Professor Pedro J. Perez

All Stories

1. 
   [Hydrotris(3-(2,4,6-trimethylphenyl))pyrazolylborate]copper

   Article • March 2016, Wiley

   Professor Pedro J. Perez

2. 
   Preface

   Article • January 2016, Elsevier

   Professor Pedro J. Perez

3. 
   Evidencing an inner-sphere mechanism for NHC-Au(I)-catalyzed carbene-transfer reactions from ethyl diazoacetate

   Article • Beilstein Journal of Organic Chemistry, November 2015, Beilstein Institut

   Professor Pedro J. Perez

4. 
   Functionalization of CnH2n+2Alkanes: Supercritical Carbon Dioxide Enhances the Reactivity towards Primary Carbon-Hydrogen Bonds

   Article • ChemCatChem, September 2015, Wiley

   Professor Pedro J. Perez

5. 
   Direct Synthesis of Hemiaminal Ethersviaa Three-Component Reaction of Aldehydes, Amines and Alcohols

   Article • Advanced Synthesis & Catalysis, September 2015, Wiley

   Professor Pedro J. Perez

6. 
   Catalyst design in the alkane C–H bond functionalization of alkanes by carbene insertion with TpxM complexes (Tpx = hydrotrispyrazolylborate ligand; M = Cu, Ag)

   Article • Journal of Organometallic Chemistry, September 2015, Elsevier

   Professor Pedro J. Perez

7. 
   Discovering Copper for Methane C–H Bond Functionalization

   Article • ACS Catalysis, June 2015, American Chemical Society (ACS)

   Professor Pedro J. Perez

8. 
   Copper-Carbene Intermediates in the Copper-Catalyzed Functionalization of OH Bonds

   Article • Chemistry - A European Journal, May 2015, Wiley

   Professor Pedro J. Perez

9. 
   A computational view on the reactions of hydrocarbons with coinage metal complexes

   Article • Journal of Organometallic Chemistry, May 2015, Elsevier

   Professor Pedro J. Perez, Ataualpa Braga

10. 
    Chiral, Sterically Demanding N-Heterocyclic Carbenes Fused into a Heterobiaryl Skeleton: Design, Synthesis, and Structural Analysis

    Article • Organometallics, April 2015, American Chemical Society (ACS)

    Professor Pedro J. Perez

11. 
    A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow

    Article • Chemical Science, January 2015, Royal Society of Chemistry

    Professor Pedro J. Perez

12. 
    Copper-catalysed azide–alkyne cycloadditions (CuAAC): an update

    Article • Organic & Biomolecular Chemistry, January 2015, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

13. 
    Catalytic functionalization of low reactive C(sp3)–H and C(sp2)–H bonds of alkanes and arenes by carbene transfer from diazo compounds

    Article • Dalton Transactions, January 2015, Royal Society of Chemistry

    Professor Pedro J. Perez

14. 
    Preface

    Article • January 2015, Elsevier

    Professor Pedro J. Perez

15. 
    Silver-Catalyzed Functionalization of Esters by Carbene Transfer: The Role of Ylide Zwitterionic Intermediates

    Article • ChemCatChem, July 2014, Wiley

    Professor Pedro J. Perez

16. 
    1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap

    Article • Chemical Communications, June 2014, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

17. 
    Catalytic Functionalization of Indoles by Copper-Mediated Carbene Transfer

    Article • ChemCatChem, June 2014, Wiley

    Professor Pedro J. Perez

18. 
    Syntheses of a Novel Fluorinated Trisphosphinoborate Ligand and Its Copper and Silver Complexes. Catalytic Activity toward Nitrene Transfer Reactions

    Article • Inorganic Chemistry, April 2014, American Chemical Society (ACS)

    Professor Pedro J. Perez

19. 
    Chemo-, Regio-, and Stereoselective Silver-Catalyzed Aziridination of Dienes: Scope, Mechanistic Studies, and Ring-Opening Reactions

    Article • Journal of the American Chemical Society, April 2014, American Chemical Society (ACS)

    Professor Pedro J. Perez

20. 
    Synthesis, Structural Characterization, Reactivity, and Catalytic Properties of Copper(I) Complexes with a Series of Tetradentate Tripodal Tris(pyrazolylmethyl)amine Ligands

    Article • Inorganic Chemistry, April 2014, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

