All Stories

  1. Dialkylterphenyl Phosphine‐Based Palladium Precatalysts for Efficient Aryl Amination of N ‐Nucleophiles

    Article • Chemistry - A European Journal, January 2020, Wiley

    Professor M Carmen Nicasio

  2. Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines

    Article • Dalton Transactions, January 2019, Royal Society of Chemistry

    Professor M Carmen Nicasio

  3. Synthesis, Structure and Nickel Carbonyl Complexes of Dialkylterphenyl Phosphines

    Article • Chemistry - A European Journal, November 2018, Wiley

    Professor M Carmen Nicasio

  4. Elucidating the Mechanism of Aryl Aminations Mediated by NHC-Supported Nickel Complexes: Evidence for a Nonradical Ni(0)/Ni(II) Pathway

    Article • ACS Catalysis, March 2018, American Chemical Society (ACS)

    Professor M Carmen Nicasio

  5. Phosphine-functionalized NHC Ni(ii) and Ni(0) complexes: synthesis, characterization and catalytic properties

    Article • Dalton Transactions, January 2017, Royal Society of Chemistry

    Professor M Carmen Nicasio

  6. Ni-Catalyzed Amination Reactions: An Overview

    Article • The Chemical Record, June 2016, Wiley

    Professor M Carmen Nicasio

  7. CN Coupling of Indoles and Carbazoles with Aromatic Chlorides Catalyzed by a Single-Component NHC-Nickel(0) Precursor

    Article • Advanced Synthesis & Catalysis, March 2015, Wiley

    Professor M Carmen Nicasio

  8. Copper-catalysed azide–alkyne cycloadditions (CuAAC): an update

    Article • Organic & Biomolecular Chemistry, January 2015, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  9. 1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap

    Article • Chemical Communications, June 2014, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  10. Synthesis, Structural Characterization, Reactivity, and Catalytic Properties of Copper(I) Complexes with a Series of Tetradentate Tripodal Tris(pyrazolylmethyl)amine Ligands

    Article • Inorganic Chemistry, April 2014, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  11. Reaction of Alkynes and Azides: Not Triazoles Through Copper–Acetylides but Oxazoles Through Copper–Nitrene Intermediates

    Article • Chemistry - A European Journal, February 2014, Wiley

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  12. Silver-catalyzed silicon–hydrogen bond functionalization by carbene insertion

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  13. ChemInform Abstract: Kumada-Tamao-Corriu Coupling of Heteroaromatic Chlorides and Aryl Ethers Catalyzed by (IPr)Ni(allyl)Cl.

    Article • ChemInform, December 2012, Wiley

    Professor M Carmen Nicasio

  14. Kumada–Tamao–Corriu Coupling of Heteroaromatic Chlorides and Aryl Ethers Catalyzed by (IPr)Ni(allyl)Cl

    Article • Organic Letters, August 2012, American Chemical Society (ACS)

    Professor M Carmen Nicasio

  15. Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2 in the Amination of Aryl Tosylates

    Article • Organometallics, August 2012, American Chemical Society (ACS)

    Professor M Carmen Nicasio

  16. Copper(I) Complexes with Trispyrazolylmethane Ligands: Synthesis, Characterization, and Catalytic Activity in Cross-Coupling Reactions

    Article • Inorganic Chemistry, July 2012, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  17. ChemInform Abstract: Regioselective Formation of 2,5‐Disubstituted Oxazoles via Copper(I)‐Catalyzed Cycloaddition of Acyl Azides and 1‐Alkynes.

    Article • ChemInform, April 2011, Wiley

    Professor M Carmen Nicasio

  18. ChemInform Abstract: Well‐Defined Allylnickel Chloride/N‐Heterocyclic Carbene [(NHC)Ni(Allyl)Cl] Complexes as Highly Active Precatalysts for C—N and C—S Cross‐Coupling Reactions.

    Article • ChemInform, December 2010, Wiley

    Professor M Carmen Nicasio

  19. Regioselective Formation of 2,5-Disubstituted Oxazoles Via Copper(I)-Catalyzed Cycloaddition of Acyl Azides and 1-Alkynes

    Article • Journal of the American Chemical Society, December 2010, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  20. Well‐Defined Allylnickel Chloride/N‐Heterocyclic Carbene [(NHC)Ni(allyl)Cl] Complexes as Highly Active Precatalysts for CN and CS Cross‐Coupling Reactions

    Article • Advanced Synthesis & Catalysis, August 2010, Wiley

    Professor M Carmen Nicasio

  21. Copper(i) complexes as catalysts for the synthesis of N-sulfonyl-1,2,3-triazoles from N-sulfonylazides and alkynes

    Article • Organic & Biomolecular Chemistry, January 2010, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  22. Hydrotrispyrazolylborate-copper complexes as catalysts for the styrene cyclopropanation reaction with ethyl diazoacetate under homogeneous and heterogeneous conditions

