All Stories

  1. Correction: Embo-Ibouanga et al. Peptide-Alkoxyamine Drugs: An Innovative Approach to Fight Schistosomiasis: “Digging Their Graves with Their Forks”. Pathogens 2024, 13, 482

    Article • Pathogens, July 2025, MDPI AG

    Professor Sylvain MARQUE

  2. Pathogen Enzyme-Mediated Alkoxyamine Homolysis as a Killing Mechanism of Aspergillus fumigatus

    Article • Journal of Fungi, July 2025, MDPI AG

    Professor Sylvain MARQUE

  3. Revising Model Reactions in Plasmonic Chemistry: From Nitrothiophenol Coupling to Alkoxyamine Homolysis

    Article • ACS Catalysis, June 2025, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  4. Controlled radical release from iron oxide nanoparticles grafted with thermosensitive alkoxyamine triggered by external stimuli

    Article • Materials Chemistry Frontiers, January 2025, Royal Society of Chemistry

    Professor Sylvain MARQUE

  5. Dynamic covalent bonding (DCB): the bond lability of alkoxyamines as drugs against Schistosoma mansoni and Plasmodium falciparum

    Article • Organic & Biomolecular Chemistry, January 2025, Royal Society of Chemistry

    Professor Sylvain MARQUE

  6. Interaction of N-acyl derivative of 4-phenoxyaniline spin label with bovine serum albumin in water and in trehalose solution

    Article • Organic & Biomolecular Chemistry, January 2025, Royal Society of Chemistry

    Professor Sylvain MARQUE

  7. Investigating dose rate effects and reactive species formation in irradiated multilayer films – part 1 EVA/EVOH/EVA

    Article • Physical Chemistry Chemical Physics, January 2025, Royal Society of Chemistry

    Professor Sylvain MARQUE

  8. Intrinsic Proteolytic Activities from Cancer Cells Are Sufficient to Activate Alkoxyamine Prodrugs and Induce Cell Death

    Article • ACS Omega, September 2024, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  9. Peptide-Alkoxyamine Drugs: An Innovative Approach to Fight Schistosomiasis: “Digging Their Graves with Their Forks”

    Article • Pathogens, June 2024, MDPI AG

    Professor Sylvain MARQUE

  10. Comparison of effects from gamma, e-beam and X-ray radiation on multilayer polymer films used in biopharmaceutical devices by chemometric treatment of spectroscopic data

    Article • Radiation Physics and Chemistry, May 2024, Elsevier

    Professor Sylvain MARQUE

  11. Hybrid Peptide-Alkoxyamine Drugs: A Strategy for the Development of a New Family of Antiplasmodial Drugs

    Article • Molecules, March 2024, MDPI AG

    Professor Sylvain MARQUE

  12. Author Correction: Compatibility of ethylene vinyl acetate (EVA)/ethylene vinyl alcohol (EVOH)/EVA films with gamma, electron-beam, and X-ray irradiation

    Article • npj Materials Degradation, January 2024, Springer Science + Business Media

    Professor Sylvain MARQUE

  13. Radical detection and electron‐spin resonance (ESR) monitoring in polymer materials irradiated with gamma and X‐rays: Polyethylene and polypropylene

    Article • Journal of Applied Polymer Science, January 2024, Wiley

    Professor Sylvain MARQUE

  14. Nanoscale solvent organization in metal–organic framework ZIF-8 probed by EPR of flexible β-phosphorylated nitroxides

    Article • Chemical Science, January 2024, Royal Society of Chemistry

    Professor Sylvain MARQUE

  15. Size-dependent plasmonic activity of AuNPs for the rational design of catalysts for organic reactions

    Article • Catalysis Science & Technology, January 2024, Royal Society of Chemistry

    Professor Sylvain MARQUE

  16. Thermal properties and radical monitoring after gamma, X-ray, and electron beam irradiation in polyamides

    Article • Physical Chemistry Chemical Physics, January 2024, Royal Society of Chemistry

    Professor Sylvain MARQUE

  17. Compatibility of ethylene vinyl acetate (EVA)/ethylene vinyl alcohol (EVOH)/EVA films with gamma, electron-beam, and X-ray irradiation

    Article • npj Materials Degradation, December 2023, Springer Science + Business Media

    Professor Sylvain MARQUE

  18. Plasmon-Assisted Chemistry Using Chiral Gold Helicoids: Toward Asymmetric Organic Catalysis

    Article • ACS Catalysis, September 2023, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  19. Dynamic Covalent Bond: Modes of Activation of the C—ON Bond in Alkoxyamines

    Article • Progress in Polymer Science, September 2023, Elsevier

    Professor Sylvain MARQUE

  20. Unraveling the Path to Efficient Plasmon Catalysts: Investigating Size Effects of Gold Nanoparticles in Organic Reactions

    Article • September 2023, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  21. Oligomers. Relations between their computed free energies

    Article • Applied Research, July 2023, Wiley

    Professor Sylvain MARQUE

  22. Gamma, E-Beam and X-ray Irradiations on PE/EVOH/PE Multilayer Film: An Industrial Point of View Regarding the Impact on Mechanical Properties

    Article • Polymers, June 2023, MDPI AG

    Professor Sylvain MARQUE

  23. Formation of Alginate/Chitosan Interpenetrated Networks Revealed by EPR Spectroscopy

    Article • Gels, March 2023, MDPI AG

    Professor Sylvain MARQUE

  24. A system for in vivo on-demand ultra-low field Overhauser-enhanced 3D-Magnetic resonance imaging

    Article • Journal of Magnetic Resonance, March 2023, Elsevier

    Professor Sylvain MARQUE

  25. Uncovering the Role of Chemical and Electronic Structures in Plasmonic Catalysis: The Case of Homolysis of Alkoxyamines

    Article • ACS Catalysis, February 2023, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  26. Cascade strategy for triggered radical release by magnetic nanoparticles grafted with thermosensitive alkoxyamine

    Article • Nanoscale, January 2023, Royal Society of Chemistry

    Professor Sylvain MARQUE

  27. Comprehensive investigation on physical and chemical properties of γ‐irradiated multilayer PE/EVOH/PE film: A multiscale approach

    Article • Applied Research, November 2022, Wiley

    Professor Sylvain MARQUE

  28. Conformational changes in β-phosphorylated nitroxides – A powerful tool to probe host–guest interactions

    Article • Journal of Molecular Liquids, October 2022, Elsevier

    Professor Sylvain MARQUE

  29. The chemical thermodynamics and diamagnetism of n-alkanes. Calculations up to n-C110H222 from quantum chemical computations and experimental values

    Article • Computational and Theoretical Chemistry, September 2022, Elsevier

    Professor Sylvain MARQUE

  30. 2,4,5,6-Substituted 4,5-dihydro-1,2,4,5-tetrazin-3(2H)-ones as non-classical initiators of controlled radical polymerization of styrene

    Article • Russian Chemical Bulletin, July 2022, Springer Science + Business Media

    Professor Sylvain MARQUE

  31. Neutrophil Elastase-Activatable Prodrugs Based on an Alkoxyamine Platform to Deliver Alkyl Radicals Cytotoxic to Tumor Cells

