All Stories

  1. Trisulfur radical anion-triggered stitching thienannulation: rapid access to largely π-extended thienoacenes
  2. Innenrücktitelbild: Scalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination (Angew. Chem. 47/2019)
  3. Inside Back Cover: Scalable Rhodium(III)-Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination (Angew. Chem. Int. Ed. 47/2019)
  4. Scalable Rhodium(III)-Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination
  5. Scalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination
  6. Dual Effects of Cyclopentadienyl Ligands on Rh(III)-Catalyzed Dehydrogenative Arylation of Electron-Rich Alkenes
  7. Efficient endo Cycloisomerization of Terminal Alkynols Catalyzed by a New Ruthenium Complex with 8-(Diphenylphosphino)quinoline Ligand and Mechanistic Investigation
  8. Rh(iii)-Catalyzed regio- and stereoselective bisindolylation of vinyl acetate: an efficient approach toward (E)-1,2-bis(2-indolyl)ethenes
  9. Ruthenium and Osmium Germyl Complexes Derived from the Reactions of MXCl(PPh3 )3 (M = Ru, Os; X = Cl, H) with Terphenylchlorogermylene (C6 H3 -2,6-Trip2 )GeCl (Trip = 2,4,6-i Pr3 C6 H2 )
  10. β-Diketiminato-Germylene Complexes of Carbonyl Ruthenium: Synthesis, Structure, and Reactivity
  11. Alkenylcarbyne Complexes Derived from the Reactions of OsXCl-(PPh3)3(X=H,Cl) with Propargyl Chloride and Phosphine Ligand-Controlled Transformation of Hydride-Carbyne to Carbene
  12. Rhodium-Catalyzed β-Selective Oxidative Heck-Type Coupling of Vinyl Acetate via C–H Activation
  13. ChemInform Abstract: Rhodium-Catalyzed/Copper-Mediated Selective C2 Alkynylation of Indoles and C1 Alkynylation of Carbazoles with γ-Substituted tert-Propargyl Alcohols.
  14. Rhodium-Catalyzed/Copper-Mediated Selective C2 Alkynylation of Indoles and C1 Alkynylation of Carbazoles withγ-Substitutedtert-Propargyl Alcohols
  15. ChemInform Abstract: Copper-Catalyzed Direct C2-Benzylation of Indoles with Alkylarenes.
  16. Synthesis of α-Aminonaphthalenes via Copper-Catalyzed Aminobenzannulation of (o-Alkynyl)arylketones with Amines
  17. Copper-Catalyzed Direct C2-Benzylation of Indoles with Alkylarenes
  18. Construction of Isoquinolin-1(2H)-ones by Copper-Catalyzed Tandem Reactions of 2-(1-Alkynyl)benzaldimines with Water
  19. Half-Sandwich B-Oxy Boratabenzene Ruthenium Complexes: Synthesis, Characterization, and Reactivity of (η6-C5H5BOR)RuCl(PPh3)2 (R = Et, Me)
  20. Palladium-Catalyzed Direct C2- and Further C7-Acylation of Indoles with Aldehydes
  21. Highly Active Gold(I)–Silver(I) Oxo Cluster Activating sp3 C–H Bonds of Methyl Ketones under Mild Conditions
  22. Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics
  23. Rearrangement of Metallabenzynes to Chlorocyclopentadienyl Complexes
  24. Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides
  25. Rh/Cu-catalyzed multiple C–H, C–C, and C–N bond cleavage: facile synthesis of pyrido[2,1-a]indoles from 1-(pyridin-2-yl)-1H-indoles and γ-substituted propargyl alcohols
  26. Correction: Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides
  27. Rh(III)-Catalyzed Oxidative Coupling of Benzoic Acids with Geminal-Substituted Vinyl Acetates: Synthesis of 3-Substituted Isocoumarins
  28. ChemInform Abstract: Copper-Catalyzed Solvent-Free Redox Condensation of Benzothiazoles with Aldehydes or Benzylic Alcohols.
