All Stories

  1. Studies on the structural diversity of MOFs containing octahedral siloxane-backboned connectors
  2. Tetramethyl Orthosilicate (TMOS) as a Reagent for Direct Amidation of Carboxylic Acids
  3. Chemical and biological assessment of metal organic frameworks (MOFs) in pulmonary cells and in an acute in vivo model: relevance to pulmonary arterial hypertension therapy
  4. Study on Gas Permeation and CO2 Separation through Ionic Liquid-Based Membranes with Siloxane-Functionalized Cations
  5. Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs
  6. A New NO-Releasing Nanoformulation for the Treatment of Pulmonary Arterial Hypertension
  7. Structures of Tetrasilylmethane Derivatives (XMe 2 Si) 2 C(SiMe 3 ) 2 (X = H, Cl, Br) in the Gas Phase, and their Dynamic Structures in Solution
  8. Silicone reaction solvents
  9. ChemInform Abstract: Preparation and Characterization of Polyhedral Oligosilsesquioxanes
  10. Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand
  11. Preparation of [Al(hfip)4]−-Based Ionic Liquids with Siloxane-Functionalized Cations and Their Physical Properties in Comparison with Their [Tf2N]−Analogues
  12. An organosilicon hexacarboxylic acid and its use in the construction of a novel metal organic framework isoreticular to MOF-5
  13. Silicon: Inorganic Chemistry
  14. The Gas-Phase Equilibrium Structures of Si 8 O 12 (OSiMe 3 ) 8 and Si 8 O 12 (CHCH 2 ) 8
  15. MgII, CaII, and CoII Metal-Organic Framework Materials with [Si(p-C6H4CO2)3(p-C6H4CO2H)]3? Struts
  16. Preparation and Characterization of Polyhedral Oligosilsesquioxanes
  17. Structural Diversity in Metal−Organic Frameworks Built from Rigid Tetrahedral [Si( p- C 6 H 4 CO 2 ) 4 ] 4− Struts
  18. ChemInform Abstract: Silicenium Ions: Experimental Aspects
  19. Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes
  20. The gas-phase structure and some reactions of the bulky primary silane (Me3Si)3CSiH3 and the solid-state structure of the bulky dialkyl disilane [(Me3Si)3CSiH2]2
  21. The gas-phase structure of octaphenyloctasilsesquioxane Si8O12Ph8 and the crystal structures of Si8O12(p-tolyl)8 and Si8O12(p-ClCH2C6H4)8
  22. Understanding siloxane functionalised ionic liquids
  23. Polysilanols
  24. Silicenium Ions-Experimental Aspects
  25. The structure of a small polyhedral molecule in the gas phase
  26. ChemInform Abstract: Fully Condensed Polyhedral Oligosilsesquioxanes (POSS): From Synthesis to Application
  27. The gas-phase structure of the decasilsesquioxane Si10O15H10
  28. Accurate Gas-Phase Experimental Structures of Octasilsesquioxanes (Si 8 O 12 X 8 ; X = H, Me)
  29. Fully Condensed Polyhedral Oligosilsesquioxanes (POSS): From Synthesis to Application
  30. Degradation of X-Ray Contrast Media Compounds by Combined Ozone and Ultrasound
  31. Framework materials assembled from magnesium carboxylate building units
  32. Silicon: Inorganic Chemistry
  33. Isolation and structure of a silicocationic species with 1,3-aryl bridging between silicon atoms: a bis-silylated benzenium ion or a bridging Ph group?
  34. Variable coordination behaviour of N-donor siloxane ligands. The structures of [M(1,3-bis(N-imidazoyl)propyl-1,1,3,3-tetramethyldisiloxane)2(NCS)2] (M=Mn, Ni) and [Ni(1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane)2(NCS)2]
  35. Diversity of polymeric structures for copper complexes of the extended-reach siloxypyridine ligands [iPr2SiO(CH2)npy]2O (n=0,1,3)
  36. ChemInform Abstract: Ultrasound in Chemical Synthesis
  37. Reactions of the SiH bonds in tetrakis(dimethylsilyl)methane and silane