21. 
    Reaction of Alkynes and Azides: Not Triazoles Through Copper–Acetylides but Oxazoles Through Copper–Nitrene Intermediates

    Article • Chemistry - A European Journal, February 2014, Wiley

    Professor M Carmen Nicasio, Professor Pedro J. Perez

22. 
    Supercritical Carbon Dioxide: A Promoter of Carbon-Halogen Bond Heterolysis

    Article • Angewandte Chemie International Edition, October 2013, Wiley

    Professor Pedro J. Perez

23. 
    Catalytic C–H amination of alkanes with sulfonimidamides: silver(I)-scorpionates vs. dirhodium(II) carboxylates

    Article • Tetrahedron, June 2013, Elsevier

    Professor Pedro J. Perez

24. 
    Introducing Copper as Catalyst for Oxidative Alkane Dehydrogenation

    Article • Journal of the American Chemical Society, March 2013, American Chemical Society (ACS)

    Professor Pedro J. Perez

25. 
    A General Mechanism for the Copper- and Silver-Catalyzed Olefin Aziridination Reactions: Concomitant Involvement of the Singlet and Triplet Pathways

    Article • Journal of the American Chemical Society, January 2013, American Chemical Society (ACS)

    Professor Pedro J. Perez

26. 
    Silver-catalyzed silicon–hydrogen bond functionalization by carbene insertion

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

27. 
    Catalytic cross-coupling of diazo compounds with coinage metal-based catalysts: an experimental and theoretical study

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor Pedro J. Perez

28. 
    Methane as raw material in synthetic chemistry: the final frontier

    Article • Chemical Society Reviews, January 2013, Royal Society of Chemistry

    Professor Pedro J. Perez

29. 
    Mild Catalytic Functionalization of Styrene–Butadiene Rubbers

    Article • Macromolecules, December 2012, American Chemical Society (ACS)

    Professor Pedro J. Perez

30. 
    Functionalization of Non-activated CH Bonds of Alkanes: An Effective and Recyclable Catalytic System Based on Fluorinated Silver Catalysts and Solvents

    Article • Chemistry - A European Journal, November 2012, Wiley

    Professor Pedro J. Perez

31. 
    Introduction to the Ennobling a Base Metal: Presenting Copper in Organometallic Chemistry Issue

    Article • Organometallics, November 2012, American Chemical Society (ACS)

    Professor Pedro J. Perez

32. 
    Copper-Catalyzed Nitrene Transfer as a Tool for the Synthesis of N-Substituted 1,2-Dihydro- and 1,2,3,4-Tetrahydropyridines

    Article • Organometallics, November 2012, American Chemical Society (ACS)

    Professor Pedro J. Perez

33. 
    Copper(I) Complexes with Trispyrazolylmethane Ligands: Synthesis, Characterization, and Catalytic Activity in Cross-Coupling Reactions

    Article • Inorganic Chemistry, July 2012, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

34. 
    [(PhBP 3 )Cu(PPh 3 )] as a Surrogate of Tp x CuL in Homogeneous Catalysis (PhBP 3 = PhB(CH 2 PPh 2 ) 3 ; Tp x = Hydrotrispyrazolylborate)

    Article • Organometallics, February 2012, American Chemical Society (ACS)

    Professor Pedro J. Perez

35. 
    Polynuclear Copper(I) Complexes with Chelating Bis- and Tris-N-Heterocyclic Carbene Ligands: Catalytic Activity in Nitrene and Carbene Transfer Reactions

    Article • European Journal of Organic Chemistry, January 2012, Wiley

    Professor Pedro J. Perez

36. 
    Catalytic Hydrocarbon Functionalization with Gold Complexes Containing N-Heterocyclic Carbene Ligands with Pendant Donor Groups

    Article • European Journal of Inorganic Chemistry, January 2012, Wiley

    Professor Antonio M Echavarren, Professor Pedro J. Perez

37. 
    Cu(i)-catalyzed atom transfer radical cyclization of trichloroacetamides tethered to electron-deficient, -neutral, and -rich alkenes: synthesis of polyfunctionalized 2-azabicyclo[3.3.1]nonanes

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Professor Pedro J. Perez, Professor Faïza DIABA

38. 
    Hydrotris(3-mesitylpyrazolyl)borato-copper(i) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalysts

    Article • Dalton Transactions, January 2012, Royal Society of Chemistry

    Professor Pedro J. Perez

39. 
    Intramolecular cycloaddition of azomethine ylides, from imines of O-acylsalicylic aldehyde and ethyl diazoacetate, to ester carbonyl – experimental and DFT computational study