    Article • Journal of Medicinal Chemistry, June 2022, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  32. Effects of X-Rays, Electron Beam, and Gamma Irradiation on Chemical and Physical Properties of EVA Multilayer Films

    Article • Frontiers in Chemistry, May 2022, Frontiers

    Professor Sylvain MARQUE

  33. CORRIGENDUM

    Article • Journal of Applied Polymer Science, March 2022, Wiley

    Professor Sylvain MARQUE

  34. Monitoring of peroxide in gamma irradiated PE/EVOH/PE multilayer film using methionine probe

    Article • Food and Bioproducts Processing, March 2022, Elsevier

    Professor Sylvain MARQUE

  35. One-year ageing FTIR monitoring of PE/EVOH/PE film after gamma or electron beam irradiation

    Article • Polymer Degradation and Stability, January 2022, Elsevier

    Professor Sylvain MARQUE

  36. Synthesis of Self-Healing Polymers by Radical Controlled Polymerization

    Article • Chemistry for Sustainable Development, January 2022, Fund Science and Culture Support Centre

    Professor Sylvain MARQUE

  37. Alkylverdazyls as a Source of Alkyl Radicals for Light-Triggered Cancer Cell Death

    Article • Molecular Pharmaceutics, December 2021, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  38. Efficacious One-pot Synthesis of 2-thiazolines and 2-oxazolines Under Solvent and Metal-Free Conditions

    Article • Current Organocatalysis, December 2021, Bentham Science Publishers

    Talbi Wassima , Professor Sylvain MARQUE

  39. Enzymatic activity monitoring through dynamic nuclear polarization in Earth magnetic field

    Article • Journal of Magnetic Resonance, December 2021, Elsevier

    Professor Sylvain MARQUE

  40. A Combined Spectroscopic and In Silico Approach to Evaluate the Interaction of Human Frataxin with Mitochondrial Superoxide Dismutase

    Article • Biomedicines, November 2021, MDPI AG

    Professor Sylvain MARQUE

  41. Unveiling the role of chemical and electronic structure in plasmon-assisted homolysis of alkoxyamines

    Article • August 2021, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  42. Investigations at the Product, Macromolecular, and Molecular Level of the Physical and Chemical Properties of a γ-Irradiated Multilayer EVA/EVOH/EVA Film: Comprehensive Analysis and Mechanistic Insights

    Article • Polymers, August 2021, MDPI AG

    Professor Sylvain MARQUE

  43. Magnetic Resonance Imaging of Protease-Mediated Lung Tissue Inflammation and Injury

    Article • ACS Omega, May 2021, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  44. Influence of Gamma Irradiation on Electric Cables Models: Study of Additive Effects by Mid-Infrared Spectroscopy

    Article • Polymers, April 2021, MDPI AG

    Professor Sylvain MARQUE

  45. Synthesis of New Chiral Triazoles Linked 1,5‐Benzodiazepine Conjugates via Copper‐Catalyzed 1,3‐Dipolar Cycloaddition Reaction

    Article • ChemistrySelect, January 2021, Wiley

    Dr Melek Hajji, Professor Sylvain MARQUE

  46. Design of a Targeting and Oxygen-Independent Platform to Improve Photodynamic Therapy: A Proof of Concept

    Article • ACS Applied Bio Materials, January 2021, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  47. Effects of X-ray, electron beam and gamma irradiation on PE/EVOH/PE multilayer film properties

    Article • Chemical Communications, January 2021, Royal Society of Chemistry

    Professor Sylvain MARQUE

  48. Establishing plasmon contribution to chemical reactions: alkoxyamines as a thermal probe

    Article • Chemical Science, January 2021, Royal Society of Chemistry

    Professor Sylvain MARQUE

  49. Homolysis/mesolysis of alkoxyamines activated by chemical oxidation and photochemical-triggered radical reactions at room temperature

    Article • Organic Chemistry Frontiers, January 2021, Royal Society of Chemistry

    Professor Sylvain MARQUE

  50. Mapping the scientific research on the ionizing radiation impacts on polymers (1975–2019)

    Article • e-Polymers, January 2021, De Gruyter

    Professor Sylvain MARQUE

  51. Effects of Fe2+/Fe3+ Binding to Human Frataxin and Its D122Y Variant, as Revealed by Site-Directed Spin Labeling (SDSL) EPR Complemented by Fluorescence and Circular Dichroism Spectroscopies

    Article • International Journal of Molecular Sciences, December 2020, MDPI AG

    Professor Sylvain MARQUE

  52. Monitoring of Peroxide in Gamma Irradiated EVA Multilayer Film Using Methionine Probe

    Article • Polymers, December 2020, MDPI AG

    Professor Sylvain MARQUE

  53. Théorie cinétique de l’équilibre chimique

    Article • Comptes Rendus Chimie, December 2020, Cellule MathDoc/CEDRAM

    Professor Sylvain MARQUE

  54. Homooligopeptides. Variations of the calculated absolute free energies G/n in function of the number n of amino acids

    Article • Computational and Theoretical Chemistry, December 2020, Elsevier

    Professor Sylvain MARQUE

  55. Study of the mechanical behavior of gamma-irradiated single-use bag seals

    Article • Food Packaging and Shelf Life, December 2020, Elsevier

    Professor Sylvain MARQUE

  56. Smart Alkoxyamines: A New Tool for Smart Applications

    Article • Accounts of Chemical Research, November 2020, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  57. NMR and EPR Study of Homolysis of Diastereomeric Alkoxyamines

    Article • Molecules, November 2020, MDPI AG

    Professor Sylvain MARQUE

  58. Alkoxyamines Designed as Potential Drugs against Plasmodium and Schistosoma Parasites

    Article • Molecules, August 2020, MDPI AG

    Professor Sylvain MARQUE

  59. New Variants of Nitroxide Mediated Polymerization

    Article • Polymers, July 2020, MDPI AG

    Professor Sylvain MARQUE

  60. Correction to Shifting-Nitroxides to Investigate Enzymatic Hydrolysis of Fatty Acids by Lipases Using Electron Paramagnetic Resonance in Turbid Media

    Article • Analytical Chemistry, May 2020, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  61. Identification of chemical species created during γ‐irradiation of antioxidant used in polyethylene and polyethylene‐co‐vinyl acetate multilayer film

    Article • Journal of Applied Polymer Science, May 2020, Wiley

    Professor Sylvain MARQUE

  62. Effect of gamma irradiation on the oxygen barrier properties in ethyl‐vinyl acetate/ethylene‐vinyl alcohol/ethyl‐vinyl acetate multilayer film

    Article • Journal of Applied Polymer Science, May 2020, Wiley

    Professor Sylvain MARQUE

  63. Mapping the scientific research on the gamma irradiated polymers degradation (1975–2018)

    Article • Radiation Physics and Chemistry, March 2020, Elsevier

    Professor Sylvain MARQUE

  64. An enzymatic acetal/hemiacetal conversion for the physiological temperature activation of the alkoxyamine C–ON bond homolysis

    Article • Organic Chemistry Frontiers, January 2020, Royal Society of Chemistry

    Professor Sylvain MARQUE

  65. Kinetic investigation of thermal and photoinduced homolysis of alkylated verdazyls

    Article • Physical Chemistry Chemical Physics, January 2020, Royal Society of Chemistry

