All Stories

  1. Progress in Photocatalysis for Organic Chemistry

    Article • The Journal of Organic Chemistry, May 2023, American Chemical Society (ACS)

    Professor Munetaka Akita

  2. Molecule‐Electrode Interfaces Controlled by Bulky Long‐Legged Ligands in Organometallic Molecular Wires

    Article • Advanced Materials Interfaces, March 2023, Wiley

    Professor Munetaka Akita

  3. Acene Size‐Dependent Transition of The Radical Centers From the Metal to The Acene Parts In Monocationic Dinuclear (Diethynylacene)diyl Complexes

    Article • Chemistry - A European Journal, August 2022, Wiley

    Professor Munetaka Akita

  4. Estimation of Electron Distribution over Dinuclear Organometallic Molecular Wires by “IR Tag” Analysis of Ancillary Acyl-Cp Ligands

    Article • ACS Organic & Inorganic Au, March 2022, American Chemical Society (ACS)

    Professor Munetaka Akita

  5. Sustainable C–H functionalization under ball-milling, microwave-irradiation and aqueous media

    Article • Green Chemistry, January 2022, Royal Society of Chemistry

    Professor Munetaka Akita

  6. Organometallic Molecular Wires with Thioacetylene Backbones, trans ‐{RS‐(C≡C) n } 2 Ru(phosphine) 4 : High Conductance through N...

    Article • Chemistry - A European Journal, May 2021, Wiley

    Professor Munetaka Akita

  7. Dimesitylborylethynylated Arenes: Unique Electronic and Photophysical Properties Caused by Ethynediyl (C≡C) Spacers

    Article • Chemistry - A European Journal, January 2021, Wiley

    Professor Munetaka Akita

  8. Dimesitylborylethynylated Arenes: Unique Electronic and Photophysical Properties Caused by Ethynediyl (C≡C) Spacers

    Article • Chemistry - A European Journal, January 2021, Wiley

    Professor Munetaka Akita

  9. Single-molecule junctions of multinuclear organometallic wires: long-range carrier transport brought about by metal–metal interaction

    Article • Chemical Science, January 2021, Royal Society of Chemistry

    Professor Munetaka Akita

  10. Simple generation of various α-monofluoroalkyl radicals by organic photoredox catalysis: modular synthesis of β-monofluoroketones

    Article • Chemical Communications, January 2021, Royal Society of Chemistry

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  11. Control of dominant conduction orbitals by peripheral substituents in paddle-wheel diruthenium alkynyl molecular junctions

    Article • Chemical Science, January 2021, Royal Society of Chemistry

    Professor Munetaka Akita

  12. Transition Metal-Free Supramolecular Photoredox Catalysis in Water: A Phenoxazine Photocatalyst Encapsulated in V-Shaped Aromatic Amphiphiles

    Article • ACS Catalysis, November 2020, American Chemical Society (ACS)

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  13. Laser Flash Photolysis Studies on Radical Monofluoromethylation by (Diarylamino)naphthalene Photoredox Catalysis: Long Lifetime of the Excited State is Not Always a Requisite

    Article • The Journal of Organic Chemistry, October 2020, American Chemical Society (ACS)

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  14. Single-Molecule Junction of a Cationic Rh(III) Polyyne Molecular Wire

    Article • Inorganic Chemistry, August 2020, American Chemical Society (ACS)

    Professor Munetaka Akita

  15. Anisotropic Contraction of a Polyaromatic Capsule and Its Cavity-Induced Compression Effect

    Article • Journal of the American Chemical Society, May 2020, American Chemical Society (ACS)

    Professor Munetaka Akita

  16. Fluoroalkanesulfinate Salts as Dual Fluoroalkyl and SO2 Sources: Atom-Economical Fluoroalkyl-Sulfonylation of Alkenes and Alkynes by Photoredox Catalysis

    Article • Organic Letters, March 2020, American Chemical Society (ACS)

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  17. Energy transfer-driven regioselective synthesis of functionalized phenanthridines by visible-light Ir photocatalysis

    Article • Organic Chemistry Frontiers, January 2020, Royal Society of Chemistry

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  18. An aromatic micelle with bent pentacene-based panels: encapsulation of perylene bisimide dyes and graphene nanosheets

    Article • Chemical Science, January 2020, Royal Society of Chemistry

    Professor Munetaka Akita

  19. Photoluminescent properties and molecular structures of dinuclear gold(i) complexes with bridged diphosphine ligands: near-unity phosphorescence from 3XMMCT/3MC

    Article • Dalton Transactions, January 2020, Royal Society of Chemistry

    Professor Munetaka Akita

  20. A Redox-Active Heterocyclic Capsule: Radical Generation, Oxygenation, and Guest Uptake/Release

    Article • Journal of the American Chemical Society, July 2019, American Chemical Society (ACS)

    Professor Munetaka Akita

  21. Keto-Difluoromethylation of Aromatic Alkenes by Photoredox Catalysis: Step-Economical Synthesis of α-CF2H-Substituted Ketones in Flow

    Article • ACS Catalysis, June 2019, American Chemical Society (ACS)

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  22. Visible-Light-Triggered Monofluoromethylation of Alkenes by Strongly Reducing 1,4-Bis(diphenylamino)naphthalene Photoredox Catalysis

    Article • ACS Catalysis, April 2019, American Chemical Society (ACS)

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  23. A polyaromatic receptor with high androgen affinity

    Article • Science Advances, April 2019, American Association for the Advancement of Science

    Professor Munetaka Akita

  24. Dinuclear ruthenium acetylide complexes with diethynylated anthrahydroquinone and anthraquinone frameworks: a multi-stimuli-responsive organometallic switch

    Article • Dalton Transactions, January 2019, Royal Society of Chemistry

    Professor Munetaka Akita

  25. Luminescence color alteration induced by trapped solvent molecules in crystals of tetrahedral gold(i) complexes: near-unity luminescence mixed with thermally activated delayed fluorescence and phosphorescence

    Article • Dalton Transactions, January 2019, Royal Society of Chemistry

    Professor Munetaka Akita

  26. Recent progress in photochemical radical di- and mono-fluoromethylation

    Article • Organic & Biomolecular Chemistry, January 2019, Royal Society of Chemistry

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  27. 18 Photocatalytic Introduction of Fluorinated Groups

    Article • January 2019, Thieme Publishing Group

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  28. Strongly Reducing (Diarylamino)anthracene Catalyst for Metal-Free Visible-Light Photocatalytic Fluoroalkylation

    Article • ACS Catalysis, September 2018, American Chemical Society (ACS)

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  29. “Doping” of Polyyne with an Organometallic Fragment Leads to Highly Conductive Metallapolyyne Molecular Wire

    Article • Journal of the American Chemical Society, July 2018, American Chemical Society (ACS)

    Professor Munetaka Akita

  30. Nonradical Light-Controlled Polymerization of Styrene and Vinyl Ethers Catalyzed by an Iridium–Palladium Photocatalyst

    Article • Organometallics, January 2018, American Chemical Society (ACS)

