All Stories

  1. Stapled helical o-OPE foldamers as new circularly polarized luminescence emitters based on carbophilic interactions with Ag(i)-sensitivity
  2. Influence of the chirality of short peptide supramolecular hydrogels in protein crystallogenesis
  3. Two-dimensional carbon-based conductive materials with dynamically controlled asymmetric Dirac cones
  4. Ti(III)-Catalyzed Cyclizations of Ketoepoxypolyprenes: Control over the Number of Rings and Unexpected Stereoselectivities
  5. Ti/Ni-Mediated Inter- and Intramolecular Conjugate Addition of Aryl and Alkenyl Halides and Triflates
  6. Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions
  7. Cp2TiCl-catalyzed highly stereoselective intramolecular epoxide allylation using allyl carbonates
  8. Recent applications of Cp2TiCl in natural product synthesis
  9. Rational design of a new fluorescent ‘ON/OFF’ xanthene dye for phosphate detection in live cells
  10. Novel ortho-OPE metallofoldamers: binding-induced folding promoted by nucleating Ag(i)–alkyne interactions
  11. Synthesis and Photophysics of a New Family of Fluorescent 9-Alkyl-Substituted Xanthenones
  12. The Role of Water-Based Hydrogen Atom Wires in Long-Range Electron-Transfer Reactions in Aqueous Media for the FeII-FeIIISelf-Exchange and Related Systems
  13. Titanocene(III)-Catalyzed 6-exoVersus 7-endoCyclizations of Epoxypolyprenes: Efficient Control and Synthesis of Versatile Terpenic Building Blocks
  14. Water Control over the Chemoselectivity of a Ti/Ni Multimetallic System: Heck- or Reductive-Type Cyclization Reactions of Alkyl Iodides
  15. Versatile Bottom-up Approach to Stapled π-Conjugated Helical Scaffolds: Synthesis and Chiroptical Properties of Cyclico-Phenylene Ethynylene Oligomers
  16. Combining the Power of TiIII-Mediated Processes for Easy Access to Hydroxylated Polycyclic Terpenoids: Synthesis of Sesterstatin 1 and C-D Rings of Aspergilloxide
  17. H2O Activation for Hydrogen-Atom Transfer: Correct Structures and Revised Mechanisms
  18. Ti/Ni-Based Multimetallic System for the Efficient Allylation of Carbonyl Compounds
  19. Reduction Reactions in Green Solvents: Water, Supercritical Carbon Dioxide, and Ionic Liquids
  20. Conductance and application of organic molecule pairs as nanofuses
  21. Ti/Pd Bimetallic Systems for the Efficient Allylation of Carbonyl Compounds and Homocoupling Reactions
  22. Ti/Pd-promoted intramolecular Michael-type addition of allylic carboxylates to activated alkenes
  23. On/off electrochemical switches based on quinone-bisketals
  24. Bioinspired terpene synthesis: a radical approach
  25. Organic-based molecular switches for molecular electronics
  26. Titanium/Palladium-Mediated Regioselective Propargylation of Ketones using Propargylic Carbonates as Pronucleophiles
  27. Mn(0)-Mediated Chemoselective Reduction of Aldehydes. Application to the Synthesis of α-Deuterioalcohols
  28. Understanding the Exceptional Hydrogen-Atom Donor Characteristics of Water in Ti III -Mediated Free-Radical Chemistry
  29. Radical Reduction of Epoxides Using a Titanocene(III)/Water System: Synthesis of β-Deuterated Alcohols and Their Use as Internal Standards in Food Analysis
  30. Unprecedented H-atom transfer from water to ketyl radicals mediated by Cp2TiCl
  31. Efficient Propargylation of Aldehydes and Ketones Catalyzed by Titanocene(III)
  32. Unexpected Ti III /Mn-Promoted Pinacol Coupling of Ketones
  33. Ti-Catalyzed Barbier-Type Allylations and Related Reactions
  34. Divergent Titanium‐Mediated Allylations with Modulation by Nickel or Palladium
  35. Titanium-Catalyzed Enantioselective Synthesis of α-Ambrinol
  36. Ti-Catalyzed Reformatsky-Type Coupling between α-Halo Ketones and Aldehydes
  37. Sodium Tetramethoxyborate:  An Efficient Catalyst for Michael Additions of Stabilized Carbon Nucleophiles
  38. Unprecedented Hydrogen Transfer from Water to Alkenes and Alkynes Mediated by Ti III and Late Transition Metals
  39. Water: The Ideal Hydrogen-Atom Source in Free-Radical Chemistry Mediated by TiIII and Other Single-Electron-Transfer Metals?
  40. Stereocontrolled Coupling between Aldehydes and Conjugated Alkenals Mediated by Ti III /H 2 O
  41. Water: The Ideal Hydrogen-Atom Source in Free-Radical Chemistry Mediated by TiIII and Other Single-Electron-Transfer Metals?
  42. 7- e ndo Radical Cyclizations Catalyzed by Titanocene(III). Straightforward Synthesis of Terpenoids with Seven-Membered Carbocycles
  43. Exploiting Pd II and Ti III Chemistry To Obtain γ-Dioxygenated Terpenoids:  Synthesis of Rostratone and Novel Approaches to Aphidicolin and Pyripyropene A
  44. General Approach to Polycyclic Meroterpenoids Based on Stille Couplings and Titanocene Catalysis
  45. Titanocene-Catalyzed Cascade Cyclization of Epoxypolyprenes: Straightforward Synthesis of Terpenoids by Free-Radical Chemistry
  46. Unprecedented Barbier-type reactions catalysed by titanocene(iii)
  47. Unified Synthesis of Eudesmanolides, Combining Biomimetic Strategies with Homogeneous Catalysis and Free-Radical Chemistry
  48. Intramolecular Coupling of Allyl Carboxylates with Allyl Stannanes and Allyl Silanes: A New Type of Reductive Elimination Reaction?
  49. Effects of Solvents and Water in Ti(III)-Mediated Radical Cyclizations of Epoxygermacrolides. Straightforward Synthesis and Absolute Stereochemistry of (+)-3α-Hydroxyreynosin and Related Eudesmanolides
  50. A New Strategy for the Synthesis of Cyclic Terpenoids Based on the Radical Opening of Acyclic Epoxypolyenes
  51. Cationic Intermediates in the Intramolecular Insertion of Alkenes into(η3-Allyl)palladium(II) Complexes
  52. Michael Reaction of Stabilized Carbon Nucleophiles Catalyzed by [RuH 2 (PPh 3 ) 4 ]