All Stories

  1. Validating the alkene and alkyne hydrophosphonylation as an entry to organophosphonates
  2. Metal-free synthesis of E-vinylphosphonates via photoinduced alkyne hydrophosphonylation and thiol promoted isomerization sequence
  3. Synthesis and biological properties of multivalent iminosugars
  4. Synthesis and glycosidase inhibition properties of triazole-linked calixarene–iminosugar clusters
  5. Synthesis of Galactoclusters by Metal-Free Thiol “Click Chemistry” and Their Binding Affinities forPseudomonas aeruginosaLectin LecA
  6. Thiol-ene and thiol-yne-based synthesis of glycodendrimers as nanomolar inhibitors of wheat germ agglutinin
  7. Metal-Catalyzed and Metal-Free Alkyne Hydrothiolation: Synthetic Aspects and Application Trends
  8. Discussion Addendum for: Diastereoselective Homologation of D-(R)-Glyceraldehyde Acetonide Using 2-(Trimethylsilyl)thiazole: 2-O-Benzyl-3,4-isopropylidene-D-erythrose
  9. Chapter 9. Electrochemical glycosylation
  10. Oxime Ligation: A Chemoselective Click-Type Reaction for Accessing Multifunctional Biomolecular Constructs
  11. Synthesis of rapamycin glycoconjugates via a CuAAC-based approach
  12. Efficiency of the Free-Radical Hydrophosphonylation of Alkenes: The Photoinduced Reaction of DimethylH-Phosphonate with Enopyranoses as an Exemplary Case
  13. Multivalent presentation of a hydrolytically stable GM3 lactone mimetic as modulator of melanoma cells motility and adhesion
  14. Free-Radical Thiol-Ene and Thiol-Yne Couplings as Click Processes for Glycoconjugation
  15. Thiyl Glycosylation of Propargylated Octasilsesquioxane: Synthesis and Lectin-Binding Properties of Densely Glycosylated Clusters on a Cubic Platform
  16. Tetravalent glycocyclopeptide with nanomolar affinity to wheat germ agglutinin
  17. Conformational Constraints: Nature Does It Best with Sialyl Lewisx
  18. Free-radical hydrothiolation of glycals: a thiol-ene-based synthesis of S-disaccharides
  19. Recent applications of thiol–ene coupling as a click process for glycoconjugation
  20. Glycoside and peptide clustering around the octasilsesquioxane scaffold via photoinduced free-radical thiol–ene coupling. The observation of a striking glycoside cluster effect
  21. Exhaustive glycosylation, pegylation, and glutathionylation of a [G4]-ene48 dendrimer via photoinduced thiol-ene coupling
  22. Sugar-Derived Ionic Liquids
  23. Multi-molecule reaction of serum albumin can occur through thiol-yne coupling
  24. Convergent synthesis and inclusion properties of novel Cn-symmetric triazole-linked cycloglucopyranosides
  25. Synthesis of S-glycosyl amino acids and S-glycopeptides via photoinduced click thiol–ene coupling
  26. Modular Approach to Triazole-Linked 1,6-α- d -Oligomannosides to the Discovery of Inhibitors of Mycobacterium tuberculosis Cell Wall Synthetase
  27. Calixarene and Calixresorcarene Glycosides: Their Synthesis and Biological Applications
  28. Photoinduced Addition of Glycosyl Thiols to Alkynyl Peptides: Use of Free-Radical Thiol−Yne Coupling for Post-Translational Double-Glycosylation of Peptides
  29. Copper(I)-Catalyzed Azide-Alkyne Cycloadditions in Ionic Liquids under Amine-Free Conditions
  30. Synthesis of Sugar-Based Silica Gels by Copper-Catalysed Azide-Alkyne Cycloaddition via a Single-Step Azido-Activated Silica Intermediate and the Use of the Gels in Hydrophilic Interaction Chromatography
  31. Immobilization of calix[4]arene-based glycoclusters on TiO2nanoparticlesvia click Cu(i)-catalyzed azide–alkyne coupling