    Professor Munetaka Akita

  31. Encapsulation-induced emission enhancement (EIEE) of Eu(iii)-complexes by aromatic micelles in water

    Article • Chemical Communications, January 2018, Royal Society of Chemistry

    Professor Munetaka Akita

  32. Photoredox radical C–H oxygenation of aromatics with aroyloxylutidinium salts

    Article • Organic Chemistry Frontiers, January 2018, Royal Society of Chemistry

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  33. Near-unity thermally activated delayed fluorescence efficiency in three- and four-coordinate Au(i) complexes with diphosphine ligands

    Article • Dalton Transactions, January 2018, Royal Society of Chemistry

    Professor Munetaka Akita

  34. Substituent Effect of the Bridging Ligand in the Trinuclear Ru Complexes on Photocatalytic Oxygenation of a Sulfide and Alkenes

    Article • Inorganic Chemistry, October 2017, American Chemical Society (ACS)

    Professor Munetaka Akita

  35. Frontispiece: Inorganic and Organometallic Molecular Wires for Single-Molecule Devices

    Article • Chemistry - A European Journal, April 2017, Wiley

    Professor Munetaka Akita

  36. A Polyaromatic Molecular Clip That Enables the Binding of Planar, Tubular, and Dendritic Compounds

    Article • Angewandte Chemie, February 2017, Wiley

    Dr. Ken Albrecht, Professor Munetaka Akita

  37. Inorganic and Organometallic Molecular Wires for Single-Molecule Devices

    Article • Chemistry - A European Journal, February 2017, Wiley

    Professor Munetaka Akita

  38. Cover Picture: Inorganic and Organometallic Molecular Wires for Single-Molecule Devices (Chem. Eur. J. 20/2017)

    Article • Chemistry - A European Journal, February 2017, Wiley

    Professor Munetaka Akita

  39. Inorganic and Organometallic Molecular Wires for Single-Molecule Devices

    Article • Chemistry - A European Journal, February 2017, Wiley

    Professor Munetaka Akita

  40. Photocatalytic trifluoromethylthiolation

    Article • Asian Journal of Organic Chemistry, January 2017, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  41. Photoredox-catalyzed oxytrifluoromethylation of allenes: stereoselective synthesis of 2-trifluoromethylated allyl acetates

    Article • Chemical Communications, January 2017, Royal Society of Chemistry

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  42. A pH-responsive molecular capsule with an acridine shell: catch and release of large hydrophobic compounds

    Article • Chemical Communications, January 2017, Royal Society of Chemistry

    Professor Munetaka Akita

  43. Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis

    Article • Chemical Science, January 2017, Royal Society of Chemistry

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  44. A Fully Charge-Delocalized Two-Dimensional Porphyrin System with Two Different Class III States

    Article • Chemistry - A European Journal, December 2016, Wiley

    Professor Munetaka Akita

  45. Inside Back Cover: A Fully Charge-Delocalized Two-Dimensional Porphyrin System with Two Different Class III States (Chem. Eur. J. 9/2017)

    Article • Chemistry - A European Journal, December 2016, Wiley

    Professor Munetaka Akita

  46. An M2L4Molecular Capsule with a Redox Switchable Polyradical Shell

    Article • Angewandte Chemie International Edition, October 2016, Wiley

    Professor Munetaka Akita

  47. Polycationic-Shelled Capsular and Tubular Nanostructures and Their Anionic-Guest Binding Properties

    Article • Chemistry - A European Journal, October 2016, Wiley

    Professor Munetaka Akita

  48. Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds

    Article • Accounts of Chemical Research, September 2016, American Chemical Society (ACS)

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  49. Diastereoselective Synthesis of CF3- and CF2H-Substituted Spiroethers from Aryl-Fused Cycloalkenylalkanols by Photoredox Catalysis

    Article • The Journal of Organic Chemistry, August 2016, American Chemical Society (ACS)

    Professor Munetaka Akita, Prof. Dr. Takashi Koike

  50. Recognition of Multiple Methyl Groups on Aromatic Rings by a Polyaromatic Cavity

    Article • Chemistry - A European Journal, August 2016, Wiley

    Professor Munetaka Akita

  51. Aminohydroxylation of olefins with iminopyridinium ylides by dual Ir photocatalysis and Sc(OTf)3 catalysis

    Article • Tetrahedron, May 2016, Elsevier

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  52. Engineering Stacks of V-Shaped Polyaromatic Compounds with Alkyl Chains for Enhanced Emission in the Solid State

    Article • Angewandte Chemie International Edition, April 2016, Wiley

    Professor Munetaka Akita

  53. Photocatalytic Oxygenation of Sulfide and Alkenes by Trinuclear Ruthenium Clusters

    Article • Inorganic Chemistry, April 2016, American Chemical Society (ACS)

    Professor Munetaka Akita

  54. Efficient Catalytic Epoxidation in Water by Axial N-Ligand-Free Mn-Porphyrins within a Micellar Capsule

    Article • Journal of the American Chemical Society, January 2016, American Chemical Society (ACS)

    Professor Munetaka Akita

  55. Combination of organotrifluoroborates with photoredox catalysis marking a new phase in organic radical chemistry

    Article • Organic & Biomolecular Chemistry, January 2016, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  56. A fluorescent molecular capsule with a flexible polyaromatic shell for the detection of monoterpene compounds in water

    Article • Chemical Communications, January 2016, Royal Society of Chemistry

    Professor Munetaka Akita

  57. M2L4 coordination capsules with tunable anticancer activity upon guest encapsulation

    Article • Dalton Transactions, January 2016, Royal Society of Chemistry

    Professor Munetaka Akita

  58. Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2 H-Containing Alcohols

    Article • Chemistry - A European Journal, December 2015, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  59. Trifluoromethylation of aromatic alkenes by visible-light-driven photoredox catalysis: Direct conversion of alkenes to 3-trifluoromethyl-1-propenyl and 1,3-bis(trifluoromethyl)-1-propenyl derivatives

    Article • Journal of Fluorine Chemistry, November 2015, Elsevier

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  60. Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes

    Article • Angewandte Chemie International Edition, September 2015, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  61. Anti -Diastereoselective Synthesis of CF 3 -Containing Spirooxazolines and Spirooxazines via Regiospecific Trifluoromethylative Spirocyclization by Photoredox Catalysis

    Article • Organic Letters, August 2015, American Chemical Society (ACS)

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  62. Preparation of Highly Fluorescent Host–Guest Complexes with Tunable Color upon Encapsulation

    Article • Journal of the American Chemical Society, July 2015, American Chemical Society (ACS)

    Professor Munetaka Akita

  63. A V-Shaped Polyaromatic Amphiphile: Solubilization of Various Nanocarbons in Water and Enhanced Photostability

    Article • Chemistry - A European Journal, July 2015, Wiley

    Professor Munetaka Akita

  64. Regiospecific Intermolecular Aminohydroxylation of Olefins by Photoredox Catalysis

    Article • Chemistry - A European Journal, July 2015, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  65. Sunlight-driven trifluoromethylation of olefinic substrates by photoredox catalysis: A green organic process

    Article • Comptes Rendus Chimie, July 2015, Elsevier

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  66. Anisotropic Expansion of an M2L4Coordination Capsule: Host Capability and Frame Rearrangement

