All Stories

  1. Progress in Photocatalysis for Organic Chemistry
  2. Molecule‐Electrode Interfaces Controlled by Bulky Long‐Legged Ligands in Organometallic Molecular Wires
  3. Acene Size‐Dependent Transition of The Radical Centers From the Metal to The Acene Parts In Monocationic Dinuclear (Diethynylacene)diyl Complexes
  4. Estimation of Electron Distribution over Dinuclear Organometallic Molecular Wires by “IR Tag” Analysis of Ancillary Acyl-Cp Ligands
  5. Sustainable C–H functionalization under ball-milling, microwave-irradiation and aqueous media
  6. Organometallic Molecular Wires with Thioacetylene Backbones, trans ‐{RS‐(C≡C) n } 2 Ru(phosphine) 4 : High Conductance through N...
  7. Dimesitylborylethynylated Arenes: Unique Electronic and Photophysical Properties Caused by Ethynediyl (C≡C) Spacers
  8. Dimesitylborylethynylated Arenes: Unique Electronic and Photophysical Properties Caused by Ethynediyl (C≡C) Spacers
  9. Single-molecule junctions of multinuclear organometallic wires: long-range carrier transport brought about by metal–metal interaction
  10. Simple generation of various α-monofluoroalkyl radicals by organic photoredox catalysis: modular synthesis of β-monofluoroketones
  11. Control of dominant conduction orbitals by peripheral substituents in paddle-wheel diruthenium alkynyl molecular junctions
  12. Transition Metal-Free Supramolecular Photoredox Catalysis in Water: A Phenoxazine Photocatalyst Encapsulated in V-Shaped Aromatic Amphiphiles
  13. Laser Flash Photolysis Studies on Radical Monofluoromethylation by (Diarylamino)naphthalene Photoredox Catalysis: Long Lifetime of the Excited State is Not Always a Requisite
  14. Single-Molecule Junction of a Cationic Rh(III) Polyyne Molecular Wire
  15. Anisotropic Contraction of a Polyaromatic Capsule and Its Cavity-Induced Compression Effect
  16. Fluoroalkanesulfinate Salts as Dual Fluoroalkyl and SO2 Sources: Atom-Economical Fluoroalkyl-Sulfonylation of Alkenes and Alkynes by Photoredox Catalysis
  17. Energy transfer-driven regioselective synthesis of functionalized phenanthridines by visible-light Ir photocatalysis
  18. An aromatic micelle with bent pentacene-based panels: encapsulation of perylene bisimide dyes and graphene nanosheets
  19. Photoluminescent properties and molecular structures of dinuclear gold(i) complexes with bridged diphosphine ligands: near-unity phosphorescence from 3XMMCT/3MC
  20. A Redox-Active Heterocyclic Capsule: Radical Generation, Oxygenation, and Guest Uptake/Release
  21. Keto-Difluoromethylation of Aromatic Alkenes by Photoredox Catalysis: Step-Economical Synthesis of α-CF2H-Substituted Ketones in Flow
  22. Visible-Light-Triggered Monofluoromethylation of Alkenes by Strongly Reducing 1,4-Bis(diphenylamino)naphthalene Photoredox Catalysis
  23. A polyaromatic receptor with high androgen affinity
  24. Dinuclear ruthenium acetylide complexes with diethynylated anthrahydroquinone and anthraquinone frameworks: a multi-stimuli-responsive organometallic switch
  25. Luminescence color alteration induced by trapped solvent molecules in crystals of tetrahedral gold(i) complexes: near-unity luminescence mixed with thermally activated delayed fluorescence and phosphorescence
  26. Recent progress in photochemical radical di- and mono-fluoromethylation
  27. 18 Photocatalytic Introduction of Fluorinated Groups
  28. Strongly Reducing (Diarylamino)anthracene Catalyst for Metal-Free Visible-Light Photocatalytic Fluoroalkylation
  29. “Doping” of Polyyne with an Organometallic Fragment Leads to Highly Conductive Metallapolyyne Molecular Wire
  30. Nonradical Light-Controlled Polymerization of Styrene and Vinyl Ethers Catalyzed by an Iridium–Palladium Photocatalyst
  31. Encapsulation-induced emission enhancement (EIEE) of Eu(iii)-complexes by aromatic micelles in water
  32. Photoredox radical C–H oxygenation of aromatics with aroyloxylutidinium salts
