All Stories

  1. Elucidating the scope and stereochemistry of Diels-Alder reactions of (E)- and (Z)-1,1,1,4,4,4-hexafluoro-2-butene: A combined NMR, quantum-chemical, and X-ray crystallographic study
  2. Development of a Multistage Technology for the Industrial Synthesis of the Levosimendan API and Enantiomeric Separation of Intermediates
  3. Hydrophosphorylation of 1,1,1,3,3,3‐hexafluorobut‐2‐yne (HFB) with Diethyl Hydrogenphosphonate: Attractive Synthetic Route to Various Types of CF 3 ‐Containing Phosphonates
  4. Introduction of the Difluoro(methoxy)methyl Group into the Aromatic Ring and the Study of Its Electronic Properties
  5. Methyl chlorothioformate as a convenient reagent for the thionoesters synthesis
  6. 1,2-Difluoroethylene (HFO-1132): synthesis and chemistry
  7. 5-Trifluoromethoxy-substituted Nicotinic Acid, Nicotinamide and Related Compounds
  8. (E,Z)-1,1,1,4,4,4-Hexafluorobut-2-enes: hydrofluoroolefins halogenation/dehydrohalogenation cascade to reach new fluorinated allene
  9. An unexplored representative of gem-difluoroalkenes`, 1,1,4,4,4-Pentafluorobut-1-ene CF3CH2CH CF2 (HFO-1345czf): Reactivity and functionalization possibilities
  10. GLP (Good Laboratory Procedure) for SCF3 construction: Useful procedure for trifluoromethylation of thiols by reaction with trifluoromethyliodide
  11. Narcotic Drug Smell Mimics for Dog Training at Cynological Departments: Composition, Principle of Action, and Legal Frame work of their Use
  12. Catalytic Hydrosilylation of Hydrofluoroolefins (HFOs): Synthesis of New Fluorinated Silanes and Diversity of their Synthetic Character
  13. Trifluoromethoxypyrazines: Preparation and Properties
  14. Narcotic Drug Smell Mimics for Dog Training at Cynological Departments: Composition, Principle of Action, and Legal Frame work of their Use
  15. 1,1,1,4,4,4‐Hexafluorobut‐2‐yne (HFB) as a Versatile Dipolarophile for [3+2] Cycloaddition with 1,3‐Dipoles toward Azoles with Adjacent CF 3 Groups
  16. General, Practical and Selective Oxidation Protocol for CF3S into CF3S(O) Group
  17. Evaluation of Efficient and Practical Methods for the Preparation of Functionalized Aliphatic Trifluoromethyl Ethers
  18. CF 3 S(O) n -containing enaminones as precursors for the synthesis of pyrimidine-4(3 H )-ones
  19. The first nucleophilic C–H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes
  20. Nature of the lowest electronic transitions of thia- and quinocyanines with fluorinated polymethine chain
  21. Alternative synthetic routes to hydrofluoroolefins
  22. Functionalized S-perfluorinated sulfoximines: Preparation and evaluation in catalytic processes
  23. N-perfluoro-tert-butylazoles
  24. Polyfluoroethoxy derivatives of malonic aldehyde acetal in the synthesis of heterocyclic compounds
  25. Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction
  26. Approaches to prepare perfluoroalkyl and pentafluorophenyl copper couples for cross-coupling reactions with organohalogen compounds
  27. Chemical properties of 5-(1,1,2,2-tetrafluoroethoxy)-4-phenylthiazole derivatives
  28. A novel family of (1-aminoalkyl)(trifluoromethyl)- and -(difluoromethyl)phosphinic acids – analogues of α-amino acids
  29. Polyfluoro- and perfluoroalkoxyenaminones in syntheses of nitrogen containing heterocycles
  30. Syntheses and crystal structures of 1-methyl-3-difluoromethylbenz-imidazolium NHC complexes with different transition metals
  31. On the reactions of trialkyl(trifluorovinyl)silanes with isocyanates and isothiocyanates − Expected and surprising results
  32. Interaction of 2,4,6-tris(fluorosulfonyl)chlorobenzene with O-, N-, S-, C-nucleophiles and F-anion
  33. Efficient synthesis of 5′-fluoroalkoxythiazoles via α-bromo-α-fluoroalkoxyacetophenones Hantzsch type cyclization with thioureas or thioamides
