All Stories

  1. Regulation of Tumor-Immune Cell Communications via Enantioselectively Targeting SLC G-Quadruplexes
  2. Optimizing Intracellular Transport of Antimicrobial Metallohelices Delivers Selective Nanomolar Potency in E. coli
  3. Exploring RNA G-quadruplex in the rabies virus genome and its potential against RABV infection
  4. Membrane lipid composition directs the cellular selectivity of antimicrobial metallohelices
  5. Biodiesel Promotes Iron-Catalyzed Oxidation of Engine Lubricating Oil
  6. Enantioselective Degrader for Elimination of Extracellular Aggregation-Prone Proteins hIAPP Associated with Type 2 Diabetes
  7. In vivo visualization of enantioselective targeting of amyloid and improvement of cognitive function by clickable chiral metallohelices
  8. Triplex metallohelices have enantiomer-dependent mechanisms of action in colon cancer cells
  9. Metallohelix vectors for efficient gene delivery via cationic DNA nanoparticles
  10. FeII Metallohelices Stabilize DNA G‐Quadruplexes and Downregulate the Expression of G‐Quadruplex‐Regulated Oncogenes
  11. Metallohelices emulate the properties of short cationic α-helical peptides
  12. Cationic FeII Triplex‐Forming Metallohelices as DNA Bulge Binders
  13. Stabilization of human telomeric RNA G-quadruplex by the water-compatible optically pure and biologically-active metallohelices
  14. Neutrophil-Membrane-Directed Bioorthogonal Synthesis of Inflammation-Targeting Chiral Drugs
  15. Glycoconjugated Metallohelices have Improved Nuclear Delivery and Suppress Tumour Growth In Vivo
  16. Shape‐Selective Targeting on RNA Bulges by Peptidomimetic Metallohelices
  17. Optically Pure Metallohelices That Accumulate in Cell Nuclei, Condense/Aggregate DNA, and Inhibit Activities of DNA Processing Enzymes
  18. Triazole-based, optically-pure metallosupramolecules; highly potent and selective anticancer compounds
  19. End-functional polyolefins for block copolymer synthesis
  20. Molecules that reduce cancer cell metastasis and destroy cancer stem cells
  21. Metallohelices that kill Gram-negative pathogens using intracellular antimicrobial peptide pathways
  22. Self-triggered click reaction in an Alzheimer's disease model:in situbifunctional drug synthesis catalyzed by neurotoxic copper accumulated in amyloid-β plaques
