All Stories

  1. Is Bigger Always Better? Why Large Clay Crystals May Wreck Their Potential for Barrier Coatings
  2. Nanoporous Organically Pillared Layered Silicates for CO 2 Capture
  3. Tuning the Dielectric Properties of Individual Clay Nanosheets by Interlayer Composition: Toward Nano‐Electret Materials
  4. Stiff and self-healing hydrogels by polymer entanglements in co-planar nanoconfinement
  5. Ultrathin Ti-Deficient TiO2 Nanosheets with Pt Single Atoms Enable Efficient Photocatalytic Nitrate Reduction to Ammonia
  6. Tunable mechanical properties and phase transitions in nanoconfined polyzwitterionic UCST hydrogels
  7. Liquid-Crystalline Photonic Sandwich: Electroresponsive Colloids of Clay Nanosheets Loading Photofunctional Dyes
  8. Reversible Snapping of Constrained Anisotropic Hydrogels Upon Light Stimulations
  9. Real-Time Monitoring of Adsorption-Induced Scrolling of Colloidal Inorganic Nanosheets
  10. Quantitative Scrolling into Microporous Nanotubes of the Hydrous Layered Silicate Ilerite
  11. Animating hydrogel knotbots with topology-invoked self-regulation
  12. Forceless spontaneous delamination of high-aspect ratio fluorohectorite into monolayer nanosheets in chloroform
  13. High‐Performance, Flame‐Retardant, Binder‐Free Li‐Hectorite‐Polybenzimidazole Fiber Separator for Li‐Ion Batteries
  14. Polycyclic aromatic hydrocarbon radical anions stabilized by a sodium diglyme cation complex
  15. Spraying Transparent Nanoglass Coatings for Food Packaging
  16. Gentle, Spontaneous Delamination of Layered Titanate Yielding New Types of Lithium Titanate Nanosheets
  17. Green and scalable processing of water‐soluble, biodegradable polymer/clay barrier films
  18. Osmotically Delaminated Silicate Nanosheet‐Coated NCM for Ultra‐Stable Li+ Storage and Chemical Stability Toward Long‐Term Air Exposure
  19. Stretchable Clay Nanocomposite Barrier Film for Flexible Packaging
  20. Fabricating defogging metasurfaces via a water-based colloidal route
  21. Fabrication of Bragg stack films of clay nanosheets and polycations via co-polymerization of intercalated monomers and functional interlayer cations
  22. Gas Barriers from In Situ Polymerized Poly(ethylene glycol) Diacrylate Clay Nanocomposites for Food Packaging
  23. Do Aqueous Suspensions of Smectite Clays Form a Smectic Liquid-Crystalline Phase?
  24. Repulsive Osmotic Delamination: 1D Dissolution of 2D Materials
  25. Disentangling the Orientations of Spectrally Overlapping Transition Dipoles in Dense Dye Layers
  26. Stretchable and Fast Composting Polyester Films with High-Performance Oxygen Barrier
  27. Delamination by Repulsive Osmotic Swelling of Synthetic Na-Hectorite with Variable Charge in Binary Dimethyl Sulfoxide–Water Mixtures
  28. Magneto‐Orientation of Magnetic Double Stacks for Patterned Anisotropic Hydrogels with Multiple Responses and Modulable Motions
  29. Magneto‐Orientation of Magnetic Double Stacks for Patterned Anisotropic Hydrogels with Multiple Responses and Modulable Motions
  30. Nematic suspension of a microporous layered silicate obtained by forceless spontaneous delamination via repulsive osmotic swelling for casting high-barrier all-inorganic films
  31. Nanoscale-Structured Hybrid Bragg Stacks with Orientation- and Composition-Dependent Mechanical and Thermal Transport Properties: Implications for Nacre Mimetics and Heat Management Applications
  32. Enhancing Hydrogen Storage Capacity of Pd Nanoparticles by Sandwiching between Inorganic Nanosheets
  33. Bright, noniridescent structural coloration from clay mineral nanosheet suspensions
  34. Realizing shape and size control for the synthesis of coordination polymer nanoparticles templated by diblock copolymer micelles
  35. Spontaneous delamination of affordable natural vermiculite as a high barrier filler for biodegradable food packaging
