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  1. The Role of Catalyst Formation–Deactivation Processes and Evidence for a Nonlinear Mechanism in the Mizoroki–Heck Reaction with Aryl Chlorides

    Article • Kinetics and Catalysis, September 2022, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  2. Fast reversible oxidative addition of demanding aryl chlorides to Pd under real conditions of catalysis in the Mizoroki-Heck reaction: The kinetic proof

    Article • Molecular Catalysis, May 2022, Elsevier

    Professor Alexander F. Schmidt

  3. The adequacy of the observed kinetic order in catalyst and the differential selectivity patterns to the hypothesis of the cooperative mechanism of catalysis of the Suzuki—Miyaura reaction

    Article • Russian Chemical Bulletin, September 2021, Springer Science + Business Media

    Professor Alexander F. Schmidt

  4. Experimental evidence for the direct involvement of Pd(0) and Pd(II) anionic phosphine complexes in the Mizoroki–Heck coupling reaction

    Article • Molecular Catalysis, August 2021, Elsevier

    Professor Alexander F. Schmidt

  5. Activation of Aryl Chlorides in the Suzuki-Miyaura Reaction by “Ligand-Free” Pd Species through a Homogeneous Catalytic Mechanism: Distinguishing between Homogeneous and Heterogeneous Catalytic Mechanisms

    Article • Organic Process Research & Development, April 2021, American Chemical Society (ACS)

    Professor Alexander F. Schmidt

  6. Discrimination of the mechanistic hypotheses for two- and three-component cross-coupling reactions by using mathematical modeling of the differential selectivity patterns

    Article • Journal of Physics Conference Series, March 2021, Institute of Physics Publishing

    Professor Alexander F. Schmidt

  7. A Study of the Step of Alkene Activation under Ligand-Free Conditions in the Mizoroki–Heck Reaction with Unreactive Aryl Chlorides

    Article • Kinetics and Catalysis, March 2021, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  8. Ligand-Free Catalytic Cross-Coupling in the System Aryl Halide–Arylacetylene–Alkene

    Article • Russian Journal of Organic Chemistry, January 2021, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  9. Nonclassical cooperative mechanism in Suzuki-Miyaura reaction – Is it possible?

    Article • Molecular Catalysis, January 2021, Elsevier

    Professor Alexander F. Schmidt

  10. Is oxidative addition indeed the rate-determining step of the Suzuki–Miyaura reaction with less-reactive aryl chlorides under “ligand-free” conditions?

    Article • Journal of Organometallic Chemistry, December 2020, Elsevier

    Professor Alexander F. Schmidt

  11. Is the Mechanistic Scheme of the Heck‐Type Coupling with Unsaturated Substrates needed to be revised?

    Article • ChemCatChem, September 2020, Wiley

    Professor Alexander F. Schmidt

  12. Analysis of Differential Selectivity Using Phase Trajectories of Catalytic Reactions: New Aspects and Applications

    Article • Kinetics and Catalysis, September 2019, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  13. A Kinetic Study of the Step of Aryl Halide Activation in a Direct Arylation Reaction of Indole under Real Catalysis Conditions

    Article • Kinetics and Catalysis, May 2019, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  14. Polyaromatic Products of Three-Component Coupling of Aryl Halide with Two Molecules of Arylacetylene and Arylboronic Acid under Ligand-Free Catalysis Conditions

    Article • Russian Journal of Organic Chemistry, May 2019, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  15. Distinguishing between Homogeneous and Heterogeneous Catalytic Activity in C–H Arylation of an Indole with Aryl Halides under “Ligandless” Conditions: Crucial Evidence from Real Catalytic Experiments

    Article • Organic Process Research & Development, April 2019, American Chemical Society (ACS)

    Professor Alexander F. Schmidt

  16. The role of phosphine ligands in the catalytic systems of the Heck reaction with aromatic carboxylic anhydrides

    Article • Russian Chemical Bulletin, April 2019, Springer Science + Business Media

    Professor Alexander F. Schmidt

  17. Mechanistic Study of Catalysis in the Mizoroki–Heck Reaction with Anhydrides of Aromatic Acids

    Article • Kinetics and Catalysis, September 2018, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  18. Mechanistic Study of Direct Arylation of Indole Using Differential Selectivity Measurements: Shedding Light on the Active Species and Revealing the Key Role of Electrophilic Substitution in the Catalytic Cycle

    Article • Organometallics, June 2018, American Chemical Society (ACS)

