All Stories

  1. NHC carbene supported half-sandwich hydridosilyl complexes of ruthenium: the impact of supporting ligands on Si⋯H interligand interactions

    Article • Dalton Transactions, January 2016, Royal Society of Chemistry

    Professor Georgii I Nikonov

  2. Main group catalysed reduction of unsaturated bonds

    Article • Dalton Transactions, January 2015, Royal Society of Chemistry

    Professor Georgii I Nikonov

  3. Inside Back Cover: Transfer Hydrogenation of Ketones, Nitriles, and Esters Catalyzed by a Half-Sandwich Complex of Ruthenium (ChemCatChem 1/2015)

    Article • ChemCatChem, January 2015, Wiley

    Professor Georgii I Nikonov

  4. Imido–hydrido complexes of Mo(iv): catalysis and mechanistic aspects of hydroboration reactions

    Article • Dalton Transactions, January 2015, Royal Society of Chemistry

    Professor Georgii I Nikonov

  5. Transfer Hydrogenation of Ketones, Nitriles, and Esters Catalyzed by a Half-Sandwich Complex of Ruthenium

    Article • ChemCatChem, December 2014, Wiley

    Professor Georgii I Nikonov

  6. Oxidative Addition of σ Bonds to an Al(I) Center

    Article • Journal of the American Chemical Society, June 2014, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  7. ChemInform Abstract: Base-Catalyzed Hydrosilylation of Ketones and Esters and Insight into the Mechanism.

    Article • ChemInform, June 2014, Wiley

    Professor Georgii I Nikonov

  8. Serendipitous Metal-Catalyzed H-H/Si-H Exchange

    Article • European Journal of Inorganic Chemistry, May 2014, Wiley

    Professor Georgii I Nikonov

  9. A Coordination Compound of Ge0Stabilized by a Diiminopyridine Ligand

    Article • Angewandte Chemie, February 2014, Wiley

    Professor Georgii I Nikonov

  10. A Coordination Compound of Ge0Stabilized by a Diiminopyridine Ligand

    Article • Angewandte Chemie International Edition, February 2014, Wiley

    Professor Georgii I Nikonov

  11. Group 5 hydride and borohydride complexes supported by cyclopentadienyl-imido ligand sets

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Professor Georgii I Nikonov

  12. Multiple coupling of silanes with imido complexes of Mo

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Professor Georgii I Nikonov

  13. Semi-catalytic reduction of secondary amides to imines and aldehydes

    Article • Dalton Transactions, January 2014, Royal Society of Chemistry

    Professor Georgii I Nikonov

  14. Base-Catalyzed Hydrosilylation of Ketones and Esters and Insight into the Mechanism

    Article • Chemistry - A European Journal, December 2013, Wiley

    Professor Georgii I Nikonov

  15. Catalytic H/D Exchange of Unactivated Aliphatic C–H Bonds

    Article • Organometallics, November 2013, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  16. Unexpected Role of Zinc Hydride in Catalytic Hydrosilylation of Ketones and Nitriles

    Article • ACS Catalysis, October 2013, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  17. Chemo- and Regioselective Catalytic Reduction of N-Heterocycles by Silane

    Article • Organometallics, August 2013, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  18. Unusual Structure, Fluxionality, and Reaction Mechanism of Carbonyl Hydrosilylation by Silyl Hydride Complex [(ArN)Mo(H)(SiH2Ph)(PMe3)3]

    Article • Chemistry - A European Journal, May 2013, Wiley

    Professor Georgii I Nikonov

  19. Imido-Supported Borohydrides of Titanium, Vanadium and Molybdenum

    Article • European Journal of Inorganic Chemistry, February 2013, Wiley

    Professor Georgii I Nikonov

  20. ChemInform Abstract: Chemoselective Ruthenium-Catalyzed Reduction of Acid Chlorides to Aldehydes with Dimethylphenylsilane.