  36. Patterned Electrode Assisted One‐Step Fabrication of Biomimetic Morphing Hydrogels with Sophisticated Anisotropic Structures
  37. Shear orientation of nematic phases of clay nanosheets: processing of barrier coatings
  38. Disorder–Order Transition—Improving the Moisture Sensitivity of Waterborne Nanocomposite Barriers
  39. The Effect of Interlayer Anion Grafting on Water Oxidation Electrocatalysis: A Comparative Study of Ni‐ and Co‐Based Brucite‐Type Layered Hydroxides, Layered Double Hydroxides and Hydroxynitrate Salts
  40. Sandwich‐Like Encapsulation of a Highly Luminescent Copper(I) Complex
  41. Large Tg Shift in Hybrid Bragg Stacks through Interfacial Slowdown
  42. Enhancing the Catalytic Activity of Palladium Nanoparticles via Sandwich-Like Confinement by Thin Titanate Nanosheets
  43. Nanoparticles Supported on Sub‐Nanometer Oxide Films: Scaling Model Systems to Bulk Materials
  44. Nanopartikel auf subnanometer dünnen oxidischen Filmen: Skalierung von Modellsystemen
  45. Colloidally stable, magnetoresponsive liquid crystals based on clay nanosheets
  46. Sustainable oxygen evolution catalysis – electrochemical generation of mössbauerite via corrosion engineering of steel
  47. Unmodified Clay Nanosheets at the Air–Water Interface
  48. Osmotic Delamination: A Forceless Alternative for the Production of Nanosheets Now in Highly Polar and Aprotic Solvents
  49. Structural and mechanical impact of synthetic clay in composite foams made via high‐internal phase emulsions
  50. Distributed Electric Field Induces Orientations of Nanosheets to Prepare Hydrogels with Elaborate Ordered Structures and Programmed Deformations
  51. Light-steered locomotion of muscle-like hydrogel by self-coordinated shape change and friction modulation
  52. Diammonium-Pillared MOPS with Dynamic CO2 Selectivity
  53. Terrestrial solar radiation driven photodecomposition of ciprofloxacin in clinical wastewater applying mesostructured iron(III) oxide
  54. Encapsulation of Fragrance in Aqueous Emulsions by Delaminated Synthetic Hectorite
  55. Rapid Low-Dimensional Li+ Ion Hopping Processes in Synthetic Hectorite-Type Li0.5[Mg2.5Li0.5]Si4O10F2
  56. Impact of Ultraconfinement on Composite Barriers
  57. Influence of Particle Size on Toughening Mechanisms of Layered Silicates in CFRP
  58. Lightweight Ultra-High-Barrier Liners for Helium and Hydrogen
  59. High Temperature Stable Maghemite Nanoparticles Sandwiched between Hectorite Nanosheets
  60. Anisotropic Thermal Transport in Spray-Coated Single-Phase Two-Dimensional Materials: Synthetic Clay Versus Graphene Oxide
  61. Osmotic Swelling of Sodium Hectorite in Ternary Solvent Mixtures: Nematic Liquid Crystals in Hydrophobic Media
  62. A Novel Synthesis Yielding Macroporous CaFe2O4 Sponges for Solar Energy Conversion
  63. Visualizing Transparent 2D Sheets by Fluorescence Quenching Microscopy
  64. Digital Programming Graphene Oxide Liquid Crystalline Hybrid Hydrogel by Shearing Microlithography
  65. Investigation of flame retarded polypropylene by high-speed planar laser-induced fluorescence of OH radicals combined with a thermal decomposition analysis
  66. Tunable Thermoelastic Anisotropy in Hybrid Bragg Stacks with Extreme Polymer Confinement
  67. Giant Multistep Crystalline vs. Osmotic Swelling of Synthetic Hectorite in Aqueous Acetonitrile
  68. Structure Determination of the Oxygen Evolution Catalyst Mössbauerite
  69. Mössbauerite as Iron-Only Layered Oxyhydroxide Catalyst for WO3 Photoanodes
  70. Structure of Na3[Al(L-Lactate)3]2·6H2O Crystallized from Lohtragon AL 250—A Commercial Cement Adjuvant
  71. Thermal expansion of clay polymer nanocomposites as a function of aspect ratio and filler content
  72. Gradient-Structured Nonflammable Flexible Polymer Membranes