    Article • Organic & Biomolecular Chemistry, January 2012, Royal Society of Chemistry

    Professor Pedro J. Perez

40. 
    Alkane C-H Activation by Single-Site Metal Catalysis

    Article • January 2012

    Professor Pedro J. Perez

41. 
    Mechanism of Side Reactions in Alkane CH Bond Functionalization by Diazo Compounds Catalyzed by Ag and Cu Homoscorpionate Complexes-A DFT Study

    Article • ChemCatChem, August 2011, Wiley

    Professor Pedro J. Perez, Ataualpa Braga

42. 
    Atom Transfer Radical Reactions as a Tool for Olefin Functionalization - On the Way to Practical Applications

    Article • European Journal of Inorganic Chemistry, June 2011, Wiley

    Professor Pedro J. Perez

43. 
    Gold-catalyzed naphthalene functionalization

    Article • Beilstein Journal of Organic Chemistry, May 2011, Beilstein Institut

    Professor Pedro J. Perez

44. 
    Exclusive Aromatic vs Aliphatic C–H Bond Functionalization by Carbene Insertion with Gold-Based Catalysts

    Article • Organometallics, May 2011, American Chemical Society (ACS)

    Professor Pedro J. Perez

45. 
    Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2

    Article • Science, May 2011, American Association for the Advancement of Science

    Professor Pedro J. Perez

46. 
    Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate: Gold as a ligand

    Article • Inorganica Chimica Acta, April 2011, Elsevier

    Professor Angeles Monge, Professor Pedro J. Perez

47. 
    Mechanistic and Computational Studies of the Atom Transfer Radical Addition of CCl 4 to Styrene Catalyzed by Copper Homoscorpionate Complexes

    Article • Inorganic Chemistry, March 2011, American Chemical Society (ACS)

    Professor Pedro J. Perez

48. 
    Direct, copper-catalyzed oxidation of aromatic C–H bonds with hydrogen peroxide under acid-free conditions

    Article • Chemical Communications, January 2011, Royal Society of Chemistry

    Professor Pedro J. Perez

49. 
    Regioselective Formation of 2,5-Disubstituted Oxazoles Via Copper(I)-Catalyzed Cycloaddition of Acyl Azides and 1-Alkynes

    Article • Journal of the American Chemical Society, December 2010, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

50. 
    Catalytic cyclopropanation of polybutadienes

    Article • Journal of Polymer Science Part A Polymer Chemistry, September 2010, Wiley

    Professor Pedro J. Perez

51. 
    Copper(I)−Olefin Complexes: The Effect of the Trispyrazolylborate Ancillary Ligand in Structure and Reactivity

    Article • Organometallics, August 2010, American Chemical Society (ACS)

    Professor Pedro J. Perez

52. 
    Efficient Silver-Catalyzed Regio- and Stereospecific Aziridination of Dienes

    Article • Angewandte Chemie International Edition, August 2010, Wiley

    Professor Pedro J. Perez

53. 
    Efficient Atom-Transfer Radical Polymerization of Methacrylates Catalyzed by Neutral Copper Complexes

    Article • Macromolecules, April 2010, American Chemical Society (ACS)

    Professor Pedro J. Perez

54. 
    Selective Synthesis of N-Substituted 1,2-Dihydropyridines from Furans by Copper-Induced Concurrent Tandem Catalysis

    Article • Journal of the American Chemical Society, April 2010, American Chemical Society (ACS)

    Professor Pedro J. Perez

55. 
    Copper(i) complexes as catalysts for the synthesis of N-sulfonyl-1,2,3-triazoles from N-sulfonylazides and alkynes

    Article • Organic & Biomolecular Chemistry, January 2010, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

56. 
    The Mechanism of the Catalytic Functionalization of Haloalkanes by Carbene Insertion: An Experimental and Theoretical Study

    Article • Organometallics, October 2009, American Chemical Society (ACS)

    Professor Pedro J. Perez, Ataualpa Braga

57. 
    Hydrotrispyrazolylborate-copper complexes as catalysts for the styrene cyclopropanation reaction with ethyl diazoacetate under homogeneous and heterogeneous conditions