    Article • Inorganica Chimica Acta, September 2009, Elsevier

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  23. Dinuclear Copper(I) Complexes as Precatalysts in Ullmann and Goldberg Coupling Reactions

    Article • Organometallics, June 2009, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  24. Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T

    Article • Dalton Transactions, January 2009, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  25. Catalytic Carbon−Hydrogen Bond Functionalization in an Ionic Liquid Medium

    Article • Organometallics, November 2007, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  26. Synthesis, Characterization, and Reactivity of Ruthenium Diene/Diamine Complexes Including Catalytic Hydrogenation of Ketones

    Article • Inorganic Chemistry, September 2007, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  27. The Carbene Insertion Methodology for the Catalytic Functionalization of Unreactive Hydrocarbons: No Classical C—H Activation but Efficient C—H Functionalization

    Article • ChemInform, June 2007, Wiley

    Professor M Carmen Nicasio

  28. Very Efficient, Reusable Copper Catalyst for Carbene Transfer Reactions under Biphasic Conditions Using Ionic Liquids

    Article • Organic Letters, January 2006, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  29. The carbene insertion methodology for the catalytic functionalization of unreactive hydrocarbons: No classical C–H activation, but efficient C–H functionalization

    Article • Dalton Transactions, January 2006, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  30. Functionalization of Primary Carbon−Hydrogen Bonds of Alkanes by Carbene Insertion with a Silver-Based Catalyst

    Article • Organometallics, February 2005, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  31. Complete Control of the Chemoselectivity in Catalytic Carbene Transfer Reactions from Ethyl Diazoacetate:  An N-Heterocyclic Carbene−Cu System That Suppresses Diazo Coupling

    Article • Journal of the American Chemical Society, August 2004, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  32. Alkane Dehydrogenation by Sequential, Double C−H Bond Activation by TpBr3Ir(C2H4)2 (TpBr3 = hydrotris(3,4,5-tribromo)pyrazolylborate)

    Article • Organometallics, March 2004, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  33. Copper-Homoscorpionate Complexes as Very Active Catalysts for the Olefin Aziridination Reaction

    Article • Organometallics, December 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  34. Reaction of Ethyl Diazoacetate with Alkyl-Aromatic Substrates:  Influence of the TpxCu Catalyst in the Addition versus Insertion Chemoselectivity (Tpx = Homoscorpionate)

    Article • Organometallics, December 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  35. Cyclohexane and Benzene Amination by Catalytic Nitrene Insertion into C−H Bonds with the Copper-Homoscorpionate Catalyst TpBr3Cu(NCMe)

    Article • Journal of the American Chemical Society, September 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  36. Functionalization of Carbon−Hydrogen Bonds of Hydrocarbons and Ethers via Carbene Insertion with Copper(I)−Homoscorpionate Catalysts

    Article • Organometallics, September 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  37. Copper-Catalyzed Carbene Insertion into O−H Bonds:  High Selective Conversion of Alcohols into Ethers

    Article • Organometallics, June 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  38. Highly Regioselective Functionalization of Aliphatic Carbon−Hydrogen Bonds with a Perbromohomoscorpionate Copper(I) Catalyst

    Article • Journal of the American Chemical Society, January 2003, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  39. Copper(I)−Homoscorpionate Catalysts for the Preferential, Kinetically Controlled Cis Cyclopropanation of α-Olefins with Ethyl Diazoacetate

    Article • Journal of the American Chemical Society, January 2002, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  40. Intermolecular Copper-Catalyzed Carbon−Hydrogen Bond Activation via Carbene Insertion

    Article • Journal of the American Chemical Society, January 2002, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  41. ChemInform Abstract: A Family of Highly Active Copper(I)—Homoscorpionate Catalysts for the Alkyne Cyclopropenation Reaction.

    Article • ChemInform, January 2002, Wiley

    Professor M Carmen Nicasio

  42. Catalytic insertion of diazo compounds into N–H bonds: the copper alternative

    Article • Chemical Communications, January 2002, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  43. Intramolecular dealkylation of chelating diamines with Ru(ii) complexes

    Article • Chemical Communications, January 2002, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  44. A family of highly active copper(i)–homoscorpionate catalysts for the alkyne cyclopropenation reaction

    Article • Chemical Communications, January 2001, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  45. Novel (Methyl)- and (Acetyl)palladium Complexes Containing Bis(pyrazolyl)borate Ligands – Dynamic Equilibrium between η2 and η1 Forms for the Complex Bp*(Me)(PCy3)Pd [Bp* = dihydridobis(3,5-dimethylpyrazolyl)borate]

    Article • European Journal of Inorganic Chemistry, June 2000, Wiley

    Professor M Carmen Nicasio

  46. From Homogeneous to Heterogeneous Catalysis:  Novel Anchoring of Polypyrazolylborate Copper(I) Complexes on Silica Gel through Classical and Nonclassical Hydrogen Bonds. Use as Catalysts of the Olefin Cyclopropanation Reaction

    Article • Organometallics, January 2000, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  47. Substitution and Hydrogenation Reactions on Rhodium(I)−Ethylene Complexes of the Hydrotris(pyrazolyl)borate Ligands Tp‘ (Tp‘ = Tp, TpMe2)

    Article • Inorganic Chemistry, December 1999, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

  48. Kinetics of the BpCu-Catalyzed Carbene Transfer Reaction (Bp = Dihydridobis(1-pyrazolyl)borate). Is a 14-Electron Species the Real Catalyst for the General Copper-Mediated Olefin Cyclopropanation?

