All Stories

  1. Competitive Isomerization and Catalyst Decomposition During Ring-Closing Metathesis
  2. Understanding the color change of the solutions of Cp 2 TiCl upon addition of water
  3. A billion times smaller than us: helping students comprehend the molecular scale
  4. Continuous Addition Kinetic Elucidation: Catalyst and Reactant Order, Rate Constant, and Poisoning from a Single Experiment
  5. Continuous Addition Kinetic Elucidation: Catalyst and Reactant Order, Rate Constant, and Poisoning from a Single Experiment
  6. Cover Picture: Pressurized Sample Infusion (Chem. Methods 1/2022)
  7. Pressurized Sample Infusion
  8. Handling considerations for the mass spectrometry of reactive organometallic compounds
  9. Pressurized Sample Infusion
  10. Are Methylaluminoxane Activators Sheets?
  11. Spectroscopic Studies of Synthetic Methylaluminoxane: Structure of Methylaluminoxane Activators
  12. A Mechanistic Investigation of the Suzuki Polycondensation Reaction Using MS/MS Methods
  13. A Mechanistic Investigation of the Suzuki Polycondensation Reaction Using MS/MS Methods
  14. Standardized Stirring for Small Scale Surveys
  15. Dynamic Ion Speciation during the Hydrolysis of Aryltrifluoroborates**
  16. Real-time analysis of methylalumoxane formation
  17. A mechanistic investigation of the Pd-catalyzed cross-coupling between N-tosylhydrazones and aryl halides
  18. A mechanistic investigation of the Suzuki polycondensation reaction using MS/MS methods
  19. Regio- and diastereoselective Pd-catalyzed aminochlorocyclization of allylic carbamates: scope, derivatization, and mechanism
  20. The signal-to-noise issue in mass spectrometric analysis of polymers
  21. Standardized Stirring for Small Scale Surveys
  22. Standardized Stirring for Small Scale Surveys
  23. Trichloro(Dinitrogen)Platinate(II)
  24. Inexpensive Open Source Laser Cut Model Kits for the Teaching of Molecular Geometry
  25. Inexpensive Open Source Laser Cut Model Kits for the Teaching of Molecular Geometry
  26. Real-Time Analysis of Methylalumoxane Formation
  27. Real-Time Analysis of Methylalumoxane Formation
  28. Disulfonated Xantphos for Mass Spectrometric Mechanistic Analysis
  29. Disulfonated Xantphos for Mass Spectrometric Mechanistic Analysis
  30. Magnesium-Accelerated Maillard Reactions Drive Differences in Adjunct and All-Malt Brewing
  31. Dynamic Ion Speciation During Hydrolysis of Aryltrifluoroborates
  32. Dynamic Ion Speciation During Hydrolysis of Aryltrifluoroborates
  33. Catalyst Deactivation Processes during 1-Hexene Polymerization
  34. Chromate Conversion Coating and Alternatives as Corrosion-Resistant Treatments for Metal Parts
  35. Chromate Conversion Coating and Alternatives as Corrosion-Resistant Treatments for Metal Parts
  36. Trichloro(Dinitrogen)platinate(II)
  37. Trichloro(Dinitrogen)platinate(II)
  38. Catalyst Deactivation Processes During 1-Hexene Polymerization
  39. Catalyst Deactivation Processes During 1-Hexene Polymerization
  40. Real-Time Monitoring of a Cobalt-Mediated One-Pot Transition Metal Catalyzed Multicomponent Reaction
  41. Real-Time Monitoring of a Cobalt-Mediated One-Pot Transition Metal Catalyzed Multicomponent Reaction
  42. Gas-Phase Oxidation of Reactive Organometallic Ions
  43. Gas-Phase Oxidation of Reactive Organometallic Ions
  44. Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water
  45. Magnesium-Accelerated Maillard Reactions Drive Differences in Adjunct and All-Malt Brewing
  46. Magnesium-Accelerated Maillard Reactions Drive Differences in Adjunct and All-Malt Brewing
  47. Orbital Shaped Standing Waves Using Chladni Plates
  48. Orbital Shaped Standing Waves Using Chladni Plates
  49. An Information-Rich Graphical Representation of Catalytic Cycles
  50. Experimental Strategies for Avoiding Saturation Effects in ESI-MS
  51. Experimental Strategies for Avoiding Saturation Effects in ESI-MS
