All Stories

  1. Electronic Properties of FC(O)SCH2CH3. A Combined Helium(I) Photoelectron Spectroscopy and Synchrotron Radiation Study

    Article • The Journal of Physical Chemistry A, July 2014, American Chemical Society (ACS)

    Professor Rosana M Romano

  2. Dimers of Perhaloacetyl Cyanides: CClF2C(O)OC(CN)2CClF2 and CF3C(O)OC(CN) 2CF3. Preparation, Properties, and Spectroscopy

    Article • The Journal of Physical Chemistry A, February 2014, American Chemical Society (ACS)

    Professor Rosana M Romano

  3. Matrix Photochemical Study and Conformational Analysis of CH3C(O)NCS and CF3C(O)NCS

    Article • The Journal of Physical Chemistry A, January 2014, American Chemical Society (ACS)

    Professor Rosana M Romano

  4. Structural, spectroscopic and theoretical studies on dixanthogens: (ROC(S)S)2, with R = n-propyl and isopropyl

    Article • New Journal of Chemistry, January 2014, Royal Society of Chemistry

    Professor Rosana M Romano

  5. Matrix isolation studies of carbonyl selenide, OCSe: Evidence of the formation of dimeric species, (OCSe)2

    Article • Vibrational Spectroscopy, January 2014, Elsevier

    Professor Rosana M Romano

  6. Electronic Properties of Fluorosulfonyl Isocyanate, FSO2NCO: A Photoelectron Spectroscopy and Synchrotron Photoionization Study

    Article • The Journal of Physical Chemistry A, September 2013, American Chemical Society (ACS)

    Professor Rosana M Romano

  7. Formation of the Matrix-Isolated Difluoromethylselanes XCF2SeH (X = H, Cl) Through Photolysis of Selenoacetic Acids, XCF2C(O)SeH

    Article • European Journal of Inorganic Chemistry, July 2013, Wiley

    Professor Rosana M Romano

  8. Chlorodifluoroacetyl Isothiocyanate, ClF2CC(O)NCS: Preparation and Structural and Spectroscopic Studies

    Article • The Journal of Physical Chemistry A, July 2013, American Chemical Society (ACS)

    Professor Rosana M Romano

  9. Spectroscopic Characterization and Constitutional and Rotational Isomerism of ClC(O)SCN and ClC(O)NCS

    Article • The Journal of Physical Chemistry A, March 2013, American Chemical Society (ACS)

    Professor Rosana M Romano

  10. Matrix Isolation of the Elusive Fluorocarbonylsulfenyl Fluoride Molecule FC(O)SF

    Article • The Journal of Physical Chemistry A, January 2013, American Chemical Society (ACS)

    Professor Rosana M Romano

  11. Chlorodifluoroacetyl Isocyanate, ClF2CC(O)NCO: Preparation and Structural and Spectroscopic Studies

    Article • The Journal of Physical Chemistry A, November 2012, American Chemical Society (ACS)

    Professor Rosana M Romano

  12. Dissociative Photoionization of Methyl Thiochloroformate, ClC(O)SCH3, Following Sulfur 2p, Chlorine 2p, Carbon 1s, and Oxygen 1s Excitations

    Article • The Journal of Physical Chemistry A, July 2012, American Chemical Society (ACS)

    Professor Rosana M Romano

  13. Interstellar H3+ and HCS+ Ions Produced in the Dissociative Photoionization Process of CH3C(O)SCH3 in the Proximity of the Sulfur 2p, Carbon 1s, and Oxygen 1s Edges

    Article • The Journal of Physical Chemistry A, March 2012, American Chemical Society (ACS)

    Professor Rosana M Romano

  14. Preparation and Properties of Two Novel Selenoacetic Acids: HCF2C(O)SeH and ClCF2C(O)SeH

    Article • Inorganic Chemistry, February 2012, American Chemical Society (ACS)

    Professor Rosana M Romano

  15. Electronic Properties and Dissociative Photoionization of Thiocyanates. Part II. Valence and Shallow-Core (Sulfur and Chlorine 2p) Regions of Chloromethyl Thiocyanate, CH2ClSCN

    Article • The Journal of Physical Chemistry A, December 2011, American Chemical Society (ACS)

    Professor Rosana M Romano

  16. Formation of XNCO species (X=F, Cl) through matrix-isolation photochemistry of XSO2NCO molecules

    Article • Journal of Photochemistry and Photobiology A Chemistry, September 2011, Elsevier

    Professor Rosana M Romano

  17. Chlorodifluoroacetyl Cyanide, ClF2CC(O)CN: Synthesis, Structure, and Spectroscopic Characterization

    Article • Inorganic Chemistry, August 2011, American Chemical Society (ACS)

    Professor Rosana M Romano

  18. Vibrational and Valence Photoelectron Spectroscopies, Matrix Photochemistry, and Conformational Studies of ClC(O)SSCl