    Article • Inorganica Chimica Acta, September 2009, Elsevier

    Professor M Carmen Nicasio, Professor Pedro J. Perez

58. 
    Dinuclear Copper(I) Complexes as Precatalysts in Ullmann and Goldberg Coupling Reactions

    Article • Organometallics, June 2009, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

59. 
    Metal-Catalyzed Olefin Cyclopropanation with Ethyl Diazoacetate: Control of the Diastereoselectivity

    Article • European Journal of Inorganic Chemistry, March 2009, Wiley

    Professor Pedro J. Perez

60. 
    Gold-catalyzed olefin cyclopropanation

    Article • Tetrahedron, February 2009, Elsevier

    Professor Antonio M Echavarren, Professor Pedro J. Perez

61. 
    Asymmetric β-Boration of α,β-Unsaturated Esters with Chiral (NHC)Cu Catalysts

    Article • Organometallics, January 2009, American Chemical Society (ACS)

    Professor Pedro J. Perez

62. 
    Highly active gold-based catalyst for the reaction of benzaldehyde with ethyl diazoacetate

    Article • Chemical Communications, January 2009, Royal Society of Chemistry

    Professor Pedro J. Perez

63. 
    Rediscovering copper-based catalysts for intramolecular carbon–hydrogen bond functionalization by carbene insertion

    Article • Organic & Biomolecular Chemistry, January 2009, Royal Society of Chemistry

    Professor Pedro J. Perez

64. 
    Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

65. 
    Copper-Catalyzed Synthesis of 1,2-Disubstituted Cyclopentanes from 1,6-Dienes by Ring-Closing Kharasch Addition of Carbon Tetrachloride

    Article • Advanced Synthesis & Catalysis, October 2008, Wiley

    Professor Pedro J. Perez

66. 
    A New Perfluorinated F 21 -Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F 21 -Tp)M Catalysts (M = Cu, Ag)

    Article • Organometallics, September 2008, American Chemical Society (ACS)

    Professor Pedro J. Perez

67. 
    Easy Alkane Catalytic Functionalization

    Article • Organometallics, August 2008, American Chemical Society (ACS)

    Professor Pedro J. Perez

68. 
    Coinage Metal Catalyzed C−H Bond Functionalization of Hydrocarbons

    Article • Chemical Reviews, August 2008, American Chemical Society (ACS)

    Professor Pedro J. Perez

69. 
    Gold-promoted styrene polymerization

    Article • Chemical Communications, January 2008, Royal Society of Chemistry

    Professor Pedro J. Perez

70. 
    Catalytic Carbon−Hydrogen Bond Functionalization in an Ionic Liquid Medium

    Article • Organometallics, November 2007, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

71. 
    Synthesis, Characterization, and Reactivity of Ruthenium Diene/Diamine Complexes Including Catalytic Hydrogenation of Ketones

    Article • Inorganic Chemistry, September 2007, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

72. 
    Effects of the Substituents in the Tp x Cu Activation of Dioxygen:  An Experimental Study

    Article • Inorganic Chemistry, September 2007, American Chemical Society (ACS)

    Professor Pedro J. Perez

73. 
    Copper−Homoscorpionate Complexes as Active Catalysts for Atom Transfer Radical Addition to Olefins

    Article • Inorganic Chemistry, September 2007, American Chemical Society (ACS)

    Professor Pedro J. Perez

74. 
    The Effect of Catalyst Loading in Copper-Catalyzed Cyclohexane Functionalization by Carbene Insertion

    Article • European Journal of Inorganic Chemistry, June 2007, Wiley

    Professor Pedro J. Perez

75. 
    A Valuable, Inexpensive CuI/N-Heterocyclic Carbene Catalyst for the Selective Diboration of Styrene

    Article • Chemistry - A European Journal, March 2007, Wiley

    Professor Pedro J. Perez, Ataualpa Braga

76. 
    Unusual Polybrominated Polypyrazolylborates and Their Copper(I) Complexes:  Synthesis, Characterization, and Catalytic Activity

    Article • Inorganic Chemistry, February 2007, American Chemical Society (ACS)

    Professor Pedro J. Perez

77. 
    Mechanism of Alkane C−H Bond Activation by Copper and Silver Homoscorpionate Complexes

    Article • Organometallics, October 2006, American Chemical Society (ACS)

    Professor Pedro J. Perez, Ataualpa Braga

78. 
    Alkane Carbon−Hydrogen Bond Functionalization with (NHC)MCl Precatalysts (M = Cu, Au; NHC = N-Heterocyclic Carbene)

