All Stories

  1. Reactivity of Rare Earth Metal Alkyl Complexes with Nitriles or Isonitrile: Versatile Ways toward Multiply Functionalized β-Diketiminato, (Iso)indolyl, and Imidazolyl Chelating Rare Earth Metal Complexes
  2. Anti‐Markovnikov Hydroamination and Hydroalkoxylation of Allylic Alcohols Promoted by a Simple Rare‐Earth Metal Trialkyl Complex
  3. Synthesis and catalytic activity of tetradentate β-diketiminato rare-earth metal monoalkyl complexes in tandem Oppenauer oxidation and cross-aldol condensation
  4. Difunctionalized indol-2-yl-ligated bimetallic rare-earth metal complexes: synthesis, characterization and high activity towards polymerization of 2-vinylpyridine
  5. Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives
  6. Synthesis, Structure, and Reactivity of Rare-Earth Metal Carboryne Complexes
  7. Aryl C–H bond functionalization with diphenyldiazomethane induced by rare-earth metal alkyl complexes
  8. Ether/Thioether-Functionalized Dianionic α-Iminopyridine Rare-Earth Metal Amido Complexes and Their Catalytic Activity toward Hydrophosphination of Alkenes
  9. Rare-Earth Metal Complexes Supported by 1,3-Functionalized Indolyl-Based Ligands for Efficient Hydrosilylation of Alkenes
  10. Indolyl-based Copper(I) Complex-Catalyzed Intermolecular Trifluoromethylazolation of Alkenes via Radical Process
  11. Unusual selective reactivity of the rare-earth metal complexes bearing a ligand with multiple functionalities
  12. Synthesis of rare-earth metal bisalkyl complexes supported by [1-(2-N-morpholinoethylene)-3-(4,4-dimethyl-2-oxazolinyl)] indolyl ligand and their application in the intermolecular hydrophosphination of aryl alkenes
  13. Synthesis and Characterization of Rare-Earth Metal Complexes Bearing a 2-N,N-Dimethylamino-Ethylene-Imino-Functionalized Indolyl Ligand and Their Catalytic Activities Toward Hydrosilylation of Imines
  14. Synthesis, structure of dinuclear o-phenylene linked bis(amidinate) rare-earth metal complexes and their catalytic activity towards Strecker reaction
  15. Synthesis and Characterization of N,N,C and N,N,O Tridentate β-Diketiminato Rare-Earth Metal Alkyl Complexes and Their Catalytic Performances on the Dimerization of Aldehydes or Terminal Alkynes
  16. Noninnocent Behavior of a (3-Imino)indol-2-yl Ligand in Metal Complexes
  17. Rare-Earth-Metal-Complex-Catalyzed Hydroalkoxylation and Tandem Hydroalkoxylation/Cyclohydroamination of Isocyanates: Synthesis of Carbamates and Oxazolidinones
  18. Halide-bridged tetranuclear organocopper(i) clusters supported by indolyl-based NCN pincer ligands and their catalytic activities towards the hydrophosphination of alkenes
  19. Synthesis and characterization of rare-earth metallate amido complexes bearing the 2-amidate-functionalized indolyl ligand and their application in the hydroboration of esters with pinacolborane
  20. Transformation of the sp2 Carbanion to Carbene with Subsequent 1,1-Migratory Insertion and Nucleophilic Substitution in Rare-Earth Metal Chemistry
  21. Synthesis, Characterization of Rare‐Earth Metal Chlorides Bearing Indolyl‐Based NCN Pincer Ligand and Their Catalytic Activity toward 1,4‐cis Polymerization of Isoprene
  22. Syntheses of Rare-Earth Metal Alkyl Complexes Bearing a Dianionic α-Iminopyridyl Ligand and Their Catalytic Activities toward Polymerization of 2-Vinylpyridine
  23. Hydroamination and Hydrophosphination of Isocyanates/Isothiocyanates under Catalyst‐Free Conditions