    Professor Sylvain MARQUE

  66. Beyond common analytical limits of radicals detection using the functional SERS substrates

    Article • Sensors and Actuators B Chemical, December 2019, Elsevier

    Professor Sylvain MARQUE

  67. Design and microwave-assisted synthesis of dimers of 1,5-benzodiazepine-1,2,3-triazole hybrids bearing alkyl/aryl spacers and their biological assessment

    Article • Journal of Molecular Structure, November 2019, Elsevier

    Professor Sylvain MARQUE

  68. Generation of O2-Permeation Barrier during the Gamma-Irradiation of Polyethylene/Ethylene-Vinyl Alcohol/Polyethylene Multilayer Film

    Article • Industrial & Engineering Chemistry Research, July 2019, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  69. Chemical modifications of imidazole-containing alkoxyamines increase C–ON bond homolysis rate: Effects on their cytotoxic properties in glioblastoma cells

    Article • Bioorganic & Medicinal Chemistry, May 2019, Elsevier

    Professor Sylvain MARQUE

  70. Shifting-Nitroxides to Investigate Enzymatic Hydrolysis of Fatty Acids by Lipases Using Electron Paramagnetic Resonance in Turbid Media

    Article • Analytical Chemistry, April 2019, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  71. Smart Control of Nitroxide-Mediated Polymerization Initiators’ Reactivity by pH, Complexation with Metals, and Chemical Transformations

    Article • Materials, February 2019, MDPI AG

    Professor Sylvain MARQUE

  72. Power Law Distribution Concerning Absolute Free Energies of Linear Sulfur Chains, Polythiazyls, Polyisoprenes, Linear trans-Polyenes, and Polyynes

    Article • The Journal of Physical Chemistry A, January 2019, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  73. Chiral arylideneaminoimidazolidin-4-ones: green synthesis and isomerisation mechanism in solution

    Article • New Journal of Chemistry, January 2019, Royal Society of Chemistry

    Professor Sylvain MARQUE

  74. Enzymatic triggering of C–ON bond homolysis of alkoxyamines

    Article • Organic Chemistry Frontiers, January 2019, Royal Society of Chemistry

    Professor Sylvain MARQUE

  75. How intramolecular coordination bonding (ICB) controls the homolysis of the C–ON bond in alkoxyamines

    Article • RSC Advances, January 2019, Royal Society of Chemistry

    Professor Sylvain MARQUE

  76. Probing the dynamic properties of two sites simultaneously in a protein–protein interaction process: a SDSL-EPR study

    Article • Physical Chemistry Chemical Physics, January 2019, Royal Society of Chemistry

    Professor Sylvain MARQUE

  77. Unprecedented plasmon-induced nitroxide-mediated polymerization (PI-NMP): a method for preparation of functional surfaces

    Article • Journal of Materials Chemistry A, January 2019, Royal Society of Chemistry

    Professor Sylvain MARQUE

  78. Green synthesis of new chiral 1-(arylamino)imidazo[2,1-a]isoindole-2,5-diones from the corresponding α-amino acid arylhydrazides in aqueous medium

    Article • Beilstein Journal of Organic Chemistry, November 2018, Beilstein Institut

    Professor Sylvain MARQUE

  79. Radical polymerization of radical‐labeled monomers: The triarylmethyl‐based radical monomer as an example

    Article • Journal of Polymer Science Part A Polymer Chemistry, October 2018, Wiley

    Professor Sylvain MARQUE

  80. An elastase activity reporter for Electronic Paramagnetic Resonance (EPR) and Overhauser-enhanced Magnetic Resonance Imaging (OMRI) as a line-shifting nitroxide

    Article • Free Radical Biology and Medicine, October 2018, Elsevier

    Professor Sylvain MARQUE

  81. Ozone, chemical reactivity and biological functions

    Article • Tetrahedron, October 2018, Elsevier

    Professor Sylvain MARQUE

  82. Unexpectedly High Levels of Organic Compounds Released by Indoor Photocatalytic Paints

    Article • Environmental Science & Technology, September 2018, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  83. Enthalpy of Combustion on n‐Alkanes. Quantum Chemical Calculations up to n‐C60H122 and Power Law Distributions

    Article • ChemistrySelect, August 2018, Wiley

    Professor Sylvain MARQUE

  84. Selective On/Off-Nitroxides as Radical Probes to Investigate Non-radical Enzymatic Activity by Electron Paramagnetic Resonance

    Article • Chemistry - A European Journal, May 2018, Wiley

    Professor Sylvain MARQUE

  85. Evaluation of multilayer film stability by Raman spectroscopy after gamma-irradiation sterilization process

    Article • Vibrational Spectroscopy, May 2018, Elsevier

    Professor Sylvain MARQUE

  86. Reconciliation of pH, conductivity, total organic carbon with carboxylic acids detected by ion chromatography in solution after contact with multilayer films after γ-irradiation

    Article • European Journal of Pharmaceutical Sciences, May 2018, Elsevier

    Professor Sylvain MARQUE

  87. The effect of the oxophilic Tb(III) cation on C ON bond homolysis in alkoxyamines

    Article • Inorganic Chemistry Communications, May 2018, Elsevier

    Professor Sylvain MARQUE

  88. Imidazoline and imidazolidine nitroxides as controlling agents in nitroxide-mediated pseudoliving radical polymerization

    Article • Russian Chemical Reviews, April 2018, Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii

    Professor Sylvain MARQUE

  89. Synthesis of new chiral bis-imidazolidin-4-ones: comparison between the classic method and green chemistry conditions

    Article • ARKIVOC, March 2018, ARKAT USA, Inc.

    Professor Sylvain MARQUE

  90. Monitoring of the discoloration on γ‐irradiated PE and EVA films to evaluate antioxidant stability

    Article • Journal of Applied Polymer Science, January 2018, Wiley

    Professor Sylvain MARQUE

  91. Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)

    Article • Australian Journal of Chemistry, January 2018, CSIRO Publishing

    Professor Sylvain MARQUE

  92. Enantiopure Schiff bases of amino acid phenylhydrazides: impact of the hydrazide function on their structures and properties

    Article • New Journal of Chemistry, January 2018, Royal Society of Chemistry

    Professor Sylvain MARQUE

  93. XPS analysis of PE and EVA samples irradiated at different γ-doses

    Article • Applied Surface Science, January 2018, Elsevier

    Professor Sylvain MARQUE

  94. Orthogonal Tyrosine and Cysteine Site-Directed Spin Labeling for Dipolar Pulse EPR Spectroscopy on Proteins

    Article • The Journal of Physical Chemistry Letters, September 2017, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  95. Impact of γ-irradiation, ageing and their interactions on multilayer films followed by AComDim

    Article • Analytica Chimica Acta, August 2017, Elsevier

    Professor Sylvain MARQUE

  96. Hyperfine coupling constants of β-phosphorylated nitroxides: Subtle interplay between steric strain, hyperconjugation, and dipole-dipole interactions

    Article • Tetrahedron, June 2017, Elsevier

    Professor Sylvain MARQUE

  97. Theoretical investigations on the conversions of cyclic polysulfides to acyclic polysulfide diradicals and subsequent reactions of biological interest

    Article • Tetrahedron, June 2017, Elsevier

    Professor Sylvain MARQUE

  98. Normal, Leveled, and Enhanced Steric Effects in Alkoxyamines Carrying a β-Phosphorylated Nitroxyl Fragment

    Article • The Journal of Organic Chemistry, May 2017, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  99. Zinc(II) Hexafluoroacetylacetonate Complexes of Alkoxyamines: NMR and Kinetic Investigations. First Step for a New Way to Prepare Hybrid Materials.

