All Stories

  1. Structural (XRD) Characterization and an Analysis of H-Bonding Motifs in Some Tetrahydroxidohexaoxidopentaborate(1-) Salts of N-Substituted Guanidinium Cations
  2. Synthesis and characterization of a tertiary amine:boric acid (1:1) co-crystal and a neutral zwitterionic diamine pentaboron adduct
  3. Oxidoborates Templated by Cationic Nickel(II) Complexes and Self-Assembled from B(OH)3
  4. Recent Advances in Crystalline Oxidopolyborate Complexes of d-Block or p-Block Metals: Structural Aspects, Syntheses, and Physical Properties
  5. Oxidopolyborate chemistry: The self-assembled, templated, synthesis, and an XRD study of a 1-D coordination polymer, [Cu(en){B6O7(OH)6}].3H2O (en = 1,2-diaminoethane)
  6. Nomenclature for boranes and related species (IUPAC Recommendations 2019)
  7. Pentaborate(1-) Salts and a Tetraborate(2-) Salt Derived from C2- or C3-Linked Bis(alkylammonium) Dications: Synthesis, Characterization, and Structural (XRD) Studies
  8. OXIDOPOLYBORATE anions templated by transition-metal complex cations: SELF-ASSEMBLED syntheses and structural studies (XRD) of [Co(NH3)6]2[B4O5(OH)4]3·11H2O, [Ni(phen)3][B7O9(OH)5].9.5H2O and [Zn(dac)2(H2O)2][B7O9(OH)5]·H2O
  9. Copper(2+) complexes of hydroxyoxidopolyborates: Synthesis and characterization of [Cu(MeNHCH2CH2NMeH)2(H2O)2][B5O6(OH)4]2.2B(OH)3
  10. Synthesis and XRD study of an C2-linked bis(quaternary ammonium) pentaborate: [Me3NCH2CH2NMe3][B5O6(OH)4]2
  11. Hexaborate(2−) and Dodecaborate(6−) Anions as Ligands to Zinc(II) Centres: Self-Assembly and Single-Crystal XRD Characterization of [Zn{κ3O-B6O7(OH)6}(κ3N-dien)]·0.5H2O (dien = NH(CH2–CH2NH2)2), (NH4)2[Zn{κ2O-B6O7(OH)6}2 (H2O)2]·2H2O and (1,3-pnH2)3[(κ...
  12. Copper(2+) Complexes of Hydroxyoxidoborates. Synthesis and Characterization of Two Clusters Containing the Hexaborate(2−) Ligand: [Cu(NH2CH2CH2NEt2){B6O7(OH)6}]·5H2O and [Cu(NH3)2{B6O7(OH)6}]·2H2O
  13. Two 1-D Coordination Polymers Containing Zinc(II) Hexaborates: [Zn(en){B6O7(OH)6}]·2H2O (en = 1,2-diaminoethane) and [Zn(pn){B6O7(OH)6}]·1.5H2O (pn = 1,2-diaminopropane)
  14. Nomenclature for boranes and related species
  15. Synthesis and Characterization by a Single-Crystal XRD Study of [H3O]4[Cu7(NH3)2(H2O)4{B24O39(OH)12}]·13H2O: An Unusual [{(H2O)2(NH3)Cu}2{B2O3(OH)2}2Cu]2+ Trimetallic Bis(dihydroxytrioxidodiborate) Chain Supported by a [{Cu4O}{B20O32(OH)8}]6− Cluster
  16. Amine adducts of (4-ClC 6 H 4 ) 3 B 3 O 3 , Lewis acidity of triarylboroxines, and an XRD study on the related tetraphenylboroxinate(1-) salt, [C 6 H 11 NMe 3 ][Ph 4 B 3 O 3 ]
  17. Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3 O,O′,O′′-B12O18(OH)6-κ1 O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterioni...