  24. Synthesis, Characterization, and Catalytic Activity of Dinuclear Rare-Earth Metal Alkyl Complexes Bearing 2,6-Diisopropylphenylamidomethyl Functionalized Pyrrolyl Ligand
  25. Synthesis of Carbamoylphosphates from Isocyanates Catalyzed by Rare-Earth-Metal Alkyl Complexes with a Silicon-Linked Diarylamido Ligand
  26. Synthesis and Reactivity of NNNNN-Pincer Multidentate Pyrrolyl Rare-Earth-Metal Amido-Chloride or Dialkyl Complexes
  27. Dehydrogenative Coupling of Terminal Alkynes with O/N-Based Monohydrosilanes Catalyzed by Rare-Earth Metal Complexes
  28. Syntheses of Dianionic α-Iminopyridine Rare-Earth Metal Complexes and Their Catalytic Acitivities toward Dehydrogenative Coupling of Amines with Hydrosilanes
  29. Rare‐Earth Metal Alkyl Complexes with 3‐Arylamido‐Functionalized Indolyl Ligands: Synthesis, Characterization and Reactivity †
  30. Heterobimetallic scandium–group 10 metal complexes with LM → Sc (LM = Ni, Pd, Pt) dative bonds
  31. Rare-earth complexes supported by an ansa-bis(amidinate) ligand with a rigid o-phenylene linker: synthesis, structure, and catalytic activity for polymerization of cyclic esters
  32. Synthesis and characterization of 2-t-butylimino-functionalized indolyl rare-earth metal amido complexes for the catalytic addition of terminal alkynes to carbodiimides: the dimeric complexes with the alkynide species in the μ–η1:η
  33. Synthesis, characterization, and reactivity of dinuclear organo-rare-earth-metal alkyl complexes supported by 2-amidate-functionalized indolyl ligands: substituent effects on coordination and reactivity
  34. Aluminum complexes with Schiff base bridged bis(indolyl) ligands: synthesis, structure, and catalytic activity for polymerization of rac-lactide
  35. Well-Defined Amidate-Functionalized N-Heterocyclic Carbene -Supported Rare-Earth Metal Complexes as Catalysts for Efficient Hydroboration of Unactivated Imines and Nitriles
  36. Syntheses, Structures, and Catalytic Activities of the Anionic Heterobimetallic Rare-Earth Metal Complexes Supported by Pyrrolyl-Substituted 1,2-Diimino Ligands
  37. Versatile reactivities of rare-earth metal dialkyl complexes supported by a neutral pyrrolyl-functionalized β-diketiminato ligand
  38. Synthesis and Characterization of Rare-Earth Metal Complexes Supported by 2-Imino or Amino Appended Indolyl Ligands with Diverse Hapticities: Tunable Selective Catalysis for Isoprene Polymerization
  39. Reactivity of 1,3-Disubstituted Indoles with Lithium Compounds: Substituents and Solvents Effects on Coordination and Reactivity of Resulting 1,3-Disubstituted-2-Indolyl Lithium Complexes
  40. Direct Access to Fused Salicylaldehydes and Salicylketones from Tetraynes
  41. Fused multifunctionalized dibenzoselenophenes from tetraynes
  42. Rare earth metal bisamido complexes with an NNO tridentate ligand and catalytic activity for the selective polymerization of isoprene
  43. Synthesis of Chiral Vicinal Diamines by Silver(I)-Catalyzed Enantioselective Aminolysis of N-Tosylaziridines
  44. Aluminum Complexes Bearing N-Protected 2-Amino- or 2-Imino-Functionalized Pyrrolyl Ligands: Synthesis, Structure, and Catalysis for Preparation of Pyrrolyl-End-Functionalized Polyesters
  45. Reactivity of 3-Imino-Functionalized Indoles with Rare-Earth-Metal Amides: Unexpected Substituent Effects on C–H Activation Pathways and Assembly of Rare-Earth-Metal Complexes
  46. Tris(pyrazolyl)methanide Complexes of Trivalent Rare-Earth Metals
  47. Aluminum alkyl complexes: synthesis, structure, and application in ROP of cyclic esters