    Article • ChemistrySelect, April 2017, Wiley

    Professor Sylvain MARQUE

  100. β-Phosphorus Hyperfine Coupling Constant in Nitroxides: Conformational Effects in 6-Membered Ring Nitroxides

    Article • Applied Magnetic Resonance, March 2017, Springer Science + Business Media

    Professor Sylvain MARQUE

  101. C–ON bond homolysis of alkoxyamines: when too high polarity is detrimental

    Article • Organic & Biomolecular Chemistry, January 2017, Royal Society of Chemistry

    Professor Sylvain MARQUE

  102. How intramolecular hydrogen bonding (IHB) controls the C–ON bond homolysis in alkoxyamines

    Article • Organic & Biomolecular Chemistry, January 2017, Royal Society of Chemistry

    Professor Sylvain MARQUE

  103. Correction: Dual-initiator alkoxyamines with an N-tert-butyl-N-(1-diethylphosphono-2,2-dimethylpropyl) nitroxide moiety for preparation of block co-polymers

    Article • RSC Advances, January 2017, Royal Society of Chemistry

    Professor Sylvain MARQUE

  104. Dual-initiator alkoxyamines with an N-tert-butyl-N-(1-diethylphosphono-2,2-dimethylpropyl) nitroxide moiety for preparation of block co-polymers

    Article • RSC Advances, January 2017, Royal Society of Chemistry

    Professor Sylvain MARQUE

  105. Products and mechanisms of the heterogeneous reactions of ozone with commonly used pyrethroids in the atmosphere

    Article • The Science of The Total Environment, December 2016, Elsevier

    Professor Sylvain MARQUE

  106. Studies of the dehydrodimerization of 2-butanone and 3-pentanone by lead dioxide

    Article • Tetrahedron Letters, December 2016, Elsevier

    Professor Sylvain MARQUE

  107. New biosourced chiral molecularly imprinted polymer: Synthesis, characterization, and evaluation of the recognition capacity of methyltestosterone

    Article • Journal of Molecular Recognition, November 2016, Wiley

    Professor Sylvain MARQUE

  108. Intramolecular Hydrogen Bond Reverting the Solvent Effect on Phosphorus Hyperfine Coupling Constants of β‐Phosphorylated Nitroxides

    Article • ChemPhysChem, November 2016, Wiley

    Professor Sylvain MARQUE

  109. New biosourced AA and AB monomers from 1,4:3,6-dianhydrohexitols, Isosorbide, Isomannide, and Isoidide

    Article • Designed Monomers & Polymers, October 2016, Taylor & Francis

    Professor Sylvain MARQUE

  110. One year monitoring by FTIR of γ-irradiated multilayer film PE/EVOH/PE

    Article • Radiation Physics and Chemistry, August 2016, Elsevier

    Professor Sylvain MARQUE

  111. FTIR study of ageing of γ-irradiated biopharmaceutical EVA based film

    Article • Polymer Degradation and Stability, July 2016, Elsevier

    Professor Sylvain MARQUE

  112. Mass spectrometry of nitroxide-terminated poly(4-vinylpyridine): A case of unwanted reactive MALDI

    Article • International Journal of Mass Spectrometry, July 2016, Elsevier

    Professor Sylvain MARQUE

  113. Computational and mechanistic studies of the acylation of cyclopropanes

    Article • Tetrahedron Letters, April 2016, Elsevier

    Professor Sylvain MARQUE

  114. C–ON Bond Homolysis of Alkoxyamines, Part 11: Activation of the Nitroxyl Fragment

    Article • The Journal of Organic Chemistry, February 2016, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  115. Solvent effect in β-phosphorylated nitroxides. Part 4: detection of traces of water by electron paramagnetic resonance

    Article • Organic & Biomolecular Chemistry, January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  116. β-Phosphorus hyperfine coupling constant in nitroxides: 5. Solvent effect

    Article • RSC Advances, January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  117. C–ON bond homolysis in alkoxyamines. Part 12: the effect of the para-substituent in the 1-phenylethyl fragment

    Article • Organic & Biomolecular Chemistry, January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  118. The β-phosphorus hyperfine coupling constant in nitroxides: 6. Solvent effects in non-cyclic nitroxides

    Article • Organic & Biomolecular Chemistry, January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  119. Nitroxides in host–guest chemistry: 2010–2016

    Article • January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  120. C–ON bond homolysis of alkoxyamines triggered by paramagnetic copper(ii) salts

    Article • Inorganic Chemistry Frontiers, January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  121. Trityl-based alkoxyamines as NMP controllers and spin-labels

    Article • Polymer Chemistry, January 2016, Royal Society of Chemistry

    Professor Sylvain MARQUE

  122. Degradation of γ-irradiated polyethylene-ethylene vinyl alcohol-polyethylene multilayer films: An ESR study

    Article • Polymer Degradation and Stability, December 2015, Elsevier

    Professor Sylvain MARQUE

  123. Enzymatically Shifting Nitroxides for EPR Spectroscopy and Overhauser‐Enhanced Magnetic Resonance Imaging

    Article • Angewandte Chemie, November 2015, Wiley

    Professor Sylvain MARQUE

  124. Energetics of the biosynthesis of prostanes from arachidonate

    Article • Tetrahedron, September 2015, Elsevier

    Professor Sylvain MARQUE

  125. Computational Studies on Intramolecular Cycloadditions of Azidoenynes and Azidobutenenitriles to Give 6H-Pyrrolo[1,2-c][1,2,3]triazoles and 5H-Pyrrolo[1,2-d]tetrazoles

    Article • Helvetica Chimica Acta, July 2015, Wiley

    Professor Sylvain MARQUE

  126. Design of Wall-Functionalized Hybrid Silicas Containing Diazene Radical Precursors. EPR Investigation of Their Photolysis and Thermolysis

    Article • The Journal of Physical Chemistry C, March 2015, American Chemical Society (ACS)

    Dr Stéphane Gastaldi, Professor Sylvain MARQUE

  127. Solvent Effect in β-Phosphorylated Nitroxides: Model Nitroxides

    Article • Applied Magnetic Resonance, February 2015, Springer Science + Business Media

    Professor Sylvain MARQUE

  128. On the structure–control relationship of amide-functionalized SG1-based alkoxyamines for nitroxide-mediated polymerization and conjugation

    Article • Polymer Chemistry, January 2015, Royal Society of Chemistry

    Professor Sylvain MARQUE

  129. Part 10: chemically triggered alkoxyamine C–ON bond homolysis in ionic liquid solvents

    Article • RSC Advances, January 2015, Royal Society of Chemistry

    Professor Sylvain MARQUE

  130. The β-phosphorus hyperfine coupling constant in nitroxide: part 3: titration of water by electron paramagnetic resonance