    Article • Organometallics, April 2006, American Chemical Society (ACS)

    Professor Pedro J. Perez

79. 
    Very Efficient, Reusable Copper Catalyst for Carbene Transfer Reactions under Biphasic Conditions Using Ionic Liquids

    Article • Organic Letters, January 2006, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

80. 
    The carbene insertion methodology for the catalytic functionalization of unreactive hydrocarbons: No classical C–H activation, but efficient C–H functionalization

    Article • Dalton Transactions, January 2006, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

81. 
    Synthesis, isolation and characterization of cationic gold(i) N-heterocyclic carbene (NHC) complexes

    Article • Chemical Communications, January 2006, Royal Society of Chemistry

    Professor Pedro J. Perez

82. 
    A non-fluorous copper catalyst for the styrene cyclopropanation reaction in a fluorous medium

    Article • Chemical Communications, January 2006, Royal Society of Chemistry

    Professor Pedro J. Perez

83. 
    Copper, silver and gold-based catalysts for carbene addition or insertion reactions

    Article • Journal of Organometallic Chemistry, December 2005, Elsevier

    Professor Pedro J. Perez

84. 
    A Gold Catalyst for Carbene-Transfer Reactions from Ethyl Diazoacetate

    Article • Angewandte Chemie International Edition, August 2005, Wiley

    Professor Pedro J. Perez

85. 
    Copper-Catalyzed Addition of Ethyl Diazoacetate to Furans:  An Alternative to Dirhodium(II) Tetraacetate

    Article • The Journal of Organic Chemistry, July 2005, American Chemical Society (ACS)

    Professor Pedro J. Perez

86. 
    Controlled, Copper-Catalyzed Functionalization of Polyolefins

    Article • Macromolecules, June 2005, American Chemical Society (ACS)

    Professor Pedro J. Perez

87. 
    Functionalization of Primary Carbon−Hydrogen Bonds of Alkanes by Carbene Insertion with a Silver-Based Catalyst

    Article • Organometallics, February 2005, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

88. 
    Novel carbon dioxide and carbonyl carbonate complexes of molybdenum. The X-ray structures of trans-[Mo(CO2)2{HN(CH2CH2PMe2)2}(PMe3)] and [Mo3(μ2-CO3...

    Article • New Journal of Chemistry, January 2005, Royal Society of Chemistry

    Professor Angeles Monge, Professor Pedro J. Perez

89. 
    Complete Control of the Chemoselectivity in Catalytic Carbene Transfer Reactions from Ethyl Diazoacetate:  An N-Heterocyclic Carbene−Cu System That Suppresses Diazo Coupling

    Article • Journal of the American Chemical Society, August 2004, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

90. 
    Alkane Dehydrogenation by Sequential, Double C−H Bond Activation by TpBr3Ir(C2H4)2 (TpBr3 = hydrotris(3,4,5-tribromo)pyrazolylborate)

    Article • Organometallics, March 2004, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

91. 
    Copper-Homoscorpionate Complexes as Very Active Catalysts for the Olefin Aziridination Reaction

    Article • Organometallics, December 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

92. 
    Reaction of Ethyl Diazoacetate with Alkyl-Aromatic Substrates:  Influence of the TpxCu Catalyst in the Addition versus Insertion Chemoselectivity (Tpx = Homoscorpionate)

    Article • Organometallics, December 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

93. 
    Cyclohexane and Benzene Amination by Catalytic Nitrene Insertion into C−H Bonds with the Copper-Homoscorpionate Catalyst TpBr3Cu(NCMe)

    Article • Journal of the American Chemical Society, September 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

94. 
    Functionalization of Carbon−Hydrogen Bonds of Hydrocarbons and Ethers via Carbene Insertion with Copper(I)−Homoscorpionate Catalysts

    Article • Organometallics, September 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

95. 
    Copper-Catalyzed Carbene Insertion into O−H Bonds:  High Selective Conversion of Alcohols into Ethers

    Article • Organometallics, June 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

96. 
    Highly Regioselective Functionalization of Aliphatic Carbon−Hydrogen Bonds with a Perbromohomoscorpionate Copper(I) Catalyst

    Article • Journal of the American Chemical Society, January 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

97. 
    CC Bond-Forming Reactions of IrIII-Alkenyls and Nitriles or Aldehydes: Generation of Reactive Hydride- and Alkyl-Alkylidene Compounds and Observation of a Reversible 1,2-H Shift in Stable Hydride–IrIII Alkylidene Complexes