  52. Step-by-Step Real Time Monitoring of a Catalytic Amination Reaction
  53. Step-by-Step Real Time Monitoring of a Catalytic Amination Reaction
  54. Structure, Anion, and Solvent Effects on Cation Response in ESI-MS
  55. An Information-Rich Graphical Representation of Catalytic Cycles
  56. An Information-Rich Graphical Representation of Catalytic Cycles
  57. Assigning the ESI Mass Spectra of Organometallic and Coordination Compounds
  58. PythoMS: A Python Framework To Simplify and Assist in the Processing and Interpretation of Mass Spectrometric Data
  59. Interaction of Neutral Donors with Methylaluminoxane
  60. Confounding contaminants in mass spectrometric reaction monitoring
  61. Structure, anion, and solvent effects on cation response in ESI-MS
  62. Structure, anion, and solvent effects on cation response in ESI-MS
  63. Interaction of Neutral Donors with Methylaluminoxane
  64. Interaction of Neutral Donors with Methylaluminoxane
  65. Open-Source Laser-Cut-Model Kits for the Teaching of Molecular Geometry
  66. How Does Methylaluminoxane Work?
  67. Step-by-step real time monitoring of a catalytic amination reaction
  68. Confounding contaminants in mass spectrometric reaction monitoring
  69. Confounding contaminants in mass spectrometric reaction monitoring
  70. Competitive Ligand Exchange and Dissociation in Ru Indenyl Complexes
  71. Real-Time Mass Spectrometric Investigations into the Mechanism of the Suzuki–Miyaura Reaction
  72. PythoMS: A Python Framework to Simplify and Assist in the Processing and Interpretation of Mass Spectrometric Data
  73. Oxidation of Methylalumoxane Oligomers: A Theoretical Study Guided by Mass Spectrometry
  74. Modifying Methylalumoxane via Alkyl Exchange
  75. Competitive Ligand Exchange and Dissociation in Ru Indenyl Complexes
  76. Ionization methods for the mass spectrometry of organometallic compounds
  77. Frontispiece: Oxidation of Methylalumoxane Oligomers
  78. Oxidation of Methylalumoxane Oligomers
  79. (Ge2P2)2−: a binary analogue of P4as a precursor to the ternary cluster anion [Cd3(Ge3P)3]3−
  80. Synthesis, characterization and mass-spectrometric analysis of [LSn(IV)F4−x]x+ salts [L = tris ((1-ethyl-benzoimidazol-2-yl)methyl)amine, x = 1–4]
  81. Modifying methylalumoxane via alkyl exchange
  82. Oxidation of Titanocene(III): The Deceptive Simplicity of a Color Change
  83. Additive and Aging Effects on Methylalumoxane Oligomers
  84. Determination of n-Alkanes in Jet Fuel by Cold-electron Ionization Gas Chromatography–Mass Spectrometry
  85. Real-time analysis of Pd2(dba)3 activation by phosphine ligands
  86. Mass transfer and convection effects in small-scale catalytic hydrogenation
  87. Phenol-selective mass spectrometric analysis of jet fuel
  88. Simultaneous Orthogonal Methods for the Real-Time Analysis of Catalytic Reactions
  89. Alkylation of [Pt2(μ-S)2(PPh3)4] with boronic acid derivatives
  90. Applying Hand-Held 3D Printing Technology to the Teaching of VSEPR Theory
  91. Reactivity of [Pt2(μ-S)2(PPh3)4] towards activated aliphatic bromoacyl electrophiles: Formation of mono-, homodi-, heterodi- and intramolecular-bridged alkylated products
  92. Mass spectrometric characterization of oligomeric phosphaalkenes
  93. Mass Spectrometry of Organoaluminum Derivatives
  94. Compounds containing P-P bonds decompose in many different ways
  95. Selective mass spectrometric analysis of thiols using charge-tagged disulfides
  96. Electron ionization mass spectrometric analysis of air- and moisture-sensitive organometallic compounds
  97. Reversible Mechanical Interlocking of D-Shaped Molecular Karabiners bearing Coordination-Bond Loaded Gates: Route to Self-Assembled [2]Catenanes
  98. How the capillary tip position affects relative ion intensity in ESI-MS
  99. Party balloons provide the driving force for continuous analysis
  100. Cationic rhodium complexes add hydrogen to alkynes much faster than to alkenes
