Professor Qilong Shen

  26. ChemInform Abstract: Palladium-Catalyzed Coupling of Polyfluorinated Arenes with Heteroarenes via C-F/C-H Activation.

    Article • ChemInform, July 2013, Wiley

    Professor Qilong Shen

  27. Palladium-Catalyzed Cross-Coupling of Fluorinated Vinyl Chlorides with Terminal Alkynes: A General Protocol to Fluorinated Enynes

    Article • Chinese Journal of Chemistry, July 2013, Wiley

    Professor Qilong Shen

  28. A General and Highly Selective Method for the Asymmetric Synthesis of Trifluoromethyl-Substitutedα- andβ-Aminophosphonates

    Article • Chinese Journal of Chemistry, July 2013, Wiley

    Professor Qilong Shen

  29. Cover Picture: Palladium-Catalyzed Cross-Coupling of Fluorinated Vinyl Chlorides with Terminal Alkynes: A General Protocol to Fluorinated Enynes (Chin. J. Chem. 7/2013)

    Article • Chinese Journal of Chemistry, July 2013, Wiley

    Professor Qilong Shen

  30. Enantioselective Organocatalytic Michael Addition of Nitroalkanes and Other Nucleophiles to β-Trifluoromethylated Acrylamides

    Article • ACS Catalysis, April 2013, American Chemical Society (ACS)

    Professor Qilong Shen

  31. ChemInform Abstract: Preparation of Trifluorostyrenes via Palladium-Catalyzed Coupling of Arylboronic Acids with Chloro- and Bromotrifluoroethylene.

    Article • ChemInform, March 2013, Wiley

    Professor Qilong Shen

  32. Rücktitelbild: An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation (Angew. Chem. 12/2013)

    Article • Angewandte Chemie, March 2013, Wiley

    Professor Qilong Shen

  33. ChemInform Abstract: Highly Selective Activation of Vinyl C-S Bonds over Aryl C-S Bonds in the Pd-Catalyzed Coupling of (E)-(β-Trifluoromethyl)vinyldiphenylsulfonium Salts: Preparation of Trifluoromethylated Alkenes and Dienes.

    Article • ChemInform, February 2013, Wiley

    Professor Qilong Shen

  34. Palladium-Catalyzed Coupling of Polyfluorinated Arenes with Heteroarenes via C–F/C–H Activation

    Article • Organic Letters, February 2013, American Chemical Society (ACS)

    Professor Qilong Shen

  35. An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

    Article • Angewandte Chemie, January 2013, Wiley

    Professor Qilong Shen

  36. An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

    Article • Angewandte Chemie International Edition, January 2013, Wiley

    Professor Qilong Shen

  37. ChemInform Abstract: General and Highly Efficient Fluorinated-N-heterocyclic Carbene-Based Catalysts for the Palladium-Catalyzed Suzuki-Miyaura Reaction.

    Article • ChemInform, December 2012, Wiley

    Professor Qilong Shen

  38. Preparation of Trifluorostyrenes via Palladium-Catalyzed Coupling of Arylboronic Acids with Chloro- and Bromotrifluoroethylene

    Article • The Journal of Organic Chemistry, November 2012, American Chemical Society (ACS)

    Professor Qilong Shen

  39. Progress in Copper-Mediated Formation of Trifluoromethylated Arenes

    Article • European Journal of Organic Chemistry, September 2012, Wiley

    Professor Qilong Shen

  40. Bis(perfluoroalkyl) Phosphino-Oxazoline: A Modular, Stable, Strongly π-Accepting Ligand for Asymmetric Catalysis

    Article • The Journal of Organic Chemistry, September 2012, American Chemical Society (ACS)

    Professor Qilong Shen

  41. ChemInform Abstract: Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature.

    Article • ChemInform, August 2012, Wiley

    Professor Qilong Shen

  42. General and highly efficient fluorinated-N-heterocyclic carbene–based catalysts for the palladium-catalyzed Suzuki–Miyaura reaction

    Article • Tetrahedron, August 2012, Elsevier

    Professor Qilong Shen

  43. Highly Selective Activation of Vinyl C-S Bonds Over Aryl C-S Bonds in the Pd-Catalyzed Coupling of (E)-(β-Trifluoromethyl)vinyldiphenylsulfonium Salts: Preparation of Trifluoromethylated Alkenes and Dienes

    Article • European Journal of Organic Chemistry, July 2012, Wiley

    Professor Qilong Shen

  44. ChemInform Abstract: Selective Palladium-Catalyzed C-F Activation/Carbon-Carbon Bond Formation of Polyfluoroaryl Oxazolines.

    Article • ChemInform, May 2012, Wiley

    Professor Qilong Shen

  45. ChemInform Abstract: A Facile Synthetic Route to 2-Trifluoromethyl-Substituted Polyfunctionalized Chromenes and Chromones.

    Article • ChemInform, May 2012, Wiley

    Professor Qilong Shen

  46. ChemInform Abstract: Polyfluoroalkylation of 2-Aminothiazoles.

    Article • ChemInform, May 2012, Wiley

    Professor Qilong Shen

  47. ChemInform Abstract: Highly Selective Trifluoromethylation of 1,3-Disubstituted Arenes Through Iridium-Catalyzed Arene Borylation.

