All Stories

  1. Organocatalytic enantioselective synthesis of 1-vinyl tetrahydroisoquinolines through allenamide activation with chiral Brønsted acids
  2. A highly enantioselective acyl-Mannich reaction of isoquinolines with aldehydes promoted by proline derivatives: an approach to 13-alkyl-tetrahydroprotoberberine alkaloids
  3. Synergistic Stereoselective Organocatalysis with Indium(III) Salts
  4. A Practical and Stereoselective Organocatalytic Alkylation of Aldehydes with Benzodithiolylium Tetrafluoroborate
  5. Synergy, Compatibility, and Innovation: Merging Lewis Acids with Stereoselective Enamine Catalysis
  6. A Straightforward Organocatalytic Alkylation of 2‐Arylacetaldehydes: An Approach towards Bisabolanes
  7. Alpha‐Alkylation by S N 1‐Type Reactions
  8. The Facile and Direct Formylation of Organoboron Aromatic Compounds with Benzodithiolylium Tetrafluoroborate
  9. A Rotaxane Turing Machine for Peptides
  10. A Rational Approach Towards a New Ferrocenyl Pyrrolidine for Stereoselective Enamine Catalysis
  11. A Highly Stereoselective Organocatalytic Approach to Lilial® and Muguesia
  12. Direct and Stereoselective Alkylation of Nitro Derivatives with Activated Alcohols in Trifluoroethanol
  13. Cover Picture: Flowing and Vibrant Organocatalysis (ChemCatChem 7/2012)
  14. Organocatalytic Stereoselective α‐Formylation of Ketones
  15. (1R,2R)-(−)-[1,2-Cyclohexanediamino-N,N′-bis(3,5-di-t-butylsalicylidene)]chromium(III) Chloride
  16. A general stereoselective enamine mediated alkylation of α-substituted aldehydes
  17. Gold meets enamine catalysis in the enantioselective α-allylic alkylation of aldehydes with alcohols
  18. Single electron tunneling in large scale nanojunction arrays with bisferrocene–nanoparticle hybrids
  19. Toward quantum-dot cellular automata units: thiolated-carbazole linked bisferrocenes
  20. Innentitelbild: Highly Enantioselective α Alkylation of Aldehydes with 1,3‐Benzodithiolylium Tetrafluoroborate: A Formal Organocatalytic α Alkylation of Aldehydes by the Carbenium Ion (Angew. Chem. 34/2011)
  21. Inside Cover: Highly Enantioselective α Alkylation of Aldehydes with 1,3‐Benzodithiolylium Tetrafluoroborate: A Formal Organocatalytic α Alkylation of Aldehydes by the Carbenium Ion (Angew. Chem. Int. Ed. 34/2011)
  22. Highly Enantioselective α Alkylation of Aldehydes with 1,3‐Benzodithiolylium Tetrafluoroborate: A Formal Organocatalytic α Alkylation of Aldehydes by the Carbenium Ion
  23. Highly Enantioselective α Alkylation of Aldehydes with 1,3‐Benzodithiolylium Tetrafluoroborate: A Formal Organocatalytic α Alkylation of Aldehydes by the Carbenium Ion
  24. Enantio and Diastereoselective Addition of Phenylacetylene to Racemic α-chloroketones
  25. Atroposelective Organocatalysis
  26. Direct Nucleophilic SN1‐Type Reactions of Alcohols
  27. Merging Organocatalysis with an Indium(III)‐Mediated Process: A Stereoselective α‐Alkylation of Aldehydes with Allylic Alcohols
  28. Organocatalytic Stereoselective α‐Alkylation of Aldehydes with Stable Carbocations
  29. Copper-promoted enantioselective Reformatsky-type reaction with ketones
  30. Stereoselective Reactions with Stabilized Carbocations
  31. The First Catalytic Enantioselective Aldol‐Type Reaction of Ethyl Diazoacetate to Ketones
  32. Electrophilic Activation of Aldehydes “On Water”: A Facile Route to Dipyrromethanes
  33. Organocatalytic Asymmetric Alkylation of Aldehydes by SN1‐Type Reaction of Alcohols
  34. Organocatalytic Asymmetric Alkylation of Aldehydes by SN1‐Type Reaction of Alcohols
  35. Catalytic stereoselective benzylic C–H functionalizations by oxidative C–H activation and organocatalysis
  36. Me2Zn as a radical source in Reformatsky-type reactions