  73. Determination of the charge of Al13 Keggin oligocations intercalated into synthetic hectorite
  74. Amphiphilic iron(ii) spin crossover coordination polymers: crystal structures and phase transition properties
  75. Electrostatic attraction of nanoobjects – a versatile strategy towards mesostructured transition metal compounds
  76. Microporous Organically Pillared Layered Silicates (MOPS): A Versatile Class of Functional Porous Materials
  77. High-Barrier, Biodegradable Food Packaging
  78. Onset of Osmotic Swelling in Highly Charged Clay Minerals
  79. Oxygen Evolution Catalysis with Mössbauerite-A Trivalent Iron-Only Layered Double Hydroxide
  80. Parallel and Perpendicular Alignment of Anisotropic Particles in Free Liquid Microjets and Emerging Microdroplets
  81. Pushing the Boundaries of Interfacial Sensitivity in Graphene FET Sensors: Polyelectrolyte Multilayers Strongly Increase the Debye Screening Length
  82. Layer charge robust delamination of organo-clays
  83. Strategies for the selective loading of patchy worm-like micelles with functional nanoparticles
  84. Purely Physisorption-Based CO-Selective Gate-Opening in Microporous Organically Pillared Layered Silicates
  85. Purely Physisorption-Based CO-Selective Gate-Opening in Microporous Organically Pillared Layered Silicates
  86. Mesostructured ZnO/Au nanoparticle composites with enhanced photocatalytic activity
  87. Large Scale Self-Assembly of Smectic Nanocomposite Films by Doctor Blading versus Spray Coating: Impact of Crystal Quality on Barrier Properties
  88. Two-Step Delamination of Highly Charged, Vermiculite-like Layered Silicates via Ordered Heterostructures
  89. Clinical wastewater treatment: Photochemical removal of an anionic antibiotic (ciprofloxacin) by mesostructured high aspect ratio ZnO nanotubes
  90. Systematic evaluation of different types of graphene oxide in respect to variations in their in-plane modulus
  91. Constant Volume Gate-Opening by Freezing Rotational Dynamics in Microporous Organically Pillared Layered Silicates
  92. Template Removal via Boudouard Equilibrium Allows for Synthesis of Mesostructured Molybdenum Compounds
  93. Fundamental theoretical and practical investigations of the polymorph formation of small amphiphilic molecules, their co-crystals and salts
  94. Sub-micron pore size tailoring for efficient chiral discrimination
  95. In-Depth Insights into the Key Steps of Delamination of Charged 2D Nanomaterials
  96. Structural Insights into Water-Based Spider Silk Protein–Nanoclay Composites with Excellent Gas and Water Vapor Barrier Properties
  97. Increasing time of ignition for PS-clay nanocomposites filled with [Fe(bpy)3]2+-modified hectorite
  98. Controlled Exfoliation of Layered Silicate Heterostructures into Bilayers and Their Conversion into Giant Janus Platelets
  99. Superior flame retardant by combining high aspect ratio layered double hydroxide and graphene oxide
  100. Behind Crime Scenes: The Crystal Structure of Commercial Luminol
  101. Microphase separation upon crystallization of small amphiphilic molecules: ‘low’ temperature form II of sodium benzoate (E 211)
  102. Synthesis of [Fe(L)(bipy)]nspin crossover nanoparticles using blockcopolymer micelles
  103. Preparation of microcellular low-density PMMA nanocomposite foams: Influence of different fillers on the mechanical, rheological and cell morphological properties
  104. Applying the flame retardant LDH as a Trojan horse for molecular flame retardants
  105. Selective Template Removal by Thermal Depolymerization to Obtain Mesostructured Molybdenum Oxycarbide
  106. Tunable Exfoliation of Synthetic Clays
  107. Transfer batch blending, an innovative solvent/solid assisted method for melt compounding to achieve good dispersion quality for polymer–clay-nanocomposites