  101. Relative binding affinities of fluorobenzene ligands in cationic rhodium bisphosphine η6–fluorobenzene complexes probed using collision-induced dissociation
  102. Mechanistic insights from mass spectrometry: examination of the elementary steps of catalytic reactions in the gas phase
  103. Mechanistic features of the copper-free Sonogashira reaction from ESI-MS
  104. Mass Spectrometric Characterization of Methylaluminoxane-Activated Metallocene Complexes
  105. ChemInform Abstract: The Application of Electrospray Ionization Mass Spectrometry to Homogeneous Catalysis
  106. The application of electrospray ionization mass spectrometry to homogeneous catalysis
  107. Solvent effects on surface activity of aggregate ions in electrospray ionization
  108. ChemInform Abstract: Practical Approaches to the ESI-MS Analysis of Catalytic Reactions
  109. Mass Spectrometric Transmutation of Fullerenes
  110. Electrostatic and Non-covalent Interactions in Dicationic Imidazolium-Sulfonium Salts with Mixed Anions
  111. A multi-pronged mechanistic study of the phosphine-mediated conjugate addition of an alcohol to an acetylenic ester
  112. Exploring the mechanism of the hydroboration of alkenes by amine–boranes catalysed by [Rh(xantphos)]+
  113. Practical approaches to the ESI-MS analysis of catalytic reactions
  114. Gas phase reactivity of iron pentacarbonyl with anionic metal clusters
  115. Oxidative Additions of Aryl Halides to Palladium Proceed through the Monoligated Complex
  116. The Color-Changing Sports Drink: An Ingestible Demonstration
  117. An Unexpected Pathway for Ligand Substitution in an Aryl Halide Complex of Palladium
  118. Mass Spectrometric Characterization of Methylaluminoxane
  119. Characterization of Isobutylaluminoxanes by Electrospray Ionization Mass Spectrometry
  120. Synthesis and characterization of a new class of anti-angiogenic agents based on ruthenium clusters
  121. Fixed-charge phosphine ligands to explore gas-phase coinage metal-mediated decarboxylation reactions
  122. A mechanistic investigation of hydrodehalogenation using ESI-MS
  123. A detailed kinetic analysis of rhodium-catalyzed alkyne hydrogenation
  124. 1,8-Bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene: An electrospray-active analogue for η6-coordinating ligands
  125. Pressurized sample infusion: An easily calibrated, low volume pumping system for ESI-MS analysis of reactions
  126. Proton Sponge Phosphanes: Reversibly Chargeable Ligands for ESI-MS Analysis
  127. The Pauson-Khand Reaction: A Gas-Phase and Solution-Phase Examination Using Electrospray Ionization Mass Spectrometry
  128. Mass Spectrometric and Theoretical Study of Polyiodides: The Connection between Solid State, Solution, and Gas Phases
  129. 3,3′-N,N′-Bis(amino)-2,2′-bipyridine — An unusually methylation-resistant amine
  130. Powerful Insight into Catalytic Mechanisms through Simultaneous Monitoring of Reactants, Products, and Intermediates
  131. Powerful Insight into Catalytic Mechanisms through Simultaneous Monitoring of Reactants, Products, and Intermediates
  132. ChemInform Abstract: Ionic Liquids: Solutions for Electrospray IoniZation Mass Spectrometry
  133. Blurring the line between solution and the gas phase: collision-induced dissociation of hypersolvated lanthanide trications provides insights into solution acidity
  134. Pressurized Sample Infusion for the Continuous Analysis of Air- And Moisture-Sensitive Reactions Using Electrospray Ionization Mass Spectrometry
  135. Using NMR and ESI-MS to Probe the Mechanism of Silane Dehydrocoupling Catalyzed by Wilkinson's Catalyst
  136. 1,3,5-Triazaadamantan-7-amine
  137. Mass spectrometry in organometallic chemistry
  138. Mass Spectrometry and Gas-Phase Chemistry of Non-Covalent Complexes. Supramolecular Chemistry in the Gas Phase. Wiley-Interscience Series on Mass Spectrometry. Von Christoph A. Schalley und Andreas Springer.
