All Stories

  1. Ethynyl‐B(dan) in [3+2] Cycloaddition and Larock Indole Synthesis: Synthesis of Stable Boron‐Containing Heteroaromatic Compounds
  2. Complexation‐Triggered Fluctuation of π‐Conjugation on an Antiaromatic Dicyanoanthracene Dianion
  3. Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines
  4. Computed ammonia affinity for evaluating Lewis acidity of organoboronates and organoboronamides
  5. Efficient one-pot synthesis of dan-substituted organo- and silyl-boron compounds
  6. Direct Suzuki‐Miyaura Coupling of Naphthalene‐1,8‐diaminato (dan)‐Substituted Cyclopropylboron Compounds
  7. Main-Group Organometallics Containing Boron or Tin that Open New Frontiers in Organic Synthesis
  8. A stable silylborane with diminished boron Lewis acidity
  9. Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes
  10. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  11. HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
  12. Borylation and Stannylation Reactions with Tuning of Lewis Acidity
  13. A leap forward in sulfonium salt and sulfur ylide chemistry
  14. Synthetic Chemistry with Lewis Acidity‐Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross‐Couplings
  15. Dithiazolylthienothiophene Bisimide-Based π-Conjugated Polymers: Improved Synthesis and Application to Organic Photovoltaics as P-Type Semiconductor
  16. Transition metal-free B(dan)-installing reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) electrophile
  17. Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons
  18. One-pot Sequential Fluorostannylation–Arylstannylation of Arynes
  19. Dithiazolylthienothiophene Bisimide: A Novel Electron-Deficient Building Unit for N-Type Semiconducting Polymers
  20. Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates
  21. Copper‐Catalyzed B(dan)‐Installing Allylic Borylation of Allylic Phosphates
  22. An anthranilamide-substituted borane [H–B(aam)]: its stability and application to iridium-catalyzed stereoselective hydroboration of alkynes
  23. Anthranilamide (aam)-substituted arylboranes in direct carbon–carbon bond-forming reactions
  24. Copper-catalyzed arylstannylation of arynes in a sequence
  25. Copper-catalyzed Borylation of Bromoaryl Triflates with Diborons: Chemoselective Replacement of an Ar–Br Bond
  26. Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer
  27. B(MIDA)-Containing Diborons
  28. NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones
  29. Naphthobispyrazine as an Electron-deficient Building Unit for π-Conjugated Polymers: Efficient Synthesis and Polymer Properties
  30. Aryne-Imine-Aryne Coupling Reaction via [4+2] Cycloaddition between Aza-o -Quinone Methides and Arynes
  31. Correction to “Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes”
  32. Ligand-Free Copper-Catalyzed Cyano- and Alkynylstannylation of Arynes
  33. Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides
  34. Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes
  35. Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)
  36. Stannylation Reactions under Base Metal Catalysis: Some Recent Advances
  37. Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments
  38. Copper Catalysis for Synthesizing Main-Group Organometallics Containing B, Sn or Si
  39. ChemInform Abstract: N-Heterocyclic Carbene-Catalyzed Double Acylation of Enones with Benzils.
  40. Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron
  41. Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide
  42. Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes
  43. Copper-Catalyzed Metallation Reactions of Unsaturated Carbon-Carbon Bonds
  44. ChemInform Abstract: Three-Component Carboboration of Alkenes under Copper Catalysis.
  45. ChemInform Abstract: A Masked Diboron in Cu-Catalyzed Borylation Reaction: Highly Regioselective Formal Hydroboration of Alkynes for Synthesis of Branched Alkenylborons.
  46. ChemInform Abstract: Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes.
  47. Facile Access to vic-Borylstannylalkanes via Copper-Catalyzed Three-Component Borylstannylation of Alkenes
  48. Aryne-Based Multicomponent Reactions
  49. Direct Synthesis of Boron-Protected Alkenyl- and Alkylborons via Copper-Catalyzed Formal Hydroboration of Alkynes and Alkenes
  50. Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes
  51. Three-Component Carboboration of Alkenes under Copper Catalysis
  52. Convenient Synthesis of 2-Amino-4H-chromenes from Photochemically Generatedo-Quinone Methides and Malononitrile
  53. ChemInform Abstract: Copper-Catalyzed Distannylation of Alkynes.
  54. ChemInform Abstract: Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes.
  55. A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons
  56. N-Heterocyclic carbene-catalyzed double acylation of enones with benzils
  57. Dearomatization-Aromatization Sequence
  58. Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes
  59. Synchronous ArF and ArSn Bond Formation through Fluorostannylation of Arynes
  60. ChemInform Abstract: Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes.
  61. ChemInform Abstract: Copper-Catalyzed Three-Component Borylstannylation of Alkynes.
  62. Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes
  63. Copper-catalyzed distannylation of alkynes
  64. ChemInform Abstract: Hetero-Diels-Alder Reaction of Photochemically Generated α-Hydroxy-o-quinodimethanes with Trifluoromethyl Ketones.