    Article • Chemistry - A European Journal, November 2002, Wiley

    Professor Pedro J. Perez

98. 
    Copper(I)−Homoscorpionate Catalysts for the Preferential, Kinetically Controlled Cis Cyclopropanation of α-Olefins with Ethyl Diazoacetate

    Article • Journal of the American Chemical Society, January 2002, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

99. 
    Intermolecular Copper-Catalyzed Carbon−Hydrogen Bond Activation via Carbene Insertion

    Article • Journal of the American Chemical Society, January 2002, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

100. 
     Catalytic insertion of diazo compounds into N–H bonds: the copper alternative

     Article • Chemical Communications, January 2002, Royal Society of Chemistry

     Professor M Carmen Nicasio, Professor Pedro J. Perez

101. 
     Intramolecular dealkylation of chelating diamines with Ru(ii) complexes

     Article • Chemical Communications, January 2002, Royal Society of Chemistry

     Professor M Carmen Nicasio, Professor Pedro J. Perez

102. 
     Unprecedented Highly cis -Diastereoselective Olefin Cyclopropanation Using Copper Homoscorpionate Catalysts

     Article • Journal of the American Chemical Society, April 2001, American Chemical Society (ACS)

     Professor Pedro J. Perez

103. 
     A family of highly active copper(i)–homoscorpionate catalysts for the alkyne cyclopropenation reaction

     Article • Chemical Communications, January 2001, Royal Society of Chemistry

     Professor M Carmen Nicasio, Professor Pedro J. Perez

104. 
     Synthesis, Characterization, and Reactivity of [(( i Pr) 2 P(CH 2 ) 3 P( i Pr) 2 )(PCy 3 )PdH][OR]

     Article • Organometallics, January 2001, American Chemical Society (ACS)

     Professor Pedro J. Perez

105. 
     From Homogeneous to Heterogeneous Catalysis:  Novel Anchoring of Polypyrazolylborate Copper(I) Complexes on Silica Gel through Classical and Nonclassical Hydrogen Bonds. Use as Catalysts of the Olefin Cyclopropanation Reaction

     Article • Organometallics, January 2000, American Chemical Society (ACS)

     Professor M Carmen Nicasio, Professor Pedro J. Perez

106. 
     Polypyrazolylborate copper(i) complexes as catalysts of the homogeneous and heterogeneous styrene epoxidation reaction

     Article • Chemical Communications, January 2000, Royal Society of Chemistry

     Professor Pedro J. Perez

107. 
     Substitution and Hydrogenation Reactions on Rhodium(I)−Ethylene Complexes of the Hydrotris(pyrazolyl)borate Ligands Tp‘ (Tp‘ = Tp, TpMe2)

     Article • Inorganic Chemistry, December 1999, American Chemical Society (ACS)

     Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

108. 
     Kinetics of the BpCu-Catalyzed Carbene Transfer Reaction (Bp = Dihydridobis(1-pyrazolyl)borate). Is a 14-Electron Species the Real Catalyst for the General Copper-Mediated Olefin Cyclopropanation?

     Article • Organometallics, June 1999, American Chemical Society (ACS)

     Professor M Carmen Nicasio, Professor Pedro J. Perez

109. 
     C−H Bond Activation of Benzene and Cyclic Ethers by TpIrIII Species

     Article • Chemistry - A European Journal, November 1998, Wiley

     Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

110. 
     Vinylic C−H Bond Activation and Hydrogenation Reactions of Tp‘Ir(C2H4)(L) Complexes

     Article • Inorganic Chemistry, August 1998, American Chemical Society (ACS)

     Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

111. 
     BpCu-Catalyzed Cyclopropanation of Olefins:  A Simple System That Operates under Homogeneous and Heterogeneous Conditions (Bp = Dihydridobis(pyrazolyl)borate)

     Article • Organometallics, June 1998, American Chemical Society (ACS)

     Professor M Carmen Nicasio, Professor Pedro J. Perez

112. 
     Substituent Effects on the Reaction Rates of Copper-Catalyzed Cyclopropanation and Aziridination of para -Substituted Styrenes †

     Article • Organometallics, September 1997, American Chemical Society (ACS)

     Professor Pedro J. Perez

113. 
     Formation of Hydrido–η3‐Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands

     Article • Chemistry - A European Journal, June 1997, Wiley

     Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

114. 
     Iridapyrrole Complexes via Formal 3 + 2 Cycloaddition of Iridium Alkenyls to Acetonitrile

     Article • Organometallics, January 1996, American Chemical Society (ACS)

     Professor Pedro J. Perez

115. 
     EXAFS investigation of the second hydration shell of metal cations in dilute aqueous solutions

     Article • Physica B Condensed Matter, March 1995, Elsevier

     Professor Pedro J. Perez

116. 
     Does the Facile Inter- and Intramolecular CH Bond Activation by Tp*–Rh Complexes Proceed via RhI or RhIII Intermediates?

