All Stories

  1. Pyrazine-imide complexes: reversible redox and MOF building blocks
  2. A family of fourteen soluble stable macrocyclic [NiII3LnIII] heterometallic 3d–4f complexes
  3. Pressure induced separation of phase-transition-triggered-abrupt vs. gradual components of spin crossover
  4. Remarkable Scan Rate Dependence for a Highly Constrained Dinuclear Iron(II) Spin Crossover Complex with a Wide Thermal Hysteresis Loop
  5. Hysteretic spin crossover in iron(ii) complexes of a new pyridine–triazole–pyrazine ligand is tuned by choice of NCE co-ligand
  6. Spin crossover with thermal hysteresis in cobalt(ii) complexes and the importance of scan rate
  7. Design of One-Dimensional Coordination Networks from a Macrocyclic {3d-4f} Single-Molecule Magnet Precursor Linked by [W(CN)8]3– Anions
  8. Effect of N4-Substituent Choice on Spin Crossover in Dinuclear Iron(II) Complexes of Bis-Terdentate 1,2,4-Triazole-Based Ligands
  9. Di‐ and Tetranuclear Complexes of Bis‐Tetradentate Pyrimidine‐Based Ligands with All‐Methylene‐ Versus Mixed Methylene/Ethylene‐Linked Arms
  10. Metal acetates form diverse polynuclear complexes with 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt)
  11. Guest Binding Subtly Influences Spin Crossover in an FeII4L4 Capsule
  12. By Design: A Macrocyclic 3d–4f Single-Molecule Magnet with Quantifiable Zero-Field Slow Relaxation of Magnetization
  13. Pressure Effect Studies on the Spin‐Transition Behavior of a Dinuclear Iron(II) Compound
  14. Spin‐Crossover in Discrete Polynuclear Complexes
  15. Complexes of a porphyrin-like N4-donor Schiff-base macrocycle
  16. Oxidative dehydrogenation of a new tetra-amine N4-donor macrocycle tunes the nickel(ii) spin state from high spin to low spin
  17. Two distinct tetranuclear motifs, rectangular vs. extended, are observed for complexes of a bis-tetradentate pyrimidine-based ligand
  18. A Mitochondria-Targeted Macrocyclic Mn(II) Superoxide Dismutase Mimetic
  19. Synthesis and Magnetic Properties of a New Family of Macrocyclic MII3LnIII Complexes: Insights into the Effect of Subtle Chemical Modification on Single-Molecule Magnet Behavior
  20. Understanding the Forces That Govern Packing: A Density Functional Theory and Structural Investigation of Anion−π–Anion and Nonclassical C–H···Anion Interactions
  21. Nine Diiron(II) Complexes of Three Bis-tetradentate Pyrimidine Based Ligands with NCE (E = S, Se, BH3) Coligands
  22. Special issue dedicated to the seventh International Symposium of Macrocyclic and Supramolecular Chemistry (ISMSC-7)
  23. Synthesis and characterisation of two high spin iron(II) complexes of 3,4-diphenyl-5-(2-pyridyl)-1,2,4-triazole
  24. Di- and Tetra-Nuclear Copper(II), Nickel(II), and Cobalt(II) Complexes of Four Bis-Tetradentate Triazole-Based Ligands: Synthesis, Structure, and Magnetic Properties
  25. Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex
  26. Solvent control: dinuclear versus tetranuclear complexes of a bis-tetradentate pyrimidine-based ligand
  27. Nine non-symmetric pyrazine-pyridine imide-based complexes: reversible redox and isolation of [MII/III(pypzca)2]0/+when M = Co, Fe
  28. Reversible Switching of a Cobalt Complex by Thermal, Pressure, and Electrochemical Stimuli: Abrupt, Complete, Hysteretic Spin Crossover
  29. An unexpected mixed-valence cobalt(II)/cobalt(III) complex of a pyrrole-containing tridentate Schiff-base ligand