  23. Mirror-Image Dependence: Targeting Enantiomeric G-Quadruplex DNA Using Triplex Metallohelices
  24. Polyolefin–Polar Block Copolymers from Versatile New Macromonomers
  25. Stereochemistry and amyloid inhibition: Asymmetric triplex metallohelices enantioselectively bind to Aβ peptide
  26. Antifreeze Protein Mimetic Metallohelices with Potent Ice Recrystallization Inhibition Activity
  27. Chiral metallohelices enantioselectively target hybrid human telomeric G-quadruplex DNA
  28. Antimicrobial Metallodrugs
  29. Anticancer metallohelices: nanomolar potency and high selectivity
  30. Iron and Manganese Complexes of 2-Carbonyl Pyrrolyls: Scorpionate Sandwich Anions and Extended Structures
  31. Shape-selective recognition of DNA abasic sites by metallohelices: inhibition of human AP endonuclease 1
  32. All about the arrow
  33. Recognition of DNA/RNA bulges by antimicrobial and antitumor metallohelices
  34. Metallohelices: potential mimetics of α-helical peptides in cancer treatment?
  35. Single Molecule Microscopy and Properties of Olympicene: Olympic Rings at the molecular level
  36. Chiral Metallohelical Complexes Enantioselectively Target Amyloid β for Treating Alzheimer’s Disease
  37. Asymmetric triplex metallohelices with high and selective activity against cancer cells
  38. Metallohelices with activity against cisplatin-resistant cancer cells; does the mechanism involve DNA binding?
  39. Optically pure heterobimetallic helicates from self-assembly and click strategies
  40. Considerations of Noise and Measurement Reproducibility of Circular Dichroism Measurements Using Na[CoIII(EDDS)]
  41. Jahn–Teller effects on π-stacking and stereoselectivity in the phenylethaniminopyridine tris-chelates Cu(NN′)32+
  42. Optically pure, water-stable metallo-helical ‘flexicate’ assemblies with antibiotic activity
  43. Structural and Electronic Modulation of Magnetic Properties in a Family of Chiral Iron Coordination Polymers
  44. Chiral Semiconductor Phases: The Optically Pure D3[MIII(S,S-EDDS)]2 (D = TTF, TSF) Family
  45. Zirconium-Catalyzed Polymerization of a Styrene: Catalyst Reactivation Mechanisms Using Alkenes and Dihydrogen
  46. Isomeric Fe(ii) MOFs: from a diamond-framework spin-crossover material to a 2D hard magnet
  47. Dalton Transactions after 40 volumes
  48. Approaches to the synthesis of optically pure helicates
  49. Explanation of an unusually high selectivity in synthesis of metal-ligand complexes
  50. d0 organometallics in catalysis
  51. Comments on “Synthesis and characterisation of enantiopure copper(ii) complexes with chiral bidentate ligands”
  52. TTF salts of optically pure cobalt pyridine amidates; detection of soluble assemblies with stoichiometry corresponding to the solid state
  53. Mechanism of Catalytic Cyclohydroamination by Zirconium Salicyloxazoline Complexes
  54. fac-Specific syntheses of homochiral [Fe(NN′)3]2+ complexes (NN′ = pyridine keto-hydrazone); origins of the stereoselectivity
  55. Organic-soluble optically pure anionic metal complexes PPh4[MIII(S,S-EDDS)]·2H2O (M = Fe, Co, Cr)
  56. Chirality and diastereoselection in the μ-oxo diiron complexes L2Fe–O–FeL2 (L = bidentate salicylaldiminato)
  57. Dalton Discussion 12: Catalytic C–H and C–X bond activation (DD12)
  58. Substituent effects in ethene/styrene copolymerization: Dormant state destabilization?
  59. Self-assembling optically pure Fe(A–B)3 chelates
  60. A new reference material for UV-visible circular dichroism spectroscopy
  61. Single Diastereomer Half-Sandwich Salicyloxazoline Complexes of Titanium and Zirconium
  62. Awakening a dormant catalyst: salicylaldimine systems for ethene/tert-butylstyrene copolymerization
  63. Constrained geometry aminooxazolinate ligands giving chiral zirconium guanidinates; catalytic cyclohydroamination
  64. Catalytic alkene cyclohydroamination via an imido mechanism
  65. Chiral Alkoxide-Functionalized Guanidinates from Ring-Opening Rearrangement of Aminooxazolinate Complexes
  66. Half-Sandwich Group 4 Salicyloxazoline Catalysts
  67. Expression of chirality in salicyloxazolinate complexes of zirconium
  68. Group 4 catalysts for ethene polymerization containing tetradentate salicylaldiminato ligands
  69. Diazaallyls of group 4 metals based on trans-1,2-diaminocyclohexane
  70. Group 4 salicyloxazolines are potent polymerization catalysts
  71. Chiral Complexes of a New Diazaallyl Ligand:  Group 4 Aminooxazolinates
  72. Chiral biarylamido/anisole complexes of yttrium in enantioselective aminoalkene hydaroamination/cyclisation
  73. Zirconium catalysed enantioselective hydroamination/cyclisationElectronic Supplementary Information (ESI) available: experimental details and characterising data for complexes and substrates, catalytic protocol, determination of ee, crystal data for [Z...
  74. Chiral metal architectures in aminopyridinato complexes of zirconium
  75. Aminooxazolinate; a chiral amidinate analogue
  76. Arylaminopyridinato complexes of zirconiumElectronic supplementary information (ESI) available: Rotatable 3-D crystal structure diagrams and NMR spectra. See http://www.rsc.org/suppdata/dt/b4/b407008a/
  77. Biaryl-bridged Schiff base complexes of zirconium alkyls: synthesis structure and stability
  78. Biaryl amine ligands for lanthanide catalysed enantioselective hydroamination/cyclisation of aminoalkenes
  79. Chiral Titanium Bis(aminopyridinates) Based on a Biaryl Backbone
  80. Predetermination of chirality at octahedral centres with tetradentate ligands: prospects for enantioselective catalysis
  81. Non-planar manganese Schiff-base complexes; synthesis and molecular structures
  82. Chiral-at-metal organolanthanides: enantioselective aminoalkene hydroamination/cyclisation with non-cyclopentadienylsElectronic supplementary information (ESI) available: complete experimental procedures and characterising data for all ligands and comp...
  83. Chiral Biarylamido Complexes of Zirconium
  84. Enantioselective Aziridination Using Copper Complexes of Biaryl Schiff Bases
  85. Reactivity of a triamidoamine complex of trivalent uranium
  86. Problems and solutions for alkene polymerisation catalysts incorporating Schiff-bases; migratory insertion and radical mechanisms of catalyst deactivationElectronic supplementary information (ESI) available: experimental details for the synthesis of al...