  18. Synthesis and characterization of polyborates templated by cationic copper(II) complexes: Structural (XRD), spectroscopic, thermal (TGA/DSC) and magnetic properties
  19. Polyborate Anions Partnered with Large Nonmetal Cations: Triborate(1-), Pentaborate(1-) and Heptaborate(2-) Salts
  20. Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts
  21. Recent advances in crystalline hydrated borates with non-metal or transition-metal complex cations
  22. DFT studies on hexaborate(2−) and heptaborate(2−) anions
  23. Polyborate anions templated by cationic transition-metal complexes: [Co(diNOsar)]2[B3O3(OH)4]Cl5.4.75 H2O
  24. Synthesis and characterization of templated pentaborate(1-) salts: X-ray structure of [(2-HOCH2CH2)C4H7NMeH][B5O6(OH)4]·0.3H2O
  25. A new polyborate anion, [B7O9(OH)6]3−: Self assembly, XRD and thermal properties of s-fac-[Co(dien)2][B7O9(OH)6]·9H2O
  26. K(I)-M(II) (M = Co, Mn) heterometallic-(perfluorinated) organic frameworks containing inorganic layered K–O–M linkages: synthesis, crystal structure, and magnetic properties
  27. A New Decaoxidooctaborate(2−) Anion, [B 8 O 10 (OH) 6 ] 2– : Synthesis and Characterization of [Co(en) 3 ][B 5 O 6 (OH) 4 ][B 8 O 10 (OH) 6 )]·5H 2 O (en = 1,2-Diaminoethane)
  28. Boron Chemistry
  29. Pentaborate(1−) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations
  30. Computational studies on gas phase polyborate anions
  31. Synthesis and X-ray structural studies of pentaborate(1−) salts containing substituted imidazolium cations
  32. Organic biomolecules bind to phosphate through borate linkages in aqueous solutions
  33. Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties
  34. CHAPTER 1. Compounds Containing Boron–Chalcogen Bonds
  35. Structural and thermal studies of non-metal cation pentaborate salts with cations derived from 1,5-diazobicyclo[4.3.0]non-5-ene, 1,8-diazobicyclo[5.4.0]undec-7-ene and 1,8-bis(dimethylamino)naphthalene
  36. Synthesis, thermal properties and structural characterisation, of the tetraphenylphosphonium pentaborate salt, [PPh4][B5O6(OH)4]·1.5H2O
  37. Templated heptaborate and pentaborate salts of cyclo-alkylammonium cations: structural and thermal properties
  38. Synthesis and Structural Characterization of an Unprecedented Nonmetal Cation Polyborate Salt Containing Two Different “Isolated” Polyborate Anions: [H2en]2[B4O5(OH)4][B7O9(OH...
  39. ChemInform Abstract: Boron
  40. Tetraphenylboroxinate(1-) salts of monoborate cations: Synthesis and single-crystal X-ray structures of [Ph2B{OCH2CH2N(Me)(CH2)n}2][Ph4B3O3] (n=4, 5)
  41. Tetraphenylphosphonium octahydrotriborate
  42. Bis(triphenylphosphoranylidene)ammonium iodide
  43. Structural (XRD) and thermal (DSC, TGA) and BET analysis of materials derived from non-metal cation pentaborate salts
  44. Synthesis, characterization, and thermal properties of benzylammonium pentaborate [C6H5CH2NH3][B5O6(OH)4]
  45. A 11B NMR study of zwitterionic and cationic monoborate complexes with cationic 1,2-diol ligands
  46. ChemInform Abstract: Compounds Containing the Boron-Chalcogen B-E (E: S, Se, Te) Bond
  47. Synthesis of aluminium borate–boron oxide and binary titanium–boron and zirconium–boron oxides from metal alkoxides and (MeO)3B3O3 in non-aqueous solvents
  48. Supramolecular structures containing ‘isolated’ pentaborate anions and non-metal cations: Crystal structures of [Me3NCH2CH2OH][B5O6(OH)4] and [4-MepyH, 4-Mepy][B5O6(OH)4]