    Professor Alexander F. Schmidt

  19. Composition and Properties of Brown Coal from the Bodonskoe Deposit in Buryatia

    Article • Solid Fuel Chemistry, March 2018, Allerton Press

    Professor Alexander F. Schmidt

  20. Direct Kinetic Evidence for the Active Anionic Palladium(0) and Palladium(II) Intermediates in the Ligand-Free Heck Reaction with Aromatic Carboxylic Anhydrides

    Article • Organometallics, August 2017, American Chemical Society (ACS)

    Professor Alexander F. Schmidt

  21. Kinetic aspects of operando studies: state-of-the-art and unexplored possibilities

    Article • Mendeleev Communications, May 2017, Elsevier

    Professor Alexander F. Schmidt

  22. Kinetic investigation of cross-coupling reaction steps by advanced competing reaction methods

    Article • Journal of Molecular Catalysis A Chemical, December 2016, Elsevier

    Professor Alexander F. Schmidt

  23. Formation of polyaromatic compounds by coupling of aryl iodides with arylacetylenes in the presence of palladium-based ligand-free catalytic systems

    Article • Russian Journal of Organic Chemistry, September 2016, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  24. Trace elements in the coals of Eastern Siberia

    Article • Solid Fuel Chemistry, September 2016, Allerton Press

    Professor Alexander F. Schmidt

  25. Role of the base and endogenous anions in “ligand-free” catalytic systems for the Suzuki–Miyaura reaction

    Article • Kinetics and Catalysis, May 2016, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  26. Measuring the kinetic isotope effect at natural isotopic abundances for discriminating between the homogeneous and heterogeneous catalytic mechanisms in the Heck and Suzuki reactions

    Article • Kinetics and Catalysis, January 2016, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  27. Study of the differential selectivity of cross-coupling reactions for elucidating the nature of the true catalyst

    Article • Kinetics and Catalysis, March 2015, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  28. Direct arylation and heterogeneous catalysis; ever the twain shall meet

    Article • Chemical Science, January 2015, Royal Society of Chemistry

    Professor Alexander F. Schmidt

  29. Differential selectivity measurements and competitive reaction methods as effective means for mechanistic studies of complex catalytic reactions

    Article • Catalysis Science & Technology, May 2014, Royal Society of Chemistry

    Professor Alexander F. Schmidt

  30. Adsorption properties of coal from the Ishideiskoe deposit, semicokes, and ash and slag wastes from the combustion of coals from Siberia and Sakhalin

    Article • Solid Fuel Chemistry, May 2014, Allerton Press

    Professor Alexander F. Schmidt

  31. Approach to the Determination of Kinetic Order of Catalyst Deactivation: Observation of Unusual Kinetics in the Suzuki – Miyaura Reaction

    Article • Mendeleev Communications, March 2014, Elsevier

    Professor Alexander F. Schmidt

  32. Mechanistic studies of the Suzuki-Miyaura reaction with aryl bromides using Pd supported on micro- and mesoporous activated carbons

    Article • Journal of Molecular Catalysis A Chemical, November 2013, Elsevier

    Professor Alexander F. Schmidt

  33. Distinguishing between the homogeneous and heterogeneous mechanisms of catalysis in the Mizoroki-Heck and Suzuki-Miyaura reactions: Problems and prospects

    Article • Kinetics and Catalysis, November 2012, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  34. competing reaction method for identification of fast and slow steps of catalytic cycles: Application to heck and Suzuki reactions

    Article • Kinetics and Catalysis, April 2012, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  35. Simple kinetic method for distinguishing between homogeneous and heterogeneous mechanisms of catalysis, illustrated by the example of “ligand-free” Suzuki and Heck reactions of aryl iodides and aryl bromides

    Article • Kinetics and Catalysis, February 2012, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  36. Coals from the Khingui coal manifestation

    Article • Solid Fuel Chemistry, October 2011, Allerton Press

    Professor Alexander F. Schmidt

  37. Role of a base in Suzuki-Miyaura reaction

    Article • Russian Journal of General Chemistry, July 2011, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  38. In situ NMR studies of the mechanism of homogeneously and heterogeneously catalysed Heck reactions of aryl chlorides and bromides

    Article • ARKIVOC, April 2011, University of Michigan Library

    Professor Alexander F. Schmidt

  39. Characterization of coals from the Luzhki section of the Zabitui deposit

    Article • Solid Fuel Chemistry, August 2010, Allerton Press

    Professor Alexander F. Schmidt

  40. Suzuki reaction with aryl bromides at room temperature in the presence of a simple “ligand-free” catalytic system

    Article • Russian Journal of Applied Chemistry, July 2010, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  41. Study of “ligand-free” catalytic systems with low palladium content for the Heck reaction