  65. Copper-Catalyzed Three-Component Borylstannylation of Alkynes
  66. ChemInform Abstract: Aryne Insertion Reactions into Carbon-Carbon σ-Bonds
  67. ChemInform Abstract: Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons
  68. Hetero-Diels–Alder reaction of photochemically generated α-hydroxy-o-quinodimethanes with trifluoromethyl ketones
  69. Aryne Insertion Reactions into Carbon-Carbon σ-Bonds
  70. ChemInform Abstract: Copper-Catalyzed Borylation Reactions of Alkynes and Arynes.
  71. ChemInform Abstract: An ortho-Quinodimethane Route to Lasofoxifene and U23469.
  72. ChemInform Abstract: Three-Component Coupling of Arynes and Organic Bromides.
  73. Multicomponent Coupling Reaction of Arynes for Construction of Heterocyclic Skeletons
  74. SYNTHESIS AND REACTIONS OF SILICON-BRIDGED DITHIENYLBIPHENYLS. FINE TUNING OF ELECTRONIC STATES BY BRIDGING SILICON CHAIN LENGTHS
  75. ChemInform Abstract: Aryne Inertion Reactions into σ-Bonds
  76. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes
  77. Copper-Catalyzed Borylation Reactions of Alkynes and Arynes
  78. ChemInform Abstract: Aryne Reaction with Trifluoromethyl Ketones in Three Modes: C-C Bond Cleavage, [2 + 2] Cycloaddition and O-Arylation.
  79. ChemInform Abstract: Three-Component Coupling Using Arynes and DMF: Straightforward Access to Coumarins via ortho-Quinone Methides.
  80. Three-Component Coupling of Arynes and Organic Bromides
  81. Three-Component Coupling of Arynes and Organic Bromides
  82. Synthesis of Dithienogermole-Containing π-Conjugated Polymers and Applications to Photovoltaic Cells
  83. Aryne reaction with trifluoromethyl ketones in three modes: C–C bond cleavage, [2+2] cycloaddition and O-arylation
  84. Three-component coupling using arynes and DMF: straightforward access to coumarins via ortho-quinone methides
  85. An ortho-Quinodimethane Route to Lasofoxifene and U23469
  86. Synthesis and Optical Properties of Pyridino End-Capped Oligothiophenes
  87. Hybridization of Carbon Nanotubes with Si–π Polymers and Attachment of Resulting Hybrids to TiO2 Surface
  88. Aryne Insertion Reactions into .SIGMA.-Bonds
  89. ChemInform Abstract: Facile Access to Boryltetralins and Borylnaphthalenes via a Cycloaddition Using o-Quinodimethanes.
  90. ChemInform Abstract: An Aryne Route to Cytosporone B and Phomopsin C.
  91. ChemInform Abstract: Platinum-Catalyzed Diborylation of Arynes: Synthesis and Reaction of 1,2-Diborylarenes.
  92. ChemInform Abstract: Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates
  93. ChemInform Abstract: Palladium-Catalyzed Dimerization-Carbostannylation of Alkynes: Synthesis of Highly Conjugated Alkenylstannanes.
  94. ChemInform Abstract: Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes: Stereoselective Synthesis of Trisubstituted Vinylstannanes.
  95. ChemInform Abstract: Copper-Catalyzed Bromoalkynylation of Arynes.
  96. ChemInform Abstract: Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism.
  97. ChemInform Abstract: Palladium-Iminophosphine-Catalyzed Carbostannylation of Arynes: Synthesis of ortho-Substituted Arylstannanes.
  98. ChemInform Abstract: Insertion of Arynes into Carbon-Chlorine Bonds of Chlorotriazines.
  99. ChemInform Abstract: Facile Synthesis of N-Alkyl-N′-arylimidazolium Salts via Addition of Imidazoles to Arynes.
  100. Copper-catalysed bromoalkynylation of arynes
  101. Facile access to boryltetralins and borylnaphthalenes via a cycloaddition using o-quinodimethanes
  102. Platinum-catalysed diborylation of arynes: synthesis and reaction of 1,2-diborylarenes
  103. An Aryne Route to Cytosporone B and Phomopsin C
  104. Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates
  105. Does Water Liquid Phase Intrude into Hydrophobic Nanospaces of Alkyl-grafted Mesoporous Silica Immersed in Water? Detection by 13C CP-MAS NMR
  106. ChemInform Abstract: Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes.
  107. ChemInform Abstract: Fluorenes as New Molecular Scaffolds for Carbon-Carbon σ-Bond Cleavage Reaction: Acylfluorenylation of Arynes.