  49. An Unprecedented Polyborate Ester Anion:  X-ray Diffraction Studies on [1,8-C 10 H 6 (NMe 2 ) 2 H][B 5 O 6 (OMe) 4 ]
  50. fac,cis-Bromidotricarbonylbis(tribenzylphosphine)rhenium(I)
  51. Chapter 1. Compounds Containing the Boron–Chalcogen B–E (ES, Se, Te) Bond
  52. Formation of borosilicate glasses from silicon alkoxides and metaborate esters in dry non-aqueous solvents
  53. Synthesis and X-ray characterization of the organotriboroxinate salts [Me3NCH2CH2OH][Ph4B3O3] and [NEt3H][Ph3B3O3(OH)], and the X-ray structure of the triarylboroxine, (4-MeOC6H4)3B3O3
  54. Pentafluorophenylboronic acid
  55. A mixed-halogen tricarbonylmanganese(I) complex:fac-[MnBr0.3Cl0.7{Ph2P(CH2)3PPh2}(CO)3]
  56. A crystallographic and spectroscopic investigation of the stereochemistry of [MBr(CO)3L2] (M=Mn, Re) complexes: crystal and molecular structures of [MBr(CO)3L2] {M=Mn, L=P(C6H4Cl-4)3, 1/2dppe, 1/2dppf; M=Re, L=P(C6H4OMe-4)3, 1/2dppf}
  57. Synthesis and characterisation of cyclo-boratetrasiloxane, (RBO)(Me2SiO)3 (R=nBu, Ar), derivatives
  58. A supramolecular assembly: aquatris(pentafluorophenyl)borane as its mixed dimethyl sulfone and water solvate, (H2O)B(C6F5)3·Me2SO2·H2O
  59. Synthesis and characterisation of a series of Group 7 metal 2,2,2,2-dicarbonylbis(triorganophosphine)-arachno-2-metallatetraboranes, [M(CO)2L2(B3H8)] (M=Re, Mn); crystal and molecular structures of [Re(CO)2(dppf)(B3H8)] and [Mn(CO)2(dppe)(B3H8)]
  60. A comparative study of seven co-ordinate Mo(II) and W(II) catalysts in the ring opening polymerization of norbornene
  61. Bis(triphenylstannyl)borate toluene solvate
  62. GELS AND POLYMERIC MATERIALS FROM ISOCYANATES AND METABORATE ESTERS.
  63. ChemInform Abstract: Synthesis and Lewis Acidity of Organo B-O-Si and B-O-Sn Derivatives
  64. Organophosphoryl adducts of tris(pentafluorophenyl)borane; crystal and molecular structure of B(C6F5)3·Ph3PO
  65. Lewis Acidity in Haloalkyl Orthoborate and Metaborate Esters
  66. Lewis acidity of tris(pentafluorophenyl)borane: crystal and molecular structure of B(C6F5)3·OPEt3
  67. Synthesis and Lewis acidity of organo B-O-Si and B-O-Sn derivatives
  68. cyclo-Boratrisiloxane and cyclo-diboratetrasiloxane derivatives and their reactions with amines: crystal and molecular structure of (p-BrC6H4BO)2(Ph2SiO)2
  69. Trimethoxyboroxine as an ‘oxygen-transfer’ reagent: a non-aqueous ‘sol–gel’ route to alkali-free borosilicate glass
  70. Synthesis and Lewis acidity of triorganosilyl and triorganostannyl esters of orthoboric, metaboric, and arylboronic acids
  71. π-Bonding in B–O ring species: Lewis acidity of Me3B3O3, synthesis of amine Me3B3O3 adducts, and the crystal and molecular structure of Me3B3O3.NH2iBu·MeB(OH)2
  72. Chapter 3. Boron
  73. Synthesis and Characterisation of Amine Adducts of Tri(4-bromophenyl) boroxine, Tri(3-nitrophenyl)boroxine, and Tri(3-aminophenyl)boroxine; Molecular Structure of 3-Picoline·tri(4-bromophenyl)boroxine
  74. The synthesis, molecular structure and fluxional properties of the 1-phenylpropyne complex [WI2(CO){Ph2P(CH2)PPh2}(η2-MeC2Ph)]
  75. Chapter 3. Boron
  76. Amine adducts of triarylboroxines: Synthesis and characterization of adducts of tri(2-tolyl) boroxine and crystal structures of (4-MeC6H4)3B3O3 and (4-MeC6H4) 3B3O3 · 4-picoline
  77. The Interaction of Benzyl Alcohol with Trimethoxyboroxine: Amine Adducts of Triarylboroxines as Model Compounds
  78. Chapter 3. Boron