  37. Synthesis of camphorsulfonamide-based quinoline ligands and their N-oxides: first use in the enantioselective addition of organozinc reagents to aldehydes
  38. A Rational Approach towards the Nucleophilic Substitutions of Alcohols “on Water”
  39. A Rational Approach towards the Nucleophilic Substitutions of Alcohols “on Water”
  40. Dimethylzinc‐Mediated, Oxidatively Promoted Reformatsky Reaction of Ethyl Iodoacetate with Aldehydes and Ketones
  41. Catalytic enantioselective Reformatsky reactions
  42. Me2Zn mediated, tert-butylhydroperoxide promoted, catalytic enantioselective Reformatsky reaction with aldehydes
  43. Iridium Catalyzed Enantioselective Hydrogenation of N-Iminopyridinium Ylides: Mechanistic Insights
  44. The Erratic Emission of Pyrene on Gold Nanoparticles
  45. Enantioselective Catalytic Formation of Quaternary Stereogenic Centers
  46. Practical Chloromanganese-Salen-Catalyzed Enantioselective Reformatsky Reaction with Ketones
  47. Asymmetric Hydrogenation of Alkenes, Enones, Ene‐Esters and Ene‐Acids
  48. Titanium-catalyzed Reformatsky-type reaction
  49. Facile Access to Optically Active Ferrocenyl Derivatives with Direct Substitution of the Hydroxy Group Catalyzed by Indium Tribromide
  50. Reformatsky Reactions Meet Catalysis and Stereoselectivity
  51. Nucleophilic substitution of ferrocenyl alcohols “on water”
  52. Convenient Preparation of Chiral Dipyrrolylmethanes Containing a Chiral Moiety
  53. The application of bis(oxazoline) ligands in the catalytic enantioselective methallylation of aldehydes
  54. A Catalytic Enantioselective Imino‐Reformatsky Reaction
  55. Chiral C2‐Boron‐Bis(oxazolines) in Asymmetric Catalysis – A Theoretical Study of the Catalyzed Enantioselective Reduction of Ketones Promoted by Catecholborane
  56. A Catalytic, Me2Zn‐Mediated, Enantioselective Reformatsky Reaction With Ketones
  57. A Catalytic, Me2Zn‐Mediated, Enantioselective Reformatsky Reaction With Ketones
  58. Highly Enantioselective Addition of Me2Zn to Aldehydes Catalyzed by ClCr(Salen)
  59. Application of Tridentate Bis(oxazoline) Ligands in Catalytic Asymmetric Nozaki–Hiyama Allylation and Crotylation: An Example of High Enantioselection with a Non‐Symmetric Bis(oxazoline) Ligand
  60. Dimethylzinc-Mediated Alkynylation of Imines
  61. First enantioselective one-pot, three-component imino Reformatsky reaction
  62. Dipeptide-Catalyzed Asymmetric Aldol Condensation of Acetone with (N-Alkylated) Isatins
  63. Me2Zn-Mediated Addition of Acetylenes to Aldehydes and Ketones
  64. Highly Enantioselective One‐Pot, Three‐Component Imino‐Reformatsky Reaction
  65. Highly Enantioselective One‐Pot, Three‐Component Imino‐Reformatsky Reaction
  66. Enantioselective Hydrogenation of Imines in Ionic Liquid/Carbon Dioxide Media
  67. Acetylenes in Catalysis: Enantioselective Additions to Carbonyl Groups and Imines and Applications Beyond
  68. HetPHOX: a new class of easily prepared modular chiral ligands
  69. Metal–Salen Schiff base complexes in catalysis: practical aspects
  70. BINOL catalyzed enantioselective addition of titanium phenylacetylide to aromatic ketones
  71. The Application of HETPHOX Ligands to the Asymmetric Intermolecular Heck Reaction
  72. The Application of HETPHOX Ligands to the Asymmetric Intermolecular Heck Reaction of 2,3-Dihydrofuran and 2,2-Disubstituted-2,3-Dihydrofurans
  73. A Cross Metathesis Based Protocol for the Effective Synthesis of Function­alised Allyl Bromides and Chlorides
  74. Kinetic Resolution of Epoxides by a CC Bond‐Forming Reaction: Highly Enantioselective Addition of Indoles to cis, trans, and meso Aromatic Epoxides Catalyzed by [Cr(salen)] Complexes