  108. Analyzing the influence of particle size and stiffness state of the nanofiller on the mechanical properties of epoxy/clay nanocomposites using a novel shear-stiff nano-mica
  109. Gas-phase Preparation of SO3-Graphite: Host-Exchange and Exfoliation
  110. Ultralight, Soft Polymer Sponges by Self-Assembly of Short Electrospun Fibers in Colloidal Dispersions
  111. Encapsulation of Functional Organic Compounds in Nanoglass for Optically Anisotropic Coatings
  112. The Same at a First Glance: The Diffractogram of a New Polymorph of Anhydrous Sodium Luminolate Almost Perfectly Resembles the Diffraction Trace of an Already Known Polymorph
  113. Evaluierung von Struktur-Eigenschaftsbeziehungen in PMMA-Nanokompositen auf Basis einer neuen Generation an Schichtsilikaten
  114. Switching-On Quantum Size Effects in Silicon Nanocrystals
  115. Facile and scalable one-step production of organically modified graphene oxide by a two-phase extraction
  116. Quasi-epitaxial Growth of [Ru(bpy)3]2+by Confinement in Clay Nanoplatelets Yields Polarized Emission
  117. Tris(2,4,6-triamino-1,3,5-triazin-1-ium) Dihydrogenphosphate Monohydrogenphosphate Tetrahydrate
  118. Ordered Heterostructures of Two Strictly Alternating Types of Nanoreactors
  119. On the importance of specific interface area in clay nanocomposites of PMMA filled with synthetic nano-mica
  120. Towards completely miscible PMMA nanocomposites reinforced by shear-stiff, nano-mica
  121. CO2gas barrier properties in polymer nanocomposite coatings containing Li-hectorite clays
  122. Facile large-scale synthetic route to monodisperse ZnO nanocrystals
  123. Modification of kaolinite by Grafting of siderophilic ligands to the external octahedral surface
  124. Relative Humidity-Induced Reversible Hydration of Sulfate-Intercalated Layered Double Hydroxides
  125. The Largely Unknown Class of Microporous Hybrid Materials: Clays Pillared by Molecules
  126. BaFe1-xTaxO3-δ – A material for temperature independent resistive oxygen sensors
  127. Smectite fluorination and its impact on interlayer water content and structure: A way to fine tune the hydrophilicity of clay surfaces?
  128. Microphase Separation with Small Amphiphilic Molecules: Crystal Structure of Preservatives Sodium Benzoate (E 211) and Potassium Benzoate (E 212)
  129. Transition metals in micas: synthesis and characterization of Co-rich Cs-tainiolite
  130. Synthesis and reversible hydration behavior of the thiosulfate intercalated layered double hydroxide of Zn and Al
  131. Anisotropy of Water Dynamics in Clays: Insights from Molecular Simulations for Experimental QENS Analysis
  132. In-Plane Modulus of Singular 2:1 Clay Lamellae Applying a Simple Wrinkling Technique
  133. Clay-Based Nanocomposite Coating for Flexible Optoelectronics Applying Commercial Polymers
  134. Pressure-Induced Water Insertion in Synthetic Clays
  135. Hybrid Janus particles based on polymer-modified kaolinite
  136. Synthesis and single crystal structure refinement of the one-layer hydrate of sodium brittle mica
  137. Nanoplatelets of Sodium Hectorite Showing Aspect Ratios of ≈20 000 and Superior Purity
  138. Influence of Cation Size on the Co-crystallisation of Benzoic Acid with Different Benzoates
  139. Porosity of Pillared Clays Studied by Hyperpolarized129Xe NMR Spectroscopy and Xe Adsorption Isotherms
  140. Hierarchically porous tungsten oxidenanotubes with crystalline walls made of the metastable orthorhombic polymorph
  141. Towards mesoporous Keggin-type polyoxometalates – systematic study on organic template removal
  142. Space-Resolved In-Plane Moduli of Graphene Oxide and Chemically Derived Graphene Applying a Simple Wrinkling Procedure
  143. Access to Ordered Porous Molybdenum Oxycarbide/Carbon Nanocomposites
  144. Completely Miscible Polyethylene Nanocomposites