  38. Crystal and molecular structures of 4,4′-bis(dimethylhydroxysilyl)-biphenyl and m-bis(dimethylhydroxysilyl)benzene
  39. Tris(trimethylsilyl)siloxides of gadolinium and lanthanum: synthesis, structure and some properties
  40. The synthesis of C[Si(CH3)2X]3SiX3 compounds (X = H, Cl, Br and OH) and the molecular structure of C[Si(CH3)2H]3SiH3 in the gas phase; a study by electron diffraction and ab initio molecular orbital calculations †
  41. Structures of Ga(hfac)3 and In(hfac)3 (hfac = 1,1,1,5,5,5-hexafluoropentane-2,4-dionate) in the gas phase as studied by electron diffraction and ab initio calculations †
  42. Organometallic compounds of bivalent tin
  43. Book review: Metal-Ligand Interactions?Structure and Reactivity, N. Russo and D. R. Salahub (eds) Kluwer Academic, Dordrecht, 1995. xiv+552 pages. UK price: �169, hardback. ISBN 0-7923-3833-2
  44. Oxidation of sterically hindered organosilicon hydrides using potassium permanganate
  45. Ultrasonic activation of SiO2 and GeO2 in basic solutions of diols
  46. Rate increases in the fluorination of bulky chlorosilanes caused by ultrasound or by water
  47. Preparation, spectroscopic properties and thermal stabilities of organomercury compounds containing the bulky ligand (Me3Si)3C or (PhMe2Si)3C
  48. EPR spectra of tris(trimethylsilyl)methyl(hydroxy)silyl radicals, (Me3Si)3CSi(R)OH˙, and of tris(trimethylsilyl)methylsilanone radical anions, (Me3Si)3CSi(R)O˙–(R = H, Me, Et, Bu, Ph, F)
  49. The breakdown of polymeric tin fluorides under the influence of ultrasound
  50. Rates of solvolysis of the compounds (Me3Si) 2(Ph2MeSi) CSiMe2X, X  I, OSO2 CF3 and OCN. Mechanistic implications
  51. The Synthesis and Structure of Organosilanols
  52. A study by gas-phase electron diffraction of tert-butyldimethylsilanol and its hemihydrate
  53. Preparation of the iodides (Me3Si)2C(SiMe2C6H4Y)(SiMe2I) and some related compounds
  54. Anchimeric assistance by the acetoxy group in the solvolysis of (Me3Si)2C(SiMe2-OCOMe)(SiMe2X), X = Cl, NCS or N3
  55. The plasma enhanced chemical vapour deposition of CuInSe2
  56. Reactions of compounds of the type (Me3Si)2C(SiMe2C6H4Y)(SiMe2X) with trifluoroacetic acid
  57. Reactions of the highly sterically hindered compounds (Me3Si)3CSiMe2X (X  Cl, Br, I, or ONO2) with NaN3, CsF, KSCN, and KOCN in MeOH
  58. The chemical vapour deposition of indium and copper/indium alloys from metal hexafluoracetylacetonate complexes
  59. The crystal structure of (HOMe2Si)2O
  60. Crystal structure of [Li(tmen)2][Li{C(SiMe3)3}2]. A multinuclear magnetic resonance study of tris(trimethylsilyl)methyllithium–tetrahydrofuran(1/2) and –N,N,N′,N′-tetramethylethylenediamine (1/1)(tmen)
  61. Proportion of 1,3-phenyl migration in trifluoroethanolysis, methanolysis, and hydrolysis of (Me3Si)2C(SiMe2Ph)(SiEt2I)
  62. 1,3-Migration of chloride and azide ligands in reactions of highly sterically hindered organosilicon halides
  63. Reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4. 1,3-Migration of the phenyl group
  64. 4-Methyl-1,2,3-selenadiazole: a liquid selenium source for the low-temperature chemical vapour deposition of selenium-containing materials
  65. Advances in sonochemistry, volume 2
  66. Preparation and reactions of some organosilicon cyanates
  67. Structure and dynamics of hindered organosilicon compounds. The conformations of symmetrical (Me3Si)3C and (PhMe2Si)3C derivatives
  68. Anchimeric assistance by γ-aryl groups in reactions of organosilicon iodides
  69. The methanolysis of the highly sterically hindered organosilicon compounds (Me3Si)3CSiMe2X with X = OSO2CF3, OCN or OClO3. A mechanistic enigma