  139. Mass Spectrometry and Gas-Phase Chemistry of Non-Covalent Complexes. Supramolecular Chemistry in the Gas Phase. Wiley-Interscience Series on Mass Spectrometry. By Christoph A. Schalley and Andreas Springer.
  140. Mono-alkylated bisphosphines as dopants for ESI-MS analysis of catalytic reactions
  141. Direct observation of key intermediates by negative-ion electrospray ionisation mass spectrometry in palladium-catalysed cross-coupling
  142. Bisphosphine monoxides with o-phenylene backbones in Pt, Pd and Fe complexes
  143. Ionic liquids: Solutions for Electrospray Ionisation Mass Spectrometry
  144. Gas-phase reactivity of ruthenium carbonyl cluster anions
  145. Distannoxane speciation during esterification catalysis: revealing insights provided by electrospray ionization mass spectrometry
  146. Evidence of asymmetric cation solvation from the instability of [Pb(H2O)n]2+ complexes
  147. Collision-induced dissociation of protonated nanodroplets
  148. Coupling an Electrospray Ionization Mass Spectrometer with a Glovebox: A Straightforward, Powerful, and Convenient Combination for Analysis of Air-Sensitive Organometallics
  149. Book Review of Inorganic Mass Spectrometry: Principles and Applications Inorganic Mass Spectrometry: Principles and Applications . By Johanna Sabine Becker  (Research Centre Jülich, Germany) . John Wiley & Sons, Ltd. : Chichester . 2007 . xx + 496 pp....
  150. Insights into the Post-Translational Methylation of Arginine from Studies of Guanidinium-Water Nanodroplets
  151. (Chloromethyl)pentacarbonylmanganese(I): a crystal structure with a non-crystallographic centre of symmetry
  152. ChemInform Abstract: Reversible Binding of Dihydrogen in Multimetallic Complexes
  153. Charged ligands for catalyst immobilisation and analysis
  154. Reversible Binding of Dihydrogen in Multimetallic Complexes
  155. Investigation into the formation of heteronuclear clusters of formula [{Ru6C(CO)16Ag2X}2]2− (X = Cl, Br or I)
  156. Sequential Reduction of High Hydride Count Octahedral Rhodium Clusters [Rh 6 (PR 3 ) 6 H 12 ][BAr F 4 ] 2 :  Redox-Switchable Hydrogen Storage
  157. Direct observation of ion evaporation from a triply charged nanodroplet
  158. Formaldehyde elimination from methoxylated transition metal carbonyl clusters
  159. The energetics of the X 2 + X – → X 3 – equilibrium (X = Cl, Br, I) in aqueous and nonaqueous solution
  160. Storing and Releasing Hydrogen with a Redox Switch
  161. Storing and Releasing Hydrogen with a Redox Switch
  162. High Hydride Count Rhodium Octahedra, [Rh6(PR3)6H12][BArF4]2: Synthesis, Structures, and Reversible Hydrogen Uptake under Mild Conditions
  163. Energy-dependent Electrospray Ionisation Mass Spectrometry of Carbonyl Clusters
  164. Ionic liquids enable electrospray ionisation mass spectrometry in hexane
  165. Proton sponge phosphines: electrospray-active ligands
  166. Hydrogen Sponge? A Heteronuclear Cluster that Absorbs Large Quantities of Hydrogen
  167. Holding onto Lots of Hydrogen: A 12-Hydride Rhodium Cluster That Reversibly Adds Two Molecules of H2
  168. Holding onto Lots of Hydrogen: A 12-Hydride Rhodium Cluster That Reversibly Adds Two Molecules of H2
  169. Hydrogen Sponge? A Heteronuclear Cluster That Absorbs Large Quantities of Hydrogen
  170. Wasserstoffschwamm? Ein heteronuclearer Cluster, der große Wasserstoffmengen absorbiert
  171. Mass Spectrometry of Inorganic, Coordination and Organometallic Compounds