  30. Effect of Counteranion X on the Spin Crossover Properties of a Family of Diiron(II) Triazole Complexes [FeII2(PMAT)2](X)4
  31. A Tetranuclear, Macrocyclic 3d−4f Complex Showing Single-Molecule Magnet Behavior
  32. Back Cover: A Non-sandwiched Macrocyclic Monolanthanide Single-Molecule Magnet: The Key Role of Axiality (Chem. Eur. J. 16/2011)
  33. A Non‐sandwiched Macrocyclic Monolanthanide Single‐Molecule Magnet: The Key Role of Axiality
  34. Metal-Free and Dicopper(II) Complexes of Schiff Base [2 + 2] Macrocycles Derived from 2,2′-Iminobisbenzaldehyde: Syntheses, Structures, and Electrochemistry
  35. Heteroleptic N6coordinated ruthenium(ii) complexes as building blocks for the formation of discrete Ru2Ag2complexes
  36. A family of 13 tetranuclear zinc(ii)-lanthanide(iii) complexes of a [3 + 3] Schiff-base macrocycle derived from 1,4-diformyl-2,3-dihydroxybenzene
  37. Synthesis and complexes of an N4 Schiff-base macrocycle derived from 2,2′-iminobisbenzaldehyde
  38. Two dinuclear iron(ii) complexes K[Fe2(L1)(SCN)4]·2(C3H8O) and [Fe2(L1)(SeCN)3(C5H5N)]·H2O are stabilised in the ‘[HS–LS]’ state by a bis-tetradentate pyrazolate-based ligand
  39. Copper(II) and palladium(II) complexes of a terdentate pyrrolidine diester ligand
  40. Synthesis of 3- and 5-formyl-4-phenyl-1H-pyrazoles: promising head units for the generation of asymmetric imineligands and mixed metal polynuclear complexes
  41. Two mononuclear iron(ii) complexes of 4-phenylpyrazole-5-carbaldehyde derived ligands are stabilised in different spin states
  42. Factors Influencing the Structural and Magnetic Properties of Octahedral Cobalt(II) and Iron(II) Complexes of Terdentate N3 Schiff Base Ligands
  43. Doubly Pyrazolate-Bridged Dinuclear Complexes of a Highly Constrained Bis-terdentate Ligand: Observation of a [High Spin-Low Spin] State for [FeII2(PMAP)2][SbF6]2·2.25(C3H8O) ...
  44. Alkylations of N4‐(4‐Pyridyl)‐3,5‐di(2‐pyridyl)‐1,2,4‐triazole: First Observation of Room‐Temperature Rearrangement of an N4‐Substituted Triazole to the N1 Analogue
  45. Octa- and hendecanuclear zinc(II) complexes of an acyclic diimine ligand derived from 1,4-diformyl-2,3-dihydroxybenzene
  46. Spin crossover in co-crystallised 2 ∶ 1 cis∶trans [FeII(pldpt)2(NCS)2] occurs only in ⅓ of the iron centres
  47. Towards Langmuir–Blodgett films of magnetically interesting materials: solution equilibria in amphiphilic iron(ii) complexes of a triazole-containing ligand
  48. Two dicobalt(iii) complexes of triazolate-containing [2+2] Schiff-base macrocycles coordinate thiocyanate ions via the sulfur atom
  49. When three is not a crowd: the first trinuclear complexes of N4-substituted-3,5-dipyridyl-1,2,4-triazole ligands, [FeII3(Rdpt)4(NCS)6]
  50. Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(ii) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog
  51. Doubly Pyridazine-bridged Dicobalt(II) and Dinickel(II) Side-by-side Complexes of Variously Substituted Conjugated Bis-bidentate Ligands
  52. Anion, Solvent and Time Dependence of High‐Spin–Low‐Spin Interactions in a 3D Coordination Polymer
  53. Monomeric and Dimeric Copper(II) Complexes of a Pyrrole‐Containing Tridentate Schiff‐Base Ligand
  54. Iron(II) Tris-[N4-substituted-3,5-di(2-pyridyl)-1,2,4-triazole] Complexes: Structural, Magnetic, NMR, and Density Functional Theory Studies
  55. A Structural Investigation of Anion–Triazole Interactions: Observation of “π‐Pockets” and “π‐Sandwiches”