  32. A theoretical study of the copper(i)-catalyzed 1,3-dipolar cycloaddition reaction in dabco-based ionic liquids: the anion effect on regioselectivity
  33. Synthesis and Applications of Ionic Liquids Derived from Natural Sugars
  34. Transformation of linear oligoketosides into macrocyclic neoglycoconjugates
  35. Photoinduced Thiol−Ene Coupling as a Click Ligation Tool for Thiodisaccharide Synthesis
  36. Design of Triazole-Tethered Glycoclusters Exhibiting Three Different Spatial Arrangements and Comparative Study of their Affinities towards PA-IL and RCA 120 by Using a DNA-Based Glycoarray
  37. Single and dual glycoside clustering around calix[4]arene scaffolds via click thiol–ene coupling and azide–alkyne cycloaddition
  38. Microwave-Enhanced Ionothermal CuAAC for the Synthesis of Glycoclusters on a Calix[4]arene Platform
  39. Validation of the Copper(I)-Catalyzed Azide−Alkyne Coupling in Ionic Liquids. Synthesis of a Triazole-Linked C-Disaccharide as a Case Study
  40. Synthesis of sialoclusters appended to calix[4]arene platforms via multiple azide-alkyne cycloaddition. New inhibitors of hemagglutination and cytopathic effect mediated by BK and influenza A viruses
  41. Addressing the scope of the azide–nitrile cycloaddition in glycoconjugate chemistry. The assembly of C-glycoclusters on a calix[4]arene scaffold through tetrazole spacers
  42. Direct epoxidation of d-glucal and d-galactal derivatives with in situ generated DMDO
  43. C -Glycoside Clustering on Calix[4]arene, Adamantane, and Benzene Scaffolds through 1,2,3-Triazole Linkers
  44. First synthesis of 1,2,3-triazolo-linked (1,6)-α-d-oligomannoses (triazolomannoses) by iterative Cu(i)-catalyzed alkyne–azide cycloaddition
  45. Concise and Practical Synthesis of C -Glycosyl Ketones from Sugar Benzothiazoles and Their Transformation into Chiral Tertiary Alcohols
  46. Hybrid Solution/Solid-Phase Synthesis of Oligosaccharides by Using Trichloroacetyl Isocyanate as Sequestration-Enabling Reagent of Sugar Alcohols
  47. Hybrid Solution/Solid-Phase Synthesis of Oligosaccharides by Using Trichloroacetyl Isocyanate as Sequestration-Enabling Reagent of Sugar Alcohols
  48. Synthesis and characterization of calix[4]arene-based copolyethers and polyurethanes. Ionophoric properties and extraction abilities towards metal cations of polymeric calix[4]arene urethanes
  49. Stereoselective Synthesis of α- and β- l - C -Fucosyl Aldehydes and Their Utility in the Assembly of C -Fucosides of Biological Relevance
  50. Thiazole-Mediated Synthetic Methodology
  51. Ring Enlargement of Polyhydroxylated Pyrrolidines to Piperidines by ­Mitsunobu Reaction: A Fortuitous Synthesis of 1-Deoxy- l -allonojirimycin
  52. A new synthetic approach to mycobacterial cell wall α-(1→5)-d-arabinofuranosyl C-oligosaccharides
  53. Novel Carboranyl C-Glycosides for the Treatment of Cancer by Boron Neutron Capture Therapy
  54. A Model Route Toward the Synthesis of Conformationally Constrained Polyhydroxylated Dipeptides from Natural Carbohydrates
  55. Multigram scale synthesis of formyl tetra-O-benzyl-β-d-C-glucopyranoside using benzothiazole as a formyl group equivalent
  56. Glycoside-Clustering Round Calixarenes toward the Development of Multivalent Carbohydrate Ligands. Synthesis and Conformational Analysis of Calix[4]arene O - and C -Glycoconjugates
  57. Linear Total Synthetic Routes to β- d - C -(1,6)-Linked Oligoglucoses and Oligogalactoses up to Pentaoses by Iterative Wittig Olefination Assembly.