  108. Diphenyl-2-Pyridylphosphine
  109. ChemInform Abstract: Palladium-Catalyzed Disilylation of o-Quinodimethanes: Synthesis of 9- and 10-Membered Disilacarbocycles.
  110. Copper-Catalyzed 2:1 Coupling Reaction of Arynes with Alkynes
  111. ChemInform Abstract: Direct Access to Anthranilic Acid Derivatives via CO2Incorporation Reaction Using Arynes.
  112. Insertion of Arynes into Carbon–Chlorine Bonds of Chlorotriazines
  113. ChemInform Abstract: Three-Component Coupling Using Arynes and Aminosilanes for ortho-Selective Double Functionalization of Aromatic Skeletons.
  114. Palladium-Catalyzed Disilylation of o -Quinodimethanes: Synthesis of 9- and 10-Membered Disilacarbocycles
  115. Direct Access to Anthranilic Acid Derivatives via CO 2 Incorporation Reaction Using Arynes
  116. Three-Component Coupling Using Arynes and Aminosilanes for ortho-Selective Double Functionalization of Aromatic Skeletons
  117. Fluorenes as new molecular scaffolds for carbon–carbon σ-bond cleavage reaction: acylfluorenylation of arynes
  118. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes.
  119. Insertion of Arynes into Carbon—Halogen σ-Bonds: Regioselective Acylation of Aromatic Rings.
  120. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles.
  121. Three-Component Coupling Using Arynes and Isocyanides: Straightforward Access to Benzo-Annulated Nitrogen or Oxygen Heterocycles.
  122. Straightforward Construction of Diarylmethane Skeletons via Aryne Insertion into Carbon—Carbon σ-Bonds.
  123. Three-Component Coupling of Arynes, Aminosilanes, and Aldehydes
  124. Three-component coupling using arynes and isocyanides: straightforward access to benzo-annulated nitrogen or oxygen heterocycles
  125. Synthesis of diarylenenaphthylene- and diaryleneanthrylene-containing organosilicon polymers and their applications to organic EL devices
  126. Palladium-Catalyzed Distannylation of ortho-Quinodimethanes.
  127. CO2 Incorporation Reaction Using Arynes: Straightforward Access to Benzoxazinone.
  128. Straightforward construction of diarylmethane skeletons via aryne insertion into carbon–carbon σ-bonds
  129. Insertion of arynes into carbon–halogen σ-bonds: regioselective acylation of aromatic rings
  130. Synthesis of organosilicon polymers containing donor–acceptor type π-conjugated units and their applications to dye-sensitized solar cells
  131. Palladium-Catalyzed Distannylation of o rtho -Quinodimethanes
  132. CO 2 Incorporation Reaction Using Arynes:  Straightforward Access to Benzoxazinone
  133. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide.
  134. Palladium-Catalyzed Dimerization—Distannylation of Arynes: Synthesis and Reaction of 2,2′-Distannylbiaryls.
  135. Aryne Insertion into α-Cyanocarbonyl Compounds: Direct Introduction of Carbonyl and Cyanomethyl Moieties into the Aromatic Skeletons.
  136. Aminosilylation of Arynes with Aminosilanes: Synthesis of 2-Silylaniline Derivatives.
  137. Transition Metal Catalyzed Reactions or Electrophilic Coupling Reactions Using Arynes
  138. Facile Insertion Reaction of Arynes into Carbon—Carbon σ-Bonds.
  139. Aryne insertion into α-cyanocarbonyl compounds: direct introduction of carbonyl and cyanomethyl moieties into the aromatic skeletons
  140. Sonogashira coupling of diethynylsilane and dibromoarene in wet solvent for the formation of poly[(ethynylenearylene)-co-(diethynylenesilylenearylene)]
  141. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent.