  56. Cobalt and Silver Complexes of Terdentate Pyrazine‐Based Amide Ligands and Assembly of Monocobalt Building Blocks through a Silver Connector
  57. Nano-magnetic materials: spin crossover compounds vs. single molecule magnets vs. single chain magnets
  58. A Tetranuclear Mixed-Valence Manganese Complex of a Diimine Ligand Derived from 1,4-Diformyl-2,3-dihydroxybenzene: Synthesis, Structure, and Magnetic Properties
  59. Hexa-, hepta- and dodeca-nuclear nickel(II) complexes of three Schiff-base ligands derived from 1,4-diformyl-2,3-dihydroxybenzene
  60. A hexanuclear iron(iii) complex of a hexadentate fully conjugated diimine ligand derived from 1,4-diformyl-2,3-dihydroxybenzene
  61. Di-, tetra- and hexanuclear iron(III), manganese(II/III) and copper(II) complexes of Schiff-base ligands derived from 6-substituted-2-formylphenols
  62. 1-Tetradecylpyridinium bromide monohydrate
  63. Factors Influencing Tetranuclear [2 × 2] Grid vs Dinuclear Side-by-Side Structures for Silver(I) Complexes of Pyridazine-Based Bis-Bidentate Ligands
  64. High and Low Spin Mononuclear and Dinuclear Iron(II) Complexes of 4-Amino and 4-Pyrrolyl-3,5-di(2-pyridyl)-4H-1,2,4-triazoles
  65. Effect of pressure and light on the spin transition behavior of the dinuclear iron(II) compound [FeII2(PMAT)2](BF4)4⋅DMF
  66. Titelbild: Mixed Spin-State [HS-LS] Pairs in a Dinuclear Spin-Transition Complex: Confirmation by Variable-Temperature57Fe Mössbauer Spectroscopy (Angew. Chem. 16/2008)
  67. Mixed Spin‐State [HS‐LS] Pairs in a Dinuclear Spin‐Transition Complex: Confirmation by Variable‐Temperature 57Fe Mössbauer Spectroscopy
  68. Mixed Spin‐State [HS‐LS] Pairs in a Dinuclear Spin‐Transition Complex: Confirmation by Variable‐Temperature 57Fe Mössbauer Spectroscopy
  69. Cover Picture: Mixed Spin‐State [HS‐LS] Pairs in a Dinuclear Spin‐Transition Complex: Confirmation by Variable‐Temperature 57Fe Mössbauer Spectroscopy (Angew. Chem. Int. Ed. 16/2008)
  70. Monomeric, dimeric and 1D chain polymeric copper(ii) complexes of a pyrrole-containing tridentate Schiff-base ligand and its 4-brominated analogue
  71. 4-(Pyrrol-1-yl)-1,2,4-triazole
  72. Synthesis and Structures of 3,5-disubstituted 1,2,4-triazole Head Units and Incorporation of 3,5-dibenzoyl-1,2,4-triazolate into New [2 + 2] Schiff-Base Macrocyclic Complexes
  73. Pyridazine-bridged copper(i) complexes of bis-bidentate ligands: tetranuclear [2 ? 2] grid versus dinuclear side-by-side architectures as a function of ligand substituents
  74. Dicopper(ii) complexes of a new pyrazolate-containing Schiff-base macrocycle and related acyclic ligand
  75. Synthesis and X-ray crystal structures of some mononuclear and dinuclear complexes of 4-isobutyl-3,5-di(2-pyridyl)-4H-1,2,4-triazole
  76. Tricopper(ii) complexes of unsymmetrical macrocycles incorporating phenol and pyridine moieties: the development of two stepwise routes
  77. A [2 × 2] nickel(ii) grid and a copper(ii) square result from differing binding modes of a pyrazine-based diamide ligand
  78. 1:1 Adduct of (S,S)-4-amino-3,5-bis(1-hydroxyethyl)-1,2,4-triazole with (S,S)-1,2-bis(2-hydroxypropionyl)hydrazine stabilized by eight hydrogen bonds
  79. Synthesis and characterisation of a series of mononuclear ruthenium(II) carbonyl complexes of heterocycle-based asymmetric bidentate ligands
  80. Probing the Dinucleating Behaviour of a Bis‐Bidentate Ligand: Synthesis and Characterisation of Some Di‐ and Mononuclear Cobalt(II), Nickel(II), Copper(II) and Zinc(II) Complexes of 3,5‐Di(2‐pyridyl)‐4‐(1H...