    Article • Chemistry - A European Journal, February 2015, Wiley

    Professor Munetaka Akita

  67. Polyaromatic Nanocapsules Displaying Aggregation-Induced Enhanced Emissions in Water

    Article • Journal of the American Chemical Society, January 2015, American Chemical Society (ACS)

    Professor Munetaka Akita

  68. Synthesis and properties of diiron complexes with heteroaromatic linkers: An approach for modulation of organometallic molecular wire

    Article • Polyhedron, January 2015, Elsevier

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  69. An aqueous molecular tube with polyaromatic frameworks capable of binding fluorescent dyes

    Article • Chemical Science, January 2015, Royal Society of Chemistry

    Professor Munetaka Akita

  70. Alkyl- and aryl-thioalkylation of olefins with organotrifluoroborates by photoredox catalysis

    Article • Organic Chemistry Frontiers, January 2015, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  71. Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis

    Article • RSC Advances, January 2015, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  72. Visible-light-controlled homo- and copolymerization of styrenes by a bichromophoric Ir–Pd catalyst

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Professor Munetaka Akita

  73. Polyaromatic molecular tubes with a subnanometer pore and the guest-induced emission enhancement behavior

    Article • Chemical Communications, January 2015, Royal Society of Chemistry

    Professor Munetaka Akita

  74. Well-defined aqueous nanoassemblies from amphiphilic meta-terphenyls and their guest incorporation

    Article • Chemical Science, January 2015, Royal Society of Chemistry

    Professor Munetaka Akita

  75. Synthesis and wire-like performance of diruthenium molecular wire with a C≡C-porphyrin-C≡C linker

    Article • Journal of Porphyrins and Phthalocyanines, January 2015, World Scientific Pub Co Pte Lt

    Professor Munetaka Akita

  76. Recent progress in transition-metal-catalyzed trifluoromethylation of olefins using electrophilic CF3 reagents

    Article • Journal of Fluorine Chemistry, November 2014, Elsevier

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  77. Synthesis of C1 symmetrical ansa-cyclopentadienylamidotitanium complexes and their application for living polymerization of propylene

    Article • Journal of Organometallic Chemistry, November 2014, Elsevier

    Professor Munetaka Akita

  78. A polyaromatic molecular tube that binds long hydrocarbons with high selectivity

    Article • Nature Communications, October 2014, Springer Science + Business Media

    Professor Munetaka Akita

  79. Micellar Polyaromatic Capsules: Enhanced Emissive Properties through Shell-Functionalization

    Article • European Journal of Organic Chemistry, October 2014, Wiley

    Professor Munetaka Akita

  80. Hydroaminomethylation of Olefins with Aminomethyltrifluoroborate by Photoredox Catalysis

    Article • Advanced Synthesis & Catalysis, September 2014, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  81. Safe storage of radical initiators within a polyaromatic nanocapsule

    Article • Nature Communications, August 2014, Springer Science + Business Media

    Professor Munetaka Akita

  82. Combining Photoredox-Catalyzed Trifluoromethylation and Oxidation with DMSO: Facile Synthesis of α-Trifluoromethylated Ketones from Aromatic Alkenes

    Article • Angewandte Chemie International Edition, May 2014, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  83. Direct C–H trifluoromethylation of di- and trisubstituted alkenes by photoredox catalysis

    Article • Beilstein Journal of Organic Chemistry, May 2014, Beilstein Institut

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  84. Trifluoromethylation by Visible-Light-Driven Photoredox Catalysis

    Article • Topics in Catalysis, March 2014, Springer Science + Business Media

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  85. Selective Host-Guest Interactions of a Transformable Coordination Capsule/Tube with Fullerenes

    Article • Angewandte Chemie International Edition, March 2014, Wiley

    Professor Munetaka Akita

  86. Infrared Vibrational Spectroscopy of [Ru(bpy) 2 (bpm)] 2+ and [Ru(bpy) 3 ] 2+ in the Excited Triplet State

    Article • Inorganic Chemistry, March 2014, American Chemical Society (ACS)

    Professor Munetaka Akita

  87. Synthesis of trinuclear Pd–Ru–Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region

    Article • Journal of Organometallic Chemistry, March 2014, Elsevier

    Professor Munetaka Akita

  88. A Solvato-Fluorochromic Macrocycle of Multiple Anthracene Fluorophores in Close Proximity

    Article • Chemistry - An Asian Journal, January 2014, Wiley

    Professor Munetaka Akita

  89. Highly Regio- and Diastereoselective Synthesis of CF3-Substituted Lactones via Photoredox-Catalyzed Carbolactonization of Alkenoic Acids

    Article • Organic Letters, January 2014, American Chemical Society (ACS)

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  90. Synthesis of Highly Conjugated Dinuclear Ru Complexes Bridged by a Novel N2^|^ndash;N3 Ligand and Their Application in Photocatalytic Oxygenation of Sulfides

    Article • Chemistry Letters, January 2014, Chemical Society of Japan

    Professor Munetaka Akita

  91. Visible-Light-Induced Photoredox Catalysis: An Easy Access to Green Radical Chemistry

    Article • Synlett, October 2013, Thieme Publishing Group

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  92. Facile Catch and Release of Fullerenes Using a Photoresponsive Molecular Tube

    Article • Journal of the American Chemical Society, September 2013, American Chemical Society (ACS)

    Professor Hsiu-Fu Hsu, Professor Munetaka Akita

  93. Revelation of the Photoactive Species in the Photocatalytic Dimerization of α-Methylstyrene by a Dinuclear Ruthenium–Palladium Complex

    Article • Inorganic Chemistry, July 2013, American Chemical Society (ACS)

    Professor Munetaka Akita

  94. Atroposelective Self-Assembly of a Molecular Capsule from Amphiphilic Anthracene Trimers

    Article • Angewandte Chemie International Edition, June 2013, Wiley

    Professor Munetaka Akita

  95. Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis

    Article • Organic Letters, April 2013, American Chemical Society (ACS)

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  96. Manganese(II) Semiquinonato and Manganese(III) Catecholato Complexes with Tridentate Ligand: Modeling the Substrate-Binding State of Manganese-Dependent Catechol Dioxygenase and Reactivity with Molecular Oxygen

    Article • Chemistry - An Asian Journal, March 2013, Wiley

    Professor Munetaka Akita

  97. Wide-Ranging Host Capability of a PdII-Linked M2L4Molecular Capsule with an Anthracene Shell

    Article • Chemistry - A European Journal, March 2013, Wiley

    Professor Munetaka Akita

  98. Micelle-like Molecular Capsules with Anthracene Shells as Photoactive Hosts

    Article • Angewandte Chemie International Edition, January 2013, Wiley

    Professor Munetaka Akita

  99. A bowl-shaped organic host using bispyridine ligands: selective encapsulation of carbonyl guests in water

    Article • Chemical Communications, January 2013, Royal Society of Chemistry

    Professor Munetaka Akita

  100. Visible-light-induced synthesis of a variety of trifluoromethylated alkenes from potassium vinyltrifluoroborates by photoredox catalysis

    Article • Chemical Communications, January 2013, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  101. Characterization of nickel(ii)-acylperoxo species relevant to catalytic alkanehydroxylation by nickel complex with mCPBA