    Article • Russian Journal of Applied Chemistry, March 2010, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  42. Polymerization of acetylene in aqueous PdCl2-CuCl solutions: Novel catalytically active palladium-copper-containing carbon materials

    Article • Doklady Chemistry, March 2010, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  43. Problems of distinguishing the homogeneous and heterogeneous mechanisms of the Suzuki reaction

    Article • Kinetics and Catalysis, February 2010, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  44. Suzuki reaction: mechanistic multiplicity versus exclusive homogeneous or exclusive heterogeneous catalysis

    Article • ARKIVOC, August 2009, University of Michigan Library

    Professor Alexander F. Schmidt

  45. State of palladium in ligandless catalytic systems for the Heck reaction of nonactivated bromobenzene

    Article • Kinetics and Catalysis, September 2008, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  46. New approaches to heck reaction testing for homogeneity-heterogeneity

    Article • Kinetics and Catalysis, May 2008, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  47. Enhancement of catalyst performance in Heck reaction of nonactivated aryl bromides in the absence of phosphine ligands

    Article • Russian Journal of Applied Chemistry, October 2007, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  48. Heck reactions of alkenes with aryl iodides and aryl bromides: Rate-determining steps deduced from a comparative kinetic study of competing and noncompeting reactions

    Article • Kinetics and Catalysis, September 2007, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  49. Kinetics of the Heck reactions of styrene with bromobenzene and iodobenzene in the presence of ligandless catalytic systems: A comparative study

    Article • Kinetics and Catalysis, May 2007, Pleiades Publishing Ltd

    Professor Alexander F. Schmidt

  50. Interplays between Reactions within and without the Catalytic Cycle of the Heck Reaction as a Clue to the Optimization of the Synthetic Protocol

    Article • Synlett, November 2006, Thieme Publishing Group

    Professor Alexander F. Schmidt

  51. 2-Arylazo-1-vinylpyrroles: A Novel Promising Family of Reactive Dyes

    Article • European Journal of Organic Chemistry, September 2006, Wiley

    Professor Alexander F. Schmidt

  52. Effect of macrokinetic factors on the ligand-free Heck reaction with non-activated bromoarenes

    Article • Journal of Molecular Catalysis A Chemical, May 2006, Elsevier

    Professor Alexander F. Schmidt

  53. Oxidative Addition Step in Reactions Involving Palladium Activation of Carbon-Halogen and Carbon-Oxygen Bonds

    Article • Kinetics and Catalysis, July 2005, Springer Science + Business Media

    Professor Alexander F. Schmidt

  54. Concept of ?magic? number clusters as a new approach to the interpretation of unusual kinetics of the Heck reaction with aryl bromides

    Article • Topics in Catalysis, February 2005, Springer Science + Business Media

    Professor Alexander F. Schmidt

  55. Role of catalyst deactivation and regeneration in the heck reaction involving unactivated aryl bromides

    Article • Kinetics and Catalysis, January 2005, Springer Science + Business Media

    Professor Alexander F. Schmidt

  56. Role of catalyst deactivation and regeneration in the heck reaction involving unactivated aryl bromides

    Article • Kinetics and Catalysis, January 2005, Springer Science + Business Media

    Professor Alexander F. Schmidt

  57. Simple method for enhancement of the ligand-free palladium catalyst activity in the Heck reaction with non-activated bromoarenes

    Article • Journal of Molecular Catalysis A Chemical, September 2003, Elsevier

    Professor Alexander F. Schmidt

  58. Article • Kinetics and Catalysis, January 2003, Springer Science + Business Media

    Professor Alexander F. Schmidt

  59. Article • Kinetics and Catalysis, January 2002, Springer Science + Business Media

    Professor Alexander F. Schmidt

  60. Article • Kinetics and Catalysis, January 2001, Springer Science + Business Media

    Professor Alexander F. Schmidt

  61. Article • Kinetics and Catalysis, January 2001, Springer Science + Business Media

    Professor Alexander F. Schmidt

  62. Article • Kinetics and Catalysis, January 2000, Springer Science + Business Media

    Professor Alexander F. Schmidt

  63. Reducing agents as components in catalytic systems of the Heck reaction

    Article • Reaction Kinetics and Catalysis Letters, July 1999, Springer Science + Business Media

    Professor Alexander F. Schmidt

  64. Regioselective ?-arylation ofN-vinylpyrroles by the Heck reaction

    Article • Russian Chemical Bulletin, April 1995, Springer Science + Business Media

    Professor Alexander F. Schmidt

  65. Effect of base on the state of palladium in the synthesis of styrene in the heck reaction

    Article • Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, January 1991, Springer Science + Business Media

    Professor Alexander F. Schmidt