  29. Copper-catalyzed solvent-free redox condensation of benzothiazoles with aldehydes or benzylic alcohols
  30. Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes
  31. Stabilization of anti-aromatic and strained five-membered rings with a transition metal
  32. Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization
  33. A half-sandwich 1,2-azaborolyl ruthenium complex: synthesis, characterization, and evaluation of its catalytic activities
  34. Synthesis and Organometallic Properties of Several Osmium Alkenylcarbyne Complexes
  35. From Osmium Hydrido Vinylidene to Osmacycles: The Key Role of Osmabutadiene Intermediates
  36. A rhodamine-deoxylactam based sensor for chromo-fluorogenic detection of nerve agent simulant
  37. Electrophilic Substitution Reactions of Metallabenzynes
  38. Mechanism Investigations of the Endo Cycloisomerization of Alkynols through Isolation and Characterization of Ruthenium Complexes from the Reactions of Alkynes with a Ruthenium Complex
  39. pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene withL- andD-Cysteine
  40. Dimethyl (E)-2-(N-phenylacetamido)but-2-enedioate
  41. cis-Dichloridotetrakis(trimethylphosphane-κP)ruthenium(II) benzene disolvate
  42. Mononuclear Bis(imino)arylcopper(I) N-Heterocyclic Carbene Complex: Synthesis, Structure, and Reaction with Organic Azide
  43. C−H Bond Activation and Subsequent C(sp2)−C(sp3) Bond Formation: Coupling of Bromomethyl and Triphenylphosphine in an Iridium Complex
  44. Synthesis, Characterization, and Electrochemical Properties of Bisosmabenzenes Bridged by Diisocyanides
  45. Selective and Efficient Cycloisomerization of Alkynols Catalyzed by a New Ruthenium Complex with a Tetradentate Nitrogen-Phosphorus Mixed Ligand
  46. Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes
  47. Synthesis of an osmafuran from photochemical hydrolysis of OsCl2(CHC(PPh3)C(O)-η2-CHCH2)(PPh3)2
  48. Visual and fluorogenic detection of a nerve agent simulant via a Lossen rearrangement of rhodamine–hydroxamate
  49. Dichlorido(η4-cycloocta-1,5-diene)bis(triphenylphosphine)osmium(II)
  50. Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole
  51. Osmapyridine and Osmapyridinium from a Formal [4+2] Cycloaddition Reaction
  52. Selective Synthesis of Osmanaphthalene and Osmanaphthalyne by Intramolecular CH Activation
  53. Osmabenzenes from Osmacycles Containing an η2-Coordinated Olefin
  54. Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3Substituents
  55. Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran
  56. Synthesis of Coordinated η2-α,β-Unsaturated Ketone Osmacycles from an Osmium-Coordinated Alkyne Alcohol Complex
  57. Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction
  58. Synthesis and Characterization of an Air-Stablep-Osmaphenol
  59. A Metallanaphthalyne Complex from Zinc Reduction of a Vinylcarbyne Complex
  60. Coupling Reactions of an Allenylcarbene Complex with Alkynes and Styrene
  61. Cyclometalation of 2-Vinylpyridine with MCl2(PPh3)3and MHCl(PPh3)3(M = Ru, Os)
  62. Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH
  63. Synthesis and characterization of a bimetallic iridium complex with a ten sp2-carbon chain bridge
  64. Osmabenzenes from the Reactions of a Dicationic Osmabenzyne Complex
  65. Osmium-Mediated Hexamerization of Phenylacetylene
  66. Osmium-Mediated Hexamerization of Phenylacetylene
  67. Synthesis and Characterization of Stable Ruthenabenzenes
  68. A Neutron Diffraction Study of [OsClH3(PPh3)3]: A Complex Containing a Highly “Stretched” Dihydrogen Ligand