    Article • ChemInform, May 2012, Wiley

    Professor Qilong Shen

  48. Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature

    Article • Journal of the American Chemical Society, April 2012, American Chemical Society (ACS)

    Professor Qilong Shen

  49. ChemInform Abstract: Polyfluoroalkylation of 2-Aminothiazoles: Unexpected sp3C-Cl Substitution under Mild Conditions.

    Article • ChemInform, March 2012, Wiley

    Professor Qilong Shen

  50. Selective Palladium-Catalyzed C–F Activation/Carbon–Carbon Bond Formation of Polyfluoroaryl Oxazolines

    Article • The Journal of Organic Chemistry, February 2012, American Chemical Society (ACS)

    Professor Qilong Shen

  51. Polyfluoroalkylation of 2-aminothiazoles

    Article • Journal of Fluorine Chemistry, January 2012, Elsevier

    Professor Qilong Shen

  52. Transition Metal-Catalyzed Arene Trifluoromethylation

    Article • Chinese Journal of Organic Chemistry, January 2012, Shanghai Institute of Organic Chemistry

    Professor Qilong Shen

  53. A facile synthetic route to 2-trifluoromethyl-substituted polyfunctionalized chromenes and chromones

    Article • Journal of Fluorine Chemistry, January 2012, Elsevier

    Professor Qilong Shen

  54. ChemInform Abstract: β-(Trifluoromethyl)vinyl Sulfonium Salts: Preparation and Reactions with Active Methylene and Methenyl Compounds.

    Article • ChemInform, December 2011, Wiley

    Professor Qilong Shen

  55. The Recent Development of Organofluorine Chemistry in China: Asymmetric Construction of Stereogenic Trifluoromethyl-substituted Carbon Centers

    Article • CHIMIA International Journal for Chemistry, December 2011, Swiss Chemical Society

    Professor Qilong Shen

  56. Polyfluoroalkylation of 2-Aminothiazoles: Unexpected sp3 CCl Substitution under Mild Conditions

    Article • Chinese Journal of Chemistry, December 2011, Wiley

    Professor Qilong Shen

  57. Highly Selective Trifluoromethylation of 1,3-Disubstituted Arenes through Iridium-Catalyzed Arene Borylation

    Article • Angewandte Chemie, November 2011, Wiley

    Professor Qilong Shen

  58. Highly Selective Trifluoromethylation of 1,3-Disubstituted Arenes through Iridium-Catalyzed Arene Borylation

    Article • Angewandte Chemie International Edition, November 2011, Wiley

    Professor Qilong Shen

  59. β-(Trifluoromethyl)vinyl Sulfonium Salts: Preparation and Reactions with Active Methylene and Methenyl Compounds

    Article • The Journal of Organic Chemistry, September 2011, American Chemical Society (ACS)

    Professor Qilong Shen

  60. ChemInform Abstract: Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with an Electrophilic Trifluoromethylating Reagent.

    Article • ChemInform, August 2011, Wiley

    Professor Qilong Shen

  61. ChemInform Abstract: Enantioselective Friedel-Crafts Alkylation of Indoles with Trifluoroethylidene Malonates by Copper-Bis(oxazoline) Complexes: Construction of Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Center.

    Article • ChemInform, June 2011, Wiley

    Professor Qilong Shen

  62. Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent

    Article • Organic Letters, May 2011, American Chemical Society (ACS)

    Professor Qilong Shen

  63. Enantioselective Friedel−Crafts Alkylation of Indoles with Trifluoroethylidene Malonates by Copper−Bis(oxazoline) Complexes: Construction of Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Center

    Article • The Journal of Organic Chemistry, April 2011, American Chemical Society (ACS)

    Professor Qilong Shen

  64. ChemInform Abstract: Highly Diastereoselective Synthesis of Optically Pure Trifluoromethyl-Substituted Imidazolidine, Oxazolidine and Thiazolidine.

    Article • ChemInform, March 2011, Wiley

    Professor Qilong Shen

  65. ChemInform Abstract: Enantioselective Organocatalytic Michael Addition of Aldehydes to Trifluoroethylidene Malonates.

    Article • ChemInform, January 2011, Wiley

    Professor Qilong Shen

  66. Highly diastereoselective synthesis of optically pure trifluoromethyl-substituted imidazolidine, oxazolidine and thiazolidine

    Article • Tetrahedron Letters, January 2011, Elsevier

    Professor Qilong Shen

  67. Enantioselective Organocatalytic Michael Addition of Aldehydes to Trifluoroethylidene Malonates

    Article • Organic Letters, October 2010, American Chemical Society (ACS)

    Professor Qilong Shen

  68. ChemInform Abstract: Highly Efficient Synthesis of 1,1-Difluoro-2-substituted-1,3-dienes and Dienynes from gem-Difluorohomoallenyl Bromide via Palladium-Catalyzed Cross-Coupling Reactions.

