All Stories

  1. Sulfur–silicon bond activation catalysed by Cl/Br ions: waste-free synthesis of unsymmetrical thioethers by replacing fluoride catalysis and fluorinated substrates in SNAr reactions
  2. Total Synthesis of (+)‐Linoxepin by Utilizing the Catellani Reaction
  3. Rhodium-Catalyzed Enantioselective Nucleophilic Fluorination: Ring Opening of Oxabicyclic Alkenes
  4. A Conjunctive Carboiodination: Indenes by a Double Carbopalladation-Reductive Elimination Domino Process
  5. Palladium-Catalyzed Allylic Alkylations via Allylic Amines
  6. Enantioselective Allylation and Crotylation of in situ Generated β,γ-Unsaturated Aldehydes
  7. Synthesis of Unsymmetrical Polysubstituted Pyridines from β-Sulfonylvinylamines via 1-Aza-Allyl Anion Intermediates
  8. Domino Rhodium-Catalyzed Alkyne Arylation/Palladium-Catalyzed N Arylation: A Mechanistic Investigation
  9. Stereoselective Nickel-Catalyzed [2+2+2] Cycloaddition of Enynes and Arynes
  10. Rhodium-Catalyzed Domino Enantioselective Synthesis of Bicyclo[2.2.2]lactones
  11. Rhodium-Catalyzed Domino Enantioselective Synthesis of Bicyclo[2.2.2]lactones
  12. Enantioselective Palladium-Catalyzed Carbozincation of Cyclopropenes
  13. The Use of Bromotrichloromethane in Chlorination Reactions
  14. Linear-Selective Rhodium(I)-Catalyzed Addition of Arylboronic Acids to Allyl Sulfones
  15. A Tandem Catalytic Approach to Methyleneindenes: Mechanistic Insights intogem-Dibromoolefin Reactivity
  16. Diastereoselective Benzylic Arylation of Tetralins
  17. Mark Lautens
  18. Mark Lautens
  19. Palladium-Catalyzed Domino Direct Arylation/N-Arylation: Convenient Synthesis of Phenanthridines
  20. Construction of Nitrogen-Containing Heterocycles by CH Bond Functionalization
  21. Synthesis of Homoallylic Alcohols via Lewis Acid Assisted Enantioselective Desymmetrization
  22. Bifunctional Reactivity of CuI: Sequential Ring Opening/N-Arylation
  23. Bifunctional Reactivity of CuI: Sequential Ring Opening/N-Arylation
  24. A Palladium-Catalyzed Approach to Polycyclic Sulfur Heterocycles
  25. Aromatic ortho-Benzylation Reveals an Unexpected Reductant
  26. Silver-Promoted Domino Pd-Catalyzed Amination/Direct Arylation: Access to Polycyclic Heteroaromatics
  27. A Simple, Cost-Effective Method for the Regioselective Deuteration of Anilines
  28. Chemodivergence in Enantioselective Desymmetrization of Diazabicycles: Ring-Opening versus Reductive Arylation
  29. Chemodivergence in Enantioselective Desymmetrization of Diazabicycles: Ring-Opening versus Reductive Arylation
  30. Enzymatic Resolution of Chlorohydrins for the Synthesis of Enantiomerically Enriched 2-Vinyloxiranes
  31. Use of a sterically demanding Lewis acid to direct ring expansion of monoactivated methylenecyclopropanes
  32. Palladium-Catalyzed Annulation of Aryl Heterocycles with Strained Alkenes
  33. Stereochemical and Mechanistic Investigations of a Palladium-Catalyzed Annulation of Secondary Alkyl Iodides
  34. Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation
  35. Palladium-Catalyzed Alkylation-Alkenylation Reactions: Rapid Access to Tricyclic Mescaline Analogues
  36. Direct, One-Step Synthesis of Condensed Heterocycles:  A Palladium-Catalyzed Coupling Approach
  37. Total Synthesis of Cryptophycin Analogues via a Scaffold Approach
  38. CuI-Catalyzed Tandem Intramolecular Amidation Using gem-Dibromovinyl Systems
  39. Palladium-Catalyzed Alkylation—Hydride Reduction Sequence: Synthesis of meta-Substituted Arenes.
  40. Palladium-catalyzed ring-forming reactions: Methods and applications
  41. Preparation of Homoallylic Homopropargylic Alcohols from 2-Vinyloxiranes.
  42. Intermolecular Heck-Type Coupling of Aryl Iodides and Allylic Acetates