  48. Di and trinuclear rare-earth metal complexes supported by 3-amido appended indolyl ligands: synthesis, characterization and catalytic activity towards isoprene 1,4-cis polymerization
  49. Synthesis of Bis(NHC)-Based CNC-Pincer Rare-Earth-Metal Amido Complexes and Their Application for the Hydrophosphination of Heterocumulenes
  50. Synthesis and Reactivity of Rare-Earth-Metal Monoalkyl Complexes Supported by Bidentate Indolyl Ligands and Their High Performance in Isoprene 1,4-cis Polymerization
  51. Copper(I)-Catalyzed Kinetic Resolution of N -Sulfonylaziridines with Indoles: Efficient Construction of Pyrroloindolines
  52. Copper-Catalyzed Electrophilic Amination of Organoaluminum Nucleophiles with O -Benzoyl Hydroxylamines
  53. Synthesis and Characterization of Organo-Rare-Earth Metal Monoalkyl Complexes Supported by Carbon σ-Bonded Indolyl Ligands: High Specific Isoprene 1,4-Cis Polymerization Catalysts
  54. Aluminum Alkyl Complexes Supported by Bidentate N,N Ligands: Synthesis, Structure, and Catalytic Activity for Guanylation of Amines
  55. Synthesis, Characterization, and Reactivity of Lanthanide Amides Incorporating Neutral Pyrrole Ligand. Isolation and Characterization of Active Catalyst for Cyanosilylation of Ketones
  56. Heterometallic rare-earth metal complexes with imino-functionalized 8-hydroxyquinolyl ligands: synthesis, characterization and catalytic activity towards hydrophosphinylation of trans-β-nitroalkene
  57. Reactivity of functionalized indoles with rare-earth metal amides. Synthesis, characterization and catalytic activity of rare-earth metal complexes incorporating indolyl ligands
  58. Dinuclear Rare-Earth Metal Alkyl Complexes Supported by Indolyl Ligands in μ-η2:η1:η1Hapticities and their High Catalytic Activity for Isoprene 1,4-cis-Polymerization
  59. Lewis Acid Catalyzed Cascade Reaction to Carbazoles and Naphthalenes via Dehydrative [3 + 3]-Annulation
  60. Synthesis, structure, and catalytic activity of rare-earth metal amides with a neutral pyrrolyl-functionalized indolyl ligand
  61. Synthesis of carborane-fused cyclobutenes and cyclobutanes
  62. CNC-Pincer Rare-Earth Metal Amido Complexes with a Diarylamido Linked Biscarbene Ligand: Synthesis, Characterization, and Catalytic Activity
  63. Synthesis, structure, and catalytic activity of novel trinuclear rare-earth metal amido complexes incorporating μ–η5:η1bonding indolyl and μ3-oxo groups
  64. Synthesis of polysubstituted pyrroles via [3 + 2]-annulation of aziridines and β-nitroalkenes under aerobic conditions
  65. Convenient one-step construction of yne-functionalized aryl halides through domino cyclization from tetraynes
  66. Rare-earth alkyl complexes supported by formamidinate ligands: synthesis, structure, and catalytic activity for isoprene polymerization
  67. Synthesis, Structure, and Reactivity of Lanthanide Complexes Incorporating Indolyl Ligands in Novel Hapticities
  68. Novel Lanthanide Amides Incorporating Neutral Pyrrole Ligand in a Constrained Geometry Architecture: Synthesis, Characterization, Reaction, and Catalytic Activity
  69. A Novel Lewis Acid Catalyzed [3 + 3]-Annulation Strategy for the Syntheses of Tetrahydro-β-Carbolines and Tetrahydroisoquinolines
  70. Controlled Synthesis of Racemic Indenyl Rare-Earth Metal Complexes via the Cooperation between the Intramolecular Coordination of Donor Atoms and a Bridge
  71. Rare-Earth Metal Chlorides Catalyzed One-pot Syntheses of Quinolines under Solvent-free Microwave Irradiation Conditions