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor Munetaka Akita

  102. Syntheses, photophysical properties, and reactivities of novel bichromophoric Pd complexes composed of Ru(ii)–polypyridyl and naphthyl moieties

    Article • Dalton Transactions, January 2013, Royal Society of Chemistry

    Professor Munetaka Akita

  103. Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

    Article • Chemical Communications, January 2013, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  104. Visible Light-Induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis

    Article • Advanced Synthesis & Catalysis, December 2012, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  105. Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts

    Article • Angewandte Chemie International Edition, August 2012, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  106. Extended Fluorochromism of Anthracene Trimers with ameta‐Substituted Triphenylamine or Triphenylphosphine Core

    Article • Chemistry - An Asian Journal, June 2012, Wiley

    Professor Munetaka Akita

  107. Isostructural M 2 L 4 Molecular Capsules with Anthracene Shells: Synthesis, Crystal Structures, and Fluorescent Properties

    Article • Chemistry - A European Journal, May 2012, Wiley

    Professor Munetaka Akita

  108. Photochromic Metal Complexes: Photoregulation of both the Nonlinear Optical and Luminescent Properties

    Article • Inorganic Chemistry, May 2012, American Chemical Society (ACS)

    Professor Munetaka Akita

  109. Color change of redox-active organometallic dithienylethene complexes by photochemical and redox processes

    Article • Dyes and Pigments, February 2012, Elsevier

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  110. Enhanced Photocatalytic Activity of α-Methylstyrene Oligomerization through Effective Metal-to-Ligand Charge-Transfer Localization on the Bridging Ligand

    Article • Inorganic Chemistry, January 2012, American Chemical Society (ACS)

    Professor Munetaka Akita

  111. Sunlight-driven synthesis of γ-diketones via oxidative coupling of enamines with silyl enol ethers catalyzed by [Ru(bpy)3]2+

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  112. A tubular macrocycle from covalently linked anthracenes and meta-phenylene spacers

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Professor Munetaka Akita

  113. Photoswitching of the second-order nonlinearity of a tetrahedral octupolar multi DTE-based copper(i) complex

    Article • Chemical Communications, January 2012, Royal Society of Chemistry

    Professor Munetaka Akita

  114. Visible-light-driven Oxidation of 1,3-Dicarbonyl Compounds via Catalytic Disproportionation of TEMPO by Photoredox Catalysis

    Article • Chemistry Letters, January 2012, Chemical Society of Japan

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  115. Theoretical Study on the Photocyclization Mechanism of Diarylethenes with Transition-Metal Substituents

    Article • Bulletin of the Chemical Society of Japan, January 2012, Chemical Society of Japan

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  116. An M 2 L 4 Molecular Capsule with an Anthracene Shell: Encapsulation of Large Guests up to 1 nm

    Article • Journal of the American Chemical Society, August 2011, American Chemical Society (ACS)

    Professor Munetaka Akita

  117. 3,5-Bis(diphenylphosphinoethyl)pyrazolate ligand (PNNPC2) and its dirhodium complexes: Comparison with related quadridentate dinucleating diphenylphosphinomethyl (PNNPPy) and phthalazine derivatives (PNNPPh)

    Article • Inorganica Chimica Acta, August 2011, Elsevier

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  118. Photochromic Organometallics, A Stimuli-Responsive System: An Approach to Smart Chemical Systems †

    Article • Organometallics, January 2011, American Chemical Society (ACS)

    Professor Munetaka Akita

  119. Highly fluorescent M2L4 molecular capsules with anthracene shells

    Article • Chemical Communications, January 2011, Royal Society of Chemistry

    Professor Munetaka Akita

  120. Making organometallic molecular wires via oxidative ligand coupling

    Article • Dalton Transactions, January 2011, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  121. Photo- and electro-chromic organometallics with dithienylethene (DTE) linker, L2CpM-DTE-MCpL2: Dually stimuli-responsive molecular switch

    Article • Dalton Transactions, January 2011, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  122. Dirhodium Complexes Bridged by Bis(diphenylphosphino)phthalazine (PNNPPh): Central Ring Size and Charge Effects As Compared with the Pyrazolate Derivative (PNNPPy)

    Article • Organometallics, November 2010, American Chemical Society (ACS)

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  123. Coordination Properties of Organoborate Ligands - Steric Hindrance Around the Distal Boron Center Directs the Conformation of the Dialkylbis(imidazolyl)borate Scaffold

    Article • European Journal of Inorganic Chemistry, October 2010, Wiley

    Professor Munetaka Akita

  124. m×nStacks of Discrete Aromatic Stacks in Solution

    Article • Journal of the American Chemical Society, July 2010, American Chemical Society (ACS)

    Professor Munetaka Akita

  125. Reversible, Fine Performance Tuning of an Organometallic Molecular Wire by Addition, Ligand Replacement and Removal of Dicobalt Fragments

    Article • European Journal of Inorganic Chemistry, July 2010, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  126. Tuning the Stability and Reactivity of Metal-bound Alkylperoxide by Remote Site Substitution of the Ligand

    Article • Chemistry - An Asian Journal, June 2010, Wiley

    Professor Munetaka Akita

  127. Visible-light promoted bimetallic catalysis

    Article • Coordination Chemistry Reviews, June 2010, Elsevier

    Professor Munetaka Akita

  128. Photochromic Organometallics with a Dithienylethene (DTE) Bridge, [YCCDTECCY] (Y={MCp*(dppe)}): Photoswitchable Molecular Wire (M=Fe) versus Dual Photo- and Electrochromism (M=Ru)

    Article • Chemistry - A European Journal, April 2010, Wiley

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  129. Engineering Double to Quintuple Stacks of a Polarized Aromatic in Confined Cavities

    Article • Journal of the American Chemical Society, January 2010, American Chemical Society (ACS)

    Professor Munetaka Akita

  130. 2-Dimensional molecular wiring based on toroidal delocalization of hexaarylbenzene

    Article • Chemical Communications, January 2010, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  131. Photocatalytic Styrene Polymerization by Novel Bichromophoric Pd Catalyst Having Long Excited-state Lifetime

    Article • Chemistry Letters, January 2010, Chemical Society of Japan

    Professor Munetaka Akita

  132. Syntheses and photophysical properties of visible-light-absorbing Ru(II) polypyridyl complexes possessing (pyridylpyrazolyl)metal tethers

    Article • Journal of Organometallic Chemistry, September 2009, Elsevier

    Professor Munetaka Akita

  133. Acetoxybis(imidazolyl)methylborate [B(ImN-Me)2(OC(O)Me)Me]−: Carboxylation of borane moiety of imidazolyl-based scorpionate

    Article • Inorganica Chimica Acta, September 2009, Elsevier

    Professor Munetaka Akita

  134. Electronic and Magnetic Couplings in Free and π-Coordinated 1,4-Diethynylnaphthalene-Bridged [Cp*(dppe)Fe] n + ( n = 0, 1) Units

    Article • Organometallics, August 2009, American Chemical Society (ACS)

    Professor Munetaka Akita

  135. Discrete stack of an odd number of polarized aromatic compounds revealing the importance of net vs. local dipoles

    Article • Proceedings of the National Academy of Sciences, June 2009, Proceedings of the National Academy of Sciences