  87. Efficient predetermination of chirality-at-zirconium
  88. New Approach for Measuring Lateral Diffusion in Langmuir Monolayers by Scanning Electrochemical Microscopy (SECM):  Theory and Application
  89. Back bonding without σ-bonding: a unique π-complex of dinitrogen with uranium
  90. Catalyst structure and the enantioselective cyclopropanation of alkenes by copper complexes of biaryldiimines: the importance of ligand acceleration
  91. Mechanism of alkene aziridination in the [(biaryldiimine)CuI] catalyst system; precise substrate orientation via two-centre binding
  92. Bidentate carbenoid ester coordination in ruthenium(ii) Schiff-base complexes leading to excellent levels of diastereo- and enantioselectivity in catalytic alkene cyclopropanation
  93. Complexes of zirconium with aryl substituted triamidoamines: molecular structures of amide and alkyl derivatives
  94. Structural Origins of a Dramatic Variation in Catalyst Efficiency in Enantioselective Alkene Aziridination:  Implications for Design of Ligands Based on Chiral Biaryldiamines
  95. Control of metal/ligand stoichiometry and structure in aminopyridinato complexes of zirconium: N-alkyl is better than trimethylsilyl
  96. Chiral N2O2 Schiff-base complexes of titanium with a biaryl backbone: highly diastereoselective migratory insertion of alkyl at imine
  97. Stereoselective catalytic tishchenko reduction of β-hydroxyketones using scandium triflate
  98. Synthesis of a highly strained uranacycle: molecular structures of organometallic products arising from reduction, oxidation and protonolysis
  99. Stabilization of Cerium(IV) in the Presence of an Iodide Ligand:  Remarkable Effects of Lewis Acidity on Valence State
  100. Triamidoamine Chemistry of Zirconium
  101. Complexes of Triamidoamines with the Early Actinides. Synthetic Routes to Monomeric Compounds of Tetravalent Uranium and Thorium Containing Halide and Amide Ligands
  102. Non-planar co-ordination of C2-symmetric biaryl-bridged Schiff-base ligands: well expressed chiral ligand environments for zirconium †
  103. Structure and reactions of a metallacyclic complex containing a remarkably long uranium–carbon bond
  104. Schiff-base chemistry of niobium: unexpected products of radical elimination and diastereoselective addition
  105. Synthesis and Molecular Structure of the Lithiated Triamidoamine [Li3{N(CH2CH2SiButMe2)3}(THF)n]
  106. Triamidoamine complexes of the actinides; from mixed-valence bimetallics to dinitrogen activation
  107. Complex of Dinitrogen with Trivalent Uranium
  108. Evidence for actinide metal to ligand π backbonding. Density functional investigations of the electronic structure of [{(NH2)3(NH3)U}2(μ2-η2:η2-N2)]
  109. Triamidoamine complexes of scandium, yttrium and the lanthanides
  110. Alkoxide and Aryloxide Derivatives of a (Triamidoamine)uranium Complex
  111. Bis(η-heteroarene) titanium complexes derived from 2,4,6-tri-tert-butylpyridine and 2,4,6-tri-tert-butylphosphorin: Conformational preference in solution and redox activity
  112. A mixed-valence uranium(III/IV) bimetallic; structure, magnetism and reactivity
  113. C 2-symmetric Schiff-base complexes of zirconium; structural analogues of the ansa-metallocenes
  114. Synthesis, structure and electrochemistry of the first fulvalene derivative of an actinide
  115. Exploring the auxiliary co-ordination sphere of tripodal amino(triamido) actinide complexes
  116. Synthesis, structure and electrochemistry of a paramagnetic (1,4-diazabutadiene)thorium complex
  117. [(C3tBu3)V(CO)4]: Partial Insertion of Vanadium into the Cyclopropenyl Ring
  118. Synthesis of Tris(tetramethylcyclopentadienyl) Derivatives of the Actinide Metals: Molecular Structure of [UCl(.eta.-C5Me4H)3]
  119. Gas-Phase Electron Diffraction Study of the Molecular Structure of (.eta.-Cycloheptatrienyl)(.eta.-cyclopentadienyl)niobium, Nb(.eta.-C7H7)(.eta.-C5H5)
  120. Synthesis of tripodal amido complexes of the early actinides; molecular structure of {N[CH2CH2N(SiMe3)3UCl}2
  121. ansa-Metallocene derivatives. 28. Homo- and heterobimetallic bis(fulvalene) complexes from bis(cyclopentadienyl)- and bis(indenyl)-substituted ferrocenes
  122. X-ray structure of [Mn(η-C6H5Me)2]+I−
  123. Synthesis and electronic and molecular structures of .eta.-cycloheptatrienyl .eta.-cyclopentadienyl derivatives of vanadium, niobium, and tantalum: photoelectron spectroscopic, electrochemical, and x-ray crystallographic study
  124. Synthesis and electronic structure of permethylindenyl complexes of iron and cobalt
  125. Synthesis and molecular structures of the sandwich anion [K(18-crown-6)][Nb(η-C7H7)(η-C5H5)] and cation [Nb(η-C7H7)(η-C5H4Me)(thf)]PF6
  126. Cycloheptatri-ene and -enyl derivatives of niobium
  127. New cycloheptatriene and cycloheptatrienyl derivatives of niobium