  34. Me3SiCF3/AgF/Cu—A new reagents combination for selective trifluoromethylation of various organic halides by trifluoromethylcopper, CuCF3
  35. A convenient synthetic route to 2,4,6-tris(chlorosulfonyl)- and 2,4,6-tris(fluorosulfonyl)phenol, aniline and chlorobenzene
  36. Novel structural analogs of glyphosate based on azoles. 2*. N-Substituted imidazoles and pyrazoles obtained by alkylation of heterocycles containing carboxyl or phosphoryl groups in the ring
  37. Novel structural analogs of glyphosate based on azoles. 1. Synthesis of 1H-imidazoles containing carboxyl and phosphoryl groups in the ring
  38. A General Route to Perfluoroalkyl- and Trifluorovinyl-Substituted Fischer Carbene Complexes of Tungsten and Chromium - Syntheses, Characterisation and Structures
  39. Equilibrium Acidities of Superacids
  40. Stable gem-trifluoromethyl anionic σ-complexes based on 1,3,5-tris(sulfonyl)benzene derivatives and their transformations
  41. A Convenient and Efficient Synthesis of Trifluoromethyl Vinyl Sulfoxide and Its Reactivity in Addition Reactions
  42. Fluorine chemistry in Ukraine
  43. On the reactions of trifluorovinylsilanes with aromatic ketones – Expected and some unexpected results
  44. Synthesis of the first representative of dicarbothiacyanine dyes with completely fluorinated polymethine chain
  45. The solid complex Zn(CF3)Br·2DMF as an alternative reagent for the preparation of both, trifluoromethyl and pentafluoroethyl copper, CuCF3 and CuC2F5
  46. New kinds of organic superacids. Bis(perfluoroalkylsulfonylimino)trifluoromethanesulfonic acids and their trimethylsilyl esters
  47. A novel synthetic route to thiacyanine dyes containing a perfluorinated polymethine chain
  48. Insight into the Reactions of Trifluorovinylsilanes with Aromatic Aldehydes
  49. A new method for the synthesis of trifluoromethylating agents—Diaryltrifluoromethylsulfonium salts
  50. A One-Pot Synthesis of 1,3-Dihydro-1,3,3-tris(perfluoroalkyl)isobenzofuran-1-olates and Their Complete NMR Spectroscopic Analysis on the Basis of 1D and 2D Experiments
  51. Trifluoromethylation of non-activated aldimines with trimethyl(trifluoromethyl)silane in the presence of tetramethylammonium fluoride: A closer look into the reaction route
  52. Silver compounds in synthetic chemistry
  53. Fluoride-mediated selective cross-coupling reactions of alkyl halides and trimethyl(perfluoroalkyl)silanes, Me3SiRf (Rf=CF3, C2F5) in the absence of any catalysts
  54. Preface
  55. The Structure of Tris(trifluoromethyl)tellurium Fluoride Dimethylformamide,
  56. New Anions of Pentacoordinate Phosphorus Containing Fluorine and Trifluoromethyl Groups
  57. Unusual reactions of N-(trifluoromethylsulfonylimino)di-and-trifluoromethanesulfinimidoyl chlorides
  58. Trifluoromethylselenato(0) and trifluoromethyltellurato(0) complexes of platinum(II)
  59. Syntheses of Trifluoromethanethiolato Platinum(II) Complexes - Crystal Structures ofcis-Pt(SCF3)2(PPh3)2 andtrans-Pt(SCF3)Cl(PPh3)2
  60. How Trimethyl(trifluoromethyl)silane Reacts with Itself in the Presence of Naked Fluoride—A One-Pot Synthesis of Bis([15]crown-5)cesium 1,1,1,3,5,5,5-Heptafluoro-2,4-bis(trifluoromethyl)pentenide
  61. Silver compounds in synthetic chemistry
  62. Novel ionic liquids—Imidazolium salts with a difluoromethylene fragment directly bonded to the nitrogen atom
  63. Convenient syntheses of 1,1,1,3,3,3-hexafluoro-2-organyl-propan-2-ols and the corresponding trimethylsilyl ethers
  64. Synthesis of new organic super acids—N-(trifluoromethylsulfonyl)imino derivatives of trifluoromethanesulfonic acid and bis(trifluoromethylsulfonyl)imide
  65. Bis(trifluoromethyltellurato(0))metallates(I) of copper, silver and gold, [M(TeCF3)2]− (M = Cu, Ag, Au)
  66. Tetramethylammonium trifluoromethyltellurate(0), [NMe4]TeCF3, synthesis, characterisation and properties
  67. S-Trifluoromethyl esters of thiocarboxylic acids, RC(O)SCF3