    Article • ChemInform, June 2012, Wiley

    Professor Georgii I Nikonov

  21. Mechanistic Aspects of Hydrosilylation Catalyzed by (ArN=)Mo(H)(Cl)(PMe 3 ) 3

    Article • Inorganic Chemistry, April 2012, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  22. Facile Activation of H–H and Si–H Bonds by Boranes

    Article • Journal of the American Chemical Society, March 2012, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  23. Chemoselective Ruthenium-Catalyzed Reduction of Acid Chlorides to Aldehydes with Dimethylphenylsilane

    Article • Advanced Synthesis & Catalysis, February 2012, Wiley

    Professor Georgii I Nikonov

  24. An Unexpected Mechanism of Hydrosilylation by a Silyl Hydride Complex of Molybdenum

    Article • Inorganic Chemistry, January 2012, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  25. Catalytic hydroboration by an imido-hydrido complex of Mo(iv)

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Professor Georgii I Nikonov

  26. Catalytic and Stoichiometric Reactivity of β-Silylamido Agostic Complex of Mo: Intermediacy of a Silanimine Complex and Applications to Multicomponent Coupling

    Article • Journal of the American Chemical Society, May 2011, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  27. Nonhydride Mechanism of Metal-Catalyzed Hydrosilylation

    Article • Journal of the American Chemical Society, May 2011, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  28. ChemInform Abstract: Chemoselective Catalytic Hydrosilylation of Nitriles.

    Article • ChemInform, January 2011, Wiley

    Professor Georgii I Nikonov

  29. Facile Catalytic Hydrosilylation of Pyridines

    Article • Angewandte Chemie, January 2011, Wiley

    Professor Georgii I Nikonov

  30. Facile Catalytic Hydrosilylation of Pyridines

    Article • Angewandte Chemie International Edition, January 2011, Wiley

    Professor Georgii I Nikonov

  31. Chemoselective Catalytic Hydrosilylation of Nitriles

    Article • Angewandte Chemie, September 2010, Wiley

    Professor Georgii I Nikonov

  32. Chemoselective Catalytic Hydrosilylation of Nitriles

    Article • Angewandte Chemie International Edition, September 2010, Wiley

    Professor Georgii I Nikonov

  33. ChemInform Abstract: Going Beyond σ Complexation: Nonclassical Interligand Interactions of Silyl Groups with Two and More Hydrides

    Article • ChemInform, May 2010, Wiley

    Professor Georgii I Nikonov

  34. Cationic Silane σ-Complexes of Ruthenium with Relevance to Catalysis

    Article • Journal of the American Chemical Society, May 2010, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  35. The unexpected mechanism of carbonyl hydrosilylation catalyzed by (Cp)(ArN)Mo(H)(PMe3)

    Article • Chemical Communications, January 2010, Royal Society of Chemistry

    Professor Georgii I Nikonov

  36. Phosphido-bridged Ta/Rh bimetallic complex: synthesis, structure, and catalytic hydrosilylation of acetophenone

    Article • Dalton Transactions, January 2010, Royal Society of Chemistry

    Professor Georgii I Nikonov

  37. β-Agostic Silylamido and Silyl-Hydrido Compounds of Molybdenum and Tungsten †

    Article • Inorganic Chemistry, October 2009, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  38. Niobium/Rhodium Bimetallic Complexes: Synthesis, Structure, and Catalytic Hydrosilylation of Acetophenone and Benzaldehyde

    Article • Organometallics, August 2009, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  39. Steric and Electronic Effects in Half-Sandwich Ruthenium Silane σ-Complexes with Si−H and Si−Cl Interligand Interactions †

    Article • Organometallics, May 2009, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  40. Dynamics of Si−H−Si Bridges in Agostically Stabilized Silylium Ions

    Article • The Journal of Physical Chemistry A, February 2009, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  41. Diversity of Catalysis by an Imido-Hydrido Complex of Molybdenum. Mechanism of Carbonyl Hydrosilylation and Silane Alcoholysis

    Article • Journal of the American Chemical Society, January 2009, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  42. Silyl Hydrides of Tantalum Supported by Cyclopentadienyl-imido Ligand Sets: Syntheses, X-ray, NMR, and DFT Studies

    Article • Organometallics, November 2008, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  43. Agostic NSiH⋅⋅⋅Mo Complexes: From Curiosity to Catalysis

    Article • Angewandte Chemie International Edition, September 2008, Wiley

    Professor Georgii I Nikonov

  44. Agostic NSiH⋅⋅⋅Mo Complexes: From Curiosity to Catalysis

    Article • Angewandte Chemie International Edition, September 2008, Wiley

    Professor Georgii I Nikonov

  45. Cp(Pr i 2 MeP)FeH 2 SiR 3 :  Nonclassical Iron Silyl Dihydride

    Article • Journal of the American Chemical Society, March 2008, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  46. Synthesis and Molecular and Electronic Structure of an Unusual Paramagnetic Borohydride Complex Mo(NAr) 2 (PMe 3 ) 2 (η 2 -BH 4 ) †

