All Stories

  1. Hydroxylamine synthesis by oxygen insertion into ReNH2 bond via Baeyer-Villiger oxidation: a Theoretical study

    Article • Journal of Physical Organic Chemistry, July 2015, Wiley

    Professor Sivasankar Chinnappan

  2. Coordinated and uncoordinated anion dictated coordination mode of PN(Me)P ligand in Pd(II) complexes and their catalytic applications

    Article • Journal of Organometallic Chemistry, August 2014, Elsevier

    Professor Sivasankar Chinnappan

  3. Corrigendum to “Lessons learned and lessons to be learned for developing homogeneous transition metal complexes catalyzed reduction of N2 to ammonia” [J. Organomet. Chem. 752 (2014) 44–58]

    Article • Journal of Organometallic Chemistry, August 2014, Elsevier

    Professor Sivasankar Chinnappan

  4. Lessons learned and lessons to be learned for developing homogeneous transition metal complexes catalyzed reduction of N2 to ammonia

    Article • Journal of Organometallic Chemistry, February 2014, Elsevier

    Professor Sivasankar Chinnappan

  5. Molecular and electronic structure analysis of some novel copper and zinc complexes of hypervalent carbon based ligand: DFT studies

    Article • Journal of Organometallic Chemistry, February 2014, Elsevier

    Professor Sivasankar Chinnappan

  6. Ammonia and hydrazine synthesis from [N2-W{(NHCH2CH2)3N}] and [AH]+[BH]− using Sivasankar catalytic cycle: DFT studies

    Article • Computational and Theoretical Chemistry, January 2014, Elsevier

    Professor Sivasankar Chinnappan

  7. Reduction of N2 by H2 to NH3 and N2H4 using [MoL] (L=triamidoamine) and organic co-catalysts: A theoretical approach

    Article • Journal of Molecular Catalysis A Chemical, April 2013, Elsevier

    Professor Sivasankar Chinnappan

  8. Calix[2]bispyrrolylarenes: New Expanded Calix[4]pyrroles for Fluorometric Sensing of Anions via Extended π-Conjugation

    Article • Organic Letters, December 2012, American Chemical Society (ACS)

    Professor Sivasankar Chinnappan

  9. A [Fe(CB6)] platform for binding of small molecules: Insights from DFT calculations

    Article • Journal of Computational Chemistry, February 2012, Wiley

    Professor Sivasankar Chinnappan

  10. Hydrogenation of dinitrogen to ammonia in [WF(PH2(CH2)2PH2)2N2] using H2: Insights from DFT calculations

    Article • New Journal of Chemistry, January 2012, Royal Society of Chemistry

    Professor Sivasankar Chinnappan

  11. A possibility of functionalizing the dinitrogen in a Chatt complex by H2: Density functional studies

    Article • Polyhedron, January 2012, Elsevier

    Professor Sivasankar Chinnappan

  12. Colorimetric Sensing of Fluoride Ion by New Expanded Calix[4]pyrrole through Anion−π Interaction

    Article • Organic Letters, December 2011, American Chemical Society (ACS)

    Professor Sivasankar Chinnappan

  13. Understanding the stability, electronic and molecular structure of some copper(III) complexes containing alkyl and non alkyl ligands: Insights from DFT calculations

    Article • Journal of Organometallic Chemistry, July 2011, Elsevier

    Professor Sivasankar Chinnappan

  14. Functionalization of Dinitrogen Using a Historically Significant Ru Complex: A New Life for an Old Complex

    Article • European Journal of Inorganic Chemistry, August 2010, Wiley

    Professor Sivasankar Chinnappan

  15. Mo– and W–N2 and –CO complexes with novel mixed P/N ligands: Structural properties and implications to synthetic nitrogen fixation

    Article • Inorganica Chimica Acta, March 2008, Elsevier

    Professor Sivasankar Chinnappan

  16. Energetics and Mechanism of Ammonia Synthesis through the Chatt Cycle: Conditions for a Catalytic Mode and Comparison with the Schrock Cycle

    Article • Chemistry - A European Journal, December 2007, Wiley

    Professor Sivasankar Chinnappan

  17. Is copper(i) hard or soft? A density functional study of mixed ligand complexes

    Article • New Journal of Chemistry, January 2007, Royal Society of Chemistry

    Professor Sivasankar Chinnappan, Professor Ashoka G Samuelson, Ashoka Samuelson

  18. Synthesis, spectroscopic characterization and electronic structure of some new Cu(I) carbene complexes

    Article • Journal of Chemical Sciences, May 2006, Springer Science + Business Media

    Professor Sivasankar Chinnappan, Professor Ashoka G Samuelson, Ashoka Samuelson

  19. Double deprotonation of coordinated ethylimide to CH3CN: molecular mechanism and relevance to the chemistry of Mo and W organoimides

    Article • Dalton Transactions, January 2006, Royal Society of Chemistry

    Professor Sivasankar Chinnappan

  20. Dismutation of a Molybdenum(IV) Acetonitrile−NNH2Complex to a Molybdenum(IV) Ethylimido Complex + N2:  Mechanistic Implications on the Protonation of Coordinated Nitriles at the β-Carbon Atom

    Article • Organometallics, September 2005, American Chemical Society (ACS)

    Professor Sivasankar Chinnappan