  70. Transition metal complexes of silylenes, silenes, disilenes, and related species
  71. Dalton perspectives. Do R3Si+ ions exist in solution?
  72. The recycling of organosilyl protecting species used in organic synthesis and the water binding ability of the silanol 1BuMe2SiOH
  73. Sonochemistry: The Uses of Ultrasound in Chemistry
  74. Preparation and reactions of tris(trimethylsilyl)silyl silicon derivatives and related tetrasilylsilanes
  75. Isolation of a tetrahydroxydisiloxane formed during hydrolysis of an alkyltrichlorosilane: crystal and molecular structure of [But(OH)2Si]2O
  76. Comparison of the reactivities of the compounds (Me3Si)2C(SiMe2OMe)(SiMe2Cl) and (MeOMe2Si)3C(SiMe2Cl). Crystal structure of (MeOMe2Si)3CSiPh2H
  77. Synthesis and crystal structure of the crowded disiloxane [{(Me3Si)3C}Cl2Si]2O
  78. 1,3-Migration of triorganosilyl groups from carbon to oxygen in highly crowded organosilanols
  79. Hydrogen-bonding in organosilanediols. The crystal structure of bis(pentamethylcyclopentadienyl)silanediol
  80. Hydrogen-bonding in organosilanetriols. The crystal structures of tris(trimethylsilyl)silyl- and tris(trimethylsilyl)-methyl-silanetriols
  81. Crystal structures of four sterically crowded 1,3-disilacyclobutanes
  82. Hydrogen bonding in organosilanediols. The crystal structure of di-o-tolylsilanediol
  83. Anchimeric assistance by γ-aryl groups in solvolysis of organosilicon iodides. Some remarkably large remote substituent effects
  84. Tris(trimethylsilyl)methyl and tris(dimethylphenylsilyl)methyl derivatives of boron. Crystal structures of dihydroxy[tris(trimethylsilyl)methyl]borane and of the lithium–boron complex [(MeOH)2Li(µ-OMe)2B(OMe)2]
  85. The crystal structure of tetrakis(hydroxydimethylsilyl)methane. A remarkable three-dimensional hydrogen-bonded network
  86. Structure and dynamics of hindered organosilicon compounds. The conformation and enantiotopomerization of (chlorodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane
  87. Preparation and X-ray crystal structure of an unusual bicyclic trisilane-tris(disoloxane)
  88. Reactions of the sterically hindered organosilicon diol (Me3Si)2C(SiMe2OH)2 and some of its derivatives
  89. The nature of the anchimeric assistance by the acetoxy group in solvolysis of (Me3Si)2C(SiMe2)OCOMe) (SiMe2Cl)
  90. Modern NMR Techniques for Chemistry Research
  91. Reactions of tris(trimethylsilyl)methylsilicon compounds with organolithium reagents
  92. Effects of the substituents Y in reactions of compounds of the type (Me3Si)3CSiH(C6H4Y-p)I. Evidence against the SN2(intermediate) mechanism for methanolysis of (Me3Si)3CSiMe2I and (Me3Si)3CSiHPhI
  93. 1,3-Migration of a phenyl group via a silicocation
  94. Migration of the methoxy group in an organosilicon cation. Reactions of (bromodiphenylsilyl)(methoxydimethylsiyl)bis(trimethylsilyl) methane with silver borofluoride and silver chloride. Crystal structure of (chlordiphenylsilyl)(methoxydimethylsilyl)bi...
  95. 1,3 Silicon to silicon migration of the methoxy group in solvolysis of (bromodiphenylsilyl)(methoxydimethylsilyl)bis(trimethylsilyl)methane. Crystal structures of (ethoxydimethylsilyl)(methoxydiphenylsilyl)bis(trimethylsilyl)-methane and (methoxydimeth...
  96. 1,3-Migration of chloride and azide substituents within organosilicon cations, and anchimeric assistance by the azido group
  97. The preparation of the sterically hindered alcohol tris(trimethylsilyl)methanol
  98. Hydrogen bonding in organosilanediols. The crystal structure of di-i-propylsilanediol
  99. Hydrogen bonding in organosilicon hydroxides: crystal structures of dicyclohexylsilanediol and bis(hydroxydimethylsilyl)bis(trimethylsilyl)methane
  100. Some tetrasilylmethane derivatives
  101. Photoisomerization of a highly substituted silene
  102. The crystal structure of [tris(trimethylsilyl)methyl]silanetriol. A novel and remarkably stable hydrogen-bonded cage structure
  103. Unimolecular alcoholysis of organosilicon halides of the type (Me3Si)2C(SiMe2OMe)(SiR′2X). Anchimeric assistance by and migration of the OMe group
  104. The crystal structure of tris(phenyldimethylsilyl)methane
  105. Tetrakis(hydroxydimethylsilyl)methane and its dehydration with rearrangement. Crystal structure of 2,2,4,4,6,6-hexamethyl-5-(hydroxydimethylsilyl)-1,3-dioxa-2,4,6-trisilacyclohexane
  106. Crystal structure and variable-temperature hydrogen-1 nuclear magnetic resonance spectrum of (dimethylnitratosilyl)[methyldiphenylsilyl]bis(trimethylsilyl)methane, C(SiMe3)2(SiMePh2)(SiMe2 ONO2)
  107. Cleavage of silicon–carbon bonds in tris(trimethylsilyl)methylsilicon compounds by trifluoroacetic acid. Rearrangements and anchimeric assistance
  108. Some derivatives of tris(dimethylsilyl)methane. A novel bicyclic tris(disiloxane) with a manxane structure
  109. [Tris(trimethylsllyl)methyl](dimethyl)silyl cyanate. The cyanate to isocyanate isomerization, and the high activity of cyanate as a leaving group in solvolysis
  110. (Dimethyl)[tris(trimethylsilyl)methyl]silyl cyanate and related species: the first silicon cyanates
  111. The molecular structure of [dimethyl(phenyl)silyl]tris(trimethylsilyl)methane
  112. Some Surprising Chemistry of Sterically Hindered Silanols
  113. Some Surprising Chemistry of Sterically Hindered Silanols
  114. Polysilanols
  115. Silicenium Ions—Experimental Aspects
  116. Synthesis and Chemistry of Some Bridged Silicocations
  117. Synthesis and Chemistry of Some Bridged Silicocations
  118. Metal Complexes Containing Extended-Reach Siloxypyridine and Related Ligands
  119. Metal Complexes Containing Extended-Reach Siloxypyridine and Related Ligands