    Professor Munetaka Akita

  136. p-Diethynylbenzene-based molecular wires, Fe–CC-p-C6H2X2–CC–Fe [Fe=Fe(η5-C5Me5)(dppe)]: Synthesis, substituent effects and unexpected formation of benzodifuran complex

    Article • Journal of Organometallic Chemistry, May 2009, Elsevier

    Professor Munetaka Akita

  137. Design, Synthesis, and Catalysis of Bio-inspired Immobilized Metallocomplex Catalyst

    Article • Topics in Catalysis, April 2009, Springer Science + Business Media

    Professor Munetaka Akita

  138. Spin Crossover by Encapsulation

    Article • Journal of the American Chemical Society, March 2009, American Chemical Society (ACS)

    Professor Munetaka Akita

  139. Switchable trans–cis interconversion of an amphiphilic anthracene trimer

    Article • Chemical Communications, January 2009, Royal Society of Chemistry

    Professor Munetaka Akita

  140. Photoinduced Oxyamination of Enamines and Aldehydes with TEMPO Catalyzed by [Ru(bpy)3]2+

    Article • Chemistry Letters, January 2009, Chemical Society of Japan

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  141. Structural Characterization and Oxidation Activity of a Nickel(II) Alkylperoxo Complex

    Article • Angewandte Chemie International Edition, November 2008, Wiley

    Professor Munetaka Akita

  142. Chemistry of polycarbon species: from clusters to molecular devices

    Article • Dalton Transactions, January 2008, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  143. Remarkable switching behavior of bimodally stimuli-responsive photochromic dithienylethenes with redox-active organometallic attachments

    Article • Chemical Communications, January 2008, Royal Society of Chemistry

    Prof. Dr. Takashi Koike, Professor Munetaka Akita

  144. Syntheses of novel di- and trinucleating ligands having a triethylbenzene core with N,N-bidentate tethers: their complexation toward Pd and Rh organometallic fragments

    Article • Dalton Transactions, January 2008, Royal Society of Chemistry

    Professor Munetaka Akita

  145. Synthesis of Pd complexes directly linked to the light-absorbing [(bpy)3Ru]2+ unit and their photochemical reactions toward styrenes

    Article • Dalton Transactions, January 2008, Royal Society of Chemistry

    Professor Munetaka Akita

  146. Preparation and Photochemical Behavior of Organoruthenium Derivatives of Photochromic Dithienylethene (DTE):  DTE−(RRuL m ) n (RRuL m = (η 6 -C 6 H 5 )Ru(η 5 -C 5 Me 5 ), (η 6 -C 6 H 5 )RuCl 2 (PPh 3 ), (η 5 -C 5 Me 4 )Ru(CO) 2 ; n = 1, 2) †

    Article • Organometallics, September 2007, American Chemical Society (ACS)

    Professor Munetaka Akita

  147. Synthesis of Pd Complexes Combined with Photosensitizing of a Ruthenium(II) Polypyridyl Moiety through a Series of Substituted Bipyrimidine Bridges. Substituent Effect of the Bridging Ligand on the Photocatalytic Dimerization of α-Methylstyrene

    Article • Inorganic Chemistry, April 2007, American Chemical Society (ACS)

    Professor Munetaka Akita

  148. Redox-active polyiron complexes with tetra(ethynylphenyl)ethene and [2,2]paracyclophane spacers containing ethynylphenyl units: extension to higher dimensional molecular wire

    Article • Dalton Transactions, January 2007, Royal Society of Chemistry

    Professor Munetaka Akita

  149. A photoswitchable molecular wire with the dithienylethene (DTE) linker, (dppe)(η5-C5Me5)Fe–CC–DTE–CC–Fe(η5-C5Me5)(dppe)

    Article • Chemical Communications, January 2007, Royal Society of Chemistry

    Professor Munetaka Akita

  150. Ruthenium and chromium complexes bearing pH-indicators as the η6-arene ligand: Synthesis, characterization, and protonation behavior

    Article • Journal of Organometallic Chemistry, January 2007, Elsevier

    Professor Munetaka Akita

  151. C−C Coupling of a Permetalated Ethene, (μ 4 -CC)Ru 2 (FeCp*) 2 (CO) 10 , with Alkynes, and Isolation of a Labile MeCN Adduct, (μ 4 -CC)Ru 2 (FeCp*) 2 (CO) 8 (NCMe) 2

    Article • Organometallics, January 2007, American Chemical Society (ACS)

    Professor Munetaka Akita

  152. Electronic Coupling in Dimetallic Complexes with π-Conjugated Bridge

    Article • Journal of Nanoscience and Nanotechnology, November 2006, American Scientific Publishers

    Professor Munetaka Akita

  153. Synthesis of a Series of Diiron Complexes Based on a Tetraethynylethene Skeleton and Related C 6 -Enediyne Spacers, (dppe)Cp*Fe−C⋮CC(R)C(R)C⋮C−FeCp*(dppe):  Tunable Molecular Wires §

    Article • Organometallics, October 2006, American Chemical Society (ACS)

    Professor Munetaka Akita

  154. Hydrogen bonding interaction between imidazolyl N–H group and peroxide: Stabilization of Mn(III)-peroxo complex TpiPr2Mn(η2-O2)(imMeH) (imMeH=2-methylimidazole)

    Article • Inorganica Chimica Acta, October 2006, Elsevier

    Professor Munetaka Akita

  155. Synthesis of a Library of Iridium-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(μ-BL)M‘L‘]BF 4 . 2. Preparation, Basic Coordination Properties, and Reactivity of the Carbonyl Complexes

    Article • Organometallics, March 2006, American Chemical Society (ACS)

    Professor Munetaka Akita

  156. Synthesis of a Library of Iridium-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(μ-BL)M‘L‘]BF 4 . 1. Specific Synthesis of Isomeric Heterodinuclear Complexes with Switched Metal Arrangements

    Article • Organometallics, March 2006, American Chemical Society (ACS)

    Professor Munetaka Akita

  157. A new method for the conversion of allyl alcohol into π-allyl species promoted by nucleophilic interaction with a CO ligand

    Article • Chemical Communications, January 2006, Royal Society of Chemistry

    Professor Munetaka Akita

  158. Stereospecific polymerization of propylene with group 4 ansa-fluorenylamidodimethyl complexes

    Article • Journal of Organometallic Chemistry, January 2006, Elsevier

    Professor Munetaka Akita

  159. Photochromic Behavior and Diastereomeric Isomerism in [(η 6 -spirobenzopyran)RuCp*]PF 6

    Article • Organometallics, December 2005, American Chemical Society (ACS)

    Professor Munetaka Akita

  160. Xenophilic Complexes Bearing a TpR Ligand, [TpRM?M?Ln] [TpR=TpiPr2, Tp# (TpMe2,4-Br); M=Ni, Co, Fe, Mn; M?Ln=Co(CO)4, Co(CO)3(PPh3), RuCp(CO)2]: The Two Metal Centers are Held Together not by Covalent Interaction but by Electrostatic Attraction

    Article • Chemistry - A European Journal, April 2005, Wiley

    Professor Munetaka Akita

  161. Polymerization of propylene with [t-BuNSiMe2Ind]TiMe2–MAO catalyst systems

    Article • Journal of Molecular Catalysis A Chemical, April 2005, Elsevier

    Professor Munetaka Akita

  162. Highly selective photo-catalytic dimerization of α-methylstyrene by a novel palladium complex with photosensitizing ruthenium(ii) polypyridyl moiety

    Article • Chemical Communications, January 2005, Royal Society of Chemistry

    Professor Munetaka Akita

  163. Polynuclear Rhodium Complexes with Dinucleating PNNP Ligand:  Dynamic and Diverse M···M Interactions in [(μ-X)Rh 2 (PNNP)(CO) 2 ] n + and [(μ 4 -X)Rh 4 (PNNP) 2 (CO) 4 ] n + [X = H, O, C⋮C−R, R−C⋮C−R, C⋮C, CHCH 2 , SMe 2 ; n = 0, 1:  PNNP = 3,5-...