  33. Near-unity thermally activated delayed fluorescence efficiency in three- and four-coordinate Au(i) complexes with diphosphine ligands
  34. Substituent Effect of the Bridging Ligand in the Trinuclear Ru Complexes on Photocatalytic Oxygenation of a Sulfide and Alkenes
  35. Frontispiece: Inorganic and Organometallic Molecular Wires for Single-Molecule Devices
  36. A Polyaromatic Molecular Clip That Enables the Binding of Planar, Tubular, and Dendritic Compounds
  37. Inorganic and Organometallic Molecular Wires for Single-Molecule Devices
  38. Cover Picture: Inorganic and Organometallic Molecular Wires for Single-Molecule Devices (Chem. Eur. J. 20/2017)
  39. Inorganic and Organometallic Molecular Wires for Single-Molecule Devices
  40. Photocatalytic trifluoromethylthiolation
  41. Photoredox-catalyzed oxytrifluoromethylation of allenes: stereoselective synthesis of 2-trifluoromethylated allyl acetates
  42. A pH-responsive molecular capsule with an acridine shell: catch and release of large hydrophobic compounds
  43. Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis
  44. A Fully Charge-Delocalized Two-Dimensional Porphyrin System with Two Different Class III States
  45. Inside Back Cover: A Fully Charge-Delocalized Two-Dimensional Porphyrin System with Two Different Class III States (Chem. Eur. J. 9/2017)
  46. An M2L4Molecular Capsule with a Redox Switchable Polyradical Shell
  47. Polycationic-Shelled Capsular and Tubular Nanostructures and Their Anionic-Guest Binding Properties
  48. Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds
  49. Diastereoselective Synthesis of CF3- and CF2H-Substituted Spiroethers from Aryl-Fused Cycloalkenylalkanols by Photoredox Catalysis
  50. Recognition of Multiple Methyl Groups on Aromatic Rings by a Polyaromatic Cavity
  51. Aminohydroxylation of olefins with iminopyridinium ylides by dual Ir photocatalysis and Sc(OTf)3 catalysis
  52. Engineering Stacks of V-Shaped Polyaromatic Compounds with Alkyl Chains for Enhanced Emission in the Solid State
  53. Photocatalytic Oxygenation of Sulfide and Alkenes by Trinuclear Ruthenium Clusters
  54. Efficient Catalytic Epoxidation in Water by Axial N-Ligand-Free Mn-Porphyrins within a Micellar Capsule
  55. Combination of organotrifluoroborates with photoredox catalysis marking a new phase in organic radical chemistry
  56. A fluorescent molecular capsule with a flexible polyaromatic shell for the detection of monoterpene compounds in water
  57. M2L4 coordination capsules with tunable anticancer activity upon guest encapsulation
  58. Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2 H-Containing Alcohols
  59. Trifluoromethylation of aromatic alkenes by visible-light-driven photoredox catalysis: Direct conversion of alkenes to 3-trifluoromethyl-1-propenyl and 1,3-bis(trifluoromethyl)-1-propenyl derivatives
  60. Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes
  61. Anti -Diastereoselective Synthesis of CF 3 -Containing Spirooxazolines and Spirooxazines via Regiospecific Trifluoromethylative Spirocyclization by Photoredox Catalysis
  62. Preparation of Highly Fluorescent Host–Guest Complexes with Tunable Color upon Encapsulation
  63. A V-Shaped Polyaromatic Amphiphile: Solubilization of Various Nanocarbons in Water and Enhanced Photostability
  64. Regiospecific Intermolecular Aminohydroxylation of Olefins by Photoredox Catalysis
  65. Sunlight-driven trifluoromethylation of olefinic substrates by photoredox catalysis: A green organic process
  66. Anisotropic Expansion of an M2L4Coordination Capsule: Host Capability and Frame Rearrangement
  67. Polyaromatic Nanocapsules Displaying Aggregation-Induced Enhanced Emissions in Water
  68. Synthesis and properties of diiron complexes with heteroaromatic linkers: An approach for modulation of organometallic molecular wire
