All Stories

  1. Optimizing Intracellular Transport of Antimicrobial Metallohelices Delivers Selective Nanomolar Potency in E. coli
  2. Exploring RNA G-quadruplex in the rabies virus genome and its potential against RABV infection
  3. Membrane lipid composition directs the cellular selectivity of antimicrobial metallohelices
  4. Biodiesel Promotes Iron-Catalyzed Oxidation of Engine Lubricating Oil
  5. Enantioselective Degrader for Elimination of Extracellular Aggregation-Prone Proteins hIAPP Associated with Type 2 Diabetes
  6. In vivo visualization of enantioselective targeting of amyloid and improvement of cognitive function by clickable chiral metallohelices
  7. Triplex metallohelices have enantiomer-dependent mechanisms of action in colon cancer cells
  8. Metallohelix vectors for efficient gene delivery via cationic DNA nanoparticles
  9. FeII Metallohelices Stabilize DNA G‐Quadruplexes and Downregulate the Expression of G‐Quadruplex‐Regulated Oncogenes
  10. Metallohelices emulate the properties of short cationic α-helical peptides
  11. Cationic FeII Triplex‐Forming Metallohelices as DNA Bulge Binders
  12. Stabilization of human telomeric RNA G-quadruplex by the water-compatible optically pure and biologically-active metallohelices
  13. Neutrophil-Membrane-Directed Bioorthogonal Synthesis of Inflammation-Targeting Chiral Drugs
  14. Glycoconjugated Metallohelices have Improved Nuclear Delivery and Suppress Tumour Growth In Vivo
  15. Shape‐Selective Targeting on RNA Bulges by Peptidomimetic Metallohelices
  16. Optically Pure Metallohelices That Accumulate in Cell Nuclei, Condense/Aggregate DNA, and Inhibit Activities of DNA Processing Enzymes
  17. Triazole-based, optically-pure metallosupramolecules; highly potent and selective anticancer compounds
  18. End-functional polyolefins for block copolymer synthesis
  19. Molecules that reduce cancer cell metastasis and destroy cancer stem cells
  20. Metallohelices that kill Gram-negative pathogens using intracellular antimicrobial peptide pathways
  21. Self-triggered click reaction in an Alzheimer's disease model:in situbifunctional drug synthesis catalyzed by neurotoxic copper accumulated in amyloid-β plaques