  145. Thermoanalytical Evidence of Metastable Molecular Defects in Form I of Benzamide
  146. Tailoring the Pore Sizes of Microporous Pillared Interlayered Clays through Layer Charge Reduction
  147. A simple approach for producing high aspect ratio fluorohectorite nanoplatelets utilizing a stirred media mill (ball mill)
  148. Template-Directed Mild Synthesis of Anatase Hybrid Nanotubes within Cylindrical Core–Shell–Corona Polymer Brushes
  149. Packing of Cylindrical Keggin-Type Polyoxometalate Hybrid Micelles as a Function of Aspect Ratio
  150. Direct Synthesis of Inverse Hexagonally Ordered Diblock Copolymer/Polyoxometalate Nanocomposite Films
  151. Impact of large aspect ratio, shear-stiff, mica-like clay on mechanical behaviour of PMMA/clay nanocomposites
  152. A Facile Polymer Templating Route Toward High-Aspect-Ratio Crystalline Titania Nanostructures
  153. Template-Directed Synthesis of Silica Nanowires and Nanotubes from Cylindrical Core–Shell Polymer Brushes
  154. UV-Cured, Flexible, and Transparent Nanocomposite Coating with Remarkable Oxygen Barrier
  155. Catalytic activity of nanoalloys from gold and palladium
  156. Polymorphism in co-crystals: a metastable form of the ionic co-crystal 2 HBz·1 NaBz crystallised by flash evaporation
  157. Co-crystallisation of benzoic acid with sodium benzoate: the significance of stoichiometry
  158. Single crystal structure refinement of one- and two-layer hydrates of sodium fluorohectorite
  159. How to maximize the aspect ratio of clay nanoplatelets
  160. Significance of Aspect Ratio on Efficiency of Layered Double Hydroxide Flame Retardants
  161. Large-Scale, Low-Cost Fabrication of Janus-Type Emulsifiers by Selective Decoration of Natural Kaolinite Platelets
  162. Complexing agent assisted synthesis of high aspect ratio Fe3+/Mg2+ layered double hydroxides
  163. A new polymorph (IV) of benzamide: Structural characterization and mechanism of the I↔IV phase transition
  164. Covalent Grafting to μ-Hydroxy-Capped Surfaces? A Kaolinite Case Study
  165. Intumescent-like behavior of polystyrene synthetic clay nanocomposites
  166. Water Dynamics in Hectorite Clays: Infuence of Temperature Studied by Coupling Neutron Spin Echo and Molecular Dynamics
  167. Shear stiff, surface modified, mica-like nanoplatelets: a novel filler for polymer nanocomposites
  168. Homogeneous Precipitation by Formamide Hydrolysis: Synthesis, Reversible Hydration, and Aqueous Exfoliation of the Layered Double Hydroxide (LDH) of Ni and Al
  169. Barrier Properties of Synthetic Clay with a Kilo-Aspect Ratio
  170. Formation of Ultrathin Birnessite-Type Nanoparticles Immobilized on Spherical Polyelectrolyte Brushes†
  171. Improvement of thermal and mechanical properties of a phenolic resin nanocomposite byin situformation of silsesquioxanes from a molecular precursor
  172. Composites of Metal Nanoparticles and TiO2Immobilized in Spherical Polyelectrolyte Brushes
  173. Large scale melt synthesis in an open crucible of Na-fluorohectorite with superb charge homogeneity and particle size
  174. Microporous PILCs — Synthesis, pillaring mechanism and selective cation exchange
  175. ORMOCERs (organic–inorganic hybrid copolymers)-zeolite Beta (BEA) nanocomposite membranes for gas separation applications
  176. Tailoring Shear-Stiff, Mica-like Nanoplatelets
  177. Facile Scalable Synthesis of Rectorites
  178. Deformation Measurements on Thin Clay Tactoids
  179. Towards a tunable pore size utilizing oxidative pillaring of the mica ferrous tainiolite
  180. Shaping Colloidal Rutile into Thermally Stable and Porous Mesoscopic Titania Balls
  181. Wöhler and Liebig Revisited: 176 Years of Polymorphism in Benzamide - and the Story Still Continues!†
  182. Melt Synthesis and Characterization of Synthetic Mn-Rich Tainiolite