    Article • Organometallics, January 2005, American Chemical Society (ACS)

    Professor Munetaka Akita

  164. Coordinatively unsaturated organometallic system based on Tp ligand: tetrahedral TpRM-R′ and TpRM-M′Ln species

    Article • Journal of Organometallic Chemistry, November 2004, Elsevier

    Professor Munetaka Akita

  165. Oxygenation of a low valent rhodium complex, TpiPr2Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species

    Article • Inorganica Chimica Acta, April 2004, Elsevier

    Professor Munetaka Akita

  166. Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements via proton-induced reversible metal migration

    Article • Chemical Communications, January 2004, Royal Society of Chemistry

    Professor Munetaka Akita

  167. Tetrakis(trimethylsilylbutadiynyl)ethene, C18(SiMe3)4: An Extended Two-Dimensional π-Conjugated System Consisting of Eighteen Carbon Atoms

    Article • Chemistry Letters, January 2004, Chemical Society of Japan

    Professor Munetaka Akita

  168. Oxygenation of a series of cationic aquoruthenium complexes, TpiPr2Ru(OH2)nL3–n·CF3SO3·(THF)x, leading to mono- and dinuclear aquo-hydroxo complexes supported by unique hydrogen bonding networks

    Article • Polyhedron, January 2004, Elsevier

    Professor Munetaka Akita

  169. Tetranuclear Complexes Based on a Dynamic Metal−Metal Linkage, [(μ4-X)Rh4(CO)4(PNNP)2]n+ (X/n = RC⋮C/1 (Acetylide), C2/0 (Dicarbide))

    Article • Organometallics, December 2003, American Chemical Society (ACS)

    Professor Munetaka Akita

  170. Synthesis and characterization of enolato-cobalt and -nickel complexes bearing TpiPr2 ligand, [TpiPr2M(XCHY)]n [TpiPr2=hydrotris(3,5-diisopropylpyrazolyl)borato; n=1, 2], obtained from hydroxometal complexes, (μ-OH)2(MTpiPr2)2, and active methylene com...

    Article • Inorganica Chimica Acta, July 2003, Elsevier

    Professor Munetaka Akita

  171. Cluster compounds containing a linear carbon chain derived from polyynediyl and polyynyl complexes, Fp*(CC)nX [X=Fp*, H; Fp*=Fe(η5-C5Me5)(CO)2]

    Article • Journal of Organometallic Chemistry, March 2003, Elsevier

    Professor Munetaka Akita

  172. A peroxochromium complex, TpiPr2Cr(O2)2, obtained by oxidative dehydrative condensation between a dihydroxochromium complex and H2O2 [TpiPr2 = hydrotris(3,5-diisopropylpyrazolyl)borato]Electronic supplementary information (ESI) available: Atomic number...

    Article • Dalton Transactions, January 2003, Royal Society of Chemistry

    Professor Munetaka Akita

  173. Interaction of hydroperoxopalladium complexes, (TpR)(py)Pd–OOH, with hydroxo-nickel and -cobalt complexes, [(μ-OH)(MTpR′)]2(M = Ni, Co), leading to oxidative dehydrogenation of the saturated hydrocarbyl moiety in the an...

    Article • Dalton Transactions, January 2003, Royal Society of Chemistry

    Professor Munetaka Akita

  174. μ4-Dicarbyne complex with a dimetallacyclobutatriene core: A new binding mode of C2species

    Article • Chemical Communications, January 2003, Royal Society of Chemistry

    Professor Munetaka Akita

  175. Conversion of a Hydroperoxo Complex, (TpiPr2)(py)Pd-OOH, into a Cyclic Alkylperoxo Complex, [HB(pziPr2)2(pz-3-CMe2-5-i-Pr)](py)Pd-OO, Catalyzed by Cu(II) Species [TpiPr2: Hydrotris(3,5-diisopropylpyrazolyl)borato]

    Article • Chemistry Letters, January 2003, Chemical Society of Japan

    Professor Munetaka Akita

  176. Synthesis and Characterization of a Series of (Hydroperoxo)-, (Alkylperoxo)-, and (μ-Peroxo)palladium Complexes Containing the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (Tp i Pr2 ):  (Tp i Pr2 )(py)Pd−OO−X [X = H, t -Bu, Pd(Tp i Pr2 )(py)] and ...

    Article • Inorganic Chemistry, October 2002, American Chemical Society (ACS)

    Professor Munetaka Akita

  177. Synthesis and Characterization of Coordinatively Unsaturated Alkynyl- and Aryl-Cobalt Complexes with 15 Valence Electrons, Tp i Pr2 Co−R, Bearing the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (Tp i Pr2 )

    Article • Organometallics, September 2002, American Chemical Society (ACS)

    Professor Munetaka Akita

  178. Di- and tri-valent chlorochromium complexes bearing hydrotris(3,5-diisopropylpyrazolyl)borato ligand (TpiPr2), TpiPr2CrCln(L) (n = 1, 2) and [TpiPr2Cr(μ-Cl)]2: flexible coordination behavior of the TpiPr2 ligand and reduction features of Cr(ii) species

    Article • Journal of the Chemical Society Dalton Transactions, January 2002, Royal Society of Chemistry

    Professor Munetaka Akita

  179. Highly labile cationic tris-acetonitrile complexes, [TpRM(NCMe)3]OTf (M = Ni, Co; TpR: hydrotrispyrazolylborato, R = Ph, Me and iPr2): versatile precursors for TpR-containing nickel and cobalt complexes

    Article • Journal of the Chemical Society Dalton Transactions, January 2002, Royal Society of Chemistry

    Professor Munetaka Akita

  180. Reactivity Control of a Dinuclear Xenophilic Species, Tp#Ni–RuCp(CO)2, via Spin Crossover across a Metal-metal Bond [Tp#: Hydrotris(4-bromo-3,5-dimethylpyrazolyl)borato]

    Article • Chemistry Letters, January 2002, Chemical Society of Japan

    Professor Munetaka Akita

  181. Structural Characterization and Intramolecular Aliphatic C−H Oxidation Ability of MIII(μ-O)2MIII Complexes of Ni and Co with the Hydrotris(3,5-dialkyl-4-X-pyrazolyl)borate Ligands TpMe2,X (X=Me, H, Br) and TpiPr2

    Article • Chemistry - A European Journal, December 2001, Wiley

    Professor Munetaka Akita

  182. N/O- and C-Bound (Enolato)palladium Complexes with Hydrotris(pyrazolyl)borato Ligands (Tp R :  R = iPr 2 , Me 2 ) Obtained via Dehydrative Condensation between the Hydroxo Complexes Tp R Pd(Py)OH and Active Methylene Compounds:  Factors Determining th...

