All Stories

  1. Unusual Kinetics Induced by Ligands in Rhodium(III)-Catalyzed Dehydrogenative Olefination Reactions
  2. Elucidating ligand effects in rhodium(III)-catalyzed arene-alkene coupling reactions
  3. Well-Defined Rhodium Diphenylphosphine Oxide Complexes Relevant to Rh(III)-Catalyzed Aryl C–H Phosphorylation
  4. Cyclometalated Platinum(II) Metallomesogens Based on Half-Disc-Shaped β-Diketonate Ligands with Hexacatenar: Crystal Structures, Mesophase Properties, and Semiconductor Devices
  5. Synthesis and characterization of rhena[10]annulynes
  6. Trisulfur radical anion-triggered stitching thienannulation: rapid access to largely π-extended thienoacenes
  7. Extension of the Simmons–Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity
  8. Innenrücktitelbild: Scalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination (Angew. Chem. 47/2019)
  9. Inside Back Cover: Scalable Rhodium(III)-Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination (Angew. Chem. Int. Ed. 47/2019)
  10. Scalable Rhodium(III)-Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination
  11. Scalable Rhodium(III)‐Catalyzed Aryl C−H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination
  12. Dual Effects of Cyclopentadienyl Ligands on Rh(III)-Catalyzed Dehydrogenative Arylation of Electron-Rich Alkenes
  13. Efficient endo Cycloisomerization of Terminal Alkynols Catalyzed by a New Ruthenium Complex with 8-(Diphenylphosphino)quinoline Ligand and Mechanistic Investigation
  14. Rh(iii)-Catalyzed regio- and stereoselective bisindolylation of vinyl acetate: an efficient approach toward (E)-1,2-bis(2-indolyl)ethenes
  15. Ruthenium and Osmium Germyl Complexes Derived from the Reactions of MXCl(PPh3 )3 (M = Ru, Os; X = Cl, H) with Terphenylchlorogermylene (C6 H3 -2,6-Trip2 )GeCl (Trip = 2,4,6-i Pr3 C6 H2 )
  16. β-Diketiminato-Germylene Complexes of Carbonyl Ruthenium: Synthesis, Structure, and Reactivity
  17. Alkenylcarbyne Complexes Derived from the Reactions of OsXCl-(PPh3)3(X=H,Cl) with Propargyl Chloride and Phosphine Ligand-Controlled Transformation of Hydride-Carbyne to Carbene
  18. Rhodium-Catalyzed β-Selective Oxidative Heck-Type Coupling of Vinyl Acetate via C–H Activation
  19. ChemInform Abstract: Rhodium-Catalyzed/Copper-Mediated Selective C2 Alkynylation of Indoles and C1 Alkynylation of Carbazoles with γ-Substituted tert-Propargyl Alcohols.
  20. Rhodium-Catalyzed/Copper-Mediated Selective C2 Alkynylation of Indoles and C1 Alkynylation of Carbazoles withγ-Substitutedtert-Propargyl Alcohols
  21. ChemInform Abstract: Copper-Catalyzed Direct C2-Benzylation of Indoles with Alkylarenes.
  22. Synthesis of α-Aminonaphthalenes via Copper-Catalyzed Aminobenzannulation of (o-Alkynyl)arylketones with Amines
  23. Copper-Catalyzed Direct C2-Benzylation of Indoles with Alkylarenes
  24. Construction of Isoquinolin-1(2H)-ones by Copper-Catalyzed Tandem Reactions of 2-(1-Alkynyl)benzaldimines with Water
  25. Half-Sandwich B-Oxy Boratabenzene Ruthenium Complexes: Synthesis, Characterization, and Reactivity of (η6-C5H5BOR)RuCl(PPh3)2 (R = Et, Me)
  26. Palladium-Catalyzed Direct C2- and Further C7-Acylation of Indoles with Aldehydes
  27. Highly Active Gold(I)–Silver(I) Oxo Cluster Activating sp3 C–H Bonds of Methyl Ketones under Mild Conditions
  28. Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics
  29. Rearrangement of Metallabenzynes to Chlorocyclopentadienyl Complexes
  30. Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides
  31. Rh/Cu-catalyzed multiple C–H, C–C, and C–N bond cleavage: facile synthesis of pyrido[2,1-a]indoles from 1-(pyridin-2-yl)-1H-indoles and γ-substituted propargyl alcohols
  32. Correction: Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides
  33. Rh(III)-Catalyzed Oxidative Coupling of Benzoic Acids with Geminal-Substituted Vinyl Acetates: Synthesis of 3-Substituted Isocoumarins
  34. ChemInform Abstract: Copper-Catalyzed Solvent-Free Redox Condensation of Benzothiazoles with Aldehydes or Benzylic Alcohols.