  58. Synthesis of α- and β-Glycosyl Asparagine Ethylene Isosteres ( C -Glycosyl Asparagines) via Sugar Acetylenes and Garner Aldehyde Coupling †
  59. Linear Total Synthetic Routes to β- d - C -(1,6)-Linked Oligoglucoses and Oligogalactoses up to Pentaoses by Iterative Wittig Olefination Assembly †
  60. Synthesis of [60]fulleropyrrolidine glycoconjugates using 1,3-dipolar cycloaddition with C-glycosyl azomethine ylides
  61. Computational and experimental studies of di- and tetrasubstituted calix[4]arenes
  62. Synthesis of All Carbon Linked Glycoside Clusters Round Benzene Scaffold via Sonogashira-Heck-Cassar Cross-Coupling of Iodobenzenes with Ethynyl C-Glycosides
  63. Selectivity in the SmI2-induced deoxygenation of thiazolylketoses for formyl C-glycoside synthesis and revised structure of C-ribofuranosides
  64. First synthesis of bridged and double calixsugars
  65. Chemical Synthesis of Linear and Cyclic Unnatural Oligosaccharides by Iterative Glycosidation of Ketoses
  66. A concise C-glycosyl amino acid synthesis by alkenyl C-glycoside–vinyloxazolidine cross-metathesis. Synthesis of glycosyl serine, asparagine and hydroxynorvaline isosteres
  67. Expeditious Synthesis of β-Linked Glycosyl Serine Methylene Isosteres (β-C-Gly Ser) via Ethynylation of Sugar Lactones
  68. Methods for Anomeric Carbon-Linked and Fused Sugar Amino Acid Synthesis:  The Gateway to Artificial Glycopeptides
  69. Convergent synthesis of pyrrolidine-based (1→6)- and (1→5)-aza-C-disaccharides
  70. Improved iterative olefination approach to oligosaccharide mimics: stereoselective synthesis of β-(1→6)-d-galactopentaose methylene isostere
  71. General, stereoselective synthesis of ethylene isosteres of α- and β-glycosylasparagines
  72. Stereoselective synthesis of C-glycosylphosphonates from their ketols. Reconsideration of an abandoned route
  73. Stereoselective Conjugate Addition of Nitrogen and Carbon Nucleophiles to Sugar-Derived Enones: Synthesis of Sialic Acid Analogues
  74. Stereoselective Conjugate Addition of Nitrogen and Carbon Nucleophiles to Sugar-Derived Enones: Synthesis of Sialic Acid Analogues
  75. Design and Use of an Oxazolidine Silyl Enol Ether as a New Homoalanine Carbanion Equivalent for the Synthesis of Carbon-Linked Isosteres of O -Glycosyl Serine and N -Glycosyl Asparagine †
  76. Thiazolylketoses: a new class of versatile intermediates for glycoside synthesis
  77. Thiazole as Leaving Group. Thermal Elimination from Thiazolylketoses
  78. Synthesis and characterization of bisphenol-A copolyethers and copolyesters carrying calix[4]arene units in the main chains and their binding properties towards silver cations
  79. Synthesis of Calix[4]arenylvinylene and Calix[4]arenylphenylene Oligomers by Stille and Suzuki Cross-Coupling Reactions
  80. Synthesis of (1→6)-C-oligogalactosides by iterative Wittig olefination
  81. Synthesis of ethylene isosteres of β-d-galactosyl- and β-d-glucosyl-l-asparagine
  82. Synthesis of ketosyl and ulosonyl phosphonates by Arbuzov-type glycosidation of thiazolylketol acetates
  83. Stereoselective synthesis of the C-linked analogue of β-d-galactopyranosyl-l-serine
  84. Synthesis of methylene isosteres of α- and β-d-galactopyranosyl-l-serine
  85. Synthesis and Properties ofO‐Glycosyl Calix[4]Arenes (Calixsugars)
  86. The assembly of carbon-linked calixarene-carbohydrate structures (C-calixsugars) by multiple wittig olefination