    Article • Organic & Biomolecular Chemistry, January 2015, Royal Society of Chemistry

    Professor Sylvain MARQUE

  131. Chapter 2. Kinetic Aspects of Nitroxide Mediated Polymerization

    Article • January 2015, Royal Society of Chemistry

    Professor Sylvain MARQUE

  132. Development and Application of Spin Traps, Spin Probes, and Spin Labels

    Article • January 2015, Elsevier

    Professor Sylvain MARQUE

  133. Hydrogen-Bonding Effects for the C-ON Bond Homolysis and Reformation Reactions of Alkoxyamines

    Article • Macromolecular Chemistry and Physics, December 2014, Wiley

    Professor Sylvain MARQUE

  134. Energetics of the biosynthesis of cyclopentenones from unsaturated fatty acids

    Article • Tetrahedron, November 2014, Elsevier

    Professor Sylvain MARQUE

  135. Efficacious and rapid metal- and solvent-free synthesis of enantiopure oxazolines

    Article • Tetrahedron Asymmetry, October 2014, Elsevier

    Professor Sylvain MARQUE

  136. Addition and corrections published 31st October 2013 to 10th July 2014

    Article • Chemical Communications, July 2014, Royal Society of Chemistry

    Professor Sylvain MARQUE, Prof. In-Hyeok Park

  137. Alkoxyamines: Toward a New Family of Theranostic Agents against Cancer

    Article • Molecular Pharmaceutics, July 2014, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  138. New biosourced alternated poly(ether)Ester-Amides (PeEA): synthesis and combined NMR/MALDI ToF MS characterization

    Article • Journal of Polymer Research, June 2014, Springer Science + Business Media

    Professor Sylvain MARQUE

  139. Scavenging of Organic C-Centered Radicals by Nitroxides

    Article • Chemical Reviews, May 2014, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  140. In vivoOverhauser-enhanced MRI of proteolytic activity

    Article • Contrast Media & Molecular Imaging, April 2014, Wiley

    Professor Sylvain MARQUE

  141. Calculated linear free energy relationships in the course of the Suzuki–Miyaura coupling reaction

    Article • Tetrahedron, April 2014, Elsevier

    Professor Sylvain MARQUE

  142. Pyridylalkylamine ligands and their palladium complexes: structure and reactivity revisited by NMR

    Article • Magnetic Resonance in Chemistry, March 2014, Wiley

    Professor Sylvain MARQUE

  143. Revised Structure, Total Synthesis, and Absolute Configuration of Kopeolin and Kopeolone

    Article • The Journal of Organic Chemistry, March 2014, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  144. Chemically triggered C-ON bond homolysis in alkoxyamines. Part 7. Remote polar effect

    Article • Journal of Physical Organic Chemistry, January 2014, Wiley

    Professor Sylvain MARQUE

  145. Alkoxyamines: a new family of pro-drugs against cancer. Concept for theranostics

    Article • Organic & Biomolecular Chemistry, January 2014, Royal Society of Chemistry

    Professor Sylvain MARQUE

  146. Diversification of EPR signatures in site directed spin labeling using a β-phosphorylated nitroxide

    Article • Physical Chemistry Chemical Physics, January 2014, Royal Society of Chemistry

    Professor Sylvain MARQUE

  147. Arylsulfanyl radical lifetime in nanostructured silica: dramatic effect of the organic monolayer structure

    Article • Chemical Science, January 2014, Royal Society of Chemistry

    Dr Stéphane Gastaldi, Professor Sylvain MARQUE

  148. Labile alkoxyamines: past, present, and future

    Article • Chemical Communications, January 2014, Royal Society of Chemistry

    Professor Sylvain MARQUE

  149. Theoretical modelling of the epoxidation of vinylallenes to give cyclopentenones

    Article • Tetrahedron Letters, November 2013, Elsevier

    Professor Sylvain MARQUE

  150. Chemically Triggered C–ON Bond Homolysis of Alkoxyamines. 8. Quaternization and Steric Effects

    Article • The Journal of Organic Chemistry, October 2013, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  151. Nazarov reagents and their use in organic synthesis

    Article • Tetrahedron, September 2013, Elsevier

    Professor Sylvain MARQUE

  152. Chemically Triggered C–ON Bond Homolysis in Alkoxyamines. 6. Effect of the Counteranion

    Article • The Journal of Organic Chemistry, August 2013, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  153. Synthesis of partially hydrogenated oxa[5] and oxa[6]helicenes from β-chlorovinylaldehydes

    Article • Tetrahedron Letters, August 2013, Elsevier

    Professor Sylvain MARQUE

  154. Structural Equilibrium in New Nitroxide-Capped Cyclodextrins: CW and Pulse EPR Study

    Article • The Journal of Physical Chemistry B, July 2013, American Chemical Society (ACS)

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  155. Enlarging the Panoply of Site-Directed Spin Labeling Electron Paramagnetic Resonance (SDSL-EPR): Sensitive and Selective Spin-Labeling of Tyrosine Using an Isoindoline-Based Nitroxide

    Article • Bioconjugate Chemistry, June 2013, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  156. Chemically triggered C–ON bond homolysis in alkoxyamines: regioselectivity and chemoselectivity

    Article • Organic & Biomolecular Chemistry, January 2013, Royal Society of Chemistry

    Professor Sylvain MARQUE

  157. On the molecular structure and geometry of pyridylalkylamine–H+ complexes: application to catalytic enantioselective hydroxyalkylation of indoles

    Article • New Journal of Chemistry, January 2013, Royal Society of Chemistry

    Professor Sylvain MARQUE

  158. Dynamics of the intrinsically disordered protein CP12 in its association with GAPDH in the green alga Chlamydomonas reinhardtii: a fuzzy complex

    Article • Molecular BioSystems, January 2013, Royal Society of Chemistry

    Professor Sylvain MARQUE

  159. Intramolecular proton transfer (IPT) in alkoxyamine: a theoretical investigation

    Article • Physical Chemistry Chemical Physics, January 2013, Royal Society of Chemistry

    Professor Sylvain MARQUE

  160. H-transfer reaction during decomposition of N -(2-methylpropyl)- N -(1-diethylphosphono-2,2-dimethylpropyl)-N -oxyl (SG1)-based alkoxyamines

    Article • Journal of Polymer Science Part A Polymer Chemistry, December 2012, Wiley

    Professor Sylvain MARQUE

  161. Benzannulated Cycloheptanones from Binaphthyl Platforms

    Article • European Journal of Organic Chemistry, December 2012, Wiley

    Professor Sylvain MARQUE

  162. Chemically Triggered C–ON Bond Homolysis of Alkoxyamines. 5. Cybotactic Effect

    Article • The Journal of Organic Chemistry, November 2012, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  163. EPR Investigation of Zinc/Iodine Exchange between Propargyl Iodides and Diethylzinc: Detection of Propargyl Radical by Spin Trapping

    Article • The Journal of Organic Chemistry, October 2012, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  164. Hyperfine Coupling Constants of β-Phosphorylated Nitroxides: A Tool to Probe the Cybotactic Effect by Electron Paramagnetic Resonance