  75. Kinetic Resolution of Epoxides by a CC Bond‐Forming Reaction: Highly Enantioselective Addition of Indoles to cis, trans, and meso Aromatic Epoxides Catalyzed by [Cr(salen)] Complexes
  76. Effective Modular Iminooxazoline (IMOX) Ligands for Asymmetric Catalysis: [Zn(IMOX)]‐Promoted Enantioselective Reduction of Ketones by Catecholborane
  77. Effective Modular Iminooxazoline (IMOX) Ligands for Asymmetric Catalysis: [Zn(IMOX)]‐Promoted Enantioselective Reduction of Ketones by Catecholborane
  78. Bis(oxazoline)titanium Complexes as Chiral Catalysts for Enantioselective Hydrosilylation of Ketones − A Combined Experimental and Theoretical Investigation
  79. Enantioselective Alkynylation of Ketones Catalyzed by Zn(Salen) Complexes
  80. Photophysical poperties of Schiff-base metal complexes
  81. Iridium-HetPHOX Complexes forthe Catalytic Asymmetric Hydrogenation of Olefins and Imines
  82. A new class of C1-symmetric monosulfoximine ligands for enantioselective hetero Diels–Alder reactions
  83. Di- and Trivalent Dinuclear Samarium Complexes Supported by Pyrrole-Based Tetradentate Schiff Bases
  84. A Convenient Catalytic Procedure for the Addition of Trimethylsilyl Cyanide to Functionalised Ketones, Mediated by InBr3 − Insight into the Reaction Mechanism
  85. InBr3-Catalyzed Friedel−Crafts Addition of Indoles to Chiral Aromatic Epoxides:  A Facile Route to Enantiopure Indolyl Derivatives
  86. Sequential One-Pot InBr3-Catalyzed 1,4- then 1,2-Nucleophilic Addition to Enones
  87. [Cr(Salen)] as a ‘bridge’ between asymmetric catalysis, Lewis acids and redox processes
  88. Chiral Phosphinopyrrolyl-Oxazolines: A New Class of Easily Prepared, Modular P,N-Ligands
  89. Chiral Phosphinopyrrolyl-Oxazolines: A New Class of Easily Prepared, Modular P,N-Ligands
  90. An Effective and Useful Synthesis of Enantiomerically Enriched Arylglycinols
  91. An Effective and Useful Synthesis of Enantiomerically Enriched Arylglycinols
  92. Chemo- and enantioselective catalytic addition of propargyl chloride to aldehydes promoted by [Cr(Salen)] complexes
  93. Indium tribromide: a highly effective catalyst for the addition of trimethylsilyl cyanide to α-hetero-substituted ketones
  94. Cr(Salen)-Catalyzed Addition of 1,3-Dichloropropene to Aromatic Aldehydes. A Simple Access to Optically Active Vinyl Epoxides
  95. Design of boron bis-oxazolinate (B-BOXate) complexes: a new class of stable organometallic catalysts
  96. Enantioselective catalytic addition of allyl organometallic reagents to aldehydes promoted by [Cr(Salen)]: the hidden role played by weak Lewis acids in metallo-Salen promoted reactions
  97. Salen as a Chiral Activator:anti versussyn Switchable Diastereoselection in the Enantioselective Addition of Crotyl Bromide to Aromatic Aldehydes
  98. Salen as a Chiral Activator:anti versussyn Switchable Diastereoselection in the Enantioselective Addition of Crotyl Bromide to Aromatic Aldehydes
  99. The first catalytic enantioselective Nozaki–Hiyama–Kishi reaction
  100. Zinc triflate–bis-oxazoline complexes as chiral catalysts: enantioselective reduction of α-alkoxy-ketones with catecholborane
  101. Synthesis and Characterization of New Enantiopure 7,7′-Disubstituted 2,2′-Dihydroxy-1,1′-binaphthyls: Useful Ligands for the Asymmetric Allylation Reaction of Aldehydes
  102. Die erste katalytische enantioselektive Nozaki-Hiyama-Reaktion
  103. The First Catalytic Enantioselective Nozaki–Hiyama Reaction
  104. The First Catalytic Enantioselective Nozaki-Hiyama Reaction
  105. Diastereoselective addition of higher order cuprates and zinc-copper reagents to imines derived from (S)-1-phenylethylamine
  106. Highly diastereoselective pinacol coupling of aldehydes catalyzed by titanium-Schiff base complexes