    Article • Inorganic Chemistry, February 2008, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  47. Unexpected effect of the ring on the extent of Si⋯H interligand interactions in half-sandwich silyl hydrides of ruthenium

    Article • Dalton Transactions, January 2008, Royal Society of Chemistry

    Professor Georgii I Nikonov

  48. Half-sandwich trihydrido ruthenium complexes

    Article • Journal of Organometallic Chemistry, October 2007, Elsevier

    Professor Georgii I Nikonov

  49. Non-Innocent Behaviour of Imido Ligands in the Reactions of Silanes with Half-Sandwich Imido Complexes of Nb and V: A Silane/Imido Coupling Route to Compounds with Nonclassical SiH Interactions

    Article • Chemistry - A European Journal, September 2007, Wiley

    Professor Georgii I Nikonov

  50. Rhodium Silyl Hydrides in Oxidation State +5:  Classical or Nonclassical? †

    Article • Organometallics, August 2007, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  51. Persistent Silylium Ions Stabilized by Polyagostic SiH⋅⋅⋅Si Interactions

    Article • Angewandte Chemie, June 2007, Wiley

    Professor Georgii I Nikonov

  52. Persistent Silylium Ions Stabilized by Polyagostic SiH⋅⋅⋅Si Interactions

    Article • Angewandte Chemie International Edition, June 2007, Wiley

    Professor Georgii I Nikonov

  53. Synthesis and structural studies of germyl and germyl/stannyl substituted tungstenocenes

    Article • Dalton Transactions, January 2007, Royal Society of Chemistry

    Professor Georgii I Nikonov

  54. Syntheses and Structures of Asymmetric Bis(silyl) Niobocene Hydrides

    Article • Inorganic Chemistry, January 2007, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  55. Unique {H(SiR3)2}, (H2SiR3), H(HSiR3), and (H2)SiR3 Ligand Sets Supported by the {Fe(Cp)(L)} Platform (L=CO, PR3)

    Article • Chemistry - A European Journal, November 2006, Wiley

    Professor Georgii I Nikonov

  56. Recent Advances in Nonclassical Interligand Si×××H Interactions

    Article • ChemInform, April 2006, Wiley

    Professor Georgii I Nikonov

  57. Agostic versus Hypervalent Si-H Interactions in Half-Sandwich Complexes of Nb and Ta

    Article • ChemInform, April 2005, Wiley

    Professor Georgii I Nikonov

  58. Syntheses and X-ray Diffraction Studies of Half-Sandwich Hydridosilyl Complexes of Ruthenium

    Article • Organometallics, February 2005, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  59. Cp*(iPr3P)Ru(Cl)(η2-HSiClMe2): the first complex with simultaneous Si–H and RuCl⋯SiCl inter-ligand interactions

    Article • Chemical Communications, January 2005, Royal Society of Chemistry

    Professor Georgii I Nikonov

  60. Recent Advances in Nonclassical Interligand Si…H Interactions

    Article • January 2005, Elsevier

    Professor Georgii I Nikonov

  61. Nonclassical Titanocene Silyl Hydrides

    Article • Chemistry - A European Journal, October 2004, Wiley

    Professor Georgii I Nikonov

  62. Neutron and X-ray Diffraction Studies and DFT Calculations of Asymmetric Bis(silyl) Niobocene Hydrides

    Article • Organometallics, June 2004, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  63. First Investigation of Non-Classical Dihydrogen Bonding between an Early Transition-Metal Hydride and Alcohols: IR, NMR, and DFT Approach

    Article • Chemistry - A European Journal, February 2004, Wiley

    Professor Georgii I Nikonov

  64. Direct Hydride/Silyl Exchange— Synthesis and X-ray Study of the Bis(silyl) Complex [Cp2NbH(SiCl3)2]

    Article • European Journal of Inorganic Chemistry, February 2004, Wiley

    Professor Georgii I Nikonov

  65. Unexpected features of stretched Si–H⋯Mo β-agostic interactions

    Article • Chemical Communications, January 2004, Royal Society of Chemistry

    Professor Georgii I Nikonov

  66. Complexation of Si—Si σ Bonds to Metals

    Article • ChemInform, July 2003, Wiley

    Professor Georgii I Nikonov

  67. Bis(germyl)-Substituted Niobocenes

    Article • Organometallics, May 2003, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  68. The Puzzle of Cp(CO) 2 Mn(HSiCl 3 ):  Classical or Nonclassical?