    Article • ChemPhysChem, August 2012, Wiley

    Professor Sylvain MARQUE

  165. Direct functionalization of labile alkoxyamines

    Article • Tetrahedron Letters, August 2012, Elsevier

    Professor Sylvain MARQUE

  166. Alkoxyamine Re-Formation Reaction. Effects of the Nitroxide Fragment: A Multiparameter Analysis.

    Article • The Journal of Organic Chemistry, June 2012, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  167. Aminomethylation of Michael Acceptors: Complementary Radical and Polar Approaches Mediated by Dialkylzincs

    Article • Chemistry - A European Journal, February 2012, Wiley

    Professor Sylvain MARQUE

  168. β-Fragmentation of Tertiary Alkoxyl Radicals: G3(MP2)-RAD and Natural Bond Orbital Investigations

    Article • ChemPhysChem, January 2012, Wiley

    Professor Sylvain MARQUE

  169. Chemically Triggered C–ON Bond Homolysis of Alkoxyamines. Quaternization of the Alkyl Fragment

    Article • Organic Letters, January 2012, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  170. Chemically triggered C–ON bond homolysis of alkoxyamines. Part 4: solvent effect

    Article • Polymer Chemistry, January 2012, Royal Society of Chemistry

    Professor Sylvain MARQUE

  171. In vivo high-resolution 3D Overhauser-enhanced MRI in mice at 0.2 T

    Article • Contrast Media & Molecular Imaging, January 2012, Wiley

    Professor Sylvain MARQUE

  172. Chemically Triggered C-ON Bond Homolysis in Alkoxyamines. Part 2: DFT Investigation and Application of the pH Effect on NMP

    Article • Macromolecular Rapid Communications, November 2011, Wiley

    Professor Sylvain MARQUE

  173. Cyclic and non cyclic aliphatic–aromatic polyesters derived from biomass: Study of structures by MALDI-ToF and NMR

    Article • European Polymer Journal, November 2011, Elsevier

    Professor Sylvain MARQUE

  174. Transition‐Metal‐Catalyzed α‐Arylation of Enolates

    Article • October 2011, Wiley

    Professor Sylvain MARQUE

  175. Time-Resolved and Pulse EPR Study of Triplet States of Alkylketones in β-Cyclodextrin

    Article • Applied Magnetic Resonance, October 2011, Springer Science + Business Media

    Professor Sylvain MARQUE

  176. Linear-Free Energy Relationships for Modeling Structure–Reactivity Trends in Controlled Radical Polymerization

    Article • Macromolecules, October 2011, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  177. Tyrosine-Targeted Spin Labeling and EPR Spectroscopy: An Alternative Strategy for Studying Structural Transitions in Proteins

    Article • Angewandte Chemie, August 2011, Wiley

    Professor Sylvain MARQUE

  178. N-Heterocyclic Pyridylmethylamines: Synthesis, Complexation, Molecular Structure, and Application to Asymmetric Suzuki–Miyaura and Oxidative Coupling Reactions

    Article • Organometallics, July 2011, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  179. Spin-Trapping Evidence for the Formation of Alkyl, Alkoxyl, and Alkylperoxyl Radicals in the Reactions of Dialkylzincs with Oxygen

    Article • Chemistry - A European Journal, January 2011, Wiley

    Professor Sylvain MARQUE

  180. First proton triggered C–ON bond homolysis in alkoxyamines

    Article • Chemical Communications, January 2011, Royal Society of Chemistry

    Professor Sylvain MARQUE

  181. Kinetic subtleties of nitroxide mediated polymerization

    Article • Chemical Society Reviews, January 2011, Royal Society of Chemistry

    Professor Sylvain MARQUE

  182. A facile preparation of trisubstituted amino-furan and -thiophene derivatives

    Article • Organic & Biomolecular Chemistry, January 2011, Royal Society of Chemistry

    Professor Sylvain MARQUE

  183. Enantioselective Friedel–Crafts alkylation of indole derivatives catalyzed by new Yb(OTf)3-pyridylalkylamine complexes as chiral Lewis acids

    Article • Organic & Biomolecular Chemistry, January 2011, Royal Society of Chemistry

    Professor Sylvain MARQUE

  184. Chemically Induced Dynamic Nuclear Polarization during the Thermolysis of Alkoxyamines: A New Approach to Detect the Occurrence of H-Transfer Reactions

    Article • Polymers, September 2010, MDPI AG

    Professor Sylvain MARQUE

  185. Diasteromeric Effect on the Homolysis of the C–ON Bond in Alkoxyamines: A DFT Investigation of 1,3-Diphenylbutyl-TEMPO

    Article • Polymers, September 2010, MDPI AG

    Professor Sylvain MARQUE

  186. A Step Towards High‐Molecular‐Weight Living/Controlled Polystyrene Using SG1‐Mediated Polymerization

    Article • Macromolecular Reaction Engineering, June 2010, Wiley

    Dr Muriel Lansalot, Professor Sylvain MARQUE

  187. Role of the alkyl fragment of initiating alkoxyamine in nitroxide mediated polymerization of styrene

    Article • Polymer Science Series B, June 2010, Pleiades Publishing Ltd

    Professor Sylvain MARQUE

  188. Polypropylene degradation: Theoretical and experimental investigations

    Article • Polymer Degradation and Stability, May 2010, Elsevier

    Professor Sylvain MARQUE

  189. Linear Free-Energy Relationships for the Alkyl Radical Affinities of Nitroxides: A Theoretical Study

    Article • Macromolecules, April 2010, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  190. Regio-Defined Amino[5]Oxa- and Thiahelicenes: A Dramatic Impact of the Nature of the Heteroatom on the Helical Shape and Racemization Barriers

    Article • The Journal of Organic Chemistry, March 2010, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  191. 5-Amino-2-furylmethylamines - Appealing Precursors of Amino­isoindolinones?

    Article • Synthesis, December 2009, Thieme Publishing Group

    Professor Sylvain MARQUE

  192. EPR, NMR, and Thermodynamic Evidences for Forced Nuclear Spin–Electron Spin Interactions in the Case of 1-Phenyl-2-Methylpropyl-1,1-Dimethyl-2-Nitroxide (TIPNO) Attached to Permethylated β-Cyclodextrin

    Article • Applied Magnetic Resonance, November 2009, Springer Science + Business Media

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  193. Kinetic study of H‐atom transfer in imidazoline‐, imidazolidine‐, and pyrrolidine‐based alkoxyamines: Consequences for nitroxide‐mediated polymerization

    Article • Journal of Polymer Science Part A Polymer Chemistry, October 2009, Wiley

    Professor Sylvain MARQUE

  194. Imidazoline-N-oxyl: A DFT Study of Its Protonation Reaction

    Article • ChemPhysChem, October 2009, Wiley

    Professor Sylvain MARQUE

  195. New Concepts in Molecular Imaging: Non-Invasive MRI Spotting of Proteolysis Using an Overhauser Effect Switch

    Article • PLOS One, April 2009, PLOS

    Professor Sylvain MARQUE

  196. Concise Synthesis of Tricyclic Isoindolinones via One-Pot Cascade Multicomponent Sequences

    Article • Organic Letters, March 2009, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  197. Role of the Adducted Cation in the Release of Nitroxide End Group of Controlled Polymer in Mass Spectrometry

    Article • Macromolecules, March 2009, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  198. Is Experimental Evidence Sufficient Enough To Account for the Stabilization Effect of Bisnitroxide on the Fate of NMP Experiments?