  79. Synthesis and Solid State11B-{1H} Mas Nmr Investigations of some Group 11arachno-2-Metallatetraboranes
  80. The Interaction of Benzyl Alcohol with Trimethoxyboroxine : Amine Adducts of Triarylboroxines as Model Compounds
  81. A convenient n.m.r. method for the measurement of Lewis acidity at boron centres: correlation of reaction rates of Lewis acid initiated epoxide polymerizations with Lewis acidity
  82. Iodotris(triphenylphosphine)silver(I), [Ag(PPh3)3I]
  83. Chapter 3. Boron
  84. [Bis(3-aminopropyl)phenylphosphine-N,P]tetracarbonylmolybdenum(0)
  85. Synthesis and characterization of amine adducts of tri(4-tolyl)boroxine and tri(3,5-xylyl)boroxine: molecular structure of (4-MeC6H4)3B3O3·cyclohexylamine
  86. Synthesis and spectroscopic characterization of 3,5-diaryl-cyclo-1,2,4-trithia-3,5-diborolanes, Ar2B2S3 (Ar  Ph, 2-MeC6H4, 3-MeC6H4, 4-MeC6H4, 4-EtC6H4, 3,5-Me2C6H3), and some related chemistry of boron-sulphur heterocyclic species
  87. Chapter 3. Boron
  88. Synthesis ofB-Aryl Boron-Sulphur Heterocycles from Arylborondibromides
  89. Synthesis and characterization of triarylborthiins, Ar3B3S3 (Ar = 4-MeC6H4, 3-MeC6H4, 2-MeC6H4, 4-EtC6H4 and 3,5-Me2C6H3)
  90. An Investigation of the Reactivity of [Rh2Cp∗2(μ-CO)2] (Cp∗ = η5-C5Me5) Towards Triorganosilanes: Isolation and Characterization of [RhCp∗(CO)(H)(SiPh3)] and Some Related Compounds
  91. Chapter 3. Boron
  92. Protodeboronation of arylboronic acids and triarylboroxines in Bu20/THF
  93. Chapter 2. Boron
  94. Chapter 2. Boron
  95. Nido-6-metalladecaborane chemistry: Molecular structure and fluxionality of [6,6,6,6-(CO)2(PPh3)2-nido-6-WB9H13]
  96. Ligand substitution reactions of metal and organometal carbonyls with group V and VI donor ligands
  97. Coordination chemistry of bis(3-aminopropyl)phenylphosphine (bap): reactions of bap with some d6 metal complexes of molybdenum(0), tungsten(0) and platinum(IV)
  98. An NMR study of some seven-coordinate organophosphine carbonyl iodide derivatives of molybdenum(II) and tungsten(II)
  99. Chapter 2. Boron
  100. Reactions of nonaborane anions with some seven-coordinate carbonyl iodide complexes of molybdenum(II) and tungsten(II)
  101. Ligand substitution reactions of metal and organometal carbonyls with group V and VI donor ligands
  102. Phosphorus-31 Fluorine-19 N.M.R. Through-Space Coupling
  103. Chapter 2. Boron
  104. Computer simulation and solvatochromic studies of the solvation of a betaine in single and mixed solvent systems
  105. Ligand substitution reactions of metal and organometal carbonyls with group 15 and 16 donor ligands
  106. Kinetics of the Co(II)(Salen) catalysed hydration of styrene to 1-phenylethan-l-ol in ethanol solution
  107. A computer simulation of the solvation of a solvatochromic pyridinium betaine
  108. Preparation, structure, and nuclear magnetic resonance properties of the nine-vertex nido-rhenaborane [(PMe2Ph)3H2ReB8H11] and some related chemistry
  109. Trimethylplatenum(IV) complexes of the dimethyldithioarsinate(V) anion: Preparation and molecular structure of the dinuclear [(PtMe3)2(Me2AsS2)2] and its selective fission to mononuclear [PtMe3(Me2AsS2)L] (L = PPh3, PPh2Me, py) complexes
  110. Interaction of the diphenyldichalcogens, C6H5EEC6H5 (E = S, Se and Te), with the tetrameric halogenotrimethylplatinums. The formation and characterization of [{PtX(CH3)3}2C6H5TeTeC6H5] (X = Br and I) and a dynamic nuclear magnetic resonance study of [{...