    Article • Organometallics, April 2003, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  69. Komplexierung von Si-Si-σ-Bindungen an Metallzentren

    Article • Angewandte Chemie International Edition, March 2003, Wiley

    Professor Georgii I Nikonov

  70. Complexation of SiSi σ Bonds to Metals

    Article • Angewandte Chemie International Edition, March 2003, Wiley

    Professor Georgii I Nikonov

  71. Tantalizing Chemistry of the Half-Sandwich Silylhydride Complexes of Niobium:  Identification of Likely Intermediates on the Way to Agostic Complexes

    Article • Inorganic Chemistry, January 2003, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  72. Are J (Si−H) NMR Coupling Constants Really a Probe for the Existence of Nonclassical H−Si Interactions?

    Article • Journal of the American Chemical Society, January 2003, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  73. Niobocene hydrides with functionalised silyl ligands. Tuning of interligand hypervalent interactions (IHI) M–H → Si–X

    Article • Journal of the Chemical Society Dalton Transactions, July 2002, Royal Society of Chemistry

    Professor Georgii I Nikonov

  74. Buchbesprechung: Metal Dihydrogen and σ-Bond Complexes. Von Gregory J. Kubas

    Article • Angewandte Chemie, April 2002, Wiley

    Professor Georgii I Nikonov

  75. Book Review: Metal Dihydrogen and σ-Bond Complexes. By Gregory J. Kubas

    Article • Angewandte Chemie International Edition, April 2002, Wiley

    Professor Georgii I Nikonov

  76. Serendipitous syntheses and structures of [Cp2Nb(H){(SiMe2)2(µ-NR)}]Electronic supplementary information (ESI) available: experimental section. Fig. 1S and Table 1S. See http://www.rsc.org/suppdata/cc/b1/b111636c/ Dedicated to Prof. Dr J. Lorberth on t...

    Article • Chemical Communications, February 2002, Royal Society of Chemistry

    Professor Georgii I Nikonov

  77. New types of non-classical interligand interactions involving silicon based ligands

    Article • Journal of Organometallic Chemistry, October 2001, Elsevier

    Professor Georgii I Nikonov

  78. Die Welt jenseits der σ-Komplexierung: nichtklassische Interligand-Wechselwirkungen von Silylgruppen mit zwei und mehr Hydriden

    Article • Angewandte Chemie, September 2001, Wiley

    Professor Georgii I Nikonov

  79. Reactions of Cp(NAr)NbMe2 with H2 and HSiMe2Cl. Molecular structure of [CpNb(μ-NAr)Me]2 (Ar=2,6-C6H3iPr2)

    Article • Journal of Organometallic Chemistry, May 2001, Elsevier

    Professor Georgii I Nikonov

  80. Surprising diversity of non-classical silicon–hydrogen interactions in half-sandwich complexes of Nb and Ta: M–H ⋯ Si–Cl interligand hypervalent interaction (IHI) versus stretched and unstretched β-Si–H⋯M agostic bonding†

    Article • Journal of the Chemical Society Dalton Transactions, January 2001, Royal Society of Chemistry

    Alexander John Blake, Professor Georgii I Nikonov

  81. Contrasting Nonclassical Silicon−Hydrogen Interactions in Niobium and Tantalum Half-Sandwich Complexes: Si−H···M Agostic versus M−H···Si−Cl Interligand Hypervalent Interactions

    Article • European Journal of Inorganic Chemistry, September 2000, Wiley

    Alexander John Blake, Professor Georgii I Nikonov

  82. Contrasting Nonclassical Silicon−Hydrogen Interactions in Niobium and Tantalum Half-Sandwich Complexes: Si−H···M Agostic versus M−H···Si−Cl Interligand Hypervalent Interactions

    Article • European Journal of Inorganic Chemistry, September 2000, Wiley

    Alexander John Blake, Professor Georgii I Nikonov

  83. Fine tuning of Si–H interligand hypervalent interactions (IHI) in half-sandwich silyl hydrido complexes of ruthenium

    Article • Inorganic Chemistry Communications, March 2000, Elsevier

    Professor Georgii I Nikonov

  84. Combined single crystal neutron diffraction and solution NMR relaxation studies of mono- and bis(silyl) substituted niobocene hydrides with nonclassical interligand interactions

    Article • Journal of the Chemical Society Dalton Transactions, January 2000, Royal Society of Chemistry