    Article • Macromolecules, February 2009, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  199. First Entry to [4+2] Cycloadditions Involving 5-Amino-2-furanmethanols

    Article • Heterocycles, January 2009, CLOCKSS Archive

    Professor Sylvain MARQUE

  200. Electron Paramagnetic Resonance Spin Trapping of Glutathiyl Radicals by PBN in the Presence of Cyclodextrins and by PBN Attached to β-Cyclodextrin

    Article • The Journal of Physical Chemistry B, October 2008, American Chemical Society (ACS)

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  201. Hydrogen-transfer reaction in nitroxide mediated polymerization of methyl methacrylate: 2,2-Diphenyl-3-phenylimino-2,3-dihydroindol-1-yloxyl nitroxide (DPAIO) vs. TEMPO

    Article • Journal of Polymer Science Part A Polymer Chemistry, September 2008, Wiley

    Professor Sylvain MARQUE

  202. Can the First Addition of Alkyl Radicals Play a Role in the Fate of NMP?

    Article • Macromolecular Chemistry and Physics, July 2008, Wiley

    Professor Sylvain MARQUE

  203. Synthesis of Highly Labile SG1-Based Alkoxyamines under Photochemical Conditions

    Article • The Journal of Organic Chemistry, June 2008, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  204. From Furans to Anilines:  Toward One-Pot Two-Step Amination/Diels−Alder Sequences

    Article • The Journal of Organic Chemistry, February 2008, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  205. Reduced sample recovery in liquid chromatography at critical adsorption point of high molar mass polystyrene

    Article • European Polymer Journal, February 2008, Elsevier

    Professor Sylvain MARQUE

  206. Effect of the Carboxylate Salt on the CON Bond Homolysis of SG1-Based Alkoxyamines

    Article • ChemPhysChem, February 2008, Wiley

    Professor Sylvain MARQUE

  207. Effect of the Penultimate Unit on the CON Bond Homolysis in SG1-Based Alkoxyamines

    Article • Macromolecular Chemistry and Physics, January 2008, Wiley

    Professor Sylvain MARQUE

  208. α-Phenyl-N-tert-butylnitrone-Type Derivatives Bound to β-Cyclodextrins: Syntheses, Thermokinetics of Self-Inclusion and Application to Superoxide Spin-Trapping

    Article • Chemistry - A European Journal, November 2007, Wiley

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  209. Iron–Palladium Association in the Preparation of Indoles and One‐Pot Synthesis of Bis(indolyl)methanes

    Article • European Journal of Organic Chemistry, October 2007, Wiley

    Professor Sylvain MARQUE

  210. Intermolecular radical addition of alkoxyamines onto olefins: An easy access to advanced macromolecular architectures precursors

    Article • Polymer, August 2007, Elsevier

    Professor Sylvain MARQUE

  211. Characterization of cyclic and non-cyclic poly-(ether-urethane)s bio-based sugar diols by a combination of MALDI-TOF and NMR

    Article • European Polymer Journal, August 2007, Elsevier

    Professor Sylvain MARQUE

  212. A DFT study of the hydrogen atom abstraction from 2,4,6-trimethylheptane: A model of peroxidic degradation for syndio polypropylene

    Article • Journal of Molecular Structure THEOCHEM, June 2007, Elsevier

    Professor Sylvain MARQUE

  213. Intermolecular FeCl3‐Catalyzed Hydroamination of Styrenes

    Article • European Journal of Organic Chemistry, May 2007, Wiley

    Professor Sylvain MARQUE

  214. First Effective Nitroxide-Mediated Polymerization of Methyl Methacrylate

    Article • Macromolecules, May 2007, American Chemical Society (ACS)

    Dr Paola Astolfi, Professor Sylvain MARQUE

  215. Synthetic Studies toward Highly Functionalized 5β-Lanosterol Derivatives:  A Versatile Approach Utilizing Anionic Cycloaddition.

    Article • The Journal of Organic Chemistry, February 2007, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  216. Living Character of Polymer Chains Prepared via Nitroxide-Mediated Controlled Free-Radical Polymerization of Methyl Methacrylate in the Presence of a Small Amount of Styrene at Low Temperature

    Article • Macromolecules, November 2006, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  217. Alkoxyamines of Stable Aromatic Nitroxides: NOvs. CO Bond Homolysis

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Dr Paola Astolfi, Professor Sylvain MARQUE

  218. Re-formation Reaction of Cyclic Nitroxide-Based Alkoxyamines: Steric and Polar/Stabilization Effects

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Professor Sylvain MARQUE

  219. Intramolecular Hydrogen Bonding: The Case ofβ-Phosphorylated Nitroxide (= Aminoxyl) Radical

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Professor Sylvain MARQUE

  220. Absolute Rate Constants for the Addition of the 1-(tert-Butoxy)carbonylethyl Radical onto Cyclic Alkenes in Solution

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Professor Sylvain MARQUE

  221. 2,5-Dihydro-1H-imidazole-Based Nitroxides as Prospective Mediators in Living Radical Polymerization

    Article • Helvetica Chimica Acta, October 2006, Wiley

    Professor Sylvain MARQUE

  222. Lewis Acid‐Catalyzed Direct Amination of Benzhydryl Alcohols

    Article • Advanced Synthesis & Catalysis, October 2006, Wiley

    Professor Sylvain MARQUE

  223. Persilylated Phosphoranyl Radicals: The First Persistent Noncyclic Phosphoranyl Radicals

    Article • Chemistry - A European Journal, September 2006, Wiley

    Professor Sylvain MARQUE

  224. Nitroxide Bound β-Cyclodextrin:  Is There an Inclusion Complex?

    Article • The Journal of Organic Chemistry, September 2006, American Chemical Society (ACS)

    Professor Sylvain MARQUE, Dr Laszlo Jicsinszky

  225. Nitroxide-Mediated Polymerization:  The Pivotal Role of the k d Value of the Initiating Alkoxyamine and the Importance of the Experimental Conditions

    Article • Macromolecules, August 2006, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  226. Laser Flash Photolysis and CIDNP Studies of Steric Effects on Coupling Rate Constants of Imidazolidine Nitroxide with Carbon-Centered Radicals, Methyl Isobutyrate-2-yl and tert -Butyl Propionate-2-yl ⊥

    Article • The Journal of Organic Chemistry, August 2006, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  227. Nitroxide-Mediated Polymerization of Methyl Methacrylate Using an SG1-Based Alkoxyamine: How the Penultimate Effect Could Lead to Uncontrolled and Unliving Polymerization

    Article • Macromolecular Chemistry and Physics, July 2006, Wiley

    Professor Sylvain MARQUE

  228. Synthetic Studies toward Highly Functionalized 5β-Lanosterol Derivatives:  A Versatile Approach Utilizing Anionic Cycloaddition

    Article • The Journal of Organic Chemistry, July 2006, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  229. Synthesis of Homo- and Heterobiarylmethylamines