    Article • Organometallics, September 2001, American Chemical Society (ACS)

    Professor Munetaka Akita

  183. Tetrahedral, Highly Coordinatively Unsaturated 14e (Fe) and 15e (Co) Hydrocarbyl Complexes Bearing Hydrotris(pyrazolyl)borato Ligands (Tp R ‘ ), Tp R ‘ M−R (M = Fe, Co, Ni)

    Article • Organometallics, August 2001, American Chemical Society (ACS)

    Professor Munetaka Akita

  184. Nucleophilic Addition to the η 2 -Alkyne Ligand in [CpFe(CO) 2 (η 2 -R−C⋮C−R)] + . Dependence of the Alkenyl Product Stereochemistry on the Basicity of the Nucleophile

    Article • Organometallics, June 2001, American Chemical Society (ACS)

    Professor Munetaka Akita

  185. Higher Nuclearity Fe,Ru Mixed-Metal Dicarbide Cluster Compounds Derived from Ethynediyldiiron Complex (η 5 -C 5 Me 5 )(CO) 2 Fe−C⋮C−Fe(η 5 -C 5 Me 5 )(CO) 2

    Article • Organometallics, April 2001, American Chemical Society (ACS)

    Professor Munetaka Akita

  186. Characterization of a dinuclear Mn(II) tri(μ-carboxylato) complex with the hindered hydrotris(3,5-diisopropyl-1-pyrazolyl)borate (=TpiPr2) ligand: intramolecular hydrogen bonding interaction between the protonated TpiPr2 and Mn-coordinating carboxylate...

    Article • Inorganica Chimica Acta, December 2000, Elsevier

    Professor Munetaka Akita

  187. Synthesis and Structural Comparison of Tp i Pr 2 Rh[ cis -1,2-bis(diphenylphosphino)ethene]:  Factors Determining Hapticity (κ 2 vs κ 3 ) of the Tp i Pr 2 Ligand in Tp i Pr 2 Rh(diphosphine) Complexes

    Article • Organometallics, September 2000, American Chemical Society (ACS)

    Professor Munetaka Akita

  188. Synthesis and Characterization of the Dodecahexaynediyldiiron Complex, Fp*−(C⋮C) 6 −Fp* [Fp* = Fe(η 5 -C 5 Me 5 )(CO) 2 ], the Longest Structurally Characterized Polyynediyl Complex.

    Article • Organometallics, January 2000, American Chemical Society (ACS)

    Professor Munetaka Akita

  189. Synthesis and Characterization of Fe,Co-Mixed Metal Polynuclear Complexes with C 4 H and C 4 Ligands Derived From Butadiynyl (X = H) and Butadiynediyl Iron Complexes (X = Fp*), Fp*−C⋮C−C⋮C−X [Fp* = (η 5 -C 5 Me 5 )Fe(CO) 2 ]:  Transformation of the C ...

    Article • Organometallics, January 2000, American Chemical Society (ACS)

    Professor Munetaka Akita

  190. Conformational analysis of cationic (R,S)- and (R,R)-(salen)manganese complexes possessing axial chirality as a chiral element based on x-ray crystallography: an explanation of the effect of apical ligand on enantioselection by (salen)manganese catalyst

    Article • Tetrahedron, December 1999, Elsevier

    Professor Munetaka Akita

  191. Reductive activation of dioxygen: A new concept for the catalytic oxidation

    Article • Catalysis Today, September 1998, Elsevier

    Professor Munetaka Akita

  192. Dioxygen activation by a novel manganese(II) thiolate complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate ligand

    Article • Journal of the Chemical Society Dalton Transactions, January 1998, Royal Society of Chemistry

    Professor Munetaka Akita

  193. X-Ray Structures of Chiral (Salen)manganese(III) Complexes: Proof of Pliability of the Salen Ligand.

    Article • Chemistry Letters, January 1998, Chemical Society of Japan

    Professor Munetaka Akita

  194. Synthesis and structural characterization of a tetrahedral sp3 carbide cluster compound

    Article • Chemical Communications, January 1997, Royal Society of Chemistry

    Professor Munetaka Akita

  195. Characterization of a μ-η 2 :η 2 -Peroxo Dinuclear Cobalt(II) Complex

    Article • Inorganic Chemistry, January 1997, American Chemical Society (ACS)

    Professor Munetaka Akita

  196. Reduction of a diruthenium bridging vinylidene species Cp2Ru2(μ-C = CH2)(CO)(μ-CO)(MeCN) by hydrosilane leading to a vinyl complex Cp2Ru2(μ-CH = CH2)(CO)2(SiR3) and vinylsilane: a model system for production of an olefinic product from a vinylidene int...

    Article • Inorganica Chimica Acta, September 1996, Elsevier

    Professor Munetaka Akita

  197. Some additional aspects of versatile starting compounds for cationic organoiron complexes: molecular structure of the aqua complex [(η5-C5Me4Et)Fe(CO)2(OH2)]BF4 and solution behavior of the THF complex [(η5C5R5)Fe(CO)2(THF)]BF4

    Article • Journal of Organometallic Chemistry, March 1996, Elsevier

    Professor Munetaka Akita

  198. C–H and Si–C bond activation on diruthenium bridging methylene complexes: evidence for reversible oxidative addition of Si–C(sp3) bonds

    Article • Chemical Communications, January 1996, Royal Society of Chemistry

    Professor Munetaka Akita

  199. Deoxygenative Reduction of Dimolybdenum Carbonyl Complexes Mo2(.eta.5-C5H4R')2(CO)4 by Hydrosilane Giving Trinuclear .mu.3-Methylidyne and .mu.3-Ethylidyne Complexes, (.mu.3-CR)[Mo(.eta.5-C5H4R')(CO)2]3 (R, R' = H, CH3), and Analysis of the Rotational ...

    Article • Organometallics, November 1995, American Chemical Society (ACS)

    Professor Munetaka Akita

  200. 1,2-H Shift on Tetranuclear Ethynyl Complexes (.mu.4-C2H)(.eta.5-C5R5)FeMCo2(CO)n (M = Fe, Ru; n = 10, 11; R = H, Me)

    Article • Organometallics, June 1995, American Chemical Society (ACS)

    Professor Munetaka Akita

  201. A versatile synthetic method for diiron bridging allenylidene complexes (η5-C5Me5)2Fe2(µ-CO)(CO)2(µ-η1-CCCR1R2)via nucleophilic addition to the ethynediyldiiron complex (µ-CC)[Fe(η5-C5Me5)(CO)2]2

    Article • Journal of the Chemical Society Chemical Communications, January 1995, Royal Society of Chemistry

    Professor Munetaka Akita

  202. Structure expansion of the mixed-metal dicarbide cluster core in [(μ3-C≡C-Fp)Ru3(μ-H)(CO9)] via direct radical and thermal coupling reactions leading to higher-nuclearity (μ-C2Hx)My cluster compounds (x = 0, 1; y = 7, 8),CpFeRu6(μ5-C2)(μ5-C2H)(CO)16,Cp...