  68. The synthesis of salts and esters of perfluorinated dithio- and thiocarboxylic acids from carbon disulfide and carbonyl sulfide reacting with RFSiMe3/F−
  69. Synthesen und Charakterisierungen der ersten Tris- und Tetrakis(trifluormethyl)palladate(II) und -platinate(II), [M(CF3)3(PPh3)]— und [M(CF3)4]2— (M = Pd, Pt)
  70. Stable trifluoromethylselenates(0), [A]SeCF3—synthesis, characterizations and properties
  71. A new synthesis of trifluoromethanethiolates—characterization and properties of tetramethylammonium, cesium and di(benzo-15-crown-5)cesium trifluoromethanethiolates
  72. Honoring Lev Moiseevich Yagupolskii, on the occasion of his 80th birthday
  73. N-(Trifluoromethylsulfonyl)trifluoromethanesulfinimidic acid and its salts
  74. Perfluoroalkylation of heterocumulenes with trimethyl(perfluoroalkyl)silanes in the presence of fluoride ions: synthesis of perfluoroalkanesulfinyl amides from N-organylsulfinyl amines
  75. Synthesis and optical activity of difluoro(organylsulfinyl)acetic acids and their esters
  76. 2,6-Difluorphenylxenon(II)bis(fluorsulfonyl)amid, -bis(trifluormethylsulfonyl)amid, -tris(fluorsulfonyl)methanid und -bis(trifluormethylsulfonyl)methanid—neue C–Xe–N- und C–Xe–C-Verbindungen?
  77. Tris(trifluoromethyl)tellurate(II), [Te(CF3)3]−, the dimeric bis(trifluoromethyl)chlorotellurate(II), [(CF3)2TeCl]22−, and bis(trifluoromethyl)iodate(I), [I(CF3)2]−: the first hypervalent alkyl [10-Te-3] and [12-Te-4] species and a novel [10-I-2] compound
  78. Trifluoromethylation of heterocumulenes with trimethyl(trifluoromethyl)silane in the presence of fluoride ions: synthesis of trifluoroacetamides and trifluorothioacetamides from isocyanates and isothiocyanates
  79. Electronic structures and electrochemical properties of LiPF6−n(CF3)n
  80. Characteristics of the electrolyte with fluoro organic lithium salts
  81. New trends in the chemistry of aromatic compounds with fluorine-containing substituents
  82. Nucleophilic trifluoromethylation of organic substrates using (trifluoromethyl)trimethylsilane in the presence of a fluoride anion II. A convenient route to aryltrifluoromethyl-sulfides, -sulfoxides and -sulfones
  83. Phenylbis(fluorosulfonyl)- and phenylbis(trifluoromethylsulfonyl)-methyliodonium triflates
  84. Synthesis and characterization of aryl(trifluoromethyl)bismuth compounds (R-C6H4)3-nBi(CF3)n [R=H, 4-CH3, 4-CF3, 3-F, 4-F; n=1 and 2] and the reactions of (C6H5)3-nnBi(CF3)n [n=0–3] with benzoylpyridinium chloride
  85. Synthesis of bismuthio methanides containing the RfSO2 group, (C6H5)3Bi=C(SO2Rf)2 [Rf=CF3, n-C4F9, OCH2CF2CF2H]
  86. Synthesis and properties of N-perfluoroalkylsulfonyltriarylbismuth imines, Ar3BiNSO2Rf
  87. The first example of the generation of carbocations by the protonation of unsaturated compounds by a CH acid
  88. Trifluoromethylation of perfluoroaromatic compounds using trifluoromethyltrimethylsilane in the presence of fluoride ions
  89. β-Fluoro-substituted aminoacids
  90. Asymmetric synthesis of amino acids via catalytic reduction of azalactone-substituted acylaminoacrylic acids. 21. Catalytic asymmetric synthesis of the phenylethylamide of N-acyl-p-difluoromethoxyphenylalanine
  91. Fluorine-containing amino acids. IV. Synthesis and biological activity of ?-polyfluoromethyl-substituted aromatic amino acids
  92. Asymmetric synthesis by catalytic reductive aminolysis of p-fluoro-?-acetaminocinnamic acid azalactone. Communication 18. Preparation of S-(-)-p-fluorophenylalanine
  93. Pyrimidinetetrasulfonic acid
  94. Transition-metal complexes with σ-bonded fluorine-containing groups
  95. Transition metal complexes with σ-bonded fluorine-containing groups
  96. Aryl esters of tris(fluorosulphonyl)methane aci form
  97. Reaction of carboxylic acid amidines with ketimines
  98. Benzylidene derivatives of 5-nitro- and 5-aminobenzo[b]-3(2H)-thiophenone