  81. Synthesis of mononuclear and dinuclear ruthenium(ii) tris(heteroleptic) complexes via photosubstitution in bis(carbonyl) precursors
  82. Control of molecular architecture by steric and electronic factors: dinuclear side-by-side vs. tetranuclear [2 × 2] grid-type silver(i) complexes
  83. Synthesis and Some First‐Row Transition‐Metal Complexes of the 1,2,4‐Triazole‐Based Bis(terdentate) Ligands TsPMAT and PMAT
  84. Dinuclear Copper(II) Complexes of Two Homologous Pyrazine‐Based Bis(terdentate) Diamide Ligands
  85. First Complexes of a 4‐Alkyl‐3,5‐di(2‐pyridyl)‐4H‐1,2,4‐triazole: Synthesis,X‐ray Crystal Structures and Magnetic Properties of Dinuclear Cobalt(II), Nickel(II) and Copper(II) Complexes of 4‐Isobutyl‐3,5‐di(2‐pyr...
  86. Dimetallic complexes of a structurally versatile pyridazine-containing Schiff-base macrocyclic ligand with pendant pyridine arms
  87. Iron(iii) activation hits a [4 + 4] macrocycle
  88. The first X-ray crystal structure determination of a dinuclear complex trapped in the [low spin–high spin] state: [FeII2(PMAT)2](BF4)4·DMF
  89. Dinickel(II), dizinc(II) and dilead(II) complexes of a pyridazine-containing Schiff-base macrocycle
  90. From N‐Substituted Thioamides to Symmetrical and Unsymmetrical 3,4,5‐Trisubstituted 4H‐1,2,4‐Triazoles: Synthesis and Characterisation of New Chelating Ligands
  91. Dicopper(II) and dinickel(II) complexes of Schiff-base macrocycles derived from 5,5-dimethyl-1,9-diformyldipyrromethane
  92. Two forms of a copper(II) complex of 3-phenyl-5-(2-pyridyl)-4-(4-pyridyl)-4H-1,2,4-triazole: a six-coordinate monomer versus a five-coordinate polymer
  93. Controlled Access to Mixed‐Metal Pyridazine‐Linked Cryptates
  94. Synthesis and X-ray crystal structure of a polymeric copper(II) complex containing the novel ligand 4,4′-(1,4-phenylene)bis[3-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole]
  95. Syntheses, Structures and Tautomers of 2,5‐Disubstituted Pyrroles.
  96. Synthesis and anion binding behaviour of diamide derivatives of pyrrole-2,5-diacetic acid
  97. POTENTIAL APPLICATIONS FOR THE USE OF LANTHANIDE COMPLEXES AS LUMINESCENT BIOLABELS
  98. Control of molecular architecture by use of the appropriate ligand isomer: a mononuclear “corner-type” versus a tetranuclear [2 × 2] grid-type cobalt(iii) complex
  99. Dimetallic complexes of acyclic pyridine-armed ligands derived from 3,6-diformylpyridazine
  100. Coordination Algorithms Control Molecular Architecture: [CuI4(L2)4]4+ Grid Complex Versus [MII2(L2)2X4]y+ Side‐By‐Side Complexes (M=Mn, Co, Ni, Zn; X=Sol...
  101. Coordination Algorithms Control Molecular Architecture: [CuI4(L2)4]4+ Grid Complex Versus [MII2(L2)2X4]y+ Side‐By‐Side Complexes (M=Mn, Co, Ni, Zn; X=Sol...
  102. Cover Picture: Coordination Algorithms Control Molecular Architecture: [CuI4(L2)4]4+ Grid Complex Versus [MII2(L2)2X4]y+ Side‐By‐Side Complexes (M=Mn, Co...