  87. Carbohydrate Homologation by the Use of 2-(Trimethylsilyl)thiazole. Preparative Scale Synthesis of Rare Sugars:  l -Gulose, l -Idose, and the Disaccharide Subunit of Bleomycin A 2
  88. Synthesis and receptor properties of calix[4]arene–bisphenol-A copolymers
  89. Thiazolylketol acetates as glycosyl donors. Stereoselective synthesis of α-linked ketodisaccharides
  90. Calixsugars: † Preparation of Upper Rim O -Ketopyranosyl Calix[4]arenes †
  91. Sugar Calixarenes: Preparation of Calix[4]arenes Substituted at the Lower and Upper Rims with O‐Glycosyl Groups
  92. Zuckercalixarene: Synthese von Calix[4]arenen mitO-Glycosylsubstituenten am oberen oder unteren Rand
  93. A General Synthetic Route to Anomeric .alpha.-Azido and .alpha.-Amino Acids and Formal Synthesis of (+)-Hidantocidin
  94. Synthesis of a sialic acid analog with the acetamido group at C-4
  95. Installation of the Pyruvate Unit in Glycidic Aldehydes via a Wittig Olefination-Michael Addition Sequence Utilizing a Thiazole-Armed Carbonyl Ylide. A New Stereoselective Route to 3-Deoxy-2-Ulosonic Acids and the Total Synthesis of DAH, KDN, and 4-epi...
  96. Furan-based synthesis of C-glycosyl carboxylates
  97. C-glycofuranosides via tandem Wittig-Michael sequence using a thiazole-armed phosphorane. A route to C-furanosyl α-hydroxy propanals and propionic acids
  98. Selective Conjugate Addition of Benzylamine to 2-Thiazolyl α,β-Enone Derived from D-Glyceraldehyde Acetonide. An Exploratory Study Toward the Synthesis of Aminated Ulosonic Acids
  99. Efficacious modification of the procedure for the aldehyde release from 2-substituted thiazoles
  100. Isopropenyl glycosides and congeners as novel classes of glycosyl donors: theme and variations
  101. A novel and convenient method for the removal of a nitrate group at the anomeric position
  102. A novel class of glycosyl donors: Anomeric S-xanthates of 2-azido-2-deoxy-D-galactopyranosyl derivatives
  103. N-p-methoxybenzylidene derivatives of 2-amino-2-deoxy-d-glucose as glycosyl donors: a reinvestigation
  104. A novel stereoselective synthesis of N-acetyl-α-neuraminosyl-galactose di-saccharide derivatives, using anomeric S-glycosyl xanthates
  105. Glycosylation Using a One-Electron-Transfer Homogeneous Reagent: A Novel and Efficient Synthesis of β-Linked Disaccharides
  106. Anomeric S -Xanthates of 2-Azido-2-deoxy- D -galactopyranosyl Derivatives as Efficient Glycosyl Donors 1
  107. Synthesis of disaccharide fragments of dermatan sulfate
  108. Acetylation of N-acetylneuraminic acid and its methyl ester
  109. Preparation of pyranoid glycal derivatives from phenyl thioglycosides and glycosyl phenyl sulphones
  110. Stereoselective synthesis of 2-thioglycosides of N-acetylneuraminic acid
  111. Convenient syntheses of substituted pyranoid glycals from thiophenyl glycosides and glycosyl phenylsulfones
  112. An improved preparation of 3,4-O-isopropylidene derivatives of α- and β-d-galactopyranosides
  113. Synthesis of 2,3:4,6-di-O-isopropylidene derivatives of alkyl α- and β-d-galactopyranosides, and elucidation of structure by n.m.r. and x-ray analysis
  114. Chemical synthesis of the desialylated human Cad-antigenic determinant
  115. New results in the isopropylidenation of galactopyranosides. Useful intermediates for the synthesis of galactose derivatives.