  43. Palladium-Catalyzed Alkylation−Hydride Reduction Sequence:  Synthesis of Meta-Substituted Arenes
  44. Preparation of Homoallylic Homopropargylic Alcohols from 2-Vinyloxiranes
  45. Total Synthesis of (−)-(α)-Kainic Acid via a Diastereoselective Methylenecyclopropane Ring Expansion
  46. A Highly Diastereoselective MgI2-Mediated Ring Expansion of Methylenecyclopropanes
  47. Scope of Palladium-Catalyzed Alkylative Ring Opening
  48. Preparation and Utility of Cyclic Enol Carbonates
  49. Rhodium-Catalyzed Heck-Type Coupling of Boronic Acids with Activated Alkenes in an Aqueous Emulsion
  50. Palladium-Catalyzed Sequential Alkylation−Alkenylation Reactions:  New Three-Component Coupling Leading to Oxacycles
  51. Mild Procedure for the Catalytic Bis(stannylation) of Alkynes with Hexaalkylditins
  52. Rhodium-Catalyzed Carbon−Carbon Bond Forming Reactions of Organometallic Compounds
  53. Halide Effects in Transition Metal Catalysis
  54. Silylstannation-Cyclization of 1,6-Enynes using Palladium(0) and Palladium(II) Catalysis
  55. Metal‐Catalyzed Hydroalumination Reactions
  56. Rhodium-catalysed asymmetric ring opening reactions with carboxylate nucleophiles
  57. Practical synthesis of acetophenones from phenoltriflates
  58. Metal-Catalyzed Hydrostannations
  59. Rhodium-Catalyzed Ring Opening of Vinyl Epoxides with Alcohols and Aromatic Amines
  60. Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Phenols
  61. A New Route to Fused Aromatic Compounds by Using a Palladium-Catalyzed Alkylation – Alkenylation Sequence
  62. Cerium(III) chloride promoted opening of [3.2.1] oxabicycles with methyllithium
  63. Selective functionalization of 1,2-dihydronaphthalenols leads to a concise, stereoselective synthesis of sertraline
  64. Scope of the nickel catalyzed asymmetric reductive ring opening reaction. Synthesis of enantiomerically enriched cyclohexenols
  65. Regioselective Hydrostannation of Allenes Catalyzed by Pd(OH)2/C
  66. Heterogenkatalysierte, regioselektive Hydrostannylierung von Alkenen
  67. Allyl 1,1-bimetallic species: Their preparation and reactivity profile
  68. Regioselective Palladium-Catalyzed Hydrostannylation of Unsymmetrical Oxabicyclic Alkenes
  69. Reductive and base-induced cleavage reactions of oxabicyclic compounds
  70. Regioselektive Palladium‐katalysierte Hydrostannylierung von unsymmetrischen Oxabicycloalkenen
  71. Transition Metal-Mediated Cycloaddition Reactions
  72. Asymmetric synthesis of the lactone moiety of mevinic acid
  73. Effect of the substituents on the diastereoselectivity in the reduction of cyclopropyl ketones
  74. Ring Opening Reactions of Oxabicyclic Compounds as a Route to Cyclic and Acyclic Compounds with Multiple Stereocenters
  75. Regioselective nucleophilic ring opening of oxabicyclic compounds
  76. The reductive ring-opening of oxabicyclic compounds
  77. Catalytic asymmetric induction in the homo Diels-Alder reaction
  78. A route to the preparation of γ-hydroxyvinylstannanes
  79. Scope of the cobalt-catalyzed [2 + 2 + 2] homo-Diels-Alder reaction
  80. Ring-opening metathesis polymerization of deltacyclene via a ruthenium catalyst
  81. Stereoselectivity in the Homo Diels-Alder Reaction
  82. Ring-opening reactions of an oxabicyclic compound with cuprates
  83. Ring opening reactions of deltacyclene epoxides
  84. Regiochemical diversity in allylic alkylations via molybdenum catalysts
  85. Regiochemical control in the molybdenum-catalyzed reactions of trimethylsilyl- and ester-substituted allylic acetates
  86. Molybdenum catalyzed eliminations of allylic acetates. new diene synthesis
  87. Molybdenum catalysts for allylic alkylation
  88. Synthesis of an isomer of the germacranolide isoaristolactone