    Article • The Journal of Physical Chemistry A, August 2011, American Chemical Society (ACS)

    Professor Rosana M Romano

  19. Outermost and Inner-Shell Electronic Properties of ClC(O)SCH2CH3 Studied Using HeI Photoelectron Spectroscopy and Synchrotron Radiation

    Article • The Journal of Physical Chemistry A, May 2011, American Chemical Society (ACS)

    Professor Rosana M Romano

  20. Vibrational Spectra, Crystal Structures, Constitutional and Rotational Isomerism of FC(O)SCN and FC(O)NCS

    Article • Inorganic Chemistry, November 2010, American Chemical Society (ACS)

    Professor Rosana M Romano

  21. Evidence for the Formation of an Interstellar Species, HCS+, during the Ionic Fragmentation of Methyl Thiofluoroformate, FC(O)SCH3, in the 100−1000 eV Region

    Article • The Journal of Physical Chemistry A, October 2010, American Chemical Society (ACS)

    Professor Rosana M Romano

  22. Trifluoroselenoacetic acid, CF3C(O)SeH: Preparation and Properties

    Article • Inorganic Chemistry, September 2010, American Chemical Society (ACS)

    Professor Rosana M Romano

  23. Matrix Photochemistry at Low Temperatures and Spectroscopic Properties of γ-Butyrothiolactone

    Article • The Journal of Physical Chemistry A, August 2010, American Chemical Society (ACS)

    Professor Rosana M Romano

  24. Infrared matrix-isolation studies of the CS2···HCl molecular complex

    Article • Journal of Molecular Structure, August 2010, Elsevier

    Professor Rosana M Romano

  25. Study of the Photodissociation Process of ClC(O)SCH3 Using both Synchrotron Radiation and HeI Photoelectron Spectroscopy in the Valence Region

    Article • The Journal of Physical Chemistry A, July 2010, American Chemical Society (ACS)

    Professor Rosana M Romano

  26. Experimental and theoretical characterization of molecular complexes formed between OCS and XY molecules (X, Y = F, Cl and Br) and their role in photochemical matrix reactions

    Article • Physical Chemistry Chemical Physics, January 2010, Royal Society of Chemistry

    Professor Rosana M Romano

  27. Perchloromethyl Mercaptan, CCl3SCl, Excited with Synchrotron Radiation in the Proximity of the Sulfur and Chlorine 2p Edges: Dissociative Photoionization of Highly Halogenated Species

    Article • The Journal of Physical Chemistry A, August 2009, American Chemical Society (ACS)

    Professor Rosana M Romano

  28. Experimental and theoretical studies on bis(chlorocarbonyl)trisulfane, ClC(O)SSSC(O)Cl

    Article • Journal of Molecular Structure, July 2009, Elsevier

    Professor Rosana M Romano

  29. Spectroscopic and structural studies of bis[isopropoxy(thiocarbonyl)]sulfide, [(CH3)2CHOC(S)]2S

    Article • Journal of Molecular Structure, July 2009, Elsevier

    Professor Rosana M Romano

  30. ChemInform Abstract: Photochemistry of SO2/Cl2/O2 Gas Mixtures: Synthesis of the New Peroxide ClSO2OOSO2Cl.

    Article • ChemInform, April 2009, Wiley

    Professor Rosana M Romano

  31. Matrix Photochemistry, Photoelectron Spectroscopy, Solid-Phase Structure, and Ring Strain Energy of β-Propiothiolactone

    Article • The Journal of Physical Chemistry A, March 2009, American Chemical Society (ACS)

    Professor Rosana M Romano

  32. Photochemistry of SO2/Cl2/O2Gas Mixtures: Synthesis of the New Peroxide ClSO2OOSO2Cl

    Article • Inorganic Chemistry, March 2009, American Chemical Society (ACS)

    Professor Rosana M Romano

  33. A comprehensive study of (CH3)2CHOC(S)SC(O)OCH3using matrix isolation technique, X‐ray analysis, spectroscopic studies and theoretical calculations

    Article • Journal of Physical Organic Chemistry, February 2009, Wiley

    Professor Rosana M Romano

  34. Dissociative Photoionization of Methyl Thiocyanate, CH3SCN, in the Proximity of the Sulfur 2p Edge

    Article • The Journal of Physical Chemistry A, December 2008, American Chemical Society (ACS)

    Professor Rosana M Romano

  35. Selenoacetic Acid, CH3C(O)SeH: Preparation, Characterization, and Conformational Properties

    Article • Angewandte Chemie, December 2008, Wiley

    Professor Rosana M Romano

  36. Selenoacetic Acid, CH3C(O)SeH: Preparation, Characterization, and Conformational Properties

    Article • Angewandte Chemie International Edition, December 2008, Wiley

    Professor Rosana M Romano

  37. HeI Photoelectron and Valence Synchrotron Photoionization Studies of the Thioester Molecule CH3C(O)SCH3: Evidence of Vibronic Structure