  22. Mirror-Image Dependence: Targeting Enantiomeric G-Quadruplex DNA Using Triplex Metallohelices
  23. Polyolefin–Polar Block Copolymers from Versatile New Macromonomers
  24. Stereochemistry and amyloid inhibition: Asymmetric triplex metallohelices enantioselectively bind to Aβ peptide
  25. Antifreeze Protein Mimetic Metallohelices with Potent Ice Recrystallization Inhibition Activity
  26. Chiral metallohelices enantioselectively target hybrid human telomeric G-quadruplex DNA
  27. Antimicrobial Metallodrugs
  28. Anticancer metallohelices: nanomolar potency and high selectivity
  29. Iron and Manganese Complexes of 2-Carbonyl Pyrrolyls: Scorpionate Sandwich Anions and Extended Structures
  30. Shape-selective recognition of DNA abasic sites by metallohelices: inhibition of human AP endonuclease 1
  31. All about the arrow
  32. Recognition of DNA/RNA bulges by antimicrobial and antitumor metallohelices
  33. Metallohelices: potential mimetics of α-helical peptides in cancer treatment?
  34. Single Molecule Microscopy and Properties of Olympicene: Olympic Rings at the molecular level
  35. Chiral Metallohelical Complexes Enantioselectively Target Amyloid β for Treating Alzheimer’s Disease
  36. Asymmetric triplex metallohelices with high and selective activity against cancer cells
  37. Metallohelices with activity against cisplatin-resistant cancer cells; does the mechanism involve DNA binding?
  38. Optically pure heterobimetallic helicates from self-assembly and click strategies
  39. Considerations of Noise and Measurement Reproducibility of Circular Dichroism Measurements Using Na[CoIII(EDDS)]
  40. Jahn–Teller effects on π-stacking and stereoselectivity in the phenylethaniminopyridine tris-chelates Cu(NN′)32+
  41. Optically pure, water-stable metallo-helical ‘flexicate’ assemblies with antibiotic activity
  42. Structural and Electronic Modulation of Magnetic Properties in a Family of Chiral Iron Coordination Polymers
  43. Chiral Semiconductor Phases: The Optically Pure D3[MIII(S,S-EDDS)]2 (D = TTF, TSF) Family
  44. Zirconium-Catalyzed Polymerization of a Styrene: Catalyst Reactivation Mechanisms Using Alkenes and Dihydrogen
  45. Isomeric Fe(ii) MOFs: from a diamond-framework spin-crossover material to a 2D hard magnet
  46. Dalton Transactions after 40 volumes
  47. Approaches to the synthesis of optically pure helicates
  48. Explanation of an unusually high selectivity in synthesis of metal-ligand complexes
  49. d0 organometallics in catalysis
  50. Comments on “Synthesis and characterisation of enantiopure copper(ii) complexes with chiral bidentate ligands”
  51. TTF salts of optically pure cobalt pyridine amidates; detection of soluble assemblies with stoichiometry corresponding to the solid state
  52. Mechanism of Catalytic Cyclohydroamination by Zirconium Salicyloxazoline Complexes
  53. fac-Specific syntheses of homochiral [Fe(NN′)3]2+ complexes (NN′ = pyridine keto-hydrazone); origins of the stereoselectivity
  54. Organic-soluble optically pure anionic metal complexes PPh4[MIII(S,S-EDDS)]·2H2O (M = Fe, Co, Cr)
  55. Chirality and diastereoselection in the μ-oxo diiron complexes L2Fe–O–FeL2 (L = bidentate salicylaldiminato)
  56. Dalton Discussion 12: Catalytic C–H and C–X bond activation (DD12)
  57. Substituent effects in ethene/styrene copolymerization: Dormant state destabilization?
  58. Self-assembling optically pure Fe(A–B)3 chelates
  59. A new reference material for UV-visible circular dichroism spectroscopy
  60. Single Diastereomer Half-Sandwich Salicyloxazoline Complexes of Titanium and Zirconium
  61. Awakening a dormant catalyst: salicylaldimine systems for ethene/tert-butylstyrene copolymerization
  62. Constrained geometry aminooxazolinate ligands giving chiral zirconium guanidinates; catalytic cyclohydroamination
  63. Catalytic alkene cyclohydroamination via an imido mechanism
  64. Chiral Alkoxide-Functionalized Guanidinates from Ring-Opening Rearrangement of Aminooxazolinate Complexes
  65. Half-Sandwich Group 4 Salicyloxazoline Catalysts
  66. Expression of chirality in salicyloxazolinate complexes of zirconium
  67. Group 4 catalysts for ethene polymerization containing tetradentate salicylaldiminato ligands
  68. Diazaallyls of group 4 metals based on trans-1,2-diaminocyclohexane
  69. Group 4 salicyloxazolines are potent polymerization catalysts
  70. Chiral Complexes of a New Diazaallyl Ligand:  Group 4 Aminooxazolinates
  71. Chiral biarylamido/anisole complexes of yttrium in enantioselective aminoalkene hydaroamination/cyclisation
  72. Zirconium catalysed enantioselective hydroamination/cyclisationElectronic Supplementary Information (ESI) available: experimental details and characterising data for complexes and substrates, catalytic protocol, determination of ee, crystal data for [Z...
  73. Chiral metal architectures in aminopyridinato complexes of zirconium
  74. Aminooxazolinate; a chiral amidinate analogue
  75. Arylaminopyridinato complexes of zirconiumElectronic supplementary information (ESI) available: Rotatable 3-D crystal structure diagrams and NMR spectra. See http://www.rsc.org/suppdata/dt/b4/b407008a/
  76. Biaryl-bridged Schiff base complexes of zirconium alkyls: synthesis structure and stability
  77. Biaryl amine ligands for lanthanide catalysed enantioselective hydroamination/cyclisation of aminoalkenes
  78. Chiral Titanium Bis(aminopyridinates) Based on a Biaryl Backbone
  79. Predetermination of chirality at octahedral centres with tetradentate ligands: prospects for enantioselective catalysis
  80. Non-planar manganese Schiff-base complexes; synthesis and molecular structures
  81. Chiral-at-metal organolanthanides: enantioselective aminoalkene hydroamination/cyclisation with non-cyclopentadienylsElectronic supplementary information (ESI) available: complete experimental procedures and characterising data for all ligands and comp...
  82. Chiral Biarylamido Complexes of Zirconium
  83. Enantioselective Aziridination Using Copper Complexes of Biaryl Schiff Bases
  84. Reactivity of a triamidoamine complex of trivalent uranium
  85. Problems and solutions for alkene polymerisation catalysts incorporating Schiff-bases; migratory insertion and radical mechanisms of catalyst deactivationElectronic supplementary information (ESI) available: experimental details for the synthesis of al...
