All Stories

  1. Accessing novel fluorinated heterocycles with the hypervalent fluoroiodane reagent by solution and mechanochemical synthesis
  2. Fluorinations of unsymmetrical diaryliodonium salts containingortho-sidearms; influence of sidearm on selectivity
  3. Activation of the hypervalent fluoroiodane reagent by hydrogen bonding to hexafluoroisopropanol
  4. Single-Fluorophore Detection in Femtoliter Droplets Generated by Flow Focusing
  5. Intramolecular Fluorocyclizations of Unsaturated Carboxylic Acids with a Stable Hypervalent Fluoroiodane Reagent
  6. Preparation of iodonium ylides: probing the fluorination of 1,3-dicarbonyl compounds with a fluoroiodane
  7. Fluorous Organometallic Chemistry
  8. Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride
  9. Synthesis of α-fluoro-β-hydroxy esters by an enantioselective Reformatsky-type reaction
  10. Enantioselective Reformatsky reaction of ethyl iododifluoroacetate with ketones
  11. A recyclable perfluoroalkylated PCP pincer palladium complex
  12. Di(1H,1H,2H,2H-perfluorooctyl)-dibenzo-18-crown-6: A “light fluorous” recyclable phase transfer catalyst
  13. Insoluble Perfluoroalkylated Polymers: New Solid Supports for Supported Fluorous Phase Catalysis
  14. Coordination chemistry of perfluoroalkylated phosphorus(III) ligands
  15. Synthesis and coordination chemistry of fluorinated phosphonic acids
  16. Controlling phase behaviour on gas expansion of fluid mixtures
  17. Probing the structure of gas expanded liquids using relative permittivity, density and polarity measurements
  18. State-of-the-Art and Typical Reactions
  19. Perfluoroalkylated 4,13-Diaza-18-Crown-6 Ethers:  Synthesis, Phase-Transfer Catalysis, and Recycling Studies
  20. Synthesis and characterisation of trisarylphosphine selenides: Further insight into the effect of fluoroalkylation on the electronic properties of trisarylphosphines
  21. Syntheses and Properties of Fluorous Quaternary Phosphonium Salts that Bear Four Ponytails; New Candidates for Phase Transfer Catalysts and Ionic Liquids
  22. Supported Fluorous Phase Catalysis on PTFE, Fluoroalkylated Micro- and Meso-porous Silica
  23. Coordination chemistry of 1,2-bis{di-(4-methoxyphenyl)phosphino}ethane (L-L) to nickel, palladium and platinum: Single crystal structures of [MCl2(L-L)] (M=Ni, Pd)
  24. Rhodium, palladium and platinum coordination complexes of fluoroalkylated-BINAP and -MonoPhos ligands
  25. 4,5-Bis[bis(diethylamino)phosphino]-9,9-dimethylxanthene
  26. (R)-2,2′-Bis(diphenylphosphino)-6,6′-bis(tridecafluoro-n-hexyl)-1,1′-binaphthyl
  27. Synthesis and coordination chemistry of fluorinated xanthate ligands
  28. Synthesis and coordination chemistry of perfluoroalkylated dithiophosphate ligands
  29. Rhodium catalysed hydroformylation of alkenes using highly fluorophilic phosphines
  30. Recycling of a perfluoroalkylated BINOL ligand using fluorous solid-phase extraction
  31. Ruthenium-catalysed asymmetric hydrogenation with fluoroalkylated BINAP ligands in supercritical CO2
  32. Towards the synthesis of perfluoroalkylated derivatives of Xantphos
  33. Hydroformylation in fluorous solvents
  34. Recovery and recycle of fluoroalkyl-derivatised BINAP ligands using FRP silica gel
  35. Phosphorous(III) compounds incorporating perfluoroalkyl-derivatised biphenolic units
  36. Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2This work was presented at the Green Solvents for Catalysis Meeting held in Bruchsal, Germany, 13–16th October 2002.
  37. Separation, recovery and recycling of a fluorous-tagged nickel catalyst using fluorous solid-phase extractionElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b3/b308543k/
  38. Synthesis and coordination chemistry of perfluoroalkyl-derivatised β-diketonates
  39. Synthesis and coordination chemistry of perfluoroalkyl-derivatised triarylphosphites
  40. Hydroformylation in perfluorinated solvents; improved selectivity, catalyst retention and product separation
  41. Synthesis and coordination chemistry of ortho-perfluoroalkyl-derivatised triarylphosphines
  42. Synthesis of fluoroalkyl-derivatised BINAP ligands
  43. Synthesis and coordination chemistry of PEt(C6H4–4-C6F13)2. Crystal structure of cis-[PtCl2{PEt(C6H4–4-C6F13)2}2]
  44. Rapid hydroformylation of alkyl acrylates in supercritical CO2
  45. Structural and electronic impact of fluorine in the ortho positions of triphenylphosphine and 1,2-bis(diphenylphosphino)ethane; a comparison of 2,6-difluorophenyl- with pentafluorophenyl-phosphines
  46. Effects of the ponytails of arylphosphines on the hydroformylation of higher olefins in supercritical CO2
  47. A convenient access to triarylphosphines with fluorous phase affinity
  48. Platinum group metal complexes of arylphosphine ligands containing perfluoroalkyl ponytails; crystal structures of [RhCl2(η5-C5Me5){P(C6H4C6F13-4)3}] and cis- and trans-[PtCl2{P(C6H4C6F13-4)3}2]
  49. Platinum group metal complexes of a bis(diphenylphosphino)ethane ligand containing perfluoroalkyl ponytails
  50. Phosphorus(III) ligands with fluorous ponytails
  51. Fluorous-phase soluble rhodium complexes: X-ray structure of [RhCl(CO)(P(C2H4C6F13)3 )2]