  72. Dehydrogenation of secondary amines: synthesis, and characterization of rare-earth metal complexes incorporating imino- or amido-functionalized pyrrolyl ligands
  73. Rare-earth metal amido complexes supported by bridged bis(β-diketiminato) ligand as efficient catalysts for hydrophosphonylation of aldehydes and ketones
  74. Lanthanide Amido Complexes Incorporating Amino-Coordinate-Lithium Bridged Bis(indolyl) Ligands: Synthesis, Characterization, and Catalysis for Hydrophosphonylation of Aldehydes and Aldimines
  75. Synthesis and Characterization of Organolanthanide Complexes with a Calix[4]-pyrrolyl Ligand and Their Catalytic Activities toward Hydrophosphonylation of Aldehydes and Unactivated Ketones
  76. Highly Efficient Hydrophosphonylation of Aldehydes and Unactivated Ketones Catalyzed by Methylene-Linked Pyrrolyl Rare Earth Metal Amido Complexes
  77. Rare-earth metal complexes having an unusual indolyl-1,2-dianion through C–H activation with a novel η1:(μ2–η1:η1) bonding with metals
  78. Construction of 3-allylidene-4-vinyltetrahydrofurans and 3-allylidene-4-vinylpyrrolidines via sequential domino allylation/olefination of C–C triple bonds
  79. Synthesis, characterization, and catalytic activities of rare-earth metal complexes with iminopyrrolyl ligands
  80. Redox Chemistry between Europium(III) Amide and Pyrrolyl-Functionalized Secondary Amines. Synthesis and Structural Characterization of Lithium and Novel Lanthanide Complexes Incorporating Functionalized Pyrrolyl Ligands
  81. Fast Synthesis of Hydrazine and Azo Derivatives by Oxidation of Rare-Earth-Metal−Nitrogen Bonds
  82. Synthesis, structure and catalytic activity of alkali metal-free bent-sandwiched lanthanide amido complexes with calix[4]-pyrrolyl ligands
  83. Coupling/cyclization of 1,6-enynes with aryl halides: an efficient and general route for the synthesis of functionalized hexahydroindole and hexahydrobenzofuran derivatives
  84. Synthesis, characterization of some organolanthanide complexes containing 2-pyridylmethyl substituted fluorenyl ligand and catalytic activity of organolanthanide(II) complexes
  85. Efficient Construction of Five-Membered Aromatic and Nonaromatic Heterocycles from 1,6-Enynes by a Palladium-Catalyzed Domino Coupling/Cycloisomerization Process
  86. Tuned CH Functionalization to Construct Aza-Podophyllotoxin/Aza-Conidendrin Derivatives by Means of Domino Cyclization
  87. Rare earth metal bis(trimethylsilyl)amido complexes bearing pyrrolyl-methylamide ligand. Synthesis, structure, and catalytic activity towards guanylation of amines
  88. “Click” tetradentate ligands
  89. Cyclopentadienyl-Free Rare-Earth Metal Amides [{(CH2SiMe2){(2,6-iPr2C6H3)N}2}Ln{N(SiMe3)2}(THF)] as Highly Efficient Versatile Catalysts for C–C and C–N Bond Formation
  90. Synthesis of amides through the Cannizzaro-type reaction catalyzed by lanthanide chlorides
  91. Synthesis, Characterization, Selective Catalytic Activity, and Reactivity of Rare Earth Metal Amides with Different Metal−Nitrogen Bonds
  92. Efficient guanylation of aromatic and heterocyclic amines catalyzed by cyclopentadienyl-free rare earth metal amides
  93. Synthesis, characterization and catalytic activity of organolanthanide(II) complexes with heterocyclic-functionalized fluorenyl ligands
  94. Synthesis, Characterization, and Catalytic Activity of Rare Earth Metal Amides Supported by a Diamido Ligand with a CH 2 SiMe 2 Link
  95. Efficient Construction of Tri- and Tetracyclic Heterocycles from Linear 1,6-Dienes by a Domino Reaction