    Professor Georgii I Nikonov

  85. Niobocene Silyl Hydride Complexes with Nonclassical Interligand Hypervalent Interactions

    Article • Chemistry - A European Journal, October 1999, Wiley

    Professor Georgii I Nikonov

  86. Niobocene Silyl Hydride Complexes with Nonclassical Interligand Hypervalent Interactions

    Article • Chemistry - A European Journal, October 1999, Wiley

    Professor Georgii I Nikonov

  87. Facile Preparation of Mono- and Bis(tin)-Substituted Niobocenes with Functionalized Stannyl Ligands: The Search for Non-Classical Interligand Interactions

    Article • European Journal of Inorganic Chemistry, May 1999, Wiley

    Professor Georgii I Nikonov

  88. Facile Preparation of Mono- and Bis(tin)-Substituted Niobocenes with Functionalized Stannyl Ligands: The Search for Non-Classical Interligand Interactions

    Article • European Journal of Inorganic Chemistry, May 1999, Wiley

    Professor Georgii I Nikonov

  89. Synthesis and structure of the phosphinophosphide niobocene complex Cp2Nb(PPh2)(PHPh2)

    Article • Polyhedron, March 1999, Elsevier

    Professor Georgii I Nikonov

  90. Cycloaddition reactions of titanium and zirconium imido, oxo and hydrazido complexes supported by tetraaza macrocyclic ligands ‡

    Article • Journal of the Chemical Society Dalton Transactions, January 1999, Royal Society of Chemistry

    Alexander John Blake, Professor Georgii I Nikonov

  91. Metal−Hydride and Hydride−Hydride Distances from Measurements of Selective and Nonselective 1 H T 1 Relaxation Times of Hydride Ligands:  Relaxation in NbCp 2 H 3

    Article • Inorganic Chemistry, January 1998, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  92. Monoarsenic, diarsenic and mixed phosphorus—arsenic substituted niobocenes

    Article • Journal of Organometallic Chemistry, December 1997, Elsevier

    Alexander John Blake, Professor Georgii I Nikonov

  93. Synthesis and Structure of Trimethyllead Niobocene Dihydride

    Article • Chemische Berichte, November 1997, Wiley

    Professor Georgii I Nikonov

  94. The carbenoid nature of halophosphines. Carbene-like insertion mechanism in the reaction of chlorophosphines with Cp2NbH3

    Article • Journal of Organometallic Chemistry, November 1997, Elsevier

    Professor Georgii I Nikonov

  95. Cp 2 NbH 2 SbPh 2 :  Synthesis and Structure of the First Antimony-Substituted Niobocene

    Article • Organometallics, August 1997, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  96. The first bismuthido-substituted niobocene

    Article • Polyhedron, May 1996, Elsevier

    Professor Georgii I Nikonov

  97. Cycloaddition reactions of tetraaza macrocycle supported group 4 imido complexes and reversible addition of aryl isocyanate to a coordinated ureate ligand

    Article • Chemical Communications, January 1996, Royal Society of Chemistry

    Alexander John Blake, Professor Georgii I Nikonov

  98. Interligand Hypervalent Interaction in the Bis(silyl) Hydride Derivatives of Niobocene J . Am . Chem . Soc . 1995 , 117 , 10133

    Article • Journal of the American Chemical Society, January 1996, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  99. Interligand Hypervalent Interaction in the Bis(silyl) Hydride Derivatives of Niobocene

    Article • Journal of the American Chemical Society, October 1995, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  100. Insertion of ClPPh2 into a Ta-H bond: Synthesis and Structure of the First Phosphido Derivative of Tantalocene

    Article • Organometallics, July 1995, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  101. Unprecedented formation of ethylene during the synthesis of a NbRh bimetallic complex: molecular structure of Cp′2Nb(μ-PPh2)2RhC2H4

    Article • Journal of Organometallic Chemistry, July 1995, Elsevier

    Professor Georgii I Nikonov

  102. The First Arsenido-Substituted Niobocene Derivative

    Article • Inorganic Chemistry, April 1995, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  103. Facile Insertion of ClPPh2 into Nb-H Bonds as a Synthetic Route to New Phosphino and Phosphido Derivatives of Niobocene

    Article • Organometallics, August 1994, American Chemical Society (ACS)

    Professor Georgii I Nikonov

  104. Agostic versus Hypervalent Si-H Interactions in Half-Sandwich Complexes of Nb and Ta

    Article • Wiley

    Professor Georgii I Nikonov

  105. Agostic versus Hypervalent Si-H Interactions in Half-Sandwich Complexes of Nb and Ta

    Article • Wiley

    Professor Georgii I Nikonov