    Article • The Journal of Physical Chemistry A, June 2008, American Chemical Society (ACS)

    Professor Rosana M Romano

  38. Matrix-isolation FTIR study of carbon dioxide: Reinvestigation of the CO2 dimer and CO2⋯N2 complex

    Article • Journal of Molecular Structure, June 2008, Elsevier

    Professor Rosana M Romano

  39. Matrix isolation study of ethyl chloroformate, ClC(O)OCH2CH3

    Article • Journal of Molecular Structure, June 2008, Elsevier

    Professor Rosana M Romano

  40. He I Photoelectron Spectra and Valence Synchrotron Photoionization for XC(O)SCl (X = F, Cl) Compounds

    Article • The Journal of Physical Chemistry A, February 2008, American Chemical Society (ACS)

    Professor Rosana M Romano

  41. Preparation of the novel XC(O)SeX species (X=Cl, Br) through matrix photochemical reactions of OCSe with Cl2 and Br2 at cryogenic temperatures

    Article • Inorganica Chimica Acta, January 2008, Elsevier

    Professor Rosana M Romano

  42. Early Barriers in the Matrix Photochemical Formation ofsyn–anti Randomized FC(O)SeF from the OCSe:F2 Complex

    Article • Chemistry - A European Journal, November 2007, Wiley

    Professor Rosana M Romano

  43. Methanesulfenyl Fluoride, CH3SF, a Missing Link in the Family of Sulfenyl Halides: Formation and Characterization through the Matrix Photochemistry of Methyl Thiofluoroformate, FC(O)SCH3

    Article • Chemistry - A European Journal, September 2007, Wiley

    Professor Rosana M Romano

  44. Dissociative Photoionization of Methoxycarbonylsulfenyl Chloride, CH3OC(O)SCl, Following Sulfur 2p, Chlorine 2p, and Oxygen 1s Excitations

    Article • The Journal of Physical Chemistry A, July 2007, American Chemical Society (ACS)

    Professor Rosana M Romano

  45. Dissociation dynamics of highly charged molecular ions of FC(O)SCl

    Article • Journal of Electron Spectroscopy and Related Phenomena, March 2007, Elsevier

    Professor Rosana M Romano

  46. Bromodifluoroacetyl fluoride, CF2BrC(O)F: Experimental and theoretical studies

    Article • Journal of Molecular Structure, December 2006, Elsevier

    Professor Rosana M Romano

  47. Matrix-Isolated van der Waals Complexes Formed between CS2 and Dihalogen Molecules XY, Where XY = Cl2, Br2, BrCl, ICl, or IBr

    Article • The Journal of Physical Chemistry A, October 2006, American Chemical Society (ACS)

    Professor Rosana M Romano

  48. Trichloromethyl Chloroformate (“Diphosgene”), ClC(O)OCCl3:  Structure and Conformational Properties in the Gaseous and Condensed Phases

    Article • The Journal of Organic Chemistry, April 2006, American Chemical Society (ACS)

    Professor Rosana M Romano

  49. Photochemical Reaction Channels of OCS with Cl2, ICl, or IBr Isolated Together in an Argon Matrix:  Isolation of syn-Iodocarbonylsulfenyl Bromide

    Article • The Journal of Physical Chemistry A, February 2006, American Chemical Society (ACS)

    Professor Rosana M Romano

  50. Gas phase structure and conformational properties of chlorocarbonyl trifluoromethanesulfonate, ClC(O)OSO2CF3

    Article • Journal of Molecular Structure, February 2006, Elsevier

    Professor Rosana M Romano

  51. Evidence of Site-Specific Fragmentation on Thioacetic Acid, CH3C(O)SH, Irradiated with Synchrotron Radiation around the S 2p and O 1s Regions

    Article • The Journal of Physical Chemistry A, December 2005, American Chemical Society (ACS)

    Professor Rosana M Romano

  52. Kinetics and Mechanism of the Thermal Gas-Phase Reaction between NO2 and Trifluorobromoethene, CF2CFBr

    Article • Zeitschrift für Physikalische Chemie, June 2005, De Gruyter

    Professor Rosana M Romano

  53. New Members of an Old Family:  Isolation of IC(O)Cl and IC(O)Br and Evidence for the Formation of Weakly Bound Br•···CO

    Article • Inorganic Chemistry, April 2005, American Chemical Society (ACS)

    Professor Rosana M Romano

  54. Ionic Fragmentation on ClC(O)SCl. Evidence of a Highly Charged Molecular Ion and Confirmation of Unusual Dissociation Mechanisms for Halocarbonylsulfenyl Chlorides