  183. Well-Defined Crystalline TiO2Nanoparticles Generated and Immobilized on a Colloidal Nanoreactor
  184. Single Nanocrystals of Platinum Prepared by Partial Dissolution of Au-Pt Nanoalloys
  185. The crystal structure of the API Montelukast
  186. Structure elucidation of cyameluric acid by combining solid-state NMR spectroscopy, molecular modeling and direct-space methods
  187. Crystal structure prediction could have helped the experimentalists with polymorphism in benzamide
  188. Water diffusion in a synthetic hectorite by neutron scattering—beyond the isotropic translational model
  189. A Route to Microporous Materials through Oxidative Pillaring of Micas
  190. Core-crosslinked block copolymernanorods as templates for grafting [SiMo12O40]4–Keggin ions
  191. Realisation of truly microporous pillared clays
  192. Water Diffusion in a Synthetic Hectorite Clay Studied by Quasi-elastic Neutron Scattering
  193. Synthesis, Structure, and Electric Conductivity of Ferrous Tainiolite and Its Oxidative Conversion into Coarse-Grained Swellable Smectite
  194. Polymorphism in Benzamide: Solving a 175-Year-Old Riddle
  195. In Situ Formation of Ag Nanoparticles in Spherical Polyacrylic Acid Brushes by UV Irradiation
  196. Crystal Structure offac−Ir(ppy)3and Emission Properties under Ambient Conditions and at High Pressure†
  197. Single crystal structure refinement of tetramethylammonium-hectorite
  198. Chiral Recognition among Tris(diimine)-metal Complexes. 9. Crystal Structure Prediction for the Chiral Molecular Salt [Ru(bpy)3](PF6)2
  199. Synthese von dreidimensional geordneten Einlagerungsverbindungen des Hectorits
  200. Fehlordnung bei Smectiten in Abhängigkeit vom Zwischenschichtkation
  201. Nucleation-Controlled Crystallization of a New, Spontaneously Resolved Solvate of [Ru(bpy)3](PF6)2 and its Desolvation Reaction
  202. Arene–arene stacking in the revised structure of 2,2′-bipyridinium hexafluorophosphate
  203. Charge Homogeneity in Synthetic Fluorohectorite
  204. Two-dimensional diffraction from enantiopure and racemic monolayers of [Ru(bpy)3]2+ intercalated into synthetic fluorohectorite
  205. Crystal Engineering as a Tool for Directed Radiationless Energy Transfer in Layered {Λ-[Ru(bpy)3]Δ-[Os(bpy)3]}(PF6)4
  206. Absolute configuration of (−)-4-(3,4-dichlorophenyl)-4-(2-pyridyl)butanoic acid: essential information to determine crucial steric features of arpromidine-type histamine H2receptor agonists
  207. Atomistic computer modeling of [Ru(bpy)3]2+ and [Ru(phen)3]2+ intercalated into low charged smectites †
  208. Enantioselective catalysis
  209. Electrogenerated Chemiluminescence and Proton-Dependent Switching of Fluorescence: Functionalized Difluoroboradiaza-s-indacenes
  210. Arene–Arene Stacking incis-Bis[2-(2-thienyl-C3)pyridine-N]platinum(II)
  211. Studies on AB2-type intermetallic compounds, IV. High-pressure synthesis and crystal structure of scandium dizinc ScZn2
  212. 3,4-diazanorcaradiene als Vorstufen neuer stabiler Azomethinylide
  213. Umlagerungen von 2,5-diarylsubstituierten dicyano[7,7-dimethyl-3,4-diazabicyclo[4.1.0]hept-2,4-dien-3-ium-3-yl]methaniden 3 in protischen solventien
  214. Chiral Recognition Among Tris(diimine)-Metal Complexes. 4. Atomistic Computer Modeling of a Monolayer of [Ru(bpy)3]2+ Intercalated into a Smectite Clay
  215. Chirale Erkennung bei Trisdiimin -Metallkomplexen: 1. Strukturen von Tris-(3,3?-bi-1,2,4-triazin)eisen(II)-Komplexen
  216. Chirale Erkennung bei Trisdiimin -Metallkomplexen: 2. Sind Tonminerale prochirale Adsorbentien?
  217. Chirale Erkennung bei Trisdiimin-Metallkomplexen: 3. Adsorption von Tris-(3,3?-bi-1,2,4-triazin)eisen(II)-Komplexen an Montmorillonit
  218. Oxidation state of iron at the interface of composite basal lining systems
  219. Structure of 5,5',6,6'-tetraphenyl-3,3'-bi-1,2,4-triazine