    Article • ChemInform, May 2010, Wiley

    Professor Qilong Shen

  69. ChemInform Abstract: Regiospecific Synthesis of Bicyclo- and Heterobicyclo-gem-difluorocyclobutenes Using Functionalized Fluoroallenes and a Novel Mo-Catalyzed Intramolecular [2 + 2] Cycloaddition Reaction.

    Article • ChemInform, May 2010, Wiley

    Professor Qilong Shen

  70. ChemInform Abstract: Mechanically-Induced Chemical Changes in Polymeric Materials

    Article • ChemInform, March 2010, Wiley

    Professor Qilong Shen

  71. Synthesis of Anilines

    Article • December 2009, Wiley

    Professor Qilong Shen

  72. Mechanically-Induced Chemical Changes in Polymeric Materials

    Article • Chemical Reviews, November 2009, American Chemical Society (ACS)

    Professor Qilong Shen

  73. ChemInform Abstract: [(CyPF-tBu)PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides.

    Article • ChemInform, February 2009, Wiley

    Professor Qilong Shen

  74. ChemInform Abstract: Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides, and Iodides: Scope and Structure-Activity Relationships.

    Article • ChemInform, September 2008, Wiley

    Professor Qilong Shen

  75. [(CyPF- t Bu)PdCl 2 ]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides

    Article • Organic Letters, September 2008, American Chemical Society (ACS)

    Professor Qilong Shen

  76. Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides, and Iodides: Scope and Structure−Activity Relationships

    Article • Journal of the American Chemical Society, July 2008, American Chemical Society (ACS)

    Professor Qilong Shen

  77. Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides, and Iodides: Scope and Structure–Activity Relationships

    Article • Journal of the American Chemical Society, May 2008, American Chemical Society (ACS)

    Professor Qilong Shen

  78. Synthesis of Anilines

    Article • ChemInform, August 2007, Wiley

    Professor Qilong Shen

  79. Lewis Acid Acceleration of C−N Bond-Forming Reductive Elimination from Heteroarylpalladium Complexes and Catalytic Amidation of Heteroaryl Bromides

    Article • Journal of the American Chemical Society, June 2007, American Chemical Society (ACS)

    Professor Qilong Shen

  80. Highly Efficient and Functional-Group-Tolerant Catalysts for the Palladium-Catalyzed Coupling of Aryl Chlorides with Thiols.

    Article • ChemInform, January 2007, Wiley

    Professor Qilong Shen

  81. Palladium-Catalyzed Coupling of Ammonia and Lithium Amide with Aryl Halides.

    Article • ChemInform, December 2006, Wiley

    Professor Qilong Shen

  82. Highly Efficient and Functional-Group-Tolerant Catalysts for the Palladium-Catalyzed Coupling of Aryl Chlorides with Thiols

    Article • Chemistry - A European Journal, October 2006, Wiley

    Professor Qilong Shen

  83. Palladium-Catalyzed Coupling of Ammonia and Lithium Amide with Aryl Halides

    Article • Journal of the American Chemical Society, August 2006, American Chemical Society (ACS)

    Professor Qilong Shen

  84. A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols.

    Article • ChemInform, June 2006, Wiley

    Professor Qilong Shen

  85. A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols

    Article • Journal of the American Chemical Society, February 2006, American Chemical Society (ACS)

    Professor Qilong Shen

  86. Highly Reactive, General, and Long-Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles.

    Article • ChemInform, June 2005, Wiley

    Professor Qilong Shen

  87. Highly Reactive, General, and Long-Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles.

    Article • ChemInform, June 2005, Wiley

    Professor Qilong Shen

  88. Highly Reactive, General, and Long-Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles

    Article • Angewandte Chemie, February 2005, Wiley

    Professor Qilong Shen

  89. Highly Reactive, General, and Long-Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles

    Article • Angewandte Chemie International Edition, February 2005, Wiley

    Professor Qilong Shen

  90. Synthesis and X-Ray Information of Substituted gem-Difluoroallenyl Amines.

    Article • ChemInform, March 2003, Wiley

    Professor Qilong Shen

  91. Synthesis and X-ray information of substituted gem-difluoroallenyl amines

    Article • Journal of Fluorine Chemistry, October 2002, Elsevier

    Professor Qilong Shen

  92. Regiospecific Synthesis of Bicyclo- and Heterobicyclo- g em -difluorocyclobutenes Using Functionalized Fluoroallenes and a Novel Mo-Catalyzed Intramolecular [2 + 2] Cycloaddition Reaction

    Article • Journal of the American Chemical Society, June 2002, American Chemical Society (ACS)

    Professor Qilong Shen

  93. Highly Efficient Synthesis of 1,1-Difluoro-2-substituted-1,3-dienes and Dienynes from g em -Difluorohomoallenyl Bromide via Palladium-Catalyzed Cross-Coupling Reactions

    Article • Organic Letters, July 2001, American Chemical Society (ACS)

    Professor Qilong Shen

  94. Synthesis of Anilines

    Article • Wiley

    Professor Qilong Shen