  69. An aqueous molecular tube with polyaromatic frameworks capable of binding fluorescent dyes
  70. Alkyl- and aryl-thioalkylation of olefins with organotrifluoroborates by photoredox catalysis
  71. Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis
  72. Visible-light-controlled homo- and copolymerization of styrenes by a bichromophoric Ir–Pd catalyst
  73. Polyaromatic molecular tubes with a subnanometer pore and the guest-induced emission enhancement behavior
  74. Well-defined aqueous nanoassemblies from amphiphilic meta-terphenyls and their guest incorporation
  75. Synthesis and wire-like performance of diruthenium molecular wire with a C≡C-porphyrin-C≡C linker
  76. Recent progress in transition-metal-catalyzed trifluoromethylation of olefins using electrophilic CF3 reagents
  77. Synthesis of C1 symmetrical ansa-cyclopentadienylamidotitanium complexes and their application for living polymerization of propylene
  78. A polyaromatic molecular tube that binds long hydrocarbons with high selectivity
  79. Micellar Polyaromatic Capsules: Enhanced Emissive Properties through Shell-Functionalization
  80. Hydroaminomethylation of Olefins with Aminomethyltrifluoroborate by Photoredox Catalysis
  81. Safe storage of radical initiators within a polyaromatic nanocapsule
  82. Combining Photoredox-Catalyzed Trifluoromethylation and Oxidation with DMSO: Facile Synthesis of α-Trifluoromethylated Ketones from Aromatic Alkenes
  83. Direct C–H trifluoromethylation of di- and trisubstituted alkenes by photoredox catalysis
  84. Trifluoromethylation by Visible-Light-Driven Photoredox Catalysis
  85. Selective Host-Guest Interactions of a Transformable Coordination Capsule/Tube with Fullerenes
  86. Infrared Vibrational Spectroscopy of [Ru(bpy) 2 (bpm)] 2+ and [Ru(bpy) 3 ] 2+ in the Excited Triplet State
  87. Synthesis of trinuclear Pd–Ru–Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region
  88. A Solvato-Fluorochromic Macrocycle of Multiple Anthracene Fluorophores in Close Proximity
  89. Highly Regio- and Diastereoselective Synthesis of CF3-Substituted Lactones via Photoredox-Catalyzed Carbolactonization of Alkenoic Acids
  90. Synthesis of Highly Conjugated Dinuclear Ru Complexes Bridged by a Novel N2^|^ndash;N3 Ligand and Their Application in Photocatalytic Oxygenation of Sulfides
  91. Visible-Light-Induced Photoredox Catalysis: An Easy Access to Green Radical Chemistry
  92. Facile Catch and Release of Fullerenes Using a Photoresponsive Molecular Tube
  93. Revelation of the Photoactive Species in the Photocatalytic Dimerization of α-Methylstyrene by a Dinuclear Ruthenium–Palladium Complex
  94. Atroposelective Self-Assembly of a Molecular Capsule from Amphiphilic Anthracene Trimers
  95. Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis
  96. Manganese(II) Semiquinonato and Manganese(III) Catecholato Complexes with Tridentate Ligand: Modeling the Substrate-Binding State of Manganese-Dependent Catechol Dioxygenase and Reactivity with Molecular Oxygen
  97. Wide-Ranging Host Capability of a PdII-Linked M2L4Molecular Capsule with an Anthracene Shell
  98. Micelle-like Molecular Capsules with Anthracene Shells as Photoactive Hosts
  99. A bowl-shaped organic host using bispyridine ligands: selective encapsulation of carbonyl guests in water
  100. Visible-light-induced synthesis of a variety of trifluoromethylated alkenes from potassium vinyltrifluoroborates by photoredox catalysis
  101. Characterization of nickel(ii)-acylperoxo species relevant to catalytic alkanehydroxylation by nickel complex with mCPBA
  102. Syntheses, photophysical properties, and reactivities of novel bichromophoric Pd complexes composed of Ru(ii)–polypyridyl and naphthyl moieties
  103. Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis
  104. Visible Light-Induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis
  105. Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts
  106. Extended Fluorochromism of Anthracene Trimers with ameta‐Substituted Triphenylamine or Triphenylphosphine Core
  107. Isostructural M 2 L 4 Molecular Capsules with Anthracene Shells: Synthesis, Crystal Structures, and Fluorescent Properties
  108. Photochromic Metal Complexes: Photoregulation of both the Nonlinear Optical and Luminescent Properties
  109. Color change of redox-active organometallic dithienylethene complexes by photochemical and redox processes
  110. Enhanced Photocatalytic Activity of α-Methylstyrene Oligomerization through Effective Metal-to-Ligand Charge-Transfer Localization on the Bridging Ligand
  111. Sunlight-driven synthesis of γ-diketones via oxidative coupling of enamines with silyl enol ethers catalyzed by [Ru(bpy)3]2+
  112. A tubular macrocycle from covalently linked anthracenes and meta-phenylene spacers
  113. Photoswitching of the second-order nonlinearity of a tetrahedral octupolar multi DTE-based copper(i) complex
  114. Visible-light-driven Oxidation of 1,3-Dicarbonyl Compounds via Catalytic Disproportionation of TEMPO by Photoredox Catalysis
  115. Theoretical Study on the Photocyclization Mechanism of Diarylethenes with Transition-Metal Substituents
  116. An M 2 L 4 Molecular Capsule with an Anthracene Shell: Encapsulation of Large Guests up to 1 nm
  117. 3,5-Bis(diphenylphosphinoethyl)pyrazolate ligand (PNNPC2) and its dirhodium complexes: Comparison with related quadridentate dinucleating diphenylphosphinomethyl (PNNPPy) and phthalazine derivatives (PNNPPh)
  118. Photochromic Organometallics, A Stimuli-Responsive System: An Approach to Smart Chemical Systems †
  119. Highly fluorescent M2L4 molecular capsules with anthracene shells
  120. Making organometallic molecular wires via oxidative ligand coupling
  121. Photo- and electro-chromic organometallics with dithienylethene (DTE) linker, L2CpM-DTE-MCpL2: Dually stimuli-responsive molecular switch
  122. Dirhodium Complexes Bridged by Bis(diphenylphosphino)phthalazine (PNNPPh): Central Ring Size and Charge Effects As Compared with the Pyrazolate Derivative (PNNPPy)
  123. Coordination Properties of Organoborate Ligands - Steric Hindrance Around the Distal Boron Center Directs the Conformation of the Dialkylbis(imidazolyl)borate Scaffold
  124. m×nStacks of Discrete Aromatic Stacks in Solution
  125. Reversible, Fine Performance Tuning of an Organometallic Molecular Wire by Addition, Ligand Replacement and Removal of Dicobalt Fragments
  126. Tuning the Stability and Reactivity of Metal-bound Alkylperoxide by Remote Site Substitution of the Ligand
  127. Visible-light promoted bimetallic catalysis
  128. Photochromic Organometallics with a Dithienylethene (DTE) Bridge, [YCCDTECCY] (Y={MCp*(dppe)}): Photoswitchable Molecular Wire (M=Fe) versus Dual Photo- and Electrochromism (M=Ru)
  129. Engineering Double to Quintuple Stacks of a Polarized Aromatic in Confined Cavities
  130. 2-Dimensional molecular wiring based on toroidal delocalization of hexaarylbenzene
  131. Photocatalytic Styrene Polymerization by Novel Bichromophoric Pd Catalyst Having Long Excited-state Lifetime
  132. Syntheses and photophysical properties of visible-light-absorbing Ru(II) polypyridyl complexes possessing (pyridylpyrazolyl)metal tethers
  133. Acetoxybis(imidazolyl)methylborate [B(ImN-Me)2(OC(O)Me)Me]−: Carboxylation of borane moiety of imidazolyl-based scorpionate
  134. Electronic and Magnetic Couplings in Free and π-Coordinated 1,4-Diethynylnaphthalene-Bridged [Cp*(dppe)Fe] n + ( n = 0, 1) Units
  135. Discrete stack of an odd number of polarized aromatic compounds revealing the importance of net vs. local dipoles
  136. p-Diethynylbenzene-based molecular wires, Fe–CC-p-C6H2X2–CC–Fe [Fe=Fe(η5-C5Me5)(dppe)]: Synthesis, substituent effects and unexpected formation of benzodifuran complex
  137. Design, Synthesis, and Catalysis of Bio-inspired Immobilized Metallocomplex Catalyst