  172. An Octahedral Rhodium Cluster with Six Phosphine and 12 Hydride Ligands and 10 Too Few Electrons
  173. EDit: a computer program to assist in the presentation of energy-dependent mass spectra
  174. An Octahedral Rhodium Cluster with Six Phosphine and 12 Hydride Ligands and 10 Too Few Electrons
  175. Ein oktaedrischer Rhodium-Cluster mit sechs Phosphan- und zwölf Hydridliganden, dem zehn Elektronen fehlen
  176. Analysis of Low Oxidation State Transition Metal Clusters by Laser Desorption/Ionization Time-of-Flight Mass Spectrometry
  177. Direct probe electrospray (and nanospray) ionization mass spectrometry of neat ionic liquids
  178. Analysis of Coordination and Organometallic Compounds Using Photoionisation Mass Spectrometric Techniques
  179. A Strategy for Generating Naked-Metal Clusters for Gas-Phase Reactivity Studies by FTICR–MS
  180. A Strategy for Generating Naked-Metal Clusters for Gas-Phase Reactivity Studies by FTICR–MS
  181. Metal Carbonyls
  182. Fragmentation of Transition Metal Carbonyl Cluster Anions: Structural Insights from Mass Spectrometry
  183. Direct analysis of catalysts immobilised in ionic liquids using electrospray ionisation ion trap mass spectrometry
  184. Studies of polyhalide ions in aqueous and non-aqueous solution by electrospray mass spectrometry
  185. The preparation and characterisation of monomeric and linked metal carbonyl clusters containing the closo-Si2Co4 pseudo-octahedral core
  186. Collision-induced dissociation and photodetachment of singly and doubly charged anionic polynuclear transition metal carbonyl clusters: Ru3Co(CO)13−, Ru6C(CO)162−, and Ru6(CO)182−
  187. Bis[dicarbonyl(cyclopentadienyl)ferrio]mercury(II)
  188. On the use of breakdown graphs combined with energy-dependent mass spectrometry to provide a complete picture of fragmentation processes
  189. Electrospray Mass Spectrometry
  190. Mass Spectrometric Method for the Rapid Characterization of Transition Metal Carbonyl Cluster Reaction Mixtures
  191. Book Review: Transition Metal Carbonyl Cluster Chemistry. Von Paul J. Dyson und J. Scott McIndoe
  192. Combining energy-dependent electrospray ionisation with tandem mass spectrometry for the analysis of inorganic compounds
  193. Electrospray mass spectrometric characterization of bimetallic group 8 — Gold clusters
  194. Applications of Laser Desorption and Electrospray Ionization Mass Spectrometry at the Transition between Clusters and Colloids
  195. Spectroscopic and mass spectrometric methods for the characterisation of metal clusters
  196. Energy-dependent electrospray ionisation mass spectrometry: applications in transition metal carbonyl chemistry
  197. Formation of the highly unusual cyclic clusters [MH(CO)4]n (M = Mn, n = 4–9; M = Re, n = 4–6) under laser desorption/ionisation conditions
  198. Insights into the elimination of HCHO from the clusters [Mn(CO)m(COOMe)]− (Mn = Ru6C, m = 16; Mn = Rh6, m = 15) provided by electrospray mass spectrometry †
  199. UV laser desorption/ionisation mass spectrometry of the triruthenium clusters Ru3(CO)12−n(PPh3)n (n=1, 2 and 3)
  200. Reactivity and Characterization of Transition-Metal Carbonyl Clusters Using UV Laser Desorption Mass Spectrometry
  201. Electrospray mass spectrometry of metal carbonyl complexes †
  202. Electrospray mass spectrometric analysis of neutral metal carbonyl complexes by derivatisation with alkoxide ions