  69. Synthesis and Photophysical Properties of Trimetallic Acetylide Complexes with a 1,3,5-Triazine Core
  70. Syntheses of Metallabenzynes from an Allenylcarbene Complex
  71. Synthesis and Characterization of C10H10-Bridged Bimetallic Ruthenium Complexes
  72. Synthesis and Characterization of Trimetallic Ruthenium and Bimetallic Osmium Complexes with Metal−Vinyl Linkages
  73. Synthesis and Characterization of [OsCl2(=C=CHR)(PPh3)2] and Related Complexes
  74. Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3(X = Cl, Br)
  75. Vinylidene, Allenylidene, and Carbyne Complexes from the Reactions of [OsCl2(PPh3)3] with HC⋮CC(OH)Ph2
  76. Coupling Reaction of Phenylacetylene with OsHn(PPh3)(2,6-(PPh2CH2)2C6H3) (n= 1, 3)
  77. Theoretical Studies on the Stabilities of Metallabenzynes
  78. Comparative Study on the Reactivity of H2, PhCHCH2, and PhC⋮CMe with [Cp*Ru(H2O)(NBD)]+
  79. Synthesis and Characterization of Bimetallic Ruthenium Complexes with (CH)6and Related Bridges
  80. Protonation and Bromination of an Osmabenzyne:  Reactions Leading to the Formation of New Metallabenzynes
  81. Synthesis and Characterization of Linear (CH)8-Bridged Bimetallic Ruthenium Complexes
  82. Synthesis and Protonation of [RuH(NBD)(2,6-(Ph2PCH2)2C6H3)]
  83. Reactions of hydrogen with ruthenium and osmium complexes containing tridentate ligands Cy2PCH2CH(CH2)2PCy2 and 2,6-(Ph2PCH2)2C6H3
  84. Protonation Reactions of [MH(Cl)(PPh3)2(norbornadiene)] (M = Ru, Os)
  85. Syntheses, structures and magnetic properties of mono- and di-manganese inclusion compounds
  86. Synthesis and Characterization of a Metallabenzyne
  87. Preparation, Characterization, and Reactivity of an Osmium Alkenyl Dihydrogen Complex
  88. Theoretical Studies of Rotational Barriers of Vinylidene Ligands in the Five-Coordinate Complexes M(X)Cl(CCHR)L2(M = Os, Ru; L = Phosphine)
  89. Reactions of MH(OTf)(NBD)(PPh3)2(M = Ru, Os) with H2
  90. Isomerization of CH3C⋮CPh to Phenylallene Promoted by an Osmium Hydride Complex
  91. Unexpected Formation of Osmium Carbyne and Vinylidene Complexes from the Reaction of OsCl2(PPh3)3with HC⋮CCMe3
  92. Vinylidene and Carbyne Complexes Derived from the Reactions of OsCl(PPh3)(PCP) (PCP = 2,6-(PPh2CH2)2C6H3) with Terminal Acetylenes
  93. Structure and characterization of a mononuclear FeII dialkyldithiocarbamate complex Fe(OC4H8dtc)2(DMF)
  94. 1,2:3,4:5,6-Tri-O-isopropylidene-D-mannitol
  95. A Novel Molybdenum−Iron−Sulfur Cluster. Synthesis, Structure, and Properties of [Et4N]2[MoFe4S4(SC6H11)7]·1/2CH3CN
  96. Chemistry of tripodal ligands. Part III.
  97. Chemistry ofo-Mercaptophenolate: Syntheses, Structures, and Characterization of Titanium(IV) Complexes
  98. Reaction of transition metal thiolato units V. Formation of a binuclear mercury(II) complex with the dithiolato ligand i-mnt (1,1-dicyanoethylene-2,2-dithiolate)
  99. Synthesis and structure of a novel MoFe4S4 cubane-like cluster (Me3PhCH2N)2 [MoFe4S4 (SC6H11)7]
  100. Studies on the Synthetic System of V/Ag/S Cluster Compounds and Structural Characterizations of V2AgS4, V2Ag2S4, and V2O2(μ-S)2Complexes
  101. A novel network of bis(2-mercapto-3-pyridinol)oxovanadium(IV)_ based on hydrogenbond interactions: synthesis, structure and EPR spectroscopic properties
  104. Chiral phosphine ligands derived from sugars-6. syntheses and spectroscopic studies on rhodium complexes with a new type of chiral phosphines
  105. Tris(2-sulfidopyridine N-oxide-O,S)chromium(III) Acetone Solvate (1/1)
  106. Alkyne activation and carbon-carbon bond formation mediated by osmium complexes