  138. Spin Crossover by Encapsulation
  139. Switchable trans–cis interconversion of an amphiphilic anthracene trimer
  140. Photoinduced Oxyamination of Enamines and Aldehydes with TEMPO Catalyzed by [Ru(bpy)3]2+
  141. Structural Characterization and Oxidation Activity of a Nickel(II) Alkylperoxo Complex
  142. Chemistry of polycarbon species: from clusters to molecular devices
  143. Remarkable switching behavior of bimodally stimuli-responsive photochromic dithienylethenes with redox-active organometallic attachments
  144. Syntheses of novel di- and trinucleating ligands having a triethylbenzene core with N,N-bidentate tethers: their complexation toward Pd and Rh organometallic fragments
  145. Synthesis of Pd complexes directly linked to the light-absorbing [(bpy)3Ru]2+ unit and their photochemical reactions toward styrenes
  146. Preparation and Photochemical Behavior of Organoruthenium Derivatives of Photochromic Dithienylethene (DTE):  DTE−(RRuL m ) n (RRuL m = (η 6 -C 6 H 5 )Ru(η 5 -C 5 Me 5 ), (η 6 -C 6 H 5 )RuCl 2 (PPh 3 ), (η 5 -C 5 Me 4 )Ru(CO) 2 ; n = 1, 2) †
  147. Synthesis of Pd Complexes Combined with Photosensitizing of a Ruthenium(II) Polypyridyl Moiety through a Series of Substituted Bipyrimidine Bridges. Substituent Effect of the Bridging Ligand on the Photocatalytic Dimerization of α-Methylstyrene
  148. Redox-active polyiron complexes with tetra(ethynylphenyl)ethene and [2,2]paracyclophane spacers containing ethynylphenyl units: extension to higher dimensional molecular wire
  149. A photoswitchable molecular wire with the dithienylethene (DTE) linker, (dppe)(η5-C5Me5)Fe–CC–DTE–CC–Fe(η5-C5Me5)(dppe)
  150. Ruthenium and chromium complexes bearing pH-indicators as the η6-arene ligand: Synthesis, characterization, and protonation behavior
  151. C−C Coupling of a Permetalated Ethene, (μ 4 -CC)Ru 2 (FeCp*) 2 (CO) 10 , with Alkynes, and Isolation of a Labile MeCN Adduct, (μ 4 -CC)Ru 2 (FeCp*) 2 (CO) 8 (NCMe) 2
  152. Electronic Coupling in Dimetallic Complexes with π-Conjugated Bridge
  153. Synthesis of a Series of Diiron Complexes Based on a Tetraethynylethene Skeleton and Related C 6 -Enediyne Spacers, (dppe)Cp*Fe−C⋮CC(R)C(R)C⋮C−FeCp*(dppe):  Tunable Molecular Wires §
  154. Hydrogen bonding interaction between imidazolyl N–H group and peroxide: Stabilization of Mn(III)-peroxo complex TpiPr2Mn(η2-O2)(imMeH) (imMeH=2-methylimidazole)
  155. Synthesis of a Library of Iridium-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(μ-BL)M‘L‘]BF 4 . 2. Preparation, Basic Coordination Properties, and Reactivity of the Carbonyl Complexes
  156. Synthesis of a Library of Iridium-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(μ-BL)M‘L‘]BF 4 . 1. Specific Synthesis of Isomeric Heterodinuclear Complexes with Switched Metal Arrangements
  157. A new method for the conversion of allyl alcohol into π-allyl species promoted by nucleophilic interaction with a CO ligand
  158. Stereospecific polymerization of propylene with group 4 ansa-fluorenylamidodimethyl complexes
  159. Photochromic Behavior and Diastereomeric Isomerism in [(η 6 -spirobenzopyran)RuCp*]PF 6
  160. Xenophilic Complexes Bearing a TpR Ligand, [TpRM?M?Ln] [TpR=TpiPr2, Tp# (TpMe2,4-Br); M=Ni, Co, Fe, Mn; M?Ln=Co(CO)4, Co(CO)3(PPh3), RuCp(CO)2]: The Two Metal Centers are Held Together not by Covalent Interaction but by Electrostatic Attraction
  161. Polymerization of propylene with [t-BuNSiMe2Ind]TiMe2–MAO catalyst systems
  162. Highly selective photo-catalytic dimerization of α-methylstyrene by a novel palladium complex with photosensitizing ruthenium(ii) polypyridyl moiety
  163. Polynuclear Rhodium Complexes with Dinucleating PNNP Ligand:  Dynamic and Diverse M···M Interactions in [(μ-X)Rh 2 (PNNP)(CO) 2 ] n + and [(μ 4 -X)Rh 4 (PNNP) 2 (CO) 4 ] n + [X = H, O, C⋮C−R, R−C⋮C−R, C⋮C, CHCH 2 , SMe 2 ; n = 0, 1:  PNNP = 3,5-...