    Article • The Journal of Physical Chemistry A, December 2004, American Chemical Society (ACS)

    Professor Rosana M Romano

  55. Chlorocarbonyl Trifluoromethanesulfonate, ClC(O)OSO2CF3:  Structure and Conformational Properties in the Gaseous and Condensed Phases

    Article • Inorganic Chemistry, November 2004, American Chemical Society (ACS)

    Professor Rosana M Romano

  56. Matrix Photochemistry of the Chlorocarbonyl Sulfenyl Compounds ClC(O)SY, with Y = Cl or CH3

    Article • The Journal of Physical Chemistry A, August 2004, American Chemical Society (ACS)

    Professor Rosana M Romano

  57. Gas Electron Diffraction Analysis on S-Methyl Thioacetate, CH3C(O)SCH3

    Article • The Journal of Organic Chemistry, July 2004, American Chemical Society (ACS)

    Professor Rosana M Romano

  58. Fluorocarbonyl Trifluoromethanesulfonate, FC(O)OSO2CF3:  Structure and Conformational Properties in the Gaseous and Condensed Phases

    Article • Inorganic Chemistry, May 2004, American Chemical Society (ACS)

    Professor Rosana M Romano

  59. Study of the Ionic Fragmentation of Shallow- and Core-Excited Fluorocarbonylsulfenyl Chloride, FC(O)SCl:  Observation of a New Three-Body Dissociation Mechanism

    Article • The Journal of Physical Chemistry A, April 2004, American Chemical Society (ACS)

    Professor Rosana M Romano

  60. Matrix-Isolated van der Waals Complexes Formed between CO and Dihalogen Molecules, XY with X, Y = Cl, Br, or I

    Article • The Journal of Physical Chemistry A, June 2003, American Chemical Society (ACS)

    Professor Rosana M Romano

  61. Structural and vibrational properties of ClC(O)SY compounds with Y = Cl and CH3

    Article • New Journal of Chemistry, February 2003, Royal Society of Chemistry

    Professor Rosana M Romano

  62. Kinetics and mechanism of the thermal gas‐phase oxidation of perfluorobutene‐2 in presence of trifluoromethyl hypofluorite

    Article • International Journal of Chemical Kinetics, January 2003, Wiley

    Professor Rosana M Romano

  63. Matrix Photochemistry of CH3C(O)SX Molecules with X = H, CH3, and C(O)CH3:  Formation of Ketene in Another Decomposition Channel of Sulfenyl Carbonyl Compounds

    Article • The Journal of Physical Chemistry A, July 2002, American Chemical Society (ACS)

    Professor Rosana M Romano

  64. ChemInform Abstract: (Bromocarbonyl)sulfenyl Bromide, BrC(O)SBr: A Novel Carbonyl Sulfenyl Compound Formed by the Photochemical Reaction Between Br2 and OCS Isolated Together in an Ar Matrix.

    Article • ChemInform, April 2002, Wiley

    Professor Rosana M Romano

  65. Anomeric and Mesomeric Effects in Methoxycarbonylsulfenyl Chloride, CH3OC(O)SCl:  An Experimental and Theoretical Study

    Article • Inorganic Chemistry, February 2002, American Chemical Society (ACS)

    Professor Rosana M Romano

  66. Kinetics and Mechanism of the Thermal Gas-Phase Reaction between NO2 and Trifluorochloroethene

    Article • Zeitschrift für Physikalische Chemie, January 2002, De Gruyter

    Professor Rosana M Romano

  67. (Bromocarbonyl)sulfenyl bromide, BrC(O)SBr: a novel carbonyl sulfenyl compound formed by the photochemical reaction between Br2 and OCS isolated together in an Ar matrix

    Article • Chemical Communications, November 2001, Royal Society of Chemistry

    Professor Rosana M Romano

  68. Structure and Conformational Properties of Diacetyl Sulfide in the Gaseous and Condensed Phases Explored by Gas Electron Diffraction, Single-Crystal X-ray Diffraction, Vibrational Spectroscopy, and Quantum Chemical Calculations

    Article • Journal of the American Chemical Society, November 2001, American Chemical Society (ACS)

    Professor Rosana M Romano

  69. Matrix Photochemistry of syn-(Chlorocarbonyl)sulfenyl Bromide, syn-ClC(O)SBr:  Precursor to the Novel Species anti-ClC(O)SBr, syn-BrC(O)SCl, and BrSCl

    Article • Journal of the American Chemical Society, May 2001, American Chemical Society (ACS)

    Professor Rosana M Romano

  70. Post-resonance Raman and theoretical studies on 1,3,2,4-benzodithiadiazines, formally anti-aromatic compounds

    Article • Physical Chemistry Chemical Physics, January 2001, Royal Society of Chemistry

    Professor Rosana M Romano