  107. A Single Langmuir−Blodgett Monolayer for Gas Separations
  108. Enantio and Diastereoselective Addition of Organometallic Reagents to Aldehydes and Imines
  109. Enantioselective reduction of ketones with triethoxysilane catalyzed by chiral bis-oxazoline titanium complexes
  110. Catalytic asymmetric synthesis of secondary alcohols using chiral cis-1-amino-2-hydroxy-1,2,3,4-tetrahydronaphthalene as chiral ligand
  111. Chiral–achiral ligand synergy: activation of a zirconium–BINOL Lewis acid complex by the addition of 4-tert-butylcalix[4]arene
  112. Enantioselective allylation of aldehydes promoted by chiral zinc bis(oxazoline) complexes
  113. Interaction Modes of Titanium Tetrachloride with the Carbonyl Functionality
  114. Enantioselective addition of Et2Zn to aldehydes promoted by a chiral Schiff base metal complex
  115. Highly diastereoselective addition of silyl enolates to chiral imines derived from (S)-valine methyl ester using lanthanide triflate
  116. (Hydroxyphenyl)oxazoline: a Novel and Remarkably Facile Entry into the Area of Chiral Cationic Alkylzirconium Complexes Which Serve as Polymerization Catalysts
  117. Catalytic allylation of imines promoted by lanthanide triflates
  118. Titanium and zirconium ferrocene-substituted enolates and their reaction products with benzaldehyde and acetophenone: structural and kinetic studies of the aldol condensation pathway
  119. Oxazoline Early Transition Metal Complexes: Functionalizable Achiral Titanium(IV), Titanium(III), Zirconium(IV), Vanadium(III), and Chiral Zirconium(IV) Bis(oxazoline) Complexes
  120. .alpha.-Sulfonyl Carbanion-Transition-Metal Bonds. Alkali-Metal .alpha.-Sulfonyl Carbanions and Their Reactivity with Metal Complexes
  121. Bis(hydroxyphenyloxazolinato)-titanium(IV) and -zirconium(IV) triflates as novel transition metal-based Lewis acids
  122. (.eta.6-Acetophenone)Cr(CO)3 Enolates Complexed to Bis(cyclopentadienyl)titanium(IV) and -zirconium(IV)
  123. Cyclodivanadazene Alkyl and Aryl Complexes
  124. Mechanism of the Mukaiyama Aldol Reaction: The First Solid-State Characterization of a Trichlorotitanium Aldolate
  125. .beta.-Keto Amino Enolates Binding to Transition Metals: Synthesis and Structure of the Ion-Pair Form and Its Mono- and Bidentate Coordination to Zirconium and Nickel
  126. A Novel Homogeneous Lewis Acid Catalyst: Bistriflatedibenzotetramethyltetraazaannulenezirconium(IV) in a Cationic Form
  127. Titanium ester homoenolates: a structural and synthetic study
  128. Nonorganometallic pathway of the Passerini reaction assisted by titanium tetrachloride
  129. Stereoselective synthesis of .beta.-lactams by condensation of titanium enolates of 2-pyridyl thioesters with imines
  130. Diastereoselective cyclocondensation of electron-rich dienes with chiral thio-substituted aldehydes
  131. Highly diastereoselective synthesis of β-lactams by addition of titanium enolates of 2-pyridyl thioesters to chiral imines
  132. Stereocontrol in the Mukaiyama aldol addition to chiral .alpha.- and .beta.-thio-substituted aldehydes
  133. Mild and convenient one-pot synthesis of β-lactams by condensation of titanium enolates of 2-pyridylthioesters with imines.
  134. Diastereoselective aldol condensation of directly generated titanium enolates of activated esters.
  135. Total synthesis of (±) pseudophrynamine A
  136. Diastereoselective addition of a silylketene acetal to chiral α-thioaldehydes.
  137. Chelation-controlled enantioselective synthesis of key intermediates for the preparation of carbapenem antibiotics PS-5 and 1.beta.-methyl-PS-5
  138. Chelation controlled aldol additions of the enolsilane derived from tert-butyl thioacetate : a stereosetective approach to 1β-methylthienamycin