  164. Coordinatively unsaturated organometallic system based on Tp ligand: tetrahedral TpRM-R′ and TpRM-M′Ln species
  165. Oxygenation of a low valent rhodium complex, TpiPr2Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species
  166. Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements via proton-induced reversible metal migration
  167. Tetrakis(trimethylsilylbutadiynyl)ethene, C18(SiMe3)4: An Extended Two-Dimensional π-Conjugated System Consisting of Eighteen Carbon Atoms
  168. Oxygenation of a series of cationic aquoruthenium complexes, TpiPr2Ru(OH2)nL3–n·CF3SO3·(THF)x, leading to mono- and dinuclear aquo-hydroxo complexes supported by unique hydrogen bonding networks
  169. Tetranuclear Complexes Based on a Dynamic Metal−Metal Linkage, [(μ4-X)Rh4(CO)4(PNNP)2]n+ (X/n = RC⋮C/1 (Acetylide), C2/0 (Dicarbide))
  170. Synthesis and characterization of enolato-cobalt and -nickel complexes bearing TpiPr2 ligand, [TpiPr2M(XCHY)]n [TpiPr2=hydrotris(3,5-diisopropylpyrazolyl)borato; n=1, 2], obtained from hydroxometal complexes, (μ-OH)2(MTpiPr2)2, and active methylene com...
  171. Cluster compounds containing a linear carbon chain derived from polyynediyl and polyynyl complexes, Fp*(CC)nX [X=Fp*, H; Fp*=Fe(η5-C5Me5)(CO)2]
  172. A peroxochromium complex, TpiPr2Cr(O2)2, obtained by oxidative dehydrative condensation between a dihydroxochromium complex and H2O2 [TpiPr2 = hydrotris(3,5-diisopropylpyrazolyl)borato]Electronic supplementary information (ESI) available: Atomic number...
  173. Interaction of hydroperoxopalladium complexes, (TpR)(py)Pd–OOH, with hydroxo-nickel and -cobalt complexes, [(μ-OH)(MTpR′)]2(M = Ni, Co), leading to oxidative dehydrogenation of the saturated hydrocarbyl moiety in the an...
  174. μ4-Dicarbyne complex with a dimetallacyclobutatriene core: A new binding mode of C2species
  175. Conversion of a Hydroperoxo Complex, (TpiPr2)(py)Pd-OOH, into a Cyclic Alkylperoxo Complex, [HB(pziPr2)2(pz-3-CMe2-5-i-Pr)](py)Pd-OO, Catalyzed by Cu(II) Species [TpiPr2: Hydrotris(3,5-diisopropylpyrazolyl)borato]
  176. Synthesis and Characterization of a Series of (Hydroperoxo)-, (Alkylperoxo)-, and (μ-Peroxo)palladium Complexes Containing the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (Tp i Pr2 ):  (Tp i Pr2 )(py)Pd−OO−X [X = H, t -Bu, Pd(Tp i Pr2 )(py)] and ...
  177. Synthesis and Characterization of Coordinatively Unsaturated Alkynyl- and Aryl-Cobalt Complexes with 15 Valence Electrons, Tp i Pr2 Co−R, Bearing the Hydrotris(3,5-diisopropylpyrazolyl)borato Ligand (Tp i Pr2 )
  178. Di- and tri-valent chlorochromium complexes bearing hydrotris(3,5-diisopropylpyrazolyl)borato ligand (TpiPr2), TpiPr2CrCln(L) (n = 1, 2) and [TpiPr2Cr(μ-Cl)]2: flexible coordination behavior of the TpiPr2 ligand and reduction features of Cr(ii) species
  179. Highly labile cationic tris-acetonitrile complexes, [TpRM(NCMe)3]OTf (M = Ni, Co; TpR: hydrotrispyrazolylborato, R = Ph, Me and iPr2): versatile precursors for TpR-containing nickel and cobalt complexes
  180. Reactivity Control of a Dinuclear Xenophilic Species, Tp#Ni–RuCp(CO)2, via Spin Crossover across a Metal-metal Bond [Tp#: Hydrotris(4-bromo-3,5-dimethylpyrazolyl)borato]
  181. Structural Characterization and Intramolecular Aliphatic C−H Oxidation Ability of MIII(μ-O)2MIII Complexes of Ni and Co with the Hydrotris(3,5-dialkyl-4-X-pyrazolyl)borate Ligands TpMe2,X (X=Me, H, Br) and TpiPr2
  182. N/O- and C-Bound (Enolato)palladium Complexes with Hydrotris(pyrazolyl)borato Ligands (Tp R :  R = iPr 2 , Me 2 ) Obtained via Dehydrative Condensation between the Hydroxo Complexes Tp R Pd(Py)OH and Active Methylene Compounds:  Factors Determining th...