     Article • Angewandte Chemie International Edition in English, February 1995, Wiley

     Professor Pedro J. Perez

117. 
     Dinitrogen, butadiene and related complexes of molybdenum. Crystal structures of [Mo(N2)(PMe3)5] and [Mo(η3-CH3CHCHCH2)(η4-C4H6)(PEt3)2...

     Article • Journal of the Chemical Society Dalton Transactions, January 1995, Royal Society of Chemistry

     Professor Angeles Monge, Professor Pedro J. Perez

118. 
     Nitrene Transfer to Trimethylphosphine from Cationic Tungsten Tosylnitrene Complexes [Tp'(CO)2W(NTs)][X]

     Article • Inorganic Chemistry, December 1994, American Chemical Society (ACS)

     Professor Pedro J. Perez

119. 
     Synthesis and Reactivity of Low-Valent Amido, Imido, Azavinylidene, and Nitrido Complexes of Tungsten

     Article • Organometallics, May 1994, American Chemical Society (ACS)

     Professor Pedro J. Perez

120. 
     Bis(ethylene) complexes of molybdenum and tungsten and their reactivity toward carbon dioxide. New examples of acrylate formation by coupling of ethylene and carbon dioxide

     Article • Organometallics, November 1993, American Chemical Society (ACS)

     Professor Pedro J. Perez

121. 
     A copper(I) catalyst for carbene and nitrene transfer to form cyclopropanes, cyclopropenes, and aziridines

     Article • Organometallics, February 1993, American Chemical Society (ACS)

     Professor Pedro J. Perez

122. 
     Simple low-valent amido, imido and nitrido complexes of tungsten

     Article • Journal of the American Chemical Society, September 1992, American Chemical Society (ACS)

     Professor Pedro J. Perez

123. 
     Double carbon-hydrogen activation at the .alpha.-carbon of cyclic ethers by Tp*Ir(C2H4)2

     Article • Journal of the American Chemical Society, August 1992, American Chemical Society (ACS)

     Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

124. 
     Ethylene dimerization: an alternative route involving vinyl hydride intermediates

     Article • Journal of the Chemical Society Chemical Communications, January 1992, Royal Society of Chemistry

     Professor Pedro J. Perez

125. 
     Rotational isomerism and fluxional behavior of bis(carbon dioxide) adducts of molybdenum

     Article • Journal of the American Chemical Society, November 1991, American Chemical Society (ACS)

     Professor Pedro J. Perez

126. 
     Formation of carbonyl-carbonate complexes of molybdenum by reductive disproportionation of carbon dioxide. X-ray structure of Mo4(.mu.4-CO3)(CO)2(O)2(.mu.2-O)2(.mu.2-OH)4(PMe3)6

     Article • Inorganic Chemistry, April 1991, American Chemical Society (ACS)

     Professor Pedro J. Perez

127. 
     Classical and nonclassical polyhydride ruthenium(II) complexes stabilized by the tetraphosphine P(CH2CH2PPh2)3

     Article • Inorganic Chemistry, January 1991, American Chemical Society (ACS)

     Professor Pedro J. Perez

128. 
     Rotational isomerism in bis(carbon dioxide) complexes of molybdenum generated by conrotatory motion of the CO2 ligands

     Article • Organometallics, April 1990, American Chemical Society (ACS)

     Professor Pedro J. Perez

129. 
     Synthesis and properties of nitrosyl complexes of molybdenum and tungsten containing halide and trimethylphosphine ligands. Crystal and molecular structures of MoCl3(NO)(PMe3)3 and MoCl(NO)(S2CPMe3-S,S',C)(PMe3)2

     Article • Inorganic Chemistry, May 1989, American Chemical Society (ACS)

     Professor Angeles Monge, Professor Pedro J. Perez