All Stories

  1. A rhodium(i)-catalysed formal intramolecular C–C/C–H bond metathesis
  2. Rhodium-catalyzed arylation of acylsilanes with sodium tetraarylborates
  3. Rhodium(III)-catalyzed synthesis of indoles from 1-alkylidene-2-arylhydrazines and alkynes via C–H and N–N bond cleavages
  4. Gold(I)-Catalyzed Ring-Expanding Spiroannulation of Cyclopropenones with Enynes
  5. Rhodium(iii)-catalysed decarbonylative coupling of maleic anhydrides with alkynes
  6. Rhodium-Catalyzed Cross-Coupling of Alkenyl Halides with Arylboron Compounds
  7. Palladium-Catalyzed Ring-Opening Alkynylation of Cyclopropenones
  8. Azulenophenanthrenes from 2,2′-Di(arylethynyl)biphenyls through CC Bond Cleavage of a Benzene Ring
  9. Synthesis of Dibenzoheteropines of Group 13–16 Elements via Ring-Closing Metathesis
  10. Synthesis of tetrasubstituted benzenes via rhodium(i)-catalysed ring-opening benzannulation of cyclobutenols with alkynes
  11. Synthesis of phthalazinones via palladium(ii)-catalysed intramolecular oxidative C–H/C–H cross-coupling of N′-methylenebenzohydrazides
  12. Double 1,4-rhodium migration cascade in rhodium-catalysed arylative ring-opening/spirocyclisation of (3-arylcyclobutylidene)acetates
  13. Rhodium-catalysed intramolecular trans-bis-silylation of alkynes to synthesise 3-silyl-1-benzosiloles
  14. Homocoupling of arylboronic acids catalyzed by simple gold salts
  15. Rhodium-Catalyzed Double 1,4-Addition of Arylboronic Acids to β-Aryloxyacrylates Involving β-Oxygen Elimination
  16. Palladium-Catalyzed Hydrometalation and Bismetalation of Biphenylene
  17. Synthesis of Siloles via Rhodium-Catalyzed Cyclization of Alkynes and Diynes with Hexamethyldisilane
  18. Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes
  19. Metal-catalysed cleavage of carbon–carbon bonds
  20. Synthesis of Pyrenes by Twofold Hydroarylation of 2,6-Dialkynylbiphenyls
  21. Hydrosilylation-Metathesis Sequence Leading to 1-Silaindenes
  22. Ruthenium-Catalyzed trans-Hydrogermylation of Alkynes: Formation of 2,5-Disubstituted Germoles through Double trans-Hydrogermylation of 1,3-Diynes
  23. Synthesis of Silole Skeletons via Metathesis Reactions
  24. Gold-catalysed intramolecular trans-allylsilylation of alkynes forming 3-allyl-1-silaindenes
  25. Rhodium-Catalyzed Carbonylation of Spiropentanes
  26. Asymmetric Synthesis of 3,4-Dihydrocoumarins by Rhodium-Catalyzed Reaction of 3-(2-Hydroxyphenyl)cyclobutanones
  27. Ruthenium-catalysed double trans-hydrosilylation of 1,4-diarylbuta-1,3-diynes leading to 2,5-diarylsiloles
  28. Rhodium-catalyzed Reactions of Cyclobutanones with Alcohols and Amines Forming Esters and Amides
  29. Synthesis of Silafluorenes by Iridium-Catalyzed [2 + 2 + 2] Cycloaddition of Silicon-Bridged Diynes with Alkynes
  30. Synthesis of 3-Acyl-4-alkenylpyrrolidines by Platinum-Catalyzed Hydrative Cyclization of Allenynes
  31. Two-carbon ring expansion of cyclobutanone skeletons by nickel-catalyzed intermolecular alkyne insertion
  32. Enantioselective C−C Bond Cleavage Creating Chiral Quaternary Carbon Centers
  33. Eight-Membered Ring Construction by [4 + 2 + 2] Annulation Involving β-Carbon Elimination
  34. A Direct Entry to Bicyclic Cyclobutenes via Platinum-Catalyzed ­Cycloisomerization of Allenynes
  35. Torque control by metal-orbital interactions
  36. Activation of a Cyclobutanone Carbon–Carbon Bond over an Aldehyde Carbon–Hydrogen Bond in the Rhodium-catalyzed Decarbonylation
  37. Construction of Carbon Frameworks through β-Carbon Elimination Mediated by Transition Metals
  38. Molybdenum-Catalyzed Ring-Closing Metathesis of Allenynes
  39. Synthesis of Seven-Membered-Ring Ketones by Arylative Ring Expansion of Alkyne-Substituted Cyclobutanones
  40. Acids Direct 2-Styrylcyclobutanone into Two Distinctly Different Reaction Pathways
  41. Nickel-Catalyzed Intermolecular Alkyne Insertion into Cyclobutanones
  42. Contrasteric Stereochemical Dictation of the Cyclobutene Ring-Opening Reaction by a Vacant Boron p Orbital
  43. Synthesis of 1H-Inden-1-ol Derivatives via Rhodium-catalyzed Annulation of o-Acylphenylboronic Acids with Alkynes
  44. Addition/Ring-Opening Reaction of Organoboronic Acids to Cyclobutanones Catalyzed by Rhodium(I)/P(t-Bu)3 Complex
  45. Dramatic Effects of Boryl Substituents on Thermal Ring-Closing Reaction of Vinylallenes
  46. Rhodium-Catalyzed Addition/Ring-Opening Reaction of Arylboronic Acids with Cyclobutanones
  47. Eight-membered Ring Formation via Olefin Insertion into a Carbon–Carbon Single Bond
  48. Stereoselective Synthesis of ( Z )-1-Silyl-2-stannylethene by Palladium-­Catalyzed Silastannation of Ethyne and Its Synthetic Transformations
  49. Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes:  Regio- and Stereoselective (E)-Allylsilane Formation via C−C Bond Cleavage
  50. Palladium- and Platinum-Catalyzed Silaboration of Methylenecyclopropanes through Selective Proximal or Distal C−C Bond Cleavage
  51. Convenient Preparation of Silylboranes
  52. Stereoselective 1,4-Silaboration of 1,3-Dienes Catalyzed by Nickel Complexes
  53. Regio- and stereoselective synthesis of (Z)-β-silylalkenylboranes by silaboration of alkynes catalyzed by palladium and platinum complexes
  54. Nickel-Catalyzed Silaborative Dimerization of Alkynes
  55. Platinum-Catalyzed Silaborative Coupling of 1,3-Dienes to Aldehydes:  Regio- and Stereoselective Allylation with Dienes through Allylic Platinum Intermediates