    Article • Journal of Organometallic Chemistry, January 1995, Elsevier

    Professor Munetaka Akita

  203. Structure and Reactivity of C2 Species on Polymetallic Systems.

    Article • Bulletin of the Chemical Society of Japan, January 1995, Chemical Society of Japan

    Professor Munetaka Akita

  204. Formation of a Trinuclear .mu.3-Methylidyne Complex, (.mu.3-CH)[MoCp(CO)2]3, through Reduction of a CO Ligand in Cp2Mo2(CO)4 by a Hydrosilane

    Article • Organometallics, November 1994, American Chemical Society (ACS)

    Professor Munetaka Akita

  205. Unusual reactivities of (μ-η2:η2-FPCCH)Co2(CO)6, the adducts of FPCCH to Co2(CO)8: photolysis, thermolysis and reduction with hydrosilanes giving polynuclear complexes, (CP)2Fe2Co3(μ5-CCH)(CO)10, (μ-CHCH)[(−μ3-C)Co3(CO)9]2 and CpFeCo3(μ-CCH2)(...

    Article • Journal of Organometallic Chemistry, June 1994, Elsevier

    Professor Munetaka Akita

  206. Reaction of the Metal-Substituted Vinylidene Complex Cp'(CO)2Mn[:C:CHFp*] with Excess BuLi, Giving Acylated Dinuclear Bridging Alkenyl Complexes, Cp'MnCp*Fe[.mu.-CH:C(E)C(O)Bu](.mu.-CO)(CO)2 (E = H, Me): Confirmation of the Intramolecular 1,2-H Shift M...

    Article • Organometallics, June 1994, American Chemical Society (ACS)

    Professor Munetaka Akita

  207. Transformation of the C2H ligand in Fp*C.tplbond.CH [Fp* = (.eta.5-C5Me5)Fe(CO)2] into various C2 functional groups via an iron-substituted vinylidene complex, (.eta.5-C5H4Me)Mn(CO)2[:C:C(H)Fp*]: its amphoteric reactivities, structural comparisons rele...

    Article • Organometallics, January 1994, American Chemical Society (ACS)

    Professor Munetaka Akita

  208. Reduction of ruthenium and iron µ-methylene complexes with hydrosilanes producing alkane: a model system for methanation via the Fischer–Tropsch mechanism

    Article • Journal of the Chemical Society Chemical Communications, January 1993, Royal Society of Chemistry

    Professor Munetaka Akita

  209. Isolation of a zerovalent iron dinitrogen complex with 1,2-bis(diethylphosphino)ethane ligands

    Article • Journal of the Chemical Society Chemical Communications, January 1993, Royal Society of Chemistry

    Professor Munetaka Akita

  210. A Practical O2-Oxidation of Functionalized Alcohols Producing Carboxylic Acids Catalyzed by the Pd-C/Pb(OAc)2 System.

    Article • Bulletin of the Chemical Society of Japan, January 1993, Chemical Society of Japan

    Professor Munetaka Akita

  211. Stereochemistry of the peptide α-amidation reaction involving two enzymes, peptidylglycine α-hydroxylating monooxygenase (PHM) and peptidylhydroxyglycine N–C lyase (PHL)

    Article • Journal of the Chemical Society Chemical Communications, January 1992, Royal Society of Chemistry

    Professor Munetaka Akita

  212. Template synthesis of substituted cyclopentanones by zirconocene/olefin/CO systems

    Article • Polyhedron, January 1991, Elsevier

    Professor Munetaka Akita

  213. Oxidative addition of allylic halides to ruthenium(II) compounds. Preparation, reactions, and x-ray crystallographic structure of ruthenium(IV)-allyl complexes

    Article • Organometallics, March 1990, American Chemical Society (ACS)

    Professor Munetaka Akita

  214. Electrophilic cleavage reations of carbonsilicon bonds in neutral hexacoordinate silicon compounds: diorgano(phthalocyaninato)silicon

    Article • Journal of Organometallic Chemistry, March 1988, Elsevier

    Professor Munetaka Akita

  215. Selective carbometallation of α,β-unsaturated carbonyl compounds and substituted oxacyclopropanes with zirconium-diene complexes

    Article • Journal of Organometallic Chemistry, June 1987, Elsevier

    Professor Munetaka Akita

  216. Silafunctional compounds in organic synthesis. 32. Stereoselective halogenolysis of alkenylsilanes: stereochemical dependence on the coordination state of the leaving silyl groups

    Article • The Journal of Organic Chemistry, March 1987, American Chemical Society (ACS)

    Professor Munetaka Akita

  217. Zirconocene-.eta.4-1,3-pentadiene complex and its higher homologs. A new synthetic method involving .sigma.-.pi. rearrangement of the hydrido-2,4-pentadienylzirconium species

    Article • Organometallics, October 1984, American Chemical Society (ACS)

    Professor Munetaka Akita

  218. Regioselective homo- and codimerization of 1-alkynes leading to 2,4-disubstituted 1-buten-3-ynes by catalysis of a (.ETA.5-C5Me5)2TiCl2/RMgX system.

    Article • Bulletin of the Chemical Society of Japan, January 1984, Chemical Society of Japan

    Professor Munetaka Akita

  219. Silafunctional compounds in organic synthesis

    Article • Journal of Organometallic Chemistry, September 1983, Elsevier

    Professor Munetaka Akita

  220. Zirconium assisted regioselective acylation of dienes with saturated or unsaturated esters to lead to .BETA.,.GAMMA.-unsaturated carbonyl compounds.

    Article • Chemistry Letters, January 1983, Chemical Society of Japan

    Professor Munetaka Akita

  221. The X-ray and NMR studies on the regio- and stereoselective courses for insertion of ketones into the s-cis- and s-trans-diene complexes of zirconium leading to (Z)-1,2-oxazirconacyclohept-4-enes.

    Article • Bulletin of the Chemical Society of Japan, January 1983, Chemical Society of Japan

    Professor Munetaka Akita

  222. Oxidative cleavage of silicon-carbon bonds in organosilicon fluorides to alcohols

    Article • Tetrahedron, January 1983, Elsevier

    Professor Munetaka Akita

  223. Highly stereoselective isomerization of monosubstituted 1-alkenes to (E)-2-alkenes by catalysis of (C5Me5)2TiCl2/NaC10H8.

    Article • Bulletin of the Chemical Society of Japan, January 1983, Chemical Society of Japan

    Professor Munetaka Akita

  224. Silyl-titanation of acetylenes and 1,3-dienes

    Article • Journal of Organometallic Chemistry, February 1982, Elsevier

    Professor Munetaka Akita

  225. Organofluorosilicates in organic synthesis. XVI. Synthesis of organo-pentafluorosilicates via the Diels-Alder, ene, and Friedel-Crafts reaction. Their transformations to organic halides and alcohols.

    Article • Bulletin of the Chemical Society of Japan, January 1982, Chemical Society of Japan

    Professor Munetaka Akita