  86. Efficient predetermination of chirality-at-zirconium
  87. New Approach for Measuring Lateral Diffusion in Langmuir Monolayers by Scanning Electrochemical Microscopy (SECM):  Theory and Application
  88. Back bonding without σ-bonding: a unique π-complex of dinitrogen with uranium
  89. Catalyst structure and the enantioselective cyclopropanation of alkenes by copper complexes of biaryldiimines: the importance of ligand acceleration
  90. Mechanism of alkene aziridination in the [(biaryldiimine)CuI] catalyst system; precise substrate orientation via two-centre binding
  91. Bidentate carbenoid ester coordination in ruthenium(ii) Schiff-base complexes leading to excellent levels of diastereo- and enantioselectivity in catalytic alkene cyclopropanation
  92. Complexes of zirconium with aryl substituted triamidoamines: molecular structures of amide and alkyl derivatives
  93. Structural Origins of a Dramatic Variation in Catalyst Efficiency in Enantioselective Alkene Aziridination:  Implications for Design of Ligands Based on Chiral Biaryldiamines
  94. Control of metal/ligand stoichiometry and structure in aminopyridinato complexes of zirconium: N-alkyl is better than trimethylsilyl
  95. Chiral N2O2 Schiff-base complexes of titanium with a biaryl backbone: highly diastereoselective migratory insertion of alkyl at imine
  96. Stereoselective catalytic tishchenko reduction of β-hydroxyketones using scandium triflate
  97. Synthesis of a highly strained uranacycle: molecular structures of organometallic products arising from reduction, oxidation and protonolysis
  98. Stabilization of Cerium(IV) in the Presence of an Iodide Ligand:  Remarkable Effects of Lewis Acidity on Valence State
  99. Triamidoamine Chemistry of Zirconium
  100. Complexes of Triamidoamines with the Early Actinides. Synthetic Routes to Monomeric Compounds of Tetravalent Uranium and Thorium Containing Halide and Amide Ligands
  101. Non-planar co-ordination of C2-symmetric biaryl-bridged Schiff-base ligands: well expressed chiral ligand environments for zirconium †
  102. Structure and reactions of a metallacyclic complex containing a remarkably long uranium–carbon bond
  103. Schiff-base chemistry of niobium: unexpected products of radical elimination and diastereoselective addition
  104. Synthesis and Molecular Structure of the Lithiated Triamidoamine [Li3{N(CH2CH2SiButMe2)3}(THF)n]
  105. Triamidoamine complexes of the actinides; from mixed-valence bimetallics to dinitrogen activation
  106. Complex of Dinitrogen with Trivalent Uranium
  107. Evidence for actinide metal to ligand π backbonding. Density functional investigations of the electronic structure of [{(NH2)3(NH3)U}2(μ2-η2:η2-N2)]
  108. Triamidoamine complexes of scandium, yttrium and the lanthanides
  109. Alkoxide and Aryloxide Derivatives of a (Triamidoamine)uranium Complex
  110. Bis(η-heteroarene) titanium complexes derived from 2,4,6-tri-tert-butylpyridine and 2,4,6-tri-tert-butylphosphorin: Conformational preference in solution and redox activity
  111. A mixed-valence uranium(III/IV) bimetallic; structure, magnetism and reactivity
  112. C 2-symmetric Schiff-base complexes of zirconium; structural analogues of the ansa-metallocenes
  113. Synthesis, structure and electrochemistry of the first fulvalene derivative of an actinide
  114. Exploring the auxiliary co-ordination sphere of tripodal amino(triamido) actinide complexes
  115. Synthesis, structure and electrochemistry of a paramagnetic (1,4-diazabutadiene)thorium complex
  116. [(C3tBu3)V(CO)4]: Partial Insertion of Vanadium into the Cyclopropenyl Ring
  117. Synthesis of Tris(tetramethylcyclopentadienyl) Derivatives of the Actinide Metals: Molecular Structure of [UCl(.eta.-C5Me4H)3]
  118. Gas-Phase Electron Diffraction Study of the Molecular Structure of (.eta.-Cycloheptatrienyl)(.eta.-cyclopentadienyl)niobium, Nb(.eta.-C7H7)(.eta.-C5H5)
  119. Synthesis of tripodal amido complexes of the early actinides; molecular structure of {N[CH2CH2N(SiMe3)3UCl}2
  120. ansa-Metallocene derivatives. 28. Homo- and heterobimetallic bis(fulvalene) complexes from bis(cyclopentadienyl)- and bis(indenyl)-substituted ferrocenes
  121. X-ray structure of [Mn(η-C6H5Me)2]+I−
  122. Synthesis and electronic and molecular structures of .eta.-cycloheptatrienyl .eta.-cyclopentadienyl derivatives of vanadium, niobium, and tantalum: photoelectron spectroscopic, electrochemical, and x-ray crystallographic study
  123. Synthesis and electronic structure of permethylindenyl complexes of iron and cobalt
  124. Synthesis and molecular structures of the sandwich anion [K(18-crown-6)][Nb(η-C7H7)(η-C5H5)] and cation [Nb(η-C7H7)(η-C5H4Me)(thf)]PF6
  125. Cycloheptatri-ene and -enyl derivatives of niobium
  126. New cycloheptatriene and cycloheptatrienyl derivatives of niobium