  183. Tetrahedral, Highly Coordinatively Unsaturated 14e (Fe) and 15e (Co) Hydrocarbyl Complexes Bearing Hydrotris(pyrazolyl)borato Ligands (Tp R ‘ ), Tp R ‘ M−R (M = Fe, Co, Ni)
  184. Nucleophilic Addition to the η 2 -Alkyne Ligand in [CpFe(CO) 2 (η 2 -R−C⋮C−R)] + . Dependence of the Alkenyl Product Stereochemistry on the Basicity of the Nucleophile
  185. Higher Nuclearity Fe,Ru Mixed-Metal Dicarbide Cluster Compounds Derived from Ethynediyldiiron Complex (η 5 -C 5 Me 5 )(CO) 2 Fe−C⋮C−Fe(η 5 -C 5 Me 5 )(CO) 2
  186. Characterization of a dinuclear Mn(II) tri(μ-carboxylato) complex with the hindered hydrotris(3,5-diisopropyl-1-pyrazolyl)borate (=TpiPr2) ligand: intramolecular hydrogen bonding interaction between the protonated TpiPr2 and Mn-coordinating carboxylate...
  187. Synthesis and Structural Comparison of Tp i Pr 2 Rh[ cis -1,2-bis(diphenylphosphino)ethene]:  Factors Determining Hapticity (κ 2 vs κ 3 ) of the Tp i Pr 2 Ligand in Tp i Pr 2 Rh(diphosphine) Complexes
  188. Synthesis and Characterization of the Dodecahexaynediyldiiron Complex, Fp*−(C⋮C) 6 −Fp* [Fp* = Fe(η 5 -C 5 Me 5 )(CO) 2 ], the Longest Structurally Characterized Polyynediyl Complex.
  189. Synthesis and Characterization of Fe,Co-Mixed Metal Polynuclear Complexes with C 4 H and C 4 Ligands Derived From Butadiynyl (X = H) and Butadiynediyl Iron Complexes (X = Fp*), Fp*−C⋮C−C⋮C−X [Fp* = (η 5 -C 5 Me 5 )Fe(CO) 2 ]:  Transformation of the C ...
  190. Conformational analysis of cationic (R,S)- and (R,R)-(salen)manganese complexes possessing axial chirality as a chiral element based on x-ray crystallography: an explanation of the effect of apical ligand on enantioselection by (salen)manganese catalyst
  191. Reductive activation of dioxygen: A new concept for the catalytic oxidation
  192. Dioxygen activation by a novel manganese(II) thiolate complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate ligand
  193. X-Ray Structures of Chiral (Salen)manganese(III) Complexes: Proof of Pliability of the Salen Ligand.
  194. Synthesis and structural characterization of a tetrahedral sp3 carbide cluster compound
  195. Characterization of a μ-η 2 :η 2 -Peroxo Dinuclear Cobalt(II) Complex
  196. Reduction of a diruthenium bridging vinylidene species Cp2Ru2(μ-C = CH2)(CO)(μ-CO)(MeCN) by hydrosilane leading to a vinyl complex Cp2Ru2(μ-CH = CH2)(CO)2(SiR3) and vinylsilane: a model system for production of an olefinic product from a vinylidene int...
  197. Some additional aspects of versatile starting compounds for cationic organoiron complexes: molecular structure of the aqua complex [(η5-C5Me4Et)Fe(CO)2(OH2)]BF4 and solution behavior of the THF complex [(η5C5R5)Fe(CO)2(THF)]BF4
  198. C–H and Si–C bond activation on diruthenium bridging methylene complexes: evidence for reversible oxidative addition of Si–C(sp3) bonds
  199. Deoxygenative Reduction of Dimolybdenum Carbonyl Complexes Mo2(.eta.5-C5H4R')2(CO)4 by Hydrosilane Giving Trinuclear .mu.3-Methylidyne and .mu.3-Ethylidyne Complexes, (.mu.3-CR)[Mo(.eta.5-C5H4R')(CO)2]3 (R, R' = H, CH3), and Analysis of the Rotational ...
  200. 1,2-H Shift on Tetranuclear Ethynyl Complexes (.mu.4-C2H)(.eta.5-C5R5)FeMCo2(CO)n (M = Fe, Ru; n = 10, 11; R = H, Me)
  201. A versatile synthetic method for diiron bridging allenylidene complexes (η5-C5Me5)2Fe2(µ-CO)(CO)2(µ-η1-CCCR1R2)via nucleophilic addition to the ethynediyldiiron complex (µ-CC)[Fe(η5-C5Me5)(CO)2]2
  202. Structure expansion of the mixed-metal dicarbide cluster core in [(μ3-C≡C-Fp)Ru3(μ-H)(CO9)] via direct radical and thermal coupling reactions leading to higher-nuclearity (μ-C2Hx)My cluster compounds (x = 0, 1; y = 7, 8),CpFeRu6(μ5-C2)(μ5-C2H)(CO)16,Cp...