  96. Highly Atom Efficient Guanylation of both Aromatic and Secondary Amines Catalyzed by Simple Lanthanide Amides
  97. Synthesis, Structure, and Diverse Catalytic Activities of [Ethylenebis(indenyl)]lanthanide(III) Amides on N−H and C−H Addition to Carbodiimides and ɛ -Caprolactone Polymerization
  98. Synthesis, characterization, and catalytic activity of divalent organolanthanide complexes with new tetrahydro-2H-pyranyl-functionlized indenyl ligands
  99. Synthesis, Characterization, and Catalytic Activity of Some Neodymium(III), Ytterbium(II), and Europium(II) Complexes with Pyrrolidinyl- and Piperidinyl-Functionalized Indenyl Ligands
  100. Synthesis and Structural Characterization of Novel Ytterbium(III) Complexes with both a μ-Oxo Group and Bridged Indenyl Ligands, and Ytterbium(II) Complexes with Bridged Indenyl Ligands
  101. Coordination and Reactivity Diversity ofN-Piperidineethyl-Functionalized Indenyl Ligands:  Synthesis, Structure, Theoretical Calculation, and Catalytic Activity of Organolanthanide Complexes with the Ligands
  102. Total Synthesis of Indole Alkaloid (±)-Subincanadine F via SmI 2 -Mediated Ring Opening and Bridge-Forming Mannich Reaction
  103. Highly Efficient and Reusable Dendritic Catalysts Derived from N -Prolylsulfonamide for the Asymmetric Direct Aldol Reaction in Water
  104. Experimental and Theoretical Evidence for the First Example of an Organolanthanide(II) Compound Having an Indenyl Ligand Bonded to the Metal through the Benzo Ring in η4Hapticity
  105. Cannizzaro-Type Disproportionation of Aromatic Aldehydes to Amides and Alcohols by Using Either a Stoichiometric Amount or a Catalytic Amount of Lanthanide Compounds
  106. Homolysis of the Ln–N bond: Synthesis, characterization and catalytic activity of organolanthanide(II) complexes with 2-pyridylmethyl and 3-pyridylmethyl-functionalized indenyl ligands
  107. Highly Regio- and Stereoselective Synthesis of Tetrasubstituted Olefins by the Three-Component Tandem Reaction of Allylzinc Bromide, Acetylenic Sulfone, and Halohydrocarbon
  108. Homolysis of the Ln–N bond: Synthesis, characterization and catalytic activity of organolanthanide(II) complexes with furfuryl- and tetrahydrofurfuryl-functionalized indenyl ligands
  109. An unexpected highly diastereoselective double Baylis–Hillman reaction of per- (or poly)fluorophenyl aromatic aldimines with methyl vinyl ketone
  110. A solvent-free synthesis of α,α′-bis(substituted benzylidene) cycloalkanones catalyzed by lanthanide amides [(Me3Si)2N]3Ln(µ-Cl)Li(THF)3 under microwave irradiation
  111. Homolysis of the Ln−N (Ln = Yb, Eu) Bond− Synthesis, Structure, and Catalytic Activity of Ytterbium(II) and Europium(II) Complexes Having (Dimethylamino)propyl- and (Dimethylamino)ethyl-Functionalized Indenyl Ligands
  112. Sidearm Effects. Synthesis, Structural Characterization, and Reactivity of Lanthanides Incorporating a Linked Carboranyl-Indenyl Ligand with a Tethered Amine Group
  113. Sidearm Effects. Synthesis, Structural Characterization, and Reactivity of Rare Earth Complexes Incorporating a Linked Carboranyl-Indenyl Ligand with a Tethered Oxygen Atom §
  114. Homolysis of the Ln–N (Ln = Yb, Eu) bond. Synthesis, structural characterization and catalytic activity of ytterbium(ii) and europium(ii) complexes with methoxyethyl functionalized indenyl ligands
  115. Zinc-Mediated Radical Reactions of Per- (or Poly)fluorophenyl Aromatic Aldimines in Aqueous Media