  111. Bis(dimethylarsino)sulphide (dmas) complexes of the trimethylplatinum halides: the synthesis and characterization of fac-[(PtXMe3)(dmas)2] and the binuclear [(PtXMe3)2(dmas)] (X = Cl, Br, I) complexes, the crystal and molecular structure of [(PtBrMe3)2...
  112. Sulphur–arsenic ligands. Dimethyl(methylthio)arsine complexes of halogenotrimethylplatinum(IV) and tricarbonylhalogenorhenium(I)
  113. Sulphur-arsenic ligands: synthesis and characterization of some rhenium(I), ruthenium(II), rhodium(III) and gold(I) complexes of bis(dimethylarsino)sulphide(Me2AsSAsMe2) and dimethyl(methylthio)arsine(Me2AsSMe)
  114. Enantiomer Discriminating Dehydrogenation of (R,S)-(±)-1-Phenylethan-1-ol to Acetophenone Catalysed by Chiral Cobalt(II) Schiff's Base Complexes and Triphenylphosphine
  115. Equatorial and axial ligand effects in square planar Co(II) complexes catalysing the oxidation of 1-phenylethan-1-ol to acetophenone
  116. The kinetics of the oxidation of 1-phenylethanol catalysed by Co(II)(salen) with triphenylphosphine
  117. Comparative ten-vertex metallaborane chemistry: some nido-6-metalladecaboranes of tungsten, rhenium, ruthenium, osmium, and iridium; including the crystal and molecular structures of [6,6,6,6,6-(PMe2Ph)3H2-nido-6-WB9H13] and [6,6,6-(PMe2Ph)3-nido-6-OsB...
  118. Synthesis, molecular structures, and nuclear magnetic resonance properties of the macropolyhedral metallaboranes [(PMe2Ph)4Pt3B14H16] and [(PMe2Ph)PtB16H18(PMe2Ph)], and a discussion of the bonding at platinum in these and some related platinaborane cl...
  119. Polyhedral phosphaborane chemistry: crystal and molecular structure of the diphenylphosphido-bridged arachno-decaboranyl cluster compound [PMePh3][6,9-µ-(PPh2)B10H12]
  120. Identification and molecular structure of the eighteen-vertex macropolyhedral diplatinaoctadecaborane [(PMe2Ph)2Pt2B16H15(C6H4Me)(PMe2Ph)]
  121. Correlation of thallium–boron nuclear spin states by two-dimensional n.m.r. spectroscopy: magnitudes and relative signs of couplingsnJ(205Tl–11B) in the nido-thallaundecaborane anion [Me2TlB10H
  122. Polyhedral rhenaborane chemistry: crystal and molecular structures of the nido-6-rhenadecaborane cluster compounds [6,6,6,6-(PMe2Ph)3H-nido-6- ReB9H13] and [2-(PMe2Ph)-6,6,6,6-(PMe2Ph)2ClH-nido-6-ReB9H12]; nuclear magnetic resonance parameters of these...
  123. Preparation, crystal and molecular structure of, and NMR parameters for, the exopolyhedral heterocyclic platinaundecaborane [μ-2,7-(SCSNEt2)-7-(PMe2Ph)-NIDO-7-PtB10H11]
  124. Synthesis and nuclear magnetic resonance study of the auranonaborane and diauradecaborane arachno-type compounds, [4-(S2CNEt2)-arachno-4-AuB8H12] and [6,9-(S2CNEt2)2-arachno-6,9-Au2B8H10]; crystal and molecular structure of [6,9-(S2CNEt2)2-arachno-6,9-...
  125. A macropolyhedral polymetallaborane cluster: molecular structure of the seventeen-vertex triplatinaheptadecaborane [(PhMe2P)4Pt3B14H16]
  126. An n.m.r. study of the arachno-[B10H12PPh2]–anion: and interesting arachno→arachno topological transition induced by deprotonation
  127. Molecular structure of the 17-vertex conjuncto-platinaheptadecaborane [(PMe2Ph){PtB16H18(PMe2Ph)}]: a 16-vertex η6-hexadecaboranyl ligand