  203. Structure and Reactivity of C2 Species on Polymetallic Systems.
  204. Formation of a Trinuclear .mu.3-Methylidyne Complex, (.mu.3-CH)[MoCp(CO)2]3, through Reduction of a CO Ligand in Cp2Mo2(CO)4 by a Hydrosilane
  205. Unusual reactivities of (μ-η2:η2-FPCCH)Co2(CO)6, the adducts of FPCCH to Co2(CO)8: photolysis, thermolysis and reduction with hydrosilanes giving polynuclear complexes, (CP)2Fe2Co3(μ5-CCH)(CO)10, (μ-CHCH)[(−μ3-C)Co3(CO)9]2 and CpFeCo3(μ-CCH2)(...
  206. Reaction of the Metal-Substituted Vinylidene Complex Cp'(CO)2Mn[:C:CHFp*] with Excess BuLi, Giving Acylated Dinuclear Bridging Alkenyl Complexes, Cp'MnCp*Fe[.mu.-CH:C(E)C(O)Bu](.mu.-CO)(CO)2 (E = H, Me): Confirmation of the Intramolecular 1,2-H Shift M...
  207. Transformation of the C2H ligand in Fp*C.tplbond.CH [Fp* = (.eta.5-C5Me5)Fe(CO)2] into various C2 functional groups via an iron-substituted vinylidene complex, (.eta.5-C5H4Me)Mn(CO)2[:C:C(H)Fp*]: its amphoteric reactivities, structural comparisons rele...
  208. Reduction of ruthenium and iron µ-methylene complexes with hydrosilanes producing alkane: a model system for methanation via the Fischer–Tropsch mechanism
  209. Isolation of a zerovalent iron dinitrogen complex with 1,2-bis(diethylphosphino)ethane ligands
  210. A Practical O2-Oxidation of Functionalized Alcohols Producing Carboxylic Acids Catalyzed by the Pd-C/Pb(OAc)2 System.
  211. Stereochemistry of the peptide α-amidation reaction involving two enzymes, peptidylglycine α-hydroxylating monooxygenase (PHM) and peptidylhydroxyglycine N–C lyase (PHL)
  212. Template synthesis of substituted cyclopentanones by zirconocene/olefin/CO systems
  213. Oxidative addition of allylic halides to ruthenium(II) compounds. Preparation, reactions, and x-ray crystallographic structure of ruthenium(IV)-allyl complexes
  214. Electrophilic cleavage reations of carbonsilicon bonds in neutral hexacoordinate silicon compounds: diorgano(phthalocyaninato)silicon
  215. Selective carbometallation of α,β-unsaturated carbonyl compounds and substituted oxacyclopropanes with zirconium-diene complexes
  216. Silafunctional compounds in organic synthesis. 32. Stereoselective halogenolysis of alkenylsilanes: stereochemical dependence on the coordination state of the leaving silyl groups
  217. Zirconocene-.eta.4-1,3-pentadiene complex and its higher homologs. A new synthetic method involving .sigma.-.pi. rearrangement of the hydrido-2,4-pentadienylzirconium species
  218. Regioselective homo- and codimerization of 1-alkynes leading to 2,4-disubstituted 1-buten-3-ynes by catalysis of a (.ETA.5-C5Me5)2TiCl2/RMgX system.
  219. Silafunctional compounds in organic synthesis
  220. Zirconium assisted regioselective acylation of dienes with saturated or unsaturated esters to lead to .BETA.,.GAMMA.-unsaturated carbonyl compounds.
  221. The X-ray and NMR studies on the regio- and stereoselective courses for insertion of ketones into the s-cis- and s-trans-diene complexes of zirconium leading to (Z)-1,2-oxazirconacyclohept-4-enes.
  222. Oxidative cleavage of silicon-carbon bonds in organosilicon fluorides to alcohols
  223. Highly stereoselective isomerization of monosubstituted 1-alkenes to (E)-2-alkenes by catalysis of (C5Me5)2TiCl2/NaC10H8.
  224. Silyl-titanation of acetylenes and 1,3-dienes
  225. Organofluorosilicates in organic synthesis. XVI. Synthesis of organo-pentafluorosilicates via the Diels-Alder, ene, and Friedel-Crafts reaction. Their transformations to organic halides and alcohols.