  116. Substituents effect on molecular structures of 13-vertex closo-metallacarboranes of rare earths. Synthesis and structural characterization of metallacarboranes bearing nido- and arachno-carborane ligands
  117. An efficient preparation of N-per- (or poly)fluorophenyl pyrroles and N-fluoroalkanesulfonyl pyrroles
  118. Homolysis of the Eu−N Bond. Synthesis, Structural Characterization, and Catalytic Activity of Novel Europium(II) Complexes
  119. Synthesis, structure, and catalytic activity of tetracoordinate lanthanide amides [(Me3Si)2N]3Ln(μ-Cl)Li(THF)3 (Ln=Nd, Sm, Eu)
  120. A New Heteroatom Coordination Promoted Homolysis of the Yb−N Bond. Synthesis and Structural Characterization of a New Class of Ytterbium(II) and Ytterbium(III) Complexes with Amido and Indenyl Ligands and Catalytic Activities of Ytterbium(II) Complexes
  121. A Novel Full-Sandwich Lanthanacarborane Complex Bearing an η 7 -Carboranyl Ligand, {{[ η 7 -Me 2 Si(C 13 H 9 )(C 2 B 10 H 11 )] 2 Yb III } 2 Yb II }{Na 8 (THF) 20 }
  122. Samarium-Mediated Tandem Reactions of o -Carborane. Synthesis and Molecular Structure of [{η 5 :η 1 :η 6 -Me 2 Si(C 9 H 5 CH 2 CH 2 G)(C 2 B 10 H 10 )Sm} 2 ( μ -Cl)][Li(THF) 4 ] (G = NMe 2 and OMe)
  123. Carbon versus Silicon Bridges. Synthesis of a New Versatile Ligand and Its Applications in Organolanthanide Chemistry
  124. Synthesis and Structural Characterization of Novel Organolanthanide Clusters Containing Amido and Imido Groups
  125. Cyclopentadienyl vs Indenyl Substituents. Organolanthanide Complexes and Biscarborane Compounds Derived from a Versatile Ligand, Me 2 Si(C 9 H 7 )(C 2 B 10 H 11 )
  126. Application of a New Versatile Ligand to Lanthanide(II) Chemistry:  Synthesis, Reactivity, and Structure of a New Class of Organolanthanide Complexes
  127. Synthesis, Reactivity, and Structural Characterization of Organolanthanide Compounds Incorporating both Cyclopentadienyl and Carboranyl Groups
  128. Synthesis and Structure of the First Tetranuclear Organolanthanide Cluster Containing a μ 4 -Imido Group
  129. Synthesis and Characterization of Divalent Organolanthanide-Fullerene Adducts Cp2LnC60(Ln=Yb, Sm): First Example of Insertion Reaction Involving Cyclopentadienyl and Fullerene
  130. Synthesis and Crystal Structure of Indenyldichlorotris(Tetrahydrofuran)-Holmium(Iii)
  131. Synthesis and Structural Characterization of the First Mixed Lanthanacarborane Incorporating η 5 -Cyclopentadienyl and η 6 -Carboranyl Ligands
  132. A New Versatile Ligand:  Its Synthesis and Applications in Organolanthanide Chemistry
  133. Synthesis and structural investigation of {CpPr[CH(COOC2H5)2][μ-CH(COOC2H5)2]}2
  134. Synthesis and structural study of cyclopentadienyl lanthanide derivatives containing the 2-naphthoyltrifluoroacetonato ligand
  135. Synthesis and x-ray structural investigation of triindenyl tetrahydrofuranato praseodymium
  136. The formation and molecular structure of [Na(THF)6][(η5-C9H7)3Pr(μ-Cl)Pr(η5-C9H7)3]
  137. Synthesis of an organolanthanoid complex with a novel high-strain anionic cyclohexen-4-yne ligand and crystal structure of [(η5-Cp)2Sm(η5-C6H5)(thf)]
  138. The formation and molecular structure of (η5-C5H5)3Sm · OC4H8
  139. Structural investigation of the organolanthanide di-η5-cyclopentadienyl 1,1,1-trifluoroacetylacetonato ytterbium
  140. Synthesis and thermal stability of pyrrolyl complexes of some lanthanides
  141. Synthesis and characterization of organolanthanide complexes with three different ligands
  142. Synthesis and structure of (η5-C5H5)3Dy·OC4H8