All Stories

  1. Machine learning studies on asymmetric relay Heck reaction—Potential avenues for reaction development
  2. Rational design of catalysts for asymmetric diamination reaction using transition state modeling
  3. The mechanism of catalytic methylation of 2-phenylpyridine using di-tert-butyl peroxide
  4. Deciphering the origin of cooperative catalysis by dirhodium acetate and chiral spiro phosphoric acid in an asymmetric amination reaction
  5. Microsolvated transition state models for improved insight into chemical properties and reaction mechanisms
  6. Mechanistic insights on platinum- and palladium-pincer catalyzed coupling and cyclopropanation reactions between olefins
  7. Conformational mapping and energetics of saccharide–aromatic residue interactions: implications for the discrimination of anomers and epimers and in protein engineering
  8. Stereocontrol in proline-catalyzed asymmetric amination: a comparative assessment of the role of enamine carboxylic acid and enamine carboxylate
  9. Quantification of binding affinities of essential sugars with a tryptophan analogue and the ubiquitous role of C–H⋯π interactions
  10. Mechanism and electronic effects in nitrogen ylide-promoted asymmetric aziridination reaction
  11. Ni-, Pd-, or Pt-catalyzed ethylene dimerization: a mechanistic description of the catalytic cycle and the active species
  12. Unraveling high precision stereocontrol in a triple cascade organocatalytic reaction
  13. Retro Diels–Alder reaction under mild conditions: experimental and theoretical studies