  35. Copper-catalyzed solvent-free redox condensation of benzothiazoles with aldehydes or benzylic alcohols
  36. Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes
  37. Stabilization of anti-aromatic and strained five-membered rings with a transition metal
  38. Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization
  39. A half-sandwich 1,2-azaborolyl ruthenium complex: synthesis, characterization, and evaluation of its catalytic activities
  40. Synthesis and Organometallic Properties of Several Osmium Alkenylcarbyne Complexes
  41. From Osmium Hydrido Vinylidene to Osmacycles: The Key Role of Osmabutadiene Intermediates
  42. A rhodamine-deoxylactam based sensor for chromo-fluorogenic detection of nerve agent simulant
  43. Electrophilic Substitution Reactions of Metallabenzynes
  44. Mechanism Investigations of the Endo Cycloisomerization of Alkynols through Isolation and Characterization of Ruthenium Complexes from the Reactions of Alkynes with a Ruthenium Complex
  45. pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene withL- andD-Cysteine
  46. Dimethyl (E)-2-(N-phenylacetamido)but-2-enedioate
  47. cis-Dichloridotetrakis(trimethylphosphane-κP)ruthenium(II) benzene disolvate
  48. Mononuclear Bis(imino)arylcopper(I) N-Heterocyclic Carbene Complex: Synthesis, Structure, and Reaction with Organic Azide
  49. C−H Bond Activation and Subsequent C(sp2)−C(sp3) Bond Formation: Coupling of Bromomethyl and Triphenylphosphine in an Iridium Complex
  50. Synthesis, Characterization, and Electrochemical Properties of Bisosmabenzenes Bridged by Diisocyanides
  51. Selective and Efficient Cycloisomerization of Alkynols Catalyzed by a New Ruthenium Complex with a Tetradentate Nitrogen-Phosphorus Mixed Ligand
  52. Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes
  53. Synthesis of an osmafuran from photochemical hydrolysis of OsCl2(CHC(PPh3)C(O)-η2-CHCH2)(PPh3)2
  54. Visual and fluorogenic detection of a nerve agent simulant via a Lossen rearrangement of rhodamine–hydroxamate
  55. Dichlorido(η4-cycloocta-1,5-diene)bis(triphenylphosphine)osmium(II)
  56. Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole
  57. Osmapyridine and Osmapyridinium from a Formal [4+2] Cycloaddition Reaction
  58. Selective Synthesis of Osmanaphthalene and Osmanaphthalyne by Intramolecular CH Activation
  59. Osmabenzenes from Osmacycles Containing an η2-Coordinated Olefin
  60. Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3Substituents
  61. Nine-Membered Osmacycles Derived from Metathesis Reactions between Alkynes and an Osmafuran
  62. Synthesis of Coordinated η2-α,β-Unsaturated Ketone Osmacycles from an Osmium-Coordinated Alkyne Alcohol Complex
  63. Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction
  64. Synthesis and Characterization of an Air-Stablep-Osmaphenol
  65. A Metallanaphthalyne Complex from Zinc Reduction of a Vinylcarbyne Complex
  66. Coupling Reactions of an Allenylcarbene Complex with Alkynes and Styrene
  67. Cyclometalation of 2-Vinylpyridine with MCl2(PPh3)3and MHCl(PPh3)3(M = Ru, Os)
  68. Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH
  69. Synthesis and characterization of a bimetallic iridium complex with a ten sp2-carbon chain bridge
  70. Osmabenzenes from the Reactions of a Dicationic Osmabenzyne Complex
  71. Osmium-Mediated Hexamerization of Phenylacetylene
  72. Osmium-Mediated Hexamerization of Phenylacetylene
  73. Synthesis and Characterization of Stable Ruthenabenzenes
  74. A Neutron Diffraction Study of [OsClH3(PPh3)3]: A Complex Containing a Highly “Stretched” Dihydrogen Ligand
  75. Synthesis and Photophysical Properties of Trimetallic Acetylide Complexes with a 1,3,5-Triazine Core
  76. Syntheses of Metallabenzynes from an Allenylcarbene Complex