  142. Addition of Silicon?Silicon ?-Bonds to Arynes or Bisarynes Catalyzed by a Palladium Complex.
  143. Straightforward Access to 2-Iminoisoindolines via Three-Component Coupling of Arynes, Isocyanides and Imines.
  144. Cyclic voltammetry and theoretical calculations of silyl-substituted 1,4-benzoquinones
  145. A 2:1 Coupling Reaction of Arynes with Aldehydes via o-Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes.
  146. Thiostannylation of Arynes with Stannyl Sulfides: Synthesis and Reaction of 2-(Arylthio)arylstannanes.
  147. Distannylation of Strained Carbon?Carbon Triple Bonds Catalyzed by a Palladium Complex.
  148. Aminosilylation of arynes with aminosilanes: synthesis of 2-silylaniline derivatives
  149. Facile insertion reaction of arynes into carbon–carbon σ-bonds
  150. Palladium-catalysed dimerisation–distannylation of arynes: synthesis and reaction of 2,2′-distannylbiaryls
  151. Facile Synthesis of Polycyclic Aromatic Hydrocarbons via a Trisaryne Equivalent
  152. Carbophosphinylation of Arynes with Cyanomethyldiphenylphosphine Oxide
  153. Addition of Silicon−Silicon σ-Bonds to Arynes or Bisarynes Catalyzed by a Palladium Complex
  154. Transition Metal-Catalyzed Reactions or Electrophilic Coupling Reactions Using Arynes
  155. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans.
  156. Straightforward access to 2-iminoisoindolines via three-component coupling of arynes, isocyanides and imines
  157. A 2:1 Coupling Reaction of Arynes with Aldehydes via o -Quinone Methides: Straightforward Synthesis of 9-Arylxanthenes
  158. Distannylation of Strained Carbon–Carbon Triple Bonds Catalyzed by a Palladium Complex
  159. Distannylation of Strained Carbon–Carbon Triple Bonds Catalyzed by a Palladium Complex
  160. 2,3,5,6-Tetrasilyl- and 2,3,5,6-Tetragermyl-1,4-benzoquinones:  X-ray Crystallographic Analysis, Cyclic Voltammetry, and DFT Calculations
  161. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans
  162. Arynes in a Three-Component Coupling Reaction: Straightforward Synthesis of Benzoannulated Iminofurans
  163. 2,3,5,6-Tetrasilyl- and 2,3,5,6-Tetragermyl-1,4-benzoquinones:  X-ray Crystallographic Analysis, Cyclic Voltammetry, and DFT Calculations
  164. Thiostannylation of arynes with stannyl sulfides: synthesis and reaction of 2-(arylthio)arylstannanesElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b4/b405883f/
  165. Activator-Free Oxidative Homocoupling of Organosilanes Catalyzed by a Palladium—DPPP Complex.
  166. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes: Synthesis of Benzo-Annulated Disilacarbocycles.
  167. Synthesis of organosilanylene–thienylene alternating oligomers bearing ether side chains
  168. Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes:  Synthesis of Benzo-Annulated Disilacarbocycles
  169. Base-Free Oxidative Homocoupling of Arylboronic Esters.
  170. Base-free oxidative homocoupling of arylboronic esters
  171. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives.
  172. Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex
  173. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives
  174. Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine Derivatives
  175. Facile Synthesis of N -Alkyl- N ‘ -arylimidazolium Salts via Addition of Imidazoles to Arynes
  176. ChemInform Abstract: Palladium-Iminophosphine-Catalyzed Alkynylstannylation of Alkynes.
  177. ChemInform Abstract: Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synthesis and Reaction of ε-Oxoallylstannanes.
  178. ChemInform Abstract: Diphenylphosphinophenolate: A Ligand for the Palladium-Catalyzed Silylation of Aryl Halides Activating Simultaneously both Palladium and Silicon.
  179. Palladium–iminophosphine-catalysed carbostannylation of arynes: synthesis of ortho-substituted arylstannanes
  180. Dimerization-Carbostannylation of Alkynes Catalyzed by a Palladium-Diimine Complex: Regioselectivity, Stereoselectivity and Mechanism.
  181. Palladium−Iminophosphine-Catalyzed Alkynylstannylation of Alkynes
  182. Nickel-Catalyzed Acylstannylation of 1,3-Dienes:  Synthesis and Reaction of ε-Oxoallylstannanes
  183. Mechanistic Aspects of Palladium-Catalyzed Allylstannylation of Alkynes
  184. Diphenylphosphinophenolate: a ligand for the palladium-catalysed silylation of aryl halides activating simultaneously both palladium and silicon
  185. Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes:  Stereoselective Synthesis of Trisubstituted Vinylstannanes
  186. Palladium-Catalyzed Dimerization−Carbostannylation of Alkynes:  Synthesis of Highly Conjugated Alkenylstannanes
  187. Carbostannylation of Alkynes Catalyzed by an Iminophosphine−Palladium Complex
  188. On the catalytic cycle of the palladium-catalyzed cross-coupling reaction of alkynylstannane with aryl iodide
  189. An iminophosphine-palladium catalyst for cross-coupling of aryl halides with organostannanes