  103. Redox-Adaptable Copper Hosts. Pyridazine-Linked Cryptands Accommodate Copper in a Range of Redox States
  104. A new bis(phenol-armed) pyridazine-containing Schiff base ligand: synthesis, complexation and reduction to the amine ligand analogue
  105. Dicobalt(ii) complexes of a triazolate-containing Schiff-base macrocycle: synthesis, structure and magnetism
  106. Some Copper and Cobalt Complexes of Schiff‐Base Macrocycles Containing Pyridazine Head Units
  107. Syntheses, structures and tautomers of 2,5-disubstituted pyrroles
  108. A dicobalt(ii) complex of a triazolate-containing macrocycle reacts with nitromethane to yield an organometallic dicobalt(iii) complex
  109. Monomeric, trimeric and polymeric assemblies of dicopper(ii) complexes of a triazolate-containing Schiff-base macrocycle
  110. Erratum to “Heterobinuclear cryptates: cooperative binding generates two different coordination sites within a symmetrical cryptand” [Inorg. Chim. Acta 337 (2002) 463–466]
  111. Control of molecular architecture by the degree of deprotonation: self-assembled di- and tetranuclear copper(ii) complexes of N,N′-bis(2-pyridylmethyl)pyrazine-2,3-dicarboxamide
  112. Heterobinuclear cryptates; cooperative binding generates two different coordination sites within a symmetrical cryptand
  113. ChemInform Abstract: Total Synthesis of (+)‐Hatomarubigin B (I).
  114. Exchange-coupled high-spin, low-spin and spin-crossover dicobalt(ii) complexes of a pyridazine-containing Schiff-base macrocycle: control of cobalt(ii) spin state by choice of axial ligands
  115. ChemInform Abstract: Complexes of Thiophenolate‐Containing Schiff Base Macrocycles and Their Amine Analogues
  116. Total Synthesis of (+)-Hatomarubigin B
  117. ChemInform Abstract: Doubly Pyridazine‐Bridged Macrocyclic Complexes of Copper in +1, +2, and Mixed Valent Oxidation States.
  118. Figure-of-eight Shaped Metal-free Amide-containing Schiff-base Macrocycles and Two Dicobalt(III) Amide Complexes
  119. A conformationally adaptable host capable of encapsulating single cations or homo and hetero dinuclear assemblies
  120. ChemInform Abstract: A Diels—Alder Strategy to 1,4‐Glycosidically Linked Monocarba‐disaccharides.
  121. Formation and Structure of the Oxygen-Centered Lead Thiolate Cluster Pb5O(SRF)8·2C7H8 [RF = 2,4,6-Tris(trifluoromethyl)phenyl]
  122. A Diels–Alder strategy to 1,4-glycosidically linked monocarba-disaccharides
  123. Dimetallic thiolate-bridged complexes: synthesis and rich electrochemistry of dinickel(II) and dizinc(II) monothiolate complexes
  124. Dithiolate-containing macrocyclic complexes in which there is no thiolate bridging: synthesis, structure and electrochemistry of some dizinc(II) complexes
  125. Complexation of copper(II) with acyclic amide ligands: structure of an unexpected rearrangement product resulting from an intramolecular reaction of an amine with an amide
  126. Conversion of some substituted phenols to the corresponding masked thiophenols, synthesis of a dinickel(II) dithiolate macrocyclic complex and isolation of some metal- and ligand-based oxidation products
  127. Synthesis, complexation and cyclisation reactions of a new acyclic diamide: observation of intramolecular ligand exchange in a structurally characterised nickel(II) complex
  128. Binuclear nickel(II) and copper(II) complexes of amide-containing two-armed and macrocyclic ligands
  129. Low-spin iron(II) in a small unsymmetrical N6 macrocycle
  130. A Facile Synthesis of 2,6-Dideoxy 6,6,6-Trifluorinated Carbohydrate Analogues
  131. A pyridazine Schiff-base macrocycle hosts a dicobalt centre in five different redox states: evidence for a mixed valent CoICoII species
  132. First of a new family of tetraamine bis(μ-thiolate)-containing macrocycles: structure and stepwise oxidations and reductions of the dinickel(ii) complex