  77. Synthesis and Characterization of C10H10-Bridged Bimetallic Ruthenium Complexes
  78. Synthesis and Characterization of Trimetallic Ruthenium and Bimetallic Osmium Complexes with Metal−Vinyl Linkages
  79. Synthesis and Characterization of [OsCl2(=C=CHR)(PPh3)2] and Related Complexes
  80. Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3(X = Cl, Br)
  81. Vinylidene, Allenylidene, and Carbyne Complexes from the Reactions of [OsCl2(PPh3)3] with HC⋮CC(OH)Ph2
  82. Coupling Reaction of Phenylacetylene with OsHn(PPh3)(2,6-(PPh2CH2)2C6H3) (n= 1, 3)
  83. Theoretical Studies on the Stabilities of Metallabenzynes
  84. Comparative Study on the Reactivity of H2, PhCHCH2, and PhC⋮CMe with [Cp*Ru(H2O)(NBD)]+
  85. Synthesis and Characterization of Bimetallic Ruthenium Complexes with (CH)6and Related Bridges
  86. Protonation and Bromination of an Osmabenzyne:  Reactions Leading to the Formation of New Metallabenzynes
  87. Synthesis and Characterization of Linear (CH)8-Bridged Bimetallic Ruthenium Complexes
  88. Synthesis and Protonation of [RuH(NBD)(2,6-(Ph2PCH2)2C6H3)]
  89. Reactions of hydrogen with ruthenium and osmium complexes containing tridentate ligands Cy2PCH2CH(CH2)2PCy2 and 2,6-(Ph2PCH2)2C6H3
  90. Protonation Reactions of [MH(Cl)(PPh3)2(norbornadiene)] (M = Ru, Os)
  91. Syntheses, structures and magnetic properties of mono- and di-manganese inclusion compounds
  92. Synthesis and Characterization of a Metallabenzyne
  93. Preparation, Characterization, and Reactivity of an Osmium Alkenyl Dihydrogen Complex
  94. Theoretical Studies of Rotational Barriers of Vinylidene Ligands in the Five-Coordinate Complexes M(X)Cl(CCHR)L2(M = Os, Ru; L = Phosphine)
  95. Reactions of MH(OTf)(NBD)(PPh3)2(M = Ru, Os) with H2
  96. Isomerization of CH3C⋮CPh to Phenylallene Promoted by an Osmium Hydride Complex
  97. Unexpected Formation of Osmium Carbyne and Vinylidene Complexes from the Reaction of OsCl2(PPh3)3with HC⋮CCMe3
  98. Vinylidene and Carbyne Complexes Derived from the Reactions of OsCl(PPh3)(PCP) (PCP = 2,6-(PPh2CH2)2C6H3) with Terminal Acetylenes
  99. Structure and characterization of a mononuclear FeII dialkyldithiocarbamate complex Fe(OC4H8dtc)2(DMF)
  100. 1,2:3,4:5,6-Tri-O-isopropylidene-D-mannitol
  101. A Novel Molybdenum−Iron−Sulfur Cluster. Synthesis, Structure, and Properties of [Et4N]2[MoFe4S4(SC6H11)7]·1/2CH3CN
  102. Chemistry of tripodal ligands. Part III.
  103. Chemistry ofo-Mercaptophenolate: Syntheses, Structures, and Characterization of Titanium(IV) Complexes
  104. Reaction of transition metal thiolato units V. Formation of a binuclear mercury(II) complex with the dithiolato ligand i-mnt (1,1-dicyanoethylene-2,2-dithiolate)
  105. Synthesis and structure of a novel MoFe4S4 cubane-like cluster (Me3PhCH2N)2 [MoFe4S4 (SC6H11)7]
  106. Studies on the Synthetic System of V/Ag/S Cluster Compounds and Structural Characterizations of V2AgS4, V2Ag2S4, and V2O2(μ-S)2Complexes
  107. A novel network of bis(2-mercapto-3-pyridinol)oxovanadium(IV)_ based on hydrogenbond interactions: synthesis, structure and EPR spectroscopic properties
  108. A TITANIUM(IV) DIMER COMPLEX CONTAINING TRLS(2-MERCAPTOPHENOLATO)TITANIUM(IV) FRAGMENTS LINKED BY SODIUM IONS. SYNTHESIS, STRUCTURE AND CHARACTERIZATION OF (Et4N)2[Ti(mp)3Na(MeOH)2]2(H2mp = 2-MERCAPTOPHENOL)
  109. CHIRAL PHOSPHINE LIGANDS DERIVED FROM SUGARS. 8. SYNTHESES OF GOLD(I) COMPLEXES CONTAINING CHIRAL SUGAR PHOSPHINES AND PYRIDINE-1-OXIDE-2-THIOLATE
  110. Chiral phosphine ligands derived from sugars-6. syntheses and spectroscopic studies on rhodium complexes with a new type of chiral phosphines
  111. Tris(2-sulfidopyridine N-oxide-O,S)chromium(III) Acetone Solvate (1/1)
  112. Alkyne activation and carbon-carbon bond formation mediated by osmium complexes