    Article • Organometallics, June 1999, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  49. Photochemistry of Os(dmpe)2H2:  Matrix, Transient Solution, and NMR Studies of 16-Electron Os(dmpe)2(dmpe = Me2PCH2CH2PMe2)

    Article • Organometallics, November 1998, American Chemical Society (ACS)

    Professor M Carmen Nicasio

  50. C−H Bond Activation of Benzene and Cyclic Ethers by TpIrIII Species

    Article • Chemistry - A European Journal, November 1998, Wiley

    Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

  51. C−H Bond Activation of Benzene and Cyclic Ethers by TpIrIII Species

    Article • Chemistry - A European Journal, November 1998, Wiley

    Professor M Carmen Nicasio, Professor Angeles Monge

  52. Vinylic C−H Bond Activation and Hydrogenation Reactions of Tp‘Ir(C2H4)(L) Complexes

    Article • Inorganic Chemistry, August 1998, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

  53. BpCu-Catalyzed Cyclopropanation of Olefins:  A Simple System That Operates under Homogeneous and Heterogeneous Conditions (Bp = Dihydridobis(pyrazolyl)borate)

    Article • Organometallics, June 1998, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Pedro J. Perez

  54. Synthesis and characterisation of rhodium(I) complexes containing the dihydrobis(pyrazolyl)borate ligands [H2B(pz′)2]. The X-ray structures of Bp*Rh(C2H4)2 and BpRh(PPh3)2 (Bp = H2B(pz)2; Bp* = H2B(3,5-Me2-pz)2

    Article • Inorganica Chimica Acta, May 1998, Elsevier

    Professor M Carmen Nicasio, Professor Angeles Monge

  55. Organometallic derivatives of Ni(II) with poly(pyrazolyl)borate ligands

    Article • Journal of Organometallic Chemistry, January 1998, Elsevier

    Professor Angeles Monge, Professor M Carmen Nicasio

  56. Synthesis and reactivity of new palladium alkyl complexes containing PMe3 ligands: Insertion reactions and formation of bis(pyrazolyl)borate derivatives

    Article • Journal of Organometallic Chemistry, December 1997, Elsevier

    Professor M Carmen Nicasio

  57. Formation of Hydrido–η3‐Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands

    Article • Chemistry - A European Journal, June 1997, Wiley

    Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

  58. Transient Photochemistry, Matrix Isolation, and Molecular Structure of cis-Ru(dmpm)2H2 (dmpm = Me2PCH2PMe2)

    Article • Organometallics, April 1997, American Chemical Society (ACS)

    Professor M Carmen Nicasio

  59. Laser Flash Photolysis and Matrix Isolation Studies of Ru[R2PCH2CH2PR2]2H2 (R = C2H5, C6H5, C2F5): Control of Oxidative Addition Rates by Phosphine Substituents

    Article • Journal of the American Chemical Society, October 1995, American Chemical Society (ACS)

    Professor M Carmen Nicasio

  60. An iridium(III) compound that thermally activates two molecules of benzene and forms a stable dinitrogen complex

    Article • Journal of the American Chemical Society, January 1994, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Angeles Monge

  61. Alkylidenes by .alpha.-hydrogen abstraction from metallacycles. Synthesis and characterization of alkylidene-bridged complexes of nickel

    Article • Organometallics, November 1993, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Angeles Monge

  62. Dialkyl complexes of nickel(II) containing chelating diphosphines. The crystal structure of [Ni(CH2SiMe2Ph)2(i Pr2PCH2CH2PiPr2)]

    Article • Journal of Organometallic Chemistry, February 1993, Elsevier

    Professor M Carmen Nicasio

  63. Double carbon-hydrogen activation at the .alpha.-carbon of cyclic ethers by Tp*Ir(C2H4)2

    Article • Journal of the American Chemical Society, August 1992, American Chemical Society (ACS)

    Professor M Carmen Nicasio, Professor Angeles Monge, Professor Pedro J. Perez

  64. Monohapto co-ordination of poly(tert-butylpyrazolyl)borate ligands in nickel and palladium complexes

    Article • Journal of the Chemical Society Dalton Transactions, January 1992, Royal Society of Chemistry

    Professor M Carmen Nicasio, Professor Angeles Monge