  133. First example of thiolate-bridged square-pyramidal and octahedral nickel(ii) ions: [Ni2(LSO)(NCS)2(dmf)]
  134. First observation of non-bridging thiolates or tetrahedral geometries within thiolate-containing Schiff-base macrocycles: [Zn2L][CF3SO3]2
  135. Tetra- and pentamanganese(II) macrocyclic complexes with bridging carboxylate groups: product control by pretreatment of manganese acetate solutions
  136. Total syntheses of the angucyclinone antibiotics (+)-emycin A and (+)-ochromycinone
  137. Synthesis and structure of dilead(II) and dimanganese(II) complexes of macrocycles derived from 3,6-diformylpyridazine
  138. Controlled synthesis and reversible oxidation of a thiolate-bridged macrocyclic dinickel(II) complex
  139. First dicopper(II) complex to contain bridging macrocyclic pyridazine units: structure, electrochemistry and magnetochemistry of [Cu2L(MeCN)2(ClO4)2][ClO4]2
  140. First macrocycle to incorporate phenol and thiophenol head units: the X-ray crystal structure of [Ni2L(MeCN)2](ClO4)2 reveals bridged square-planar and octahedral nickel(II) ions
  141. Trinickel(II) complex of an acyclic thiophenolate ligand: the X-ray crystal structure of [Ni2L2Ni](ClO4)2(H2O) reveals alternating square-planar and octahedral nickel ions
  142. First synthesis of a macrocycle from 3,6-diformylpyridazine: X-ray crystal structure of [Pb2(4 + 4)](ClO4)4
  143. Synthesis of a new unsymmetrical trinucleating macrocycle incorporating both phenolic and pyridine head units: x-ray crystal structure of {[Pb2(L1)(Cl)](ClO4)2} x
  144. Synthese und Kristallstrukturen von monomeren bis(thiophenolato)metall(II)‐Komplexen
  145. Main-group chemistry of the 2,4,6-tris(trifluoromethyl)phenyl substituent: x-ray crystal structures of [2,4,6-(CF3)3C6H2]2Zn, [2,4,6-(CF3)3C6H2]2Cd(MeCN) and [2,4,6-(CF3)3C6H3]2Hg
  146. Synthesis and Molecular Structure of the Solvent‐Free [LiN(SiMe3)(2,6iPr2C6H3)]2 Dimer
  147. Alkoxysilylamide des Neodyms, Samariums und Ytterbiums: Viergliedrige anorganische Ringsysteme in der Lanthanidchemie
  148. Diiminophosphinate des Lithiums, Samariums und Ytterbiums: Moleku¨lstrukturen von Li[Ph2P(NSiMe3)2](THF)2 und [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2
  149. Organolanthanid(II)-Chemie: Synthese und Struktur von [Cp2*Sm(μ-OC)2FeCp*]2
  150. Synthesis, structure, and reactivity of the first stable diaryllead(II) compound
  151. CF bond activation in the reaction of BiCl3 with sodium 2,4,6-tris(trifluoromethyl)phenoxide
  152. Comparison of the X-ray crystal structures of the sodium and potassium 2,4,6-tris(trifluoromethyl)phenoxides (RO–) and 2,4,6-tris(trifluoromethyl)benzenethiolates (RS–); [Na(OR)(thf)2]2, [K(OR)(thf)2
  153. Complexes of ligands derived from the condensation of 2-formyl- or 2-acetylpyridine with ethanolamine and the formation of two rearrangement products; X-ray crystal structures of Mn(L1)2(NCS)2, [Mn(L1)(NCS)2]x, [Cu(L1)(H2O)2(ClO4)]2(ClO4)2, [Zn(L1)(H2O...
  154. Six- and seven-co-ordinate manganese(II) complexes of Schiff-base ligands derived from the condensation of 2,6-diacetylpyridine with ethanolamine (L1) or propanolamine (L2); X-ray crystal structures of [MnL1C...
  155. Nickel(II) complexes of Schiff-base ligands derived from the condensation of 2,6-diacetylpyridine with ethanolamine (L1) or propanolamine (L2); X-ray crystal structures of [NiL12][ClO4]<...
  156. Macrocyclic tetramanganese(II) complexes with alkoxy and chloro or azido bridges; X-ray crystal structures of [Mn2(HL)(Cl)2]2(ClO4)2·2dmf·H2O and [Mn2(HL)(N3...
  157. Formation of a (4 + 4) Schiff-base macrocyclic ligand by a template rearrangement. Crystal and molecular structures of two tetranuclear manganese(II) complexes