    Article • Synthesis, June 2006, Thieme Publishing Group

    Professor Sylvain MARQUE

  230. Long-range polar and steric effects in propionate-SG1-type alkoxyamines (SG1-CHMeCOOX): a multiparameter analysis

    Article • Journal of Physical Organic Chemistry, April 2006, Wiley

    Professor Sylvain MARQUE

  231. Alkoxyamine C–ON Bond Homolysis: Stereoelectronic Effects

    Article • European Journal of Organic Chemistry, April 2006, Wiley

    Professor Sylvain MARQUE

  232. Polystyrene-block-poly(ethylene oxide) from nitroxide mediated polymerization: detection of minor species by coupled chromatographic techniques

    Article • Polymer, January 2006, Elsevier

    Professor Sylvain MARQUE

  233. Steric and Polar Effects of the Cyclic Nitroxyl Fragment on the C−ON Bond Homolysis Rate Constant

    Article • Macromolecules, November 2005, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  234. SG1 based alkoxyamines as radical initiators for the synthesis of lactones and lactames

    Article • Tetrahedron, September 2005, Elsevier

    Professor Sylvain MARQUE

  235. Polar, Steric, and Stabilization Effects in Alkoxyamines C−ON Bond Homolysis:  A Multiparameter Analysis

    Article • Macromolecules, April 2005, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  236. Reactivity of Phosphorus Centered Radicals

    Article • February 2005, Springer Science + Business Media

    Professor Sylvain MARQUE

  237. β-Fragmentation of alkoxyl radicals: Natural bond orbital analysis

    Article • International Journal of Quantum Chemistry, January 2005, Wiley

    Professor Sylvain MARQUE

  238. Selective and efficient fluorination of chlorodiazines under solvent-free phase transfer catalysis

    Article • Journal of Fluorine Chemistry, December 2004, Elsevier

    Professor Sylvain MARQUE

  239. Evolution of the partition coefficients of peroxide initiators during the synthesis of high-impact polystyrene

    Article • e-Polymers, December 2004, De Gruyter

    Professor Sylvain MARQUE

  240. Synthesis of phosphonium salts under microwave activation — Leaving group and phosphine substituents effects

    Article • Canadian Journal of Chemistry, September 2004, Canadian Science Publishing

    Professor Sylvain MARQUE

  241. Factors Influencing C−ON Bond Homolysis in Alkoxyamines:  Unexpected Behavior of SG1 ( N -(2-methyl-2-propyl)- N -(1-diethylphosphono-2,2-dimethylpropyl)- N -oxyl)-Based Alkoxyamines

    Article • The Journal of Organic Chemistry, July 2004, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  242. Leveled Steric Effect in Alkoxyamines of SG1-Type

    Article • Macromolecular Chemistry and Physics, May 2004, Wiley

    Professor Sylvain MARQUE

  243. Diastereomeric excess upon cleavage and reformation of diastereomeric alkoxyamines

    Article • Organic & Biomolecular Chemistry, January 2004, Royal Society of Chemistry

    Professor Sylvain MARQUE

  244. Switched external magnetic field CIDNP studies of coupling reaction of carbon-centered radicals with TEMPO

    Article • Physical Chemistry Chemical Physics, January 2004, Royal Society of Chemistry

    Professor Sylvain MARQUE

  245. Synthesis of a series of SG1 2-[N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)aminoxyl] based alkoxyamines, SG1-CH(Me)CO2R, and measurement of the homolysis rate constants of the C?ON bond

    Article • Journal of Polymer Science Part A Polymer Chemistry, January 2004, Wiley

    Professor Sylvain MARQUE

  246. Long-Range Polar Effect on the C-ON Bond Homolysis in (tert-Butyl[1-(diethylphosphonyl)-2,2-dimethylpropyl]aminoxyl) SG1-Based Alkoxyamines

    Article • Collection of Czechoslovak Chemical Communications, January 2004, Institute of Organic Chemistry & Biochemistry

    Professor Sylvain MARQUE

  247. Etherificaiton of Heterocyclic Compounds by Nucleophilic Aromatic Substitutions under Green Chemistry Conditions

    Article • Heterocycles, January 2004, CLOCKSS Archive

    Professor Sylvain MARQUE

  248. Alkoxyamine-Mediated Radical Synthesis of Indolinones and Indolines

    Article • Organic Letters, December 2003, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  249. 31P NMR measurement of the homolysis rate constant of the C-ON bond of β-phosphorylated alkoxyamines

    Article • e-Polymers, December 2003, De Gruyter

    Professor Sylvain MARQUE

  250. Influence of the Nitroxide Structure on the Homolysis Rate Constant of Alkoxyamines:  A Taft−Ingold Analysis

    Article • The Journal of Organic Chemistry, October 2003, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  251. Indium-catalyzed Barbier allylation reaction

    Article • Journal of Organometallic Chemistry, August 2003, Elsevier

    Professor Sylvain MARQUE

  252. Influence of Solvent and Polymer Chain Length on the Hemolysis of SG1-Based Alkoxyamines

    Article • June 2003, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  253. Steric Effects of Ring Substituents on the Decay and Reformation Kinetics of Piperazinone-Based Alkoxyamines

    Article • Macromolecules, May 2003, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  254. Tetrathiophosphoric acid tri(1-phenylethyl) ester and1-phenylethyl-diphenylphosphinodithioate as controlled radical polymerization agents

    Article • Tetrahedron Letters, February 2003, Elsevier

    Professor Sylvain MARQUE

  255. Design and use ofβ-phosphorus nitroxides and alkoxyamines in controlled/“living” free radical polymerizations

    Article • Macromolecular Symposia, June 2002, Wiley

    Dr Muriel Lansalot, Professor Sylvain MARQUE

  256. Lack of Chain Length Effect on the Rate of Homolysis of Polystyryl-SG1 Alkoxyamines

    Article • Macromolecules, May 2002, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  257. Solvent-Free Microwave-Assisted Aromatic Nucleophilic Substitution − Synthesis of Aromatic Ethers

    Article • European Journal of Organic Chemistry, April 2002, Wiley

    Professor Sylvain MARQUE

  258. Absolute Rate Constants for the Addition of the 1-(tert-Butoxy)carbonylethyl Radical to Alkenes in Solution

    Article • Helvetica Chimica Acta, August 2001, Wiley

    Professor Sylvain MARQUE

  259. Factors Influencing the C−O Bond Homolysis of Alkoxyamines:  Effects of H−Bonding and Polar Substituents

    Article • The Journal of Organic Chemistry, February 2001, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  260. Factors Influencing the C−O−Bond Homolysis of Trialkylhydroxylamines

    Article • Macromolecules, June 2000, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  261. Radical reaction kinetics during homolysis of N-alkoxyamines: verification of the persistent radical effect

    Article • Journal of the Chemical Society Perkin Transactions 2, January 1998, Royal Society of Chemistry

    Professor Sylvain MARQUE

  262. Persistent Silylated Phosphoranyl Radicals. Application to Dynamic Nuclear Polarization

    Article • The Journal of Physical Chemistry A, July 1997, American Chemical Society (ACS)

    Professor Sylvain MARQUE

  263. Synthesis, X-ray Geometry, and Anodic Behavior of Tris[2-(hydroxymethyl)phenyl]phosphane

    Article • The Journal of Physical Chemistry B, January 1996, American Chemical Society (ACS)

    Professor Sylvain MARQUE